title: Marine corrosion protective coatings of hexagonal boron nitride thin films on stainless steel.
abstract: Recently, two-dimensional, layered materials such as graphene and hexagonal boron nitride (h-BN) have been identified as interesting materials for a range of applications. Here, we demonstrate the corrosion prevention applications of h-BN in marine coatings. The performance of h-BN/polymer hybrid coatings, applied on stainless steel, were evaluated using electrochemical techniques in simulated seawater media [marine media]. h-BN/polymer coating shows an efficient corrosion protection with a low corrosion current density of 5.14 × 10(-8) A/cm(2) and corrosion rate of 1.19 × 10(-3) mm/year and it is attributed to the hydrofobic, inert and dielectric nature of boron nitride. The results indicated that the stainless steel with coatings exhibited improved corrosion resistance. Electrochemical impedance spectroscopy and potentiodynamic analysis were used to propose a mechanism for the increased corrosion resistance of h-BN coatings.
authors.affiliation: Department of Mechanical Engineering & Materials Science, Rice University, Houston, Texas, United States. e.matouq@paaet.edu.kw
authors.forename: Esam
authors.initials: E
authors.lastname: Husain
authors.forename: Tharangattu N
authors.initials: TN
authors.lastname: Narayanan
authors.forename: Jose Jaime
authors.initials: JJ
authors.lastname: Taha-Tijerina
authors.forename: Soumya
authors.initials: S
authors.lastname: Vinod
authors.forename: Robert
authors.initials: R
authors.lastname: Vajtai
authors.forename: Pulickel M
authors.initials: PM
authors.lastname: Ajayan