title: Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster.
abstract: We report a novel cluster, [{Pt(C6F5)(bzq)}2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the Pb(II) in the ground state and to the distinct distortion of the coordination environment (1 and 1-solvent) upon photoexcitation.
authors.affiliation: Departamento de Química-Centro de Síntesis Química de La Rioja, (CISQ), Universidad de La Rioja, 26006, Logroño, Spain.
authors.forename: Jesús R
authors.initials: JR
authors.lastname: Berenguer
authors.forename: Elena
authors.initials: E
authors.lastname: Lalinde
authors.forename: Antonio
authors.initials: A
authors.lastname: Martín
authors.forename: M Teresa
authors.initials: MT
authors.lastname: Moreno
authors.forename: Santiago
authors.initials: S
authors.lastname: Ruiz
authors.forename: Sergio
authors.initials: S
authors.lastname: Sánchez
authors.forename: Hamid R
authors.initials: HR
authors.lastname: Shahsavari