title: Water-assisted growth of graphene on carbon nanotubes by the chemical vapor deposition method.
abstract: Combining carbon nanotubes (CNTs) with graphene has been proved to be a feasible method for improving the performance of graphene for some practical applications. This paper reports a water-assisted route to grow graphene on CNTs from ferrocene and thiophene dissolved in ethanol by the chemical vapor deposition method in an argon flow. A double injection technique was used to separately inject ethanol solution and water for the preparation of graphene/CNTs. First, CNTs were prepared from ethanol solution and water. The injection of ethanol solution was suspended and water alone was injected into the reactor to etch the CNTs. Thereafter, ethanol solution was injected along with water, which is the key factor in obtaining graphene/CNTs. Transmission electron microscopy, scanning electron microscopy, X-ray diffraction, and Raman scattering analyses confirmed that the products were the hybrid materials of graphene/CNTs. X-ray photo-electron spectroscopy analysis showed the presence of oxygen rich functional groups on the surface of the graphene/CNTs. Given the activity of the graphene/CNT surface, CdS quantum dots adhered onto it uniformly through simple mechanical mixing.
authors.affiliation: School of Materials Science and Engineering, Tianjin University, Tianjin, China. fjmtjuCN@yahoo.com.cn
authors.forename: Jian-Min
authors.initials: JM
authors.lastname: Feng
authors.forename: Ye-Jing
authors.initials: YJ
authors.lastname: Dai
mesh_terms: D000431:Ethanol / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure; D045663:Quantum Dots; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D037742:Nanotubes, Carbon; D014867:Water; D000431:Ethanol; D006108:Graphite