title: Enhancing the luminescence properties and stability of cationic iridium(III) complexes based on phenylbenzoimidazole ligand: a combined experimental and theoretical study.
abstract: Herein we designed and synthesized a series of cationic iridium(III) complexes with a phenylbenzoimidazole-based cyclometalated ligand, containing different numbers of carbazole moieties from zero to three (complexes 1-4). The photophysical and electrochemical properties of this series have been systematically investigated. The complexes exhibit strong luminescence in both solution and in neat films, as well as excellent redox reversibility. Introducing carbazole groups into the complexes is found to lead to substantially enhanced photoluminescence quantum efficiency in the neat film, but has little effect on the emitting color and excited-state characteristics as supported by density functional theory (DFT) results. DFT calculations also suggest that functionalized complexes 2-4 reveal better hole-transporting properties than 1. More importantly, all complexes effectively reduce the degradation reaction to some extent in metal-centered (³MC) excited-states, demonstrating their stability. Further studies indicate that restriction of opening of the structures in the ³MC state is caused by the unique molecular conformation of the phenylbenzoimidazole ligand, which is first demonstrated here in cationic iridium(III) complexes without intramolecular π-π stacking. These results presented here would provide valuable information for designing and synthesizing highly efficient and stable cationic iridium(III) complexes suitable for the optical devices.
authors.affiliation: Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Guo-Gang
authors.initials: GG
authors.lastname: Shan
authors.forename: Hai-Bin
authors.initials: HB
authors.lastname: Li
authors.forename: Hai-Zhu
authors.initials: HZ
authors.lastname: Sun
authors.forename: Hong-Tao
authors.initials: HT
authors.lastname: Cao
authors.forename: Dong-Xia
authors.initials: DX
authors.lastname: Zhu
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
mesh_terms: D002227:Carbazoles / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007093:Imidazoles / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D011789:Quantum Theory; D013050:Spectrometry, Fluorescence
chemical_list: D002227:Carbazoles; D002412:Cations; D056831:Coordination Complexes; D007093:Imidazoles; D008024:Ligands; C041514:carbazole; D007495:Iridium; C029899:imidazole