title: Cationic iridium(III) complexes bearing a bis(triazole) ancillary ligand.
abstract: Three new heteroleptic cationic iridium complexes of the form [Ir(C^N)(btl)](+), where btl = 1,1'-benzyl-4,4'-bi-1H-1,2,3-triazolyl and C^N = 2-phenylpyridine (ppyH) (1), 1-benzyl-4-phenyl-1H-1,2,3-triazole (phtl) (2) or 1-benzyl-4-(2,4-difluorophenyl)-1H-1,2,3-triazole (dFphtl) (3), were synthesized and isolated as their hexafluorophosphate (PF6(-)) salts and fully characterized. The single crystal structure of 3 has been solved. Along the series from 1-3 the absorption spectra shift hypsochromically while the electrochemical gap increases from 3.25 to 3.54 to 3.88 V. Acetonitrile solutions of 1 and 2 are poorly luminescent, sky-blue emitters with predominant ligand-centered and charge transfer character, respectively. Theoretical calculations support these assignments. Complex 3 is not photostable and decomposes to solvento-based structures of the form [Ir(dFphtl)2(ACN)n](+) (n = 1, 2) through a dissociation and degradation of the btl ligand.
authors.affiliation: Département de Chimie, Université de Sherbrooke, 2500 Boul. de l'Université, Sherbrooke, QC, Canada J1K 2R1.
authors.forename: Loïc
authors.initials: L
authors.lastname: Donato
authors.forename: Philippe
authors.initials: P
authors.lastname: Abel
authors.forename: Eli
authors.initials: E
authors.lastname: Zysman-Colman