title: [Ru(IV)(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C-H bonds of hydrocarbons using phosphoryl azides as nitrene sources.
abstract: [Ru(IV)(F20-TPP)Cl2][H2(F20-TPP) = meso-tetrakis(pentafluorophenyl)porphyrin] is an active catalyst for both inter- and intra-molecular nitrene insertion into sp(3) C-H bonds of hydrocarbons in good to high product yields using phosphoryl azides as nitrene sources.
authors.affiliation: Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
authors.forename: Wenbo
authors.initials: W
authors.lastname: Xiao
authors.forename: Jinhu
authors.initials: J
authors.lastname: Wei
authors.forename: Cong-Ying
authors.initials: CY
authors.lastname: Zhou
authors.forename: Chi-Ming
authors.initials: CM
authors.lastname: Che
mesh_terms: D001386:Azides / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry*; D011789:Quantum Theory; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D001386:Azides; D056831:Coordination Complexes; D006838:Hydrocarbons; D011166:Porphyrins; D002244:Carbon; D012428:Ruthenium; D006859:Hydrogen; C049692:tetraphenylporphine