title: Additive-free size-controlled synthesis of gold square nanoplates using photochemical reaction in dynamic phase-separating media.
abstract: Ultrafast phase separation of water and 2-butoxyethanol mixture was induced by nanosecond IR laser pulse irradiation. After a certain delay time, a UV laser pulse was introduced to induce photoreduction of aurate ions, which led to the formation of gold nanoparticles in dynamic phase-separating media. The structure and size of the nanoparticles varied depending on the delay time between the IR and UV pulses. For a delay time of 5 and 6 μs, gold square plates having edge lengths of 150 and 100 nm were selectively obtained, respectively. With a delay time of 3 μs, on the other hand, the size of the square plates varied widely from 100 nm to a few micrometers. The size of the gold square plates was also varied by varying the total irradiation time of the IR and UV pulses. The size distribution of the square plates obtained under different conditions suggests that the growth process of the square plates was affected by the size of the nanophases during phase separation. Electron diffraction patterns of the synthesized square plates showed that the square plates were highly crystalline with a Au(100) surface. These results showed that the nanophases formed during laser-induced phase separation can provide detergent-free reaction fields for size-controlled nanomaterial synthesis.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai, Japan. kajimoto@m.tohoku.ac.jp
authors.forename: Shinji
authors.initials: S
authors.lastname: Kajimoto
authors.forename: Daisuke
authors.initials: D
authors.lastname: Shirasawa
authors.forename: Noriko Nishizawa
authors.initials: NN
authors.lastname: Horimoto
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Fukumura