title: A photoelectrochemical sensor based on nickel hydroxyl-oxide modified n-silicon electrode for hydrogen peroxide detection in an alkaline solution.
abstract: A novel photoelectrochemical hydrogen peroxide (H2O2) sensor was constructed with platinum (Pt) and nickel hydroxyl-oxide (NiOOH) double layers modified n-silicon electrode (NiOOH/Pt/n-n(+)-Si). About 40nm Pt layer and about 100nm Ni layer were successively coated on the front surface of n-n(+)-Si (111) wafers by vacuum evaporating. A stable layer of NiOOH was formed through oxidation of the Ni layer on the coated silicon wafer by the electrochemical method. The surface of modified electrode was characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The NiOOH/Pt/n-n(+)-Si electrode has been used for determination of H2O2 with a two-electrode cell in the absence of reference electrode by photocurrent measurement at a zero bias. The photoelectrochemical sensor showed a good linear response to H2O2 concentrations in a range from 1.0×10(-5) to 6×10(-5)M with a determination limit (S/N=3) of 2.2μM. The NiOOH/Pt/n-n(+)-Si electrode exhibited excellent reproducibility and stability. Particularly, the facile measurement requirements made this novel modified electrode promising for the development of outdoor H2O2 sensors.
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan 250014, PR China. lihuaixiang@sdnu.edu.cn
authors.forename: Huaixiang
authors.initials: H
authors.lastname: Li
authors.forename: Wenlong
authors.initials: W
authors.lastname: Hao
authors.forename: Jinchao
authors.initials: J
authors.lastname: Hu
authors.forename: Hongyan
authors.initials: H
authors.lastname: Wu
mesh_terms: D015374:Biosensing Techniques; D002244:Carbon / Q000737:chemistry; D055664:Electrochemical Techniques; D004566:Electrodes; D006861:Hydrogen Peroxide / Q000737:chemistry / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D017665:Hydroxyl Radical / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry; D009532:Nickel / Q000737:chemistry*; D010084:Oxidation-Reduction; D056951:Photoelectron Spectroscopy; D012825:Silicon / Q000737:chemistry; D012996:Solutions
chemical_list: D012996:Solutions; D017665:Hydroxyl Radical; D002244:Carbon; D009532:Nickel; D006861:Hydrogen Peroxide; C028007:nickel monoxide; D012825:Silicon