title: Formaldehyde emissions from ventilation filters under different relative humidity conditions.
abstract: Formaldehyde emissions from fiberglass and polyester filters used in building heating, ventilation, and air conditioning (HVAC) systems were measured in bench-scale tests using 10 and 17 cm(2) coupons over 24 to 720 h periods. Experiments were performed at room temperature and four different relative humidity settings (20, 50, 65, and 80% RH). Two different air flow velocities across the filters were explored: 0.013 and 0.5 m/s. Fiberglass filters emitted between 20 and 1000 times more formaldehyde than polyester filters under similar RH and airflow conditions. Emissions increased markedly with increasing humidity, up to 10 mg/h-m(2) at 80% RH. Formaldehyde emissions from fiberglass filters coated with tackifiers (impaction oils) were lower than those from uncoated fiberglass media, suggesting that hydrolysis of other polymeric constituents of the filter matrix, such as adhesives or binders was likely the main formaldehyde source. These laboratory results were further validated by performing a small field study in an unoccupied office. At 80% RH, indoor formaldehyde concentrations increased by 48-64%, from 9-12 μg/m(3) to 12-20 μg/m(3), when synthetic filters were replaced with fiberglass filtration media in the HVAC units. Better understanding of the reaction mechanisms and assessing their overall contributions to indoor formaldehyde levels will allow for efficient control of this pollution source.
authors.affiliation: Lawrence Berkeley National Laboratory, Indoor Environment Group, Berkeley, California, USA.
authors.forename: Meera
authors.initials: M
authors.lastname: Sidheswaran
authors.forename: Wenhao
authors.initials: W
authors.lastname: Chen
authors.forename: Agatha
authors.initials: A
authors.lastname: Chang
authors.forename: Robert
authors.initials: R
authors.lastname: Miller
authors.forename: Sebastian
authors.initials: S
authors.lastname: Cohn
authors.forename: Douglas
authors.initials: D
authors.lastname: Sullivan
authors.forename: William J
authors.initials: WJ
authors.lastname: Fisk
authors.forename: Kazukiyo
authors.initials: K
authors.lastname: Kumagai
authors.forename: Hugo
authors.initials: H
authors.lastname: Destaillats
mesh_terms: D005374:Filtration / Q000295:instrumentation*; D005557:Formaldehyde / Q000737:chemistry*; D006813:Humidity; D014691:Ventilation
chemical_list: D005557:Formaldehyde