title: Preparation and properties of enzyme-modified cassava starch-zinc complexes.
abstract: Starch-zinc complexes were synthesized by reaction of enzyme-modified starch with zinc acetate. The effect of reaction parameters such as hydrolysis rate, reaction temperature, reaction time, pH value, and concentration of zinc acetate on the zinc content and zinc conversion rate was studied. The zinc content and conversion rate of the product prepared under optimal conditions were 100.24 mg/g and 87.06%, respectively. The results of scanning electron microscopy (SEM) demonstrated that the obtained starch-zinc complexes displayed a porous appearance. The results of Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and (13)C cross-polarization/magic-angle spinning nuclear magnetic resonance ((13)C CP/MAS NMR) showed that zinc was mainly coordinated to the oxygen atoms of the glucose unit 6-CH2OH. The formation of starch-zinc complexes was also indirectly confirmed by the results of conductivity measurements. Thermal properties of the complexes were influenced by the zincatation process. This study revealed that nonallergenic starch might be used effectively as a carrier of zinc for zinc supplementation purpose.
authors.affiliation: Carbohydrate Lab, College of Light Industry & Food Sciences, South China University of Technology, Guangzhou 510640, China. zhgluo@scut.edu.cn
authors.forename: Zhigang
authors.initials: Z
authors.lastname: Luo
authors.forename: Weiwei
authors.initials: W
authors.lastname: Cheng
authors.forename: Haiming
authors.initials: H
authors.lastname: Chen
authors.forename: Xiong
authors.initials: X
authors.lastname: Fu
authors.forename: Xichun
authors.initials: X
authors.lastname: Peng
authors.forename: Faxing
authors.initials: F
authors.lastname: Luo
authors.forename: Lihong
authors.initials: L
authors.lastname: Nie
mesh_terms: D006863:Hydrogen-Ion Concentration; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D002365:Manihot / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D056951:Photoelectron Spectroscopy; D016062:Porosity; D017550:Spectroscopy, Fourier Transform Infrared; D013213:Starch / Q000737:chemistry*; D013696:Temperature; D015032:Zinc / Q000737:chemistry*; D019345:Zinc Acetate / Q000737:chemistry
chemical_list: D013213:Starch; D019345:Zinc Acetate; D015032:Zinc