title: Slow magnetic relaxation in a hydrogen-bonded 2D array of mononuclear dysprosium(III) oxamates.
abstract: The reaction of N-(2,6-dimethylphenyl)oxamic acid with dysprosium(III) ions in a controlled basic media afforded the first example of a mononuclear lanthanide oxamate complex exhibiting a field-induced slow magnetic relaxation behavior typical of single-ion magnets (SIMs). The hydrogen-bond-mediated self-assembly of this new bifunctional dysprosium(III) SIM in the solid state provides a unique example of 2D hydrogen-bonded polymer with a herringbone net topology.
authors.affiliation: Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, 46980 Paterna, València, Spain.
authors.forename: Francisco R
authors.initials: FR
authors.lastname: Fortea-Pérez
authors.forename: Julia
authors.initials: J
authors.lastname: Vallejo
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.forename: Giovanni
authors.initials: G
authors.lastname: De Munno
authors.forename: Donatella
authors.initials: D
authors.lastname: Armentano
authors.forename: Emilio
authors.initials: E
authors.lastname: Pardo
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D004419:Dysprosium / Q000737:chemistry*; D006860:Hydrogen Bonding; D059346:Magnets / Q000737:chemistry; D008958:Models, Molecular; D010072:Oxamic Acid / Q000031:analogs & derivatives*
chemical_list: D056831:Coordination Complexes; D004419:Dysprosium; D010072:Oxamic Acid