title: Size-, mass-, and density-controlled preparation of TiO2 nanoparticles in a spherical coordination template.
abstract: TiO2 nanoparticles were prepared with strict control of the size, molecular mass (PDI = 1.02), and mass density by hydrolyzing a precursor, Ti(acac)2(biphen), in the presence of a well-defined hollow Pd12L24 spherical endotemplate. The formation of highly monodisperse TiO2 nanoparticles was confirmed by (1)H NMR spectroscopy, MALDI-TOF mass spectrometry, transmission electron microscopy, and atomic force microscopy. The template was easily removed by treating the sphere with a metal scavenger followed by calcination to give crystalline TiO2 nanoparticles (2.0 ± 0.2 nm in diameter), which showed photocatalytic activity.
authors.affiliation: Department of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Ichijo
authors.forename: Sota
authors.initials: S
authors.lastname: Sato
authors.forename: Makoto
authors.initials: M
authors.lastname: Fujita