title: Mild rhodium(III)-catalyzed cyclization of amides with α,β-unsaturated aldehydes and ketones to azepinones: application to the synthesis of the homoprotoberberine framework.
authors.affiliation: Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149 Münster, Germany.
authors.forename: Zhuangzhi
authors.initials: Z
authors.lastname: Shi
authors.forename: Christoph
authors.initials: C
authors.lastname: Grohmann
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D001381:Azepines / Q000138:chemical synthesis* / Q000737:chemistry; D001549:Benzamides / Q000737:chemistry*; D001600:Berberine Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D061565:Cycloaddition Reaction; D006860:Hydrogen Bonding; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D001381:Azepines; D001549:Benzamides; D001600:Berberine Alkaloids; D007659:Ketones; C009090:protoberberine; D012238:Rhodium