title: Ionothermal synthesis of chiral metal phosphite open frameworks with in situ generated organic templates.
abstract: Two novel three-dimensional chiral metal phosphite open frameworks with 4-connected quartz topology, [Me2-DABCO][M2(HPO3)3] [M = Co (1), Zn (2); Me2-DABCO = N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane], have been ionothermally synthesized in deep eutectic solvents (choline chloride/1,3-dimethylurea). It is interesting that the organic template, Me2-DABCO, is in situ generated from the alkylation reaction of 1,4-diazabicyclo[2.2.2]octane and dimethyl phosphites.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
authors.forename: Li-Ming
authors.initials: LM
authors.lastname: Li
authors.forename: Kai
authors.initials: K
authors.lastname: Cheng
authors.forename: Fei
authors.initials: F
authors.lastname: Wang
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
mesh_terms: D003035:Cobalt / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D017905:Phosphites / Q000737:chemistry*; D013696:Temperature; D015032:Zinc / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D017905:Phosphites; D003035:Cobalt; D015032:Zinc