title: Structural, morphological and sensing properties of layered polyaniline nanosheets towards hazardous phenol chemical.
abstract: Reliable sensing properties towards hazardous phenol chemical were detected by the novel working electrode of layered polyaniline (PANI) nanosheets. The layered PANI nanosheets were synthesized by the chemical polymerization of aniline monomer in the presence of hydrochloric acid and ammonium persulphate at 5 °C. The morphological, structural, optical, electrical and electrochemical properties of layered PANI nanosheets were extensively studied. The electrochemical behavior of layered PANI nanosheets based electrode was demonstrated by the electrochemical impedance spectroscopy (EIS) and cyclovoltametry (CV) measurements. The layered PANI nanosheets electrode showed reasonably good electrocatalytic activity towards the detection of phenol chemical, which resulted from the high redox current and low RCT. The current-voltage (I-V) characteristics were used to elucidate the sensing parameters of the fabricated phenol chemical sensor with layered PANI nanosheets electrode. The fabricated phenol chemical sensor with layered PANI nanosheets electrode significantly attained the high sensitivity of ~1485.3 μA mM(-1)cm(-2) and the detection limit of ~4.43 μM with correlation coefficient (R) of ~0.9981 and short response time (10 s).
authors.affiliation: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA.
authors.forename: Hyung-Kee
authors.initials: HK
authors.lastname: Seo
authors.forename: Sadia
authors.initials: S
authors.lastname: Ameen
authors.forename: M Shaheer
authors.initials: MS
authors.lastname: Akhtar
authors.forename: Hyung Shik
authors.initials: HS
authors.lastname: Shin
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D004566:Electrodes; D018625:Microscopy, Atomic Force; D008855:Microscopy, Electron, Scanning; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D019800:Phenol / Q000032:analysis* / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
chemical_list: D000814:Aniline Compounds; C416807:polyaniline; D019800:Phenol