title: Facile one-pot synthesis of gold and silver nanocatalysts using edible coconut oil.
abstract: The use of edible oil for the synthesis of metal nanoparticles by wet chemical method is reported for the first time. The paper presents an environmentally benign bottom up approach for the synthesis of gold and silver nanoparticles using edible coconut oil at 373 K. The formation of silver nanoparticles is signaled by the brownish yellow color and that of gold nanoparticles by the purple color. Fine control over the nanoparticle size and shape from triangular to nearly spherical is achieved by varying the quantity of coconut oil. The nanoparticles have been characterized by UV-Visible, Transmission Electron Microscopy and X-ray Diffraction. The chemical interaction of capping agents with metal nanoparticles is manifested using Fourier Transform Infrared Spectroscopy. The stable and crystalline nanoparticles obtained using this simple method show remarkable size-dependent catalytic activity in the reduction of the cationic dye methylene blue (MB) to leuco methylene blue (LMB). The first order rate constants calculated uphold the size dependent catalytic activity of the synthesized nanoparticles.
authors.affiliation: Department of Physics, Mar Ivanios College, Thiruvananthapuram 695 015, India.
authors.forename: M
authors.initials: M
authors.lastname: Meena Kumari
authors.forename: Daizy
authors.initials: D
authors.lastname: Philip
mesh_terms: D000042:Absorption; D001894:Borohydrides / Q000737:chemistry; D002384:Catalysis; D000074263:Coconut Oil; D003102:Colloids / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D008751:Methylene Blue / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods*; D010938:Plant Oils / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
chemical_list: D001894:Borohydrides; D003102:Colloids; D010938:Plant Oils; D012996:Solutions; D012834:Silver; D006046:Gold; C025364:sodium borohydride; D000074263:Coconut Oil; D008751:Methylene Blue