title: Hybrid electrolytes prepared from ionic liquid-grafted alumina for high-efficiency quasi-solid-state dye-sensitized solar cells.
abstract: Alumina (Al2O3) nanoparticles were covalently surface-modified with an ionic liquid (IL) to improve their miscibility with ILs such as 1-methyl-3-propylimidazolium iodide (MPII). Hybrids consisting of MPII and the surface-modified IL-Al2O3 nanoparticles were utilized as an I2-free electrolyte for quasi-solid-state dye-sensitized solar cells (DSSCs). The synthesis and properties of the IL-Al2O3 nanoparticles and hybrid electrolytes were characterized by Fourier transform infrared (FT-IR) spectroscopy, UV-visible spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The viscosity of the electrolyte continuously increased with the content of IL-Al2O3, and the fluidity almost disappeared completely when the MPII:IL-Al2O3 weight ratio was 95 : 5 or 90 : 10. The energy conversion efficiencies of DSSCs fabricated with IL-Al2O3 were always greater than those with pristine Al2O3. Such a finding is due to the favorable interactions and good miscibility between MPII and IL-Al2O3, which in turn results in the formation of an interconnected channel pathway for ion transport. Incident photon-to-electron conversion efficiency (IPCE), intensity modulated photocurrent spectroscopy (IMPS)/intensity-modulated photovoltage spectroscopy (IMVS), and electrochemical impedance spectroscopy (EIS) measurements were used to investigate the interfacial properties and electron transport characteristics. Upon utilizing double-layer structures with mesoporous TiO2 beads, the efficiency increased to 7.6% at 100 mW cm(-2), one of the highest values reported for quasi-solid-state DSSCs.
authors.affiliation: Department of Chemical and Biomolecular Engineering, Yonsei University, 262 Seongsanno, Seodaemun-gu, Seoul 120-749, South Korea.
authors.forename: Won Seok
authors.initials: WS
authors.lastname: Chi
authors.forename: Dong Kyu
authors.initials: DK
authors.lastname: Roh
authors.forename: Sang Jin
authors.initials: SJ
authors.lastname: Kim
authors.forename: Sung Yeon
authors.initials: SY
authors.lastname: Heo
authors.forename: Jong Hak
authors.initials: JH
authors.lastname: Kim
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D004573:Electrolytes / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry; D016062:Porosity; D012993:Solar Energy; D014025:Titanium / Q000737:chemistry
chemical_list: D004396:Coloring Agents; D004573:Electrolytes; C009495:titanium dioxide; D014025:Titanium; D000537:Aluminum Oxide