title: Palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes.
abstract: The palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes has been achieved. The reactions proceed with commercially available Pd(OAc)2 as a catalyst and HSi(iPr)3 as a reducing reagent, giving the corresponding α,β-unsaturated ketones regio- and stereoselectively.
authors.affiliation: Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
authors.forename: Tetsuaki
authors.initials: T
authors.lastname: Fujihara
authors.forename: Kenta
authors.initials: K
authors.lastname: Tatsumi
authors.forename: Jun
authors.initials: J
authors.lastname: Terao
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Tsuji