title: Cu-catalyzed synthesis of diaryl thioethers and S-cycles by reaction of aryl iodides with carbon disulfide in the presence of DBU.
abstract: Diaryl thioethers and S-cycles were obtained on the basis of the copper-catalyzed reaction of carbon disulfide and aryl iodides in the presence of DBU. This reaction enables the one-pot synthesis of diaryl thioethers by employing cheap, available, and easy-to-handle carbon disulfide with aryl iodides. The reaction was successfully employed in the construction of sulfur-containing cyclic molecules.
authors.affiliation: Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
authors.forename: Peng
authors.initials: P
authors.lastname: Zhao
authors.forename: Hang
authors.initials: H
authors.lastname: Yin
authors.forename: Hongxin
authors.initials: H
authors.lastname: Gao
authors.forename: Chanjuan
authors.initials: C
authors.lastname: Xi
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D002246:Carbon Disulfide / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D015394:Molecular Structure; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D006847:Hydrocarbons, Iodinated; D013440:Sulfides; D003300:Copper; C031033:1,8-diazabicyclo(5.4.0)undec-7-ene; D002246:Carbon Disulfide