title: Engineered carbon (biochar) prepared by direct pyrolysis of Mg-accumulated tomato tissues: characterization and phosphate removal potential.
abstract: An innovative method was developed to produce engineered biochar from magnesium (Mg) enriched tomato tissues through slow pyrolysis in a N2 environment. Tomato plants treated with 25mM Mg accumulated much higher level of Mg in tissue, indicating Mg can be substantially enriched in tomato plants, and pyrolysis process further concentrated Mg in the engineered biochar (8.8% Mg). The resulting Mg-biochar composites (MgEC) showed better sorption ability to phosphate (P) in aqueous solutions compared to the other four tomato leaves biochars. Statistical analysis showed a strong and significant correlation between P removal rate and biochar Mg content (R(2)=0.78, and p<0.001), indicating the enriched Mg in the engineered biochar is the main factor controlling its P removal ability. SEM-EDX, XRD and XPS analyses showed that nanoscale Mg(OH)2 and MgO particles were presented on the surface of MgEC, which serve as the main adsorption sites for aqueous P.
authors.affiliation: Department of Agricultural and Biological Engineering, University of Florida, Gainesville, FL 32611, USA.
authors.forename: Ying
authors.initials: Y
authors.lastname: Yao
authors.forename: Bin
authors.initials: B
authors.lastname: Gao
authors.forename: Jianjun
authors.initials: J
authors.lastname: Chen
authors.forename: Ming
authors.initials: M
authors.lastname: Zhang
authors.forename: Mandu
authors.initials: M
authors.lastname: Inyang
authors.forename: Yuncong
authors.initials: Y
authors.lastname: Li
authors.forename: Ashok
authors.initials: A
authors.lastname: Alva
authors.forename: Liuyan
authors.initials: L
authors.lastname: Yang
mesh_terms: D000327:Adsorption; D001709:Biotechnology / Q000379:methods*; D002118:Calcium / Q000378:metabolism; D002244:Carbon / Q000494:pharmacology*; D002606:Charcoal / Q000494:pharmacology*; D018551:Solanum lycopersicum / Q000187:drug effects*; D008274:Magnesium / Q000378:metabolism*; D010710:Phosphates / Q000302:isolation & purification*; D013696:Temperature; D013818:Thermogravimetry
chemical_list: D010710:Phosphates; C540010:biochar; D002606:Charcoal; D002244:Carbon; D008274:Magnesium; D002118:Calcium