title: FT-IR standoff detection of thermally excited emissions of trinitrotoluene (TNT) deposited on aluminum substrates.
abstract: A standoff detection system was assembled by coupling a reflecting telescope to a Fourier transform infrared spectrometer equipped with a cryo-cooled mercury cadmium telluride detector and used for detection of solid-phase samples deposited on substrates. Samples of highly energetic materials were deposited on aluminum substrates and detected at several collector-target distances by performing passive-mode, remote, infrared detection measurements on the heated analytes. Aluminum plates were used as support material, and 2,4,6-Trinitrotoluene (TNT) was used as the target. For standoff detection experiments, the samples were placed at different distances (4 to 55 m). Several target surface temperatures were investigated. Partial least squares regression analysis was applied to the analysis of the intensities of the spectra obtained. Overall, standoff detection in passive mode was useful for quantifying TNT deposited on the aluminum plates with high confidence up to target-collector distances of 55 m.
authors.affiliation: Department of Chemistry, University of Puerto Rico, Mayagüez, Puerto Rico 00681.
authors.forename: John R
authors.initials: JR
authors.lastname: Castro-Suarez
authors.forename: Leonardo C
authors.initials: LC
authors.lastname: Pacheco-Londoño
authors.forename: Miguel
authors.initials: M
authors.lastname: Vélez-Reyes
authors.forename: Max
authors.initials: M
authors.lastname: Diem
authors.forename: Thomas J
authors.initials: TJ
authors.lastname: Tague
authors.forename: Samuel P
authors.initials: SP
authors.lastname: Hernandez-Rivera
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D016018:Least-Squares Analysis; D015203:Reproducibility of Results; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D014303:Trinitrotoluene / Q000737:chemistry*
chemical_list: D014303:Trinitrotoluene; D000535:Aluminum