title: Fluorine NMR reporter for phosphate anions.
abstract: A fluorine-labelled zinc(II)-dipicolylamine coordination complex reports the presence of phosphate anions in aqueous solution, especially pyrophosphate and ADP, and is used to monitor the enzymatic hydrolysis of ATP.
authors.affiliation: Department of Chemistry and Biochemistry, University of Notre Dame, 236 Nieuwland Science Hall, Notre Dame, IN, USA.
authors.forename: Haiying
authors.initials: H
authors.lastname: Gan
authors.forename: Allen G
authors.initials: AG
authors.lastname: Oliver
authors.forename: Bradley D
authors.initials: BD
authors.lastname: Smith
mesh_terms: D000255:Adenosine Triphosphate / Q000737:chemistry / Q000378:metabolism; D000588:Amines / Q000737:chemistry; D000838:Anions / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D005461:Fluorine / Q000737:chemistry*; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D010710:Phosphates / Q000737:chemistry*; D010848:Picolinic Acids / Q000737:chemistry; D014867:Water / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: C501847:2,2'-dipicolylamine; D000588:Amines; D000838:Anions; D056831:Coordination Complexes; D010710:Phosphates; D010848:Picolinic Acids; D014867:Water; D005461:Fluorine; D000255:Adenosine Triphosphate; D015032:Zinc