title: A novel array of chemiluminescence sensors for sensitive, rapid and high-throughput detection of explosive triacetone triperoxide at the scene.
abstract: Triacetone triperoxide (TATP) is relatively easy to make and has been used in various terrorist acts. Early but easy detection of TATP is highly desired. We designed a new type sensor array for H2O2. The unique CL sensor array was based on CeO2 nanoparticles' membranes, which have an excellent catalytic effect on the luminol-H2O2 CL reaction in alkaline medium. It exhibits a linear range for the detection of H2O2 from 1.0×10(-8) to 5.0×10(-5)M (R(2)=0.9991) with a 1s response time. The detection limit is 1.0×10(-9)M. Notably, the present approach allows the design of CL sensor array assays in a more simple, time-saving, long-lifetime, high-throughput, and economical approach when compared with conventional CL sensor. It is conceptually different from conventional CL sensor assays. The novel sensor array has been successfully applied for the detection of TATP at the scene.
authors.affiliation: Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, China.
authors.forename: Xiaohua
authors.initials: X
authors.lastname: Li
authors.forename: Zhujun
authors.initials: Z
authors.lastname: Zhang
authors.forename: Liang
authors.initials: L
authors.lastname: Tao
mesh_terms: D015374:Biosensing Techniques / Q000379:methods*; D002563:Cerium / Q000737:chemistry; D053834:Explosive Agents / Q000737:chemistry / Q000302:isolation & purification*; D006573:Heterocyclic Compounds, 1-Ring / Q000737:chemistry / Q000302:isolation & purification*; D057166:High-Throughput Screening Assays; D006861:Hydrogen Peroxide / Q000737:chemistry; D057230:Limit of Detection; D049449:Luminescence; D008165:Luminol / Q000737:chemistry; D053758:Nanoparticles / Q000737:chemistry; D010545:Peroxides / Q000737:chemistry / Q000302:isolation & purification*
chemical_list: D053834:Explosive Agents; D006573:Heterocyclic Compounds, 1-Ring; D010545:Peroxides; D002563:Cerium; D008165:Luminol; C030583:ceric oxide; C495284:triacetone triperoxide; D006861:Hydrogen Peroxide