title: Phosphorus(V) complexes with acyclic monoaminocarbene ligands via oxidative addition.
abstract: (Difluoroorganyl)dimethylamines, RCF2NMe2 (R = H, Ph, tBu), can be used as carbene precursors for phosphorus trifluoride in an oxidative addition reaction. By this method, complexes of sterically nondemanding asymmetric and acyclic carbenes were obtained that are otherwise not accessible.
authors.affiliation: School of Engineering and Science, Jacobs University Bremen, Campus-Ring 1, 28759 Bremen, Germany.
authors.forename: Tobias
authors.initials: T
authors.lastname: Böttcher
authors.forename: Bassem S
authors.initials: BS
authors.lastname: Bassil
authors.forename: Lyuben
authors.initials: L
authors.lastname: Zhechkov
authors.forename: Gerd-Volker
authors.initials: GV
authors.lastname: Röschenthaler
mesh_terms: D000588:Amines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry*; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010758:Phosphorus / Q000737:chemistry*
chemical_list: D000588:Amines; D008024:Ligands; C030011:carbene; D010758:Phosphorus; D008697:Methane; D005459:Fluorides