title: Characterization of cadmium removal from aqueous solution by biochar produced from a giant Miscanthus at different pyrolytic temperatures.
abstract: The objective of this study was to investigate the feasibility of biochar for removing Cd from aqueous solution. Biochars were produced from a Miscanthus sacchariflorus via slow pyrolysis at 300, 400, 500 and 600°C. Higher pyrolytic temperature resulted in biochar with a higher aromatic structure and fewer polar functional groups. In particular, pH and surface area of biochar increased greatly at pyrolytic temperatures ≥ 500°C, which increased Cd sorption capacity up to 13.24 mgg(-1). The diffuse-controlled Cd removal was likely due to a surface sorption or a precipitation reaction depending on pH. A simulation with the visual MINTEQ program indicated that the precipitate was Cd(OH)2. In addition, biochar treatment significantly removed the acute toxicity of Cd toward Daphnia magna, resulting in increase of EC50 (50% effective concentration) value from 0.16 to 0.76 mgL(-1).
authors.affiliation: Division of Environmental Science & Ecological Engineering, Korea University, Seoul 136-713, Republic of Korea.
authors.forename: Woong-Ki
authors.initials: WK
authors.lastname: Kim
authors.forename: Taeyong
authors.initials: T
authors.lastname: Shim
authors.forename: Yong-Seong
authors.initials: YS
authors.lastname: Kim
authors.forename: Seunghun
authors.initials: S
authors.lastname: Hyun
authors.forename: Changkook
authors.initials: C
authors.lastname: Ryu
authors.forename: Young-Kwon
authors.initials: YK
authors.lastname: Park
authors.forename: Jinho
authors.initials: J
authors.lastname: Jung
mesh_terms: D000327:Adsorption / Q000187:drug effects; D000818:Animals; D001673:Biodegradation, Environmental / Q000187:drug effects; D002104:Cadmium / Q000302:isolation & purification* / Q000633:toxicity; D002606:Charcoal / Q000737:chemistry*; D003621:Daphnia / Q000187:drug effects; D006358:Hot Temperature; D007700:Kinetics; D006109:Poaceae / Q000737:chemistry*; D023382:Toxicity Tests, Acute; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D014874:Water Pollutants, Chemical; C540010:biochar; D002104:Cadmium; D002606:Charcoal