title: Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.
abstract: The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential.
authors.affiliation: Department of Bioinspired Science, Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
authors.forename: Seungwoo
authors.initials: S
authors.lastname: Hong
authors.forename: Hee
authors.initials: H
authors.lastname: So
authors.forename: Heejung
authors.initials: H
authors.lastname: Yoon
authors.forename: Kyung-Bin
authors.initials: KB
authors.lastname: Cho
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Lee
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
mesh_terms: D006571:Heterocyclic Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry*; D008024:Ligands; D008745:Methylation; D008958:Models, Molecular; D010100:Oxygen / Q000737:chemistry*
chemical_list: D006571:Heterocyclic Compounds; D058085:Iron Compounds; D008024:Ligands; C066317:ferryl iron; C024560:cyclam; D006859:Hydrogen; D007501:Iron; D010100:Oxygen