title: Adsorption and photocatalytic degradation of methylene blue over hydrogen-titanate nanofibres produced by a peroxide method.
abstract: In this study, Degussa P25 TiO2 was partially dissolved in a mixture of hydrogen peroxide and sodium hydroxide at high pH. The fabrication of nanofibres proceeded by the hydrothermal treatment of the solution at 80 °C. This was followed by acid wash in HCl at pH 2 for 60 min, which resulted in the formation of hydrogen-titanate nanofibres. The nanofibres were annealed at 550 °C for 6 h to produce crystalline anatase nanofibres. The nanofibres were characterised for physico-chemical modifications and tested for the adsorption and photocatalytic degradation of methylene blue as a model water pollutant. An average specific surface area of 31.54 m(2)/g, average pore volume of 0.10 cm(3)/g and average pore size of 50 Å were recorded. The nanofibres were effective adsorbents of the model pollutant and adsorbents and good photocatalysts under simulated solar light illumination. No reduction in photocatalytic activity was observed over three complete treatment cycles, and the effective separation of nanofibres was achieved by gravity settling resulting in low residual solution turbidity.
authors.affiliation: Faculty of Engineering and Information Technology, University of Technology, Sydney (UTS), PO Box 123, Broadway 2007, Australia. ibrahim.elsaliby@uts.edu.au
authors.forename: Ibrahim
authors.initials: I
authors.lastname: El Saliby
authors.forename: Laszlo
authors.initials: L
authors.lastname: Erdei
authors.forename: Jong-Ho
authors.initials: JH
authors.lastname: Kim
authors.forename: Ho Kyong
authors.initials: HK
authors.lastname: Shon
mesh_terms: D000327:Adsorption / Q000528:radiation effects; D002244:Carbon / Q000032:analysis; D002384:Catalysis / Q000528:radiation effects; D006859:Hydrogen / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008027:Light; D008751:Methylene Blue / Q000302:isolation & purification / Q000528:radiation effects*; D057139:Nanofibers / Q000737:chemistry* / Q000648:ultrastructure; D009391:Nephelometry and Turbidimetry; D010782:Photolysis / Q000528:radiation effects*; D012996:Solutions; D013052:Spectrometry, X-Ray Emission; D013056:Spectrophotometry, Ultraviolet; D055672:Static Electricity; D013535:Suspensions; D013696:Temperature; D014025:Titanium / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: D012996:Solutions; D013535:Suspensions; C009495:titanium dioxide; D002244:Carbon; D006859:Hydrogen; D006861:Hydrogen Peroxide; D014025:Titanium; D008751:Methylene Blue