title: Carbonate-containing apatite (CAP) synthesis under moderate conditions starting from calcium carbonate and orthophosphoric acid.
abstract: The synthesis of carbonate-containing apatite (CAP) from calcium carbonate and orthophosphoric acid under moderate conditions was investigated. In all cases, complete precipitation of orthophosphate species was observed. The reaction temperature influenced strongly the decomposition of calcium carbonate and therefore the composition of formed products. The reaction temperature of 80 °C was found to be effective for the complete decomposition of calcium carbonate particles after 48 h of reaction. Infra-red spectroscopy (IR), nuclear magnetic resonance (NMR), thermogravimetry/mass spectroscopy (TG-MS) coupling, and X-ray diffraction (XRD) characterizations allowed the identification of the composition of formed products. By increasing the reaction temperature from 20 °C to 80 °C, the content of A-type CAP increased and that of B-type CAP decreased, according to the favorable effect of temperature on the formation of A-type CAP. The total amount of carbonate content incorporated in CAP's structure, which was determined by TG-MS analysis, increased with the reaction temperature and reached up to 4.1% at 80 °C. At this temperature, the solid product was mainly composed of apatitic components and showed the typical flat-needle-like structure of CAP particles obtained in hydrothermal conditions. These results show an interesting one-step synthesis of CAP from calcium carbonate and orthophosphoric acid as low cost but high purity starting materials.
authors.affiliation: Université de Toulouse, Mines Albi, CNRS, Centre RAPSODEE, Campus Jarlard, F-81013 Albi cedex 09, France. doan.phamminh@mines-albi.fr
authors.forename: Doan
authors.initials: D
authors.lastname: Pham Minh
authors.forename: Ngoc Dung
authors.initials: ND
authors.lastname: Tran
authors.forename: Ange
authors.initials: A
authors.lastname: Nzihou
authors.forename: Patrick
authors.initials: P
authors.lastname: Sharrock
mesh_terms: D001031:Apatites / Q000138:chemical synthesis* / Q000737:chemistry; D002119:Calcium Carbonate / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008855:Microscopy, Electron, Scanning; D010756:Phosphoric Acids / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013696:Temperature; D013818:Thermogravimetry; D014961:X-Ray Diffraction
chemical_list: D001031:Apatites; D010756:Phosphoric Acids; C030242:phosphoric acid; D002119:Calcium Carbonate