title: Effective treatment of olive mill effluents from two-phase and three-phase extraction processes by batch membranes in series operation upon threshold conditions.
abstract: Production of olive oil results in the generation of high amounts of heavy polluted effluents characterized by extremely variable contaminants degree, leading to sensible complexity in treatment. In this work, batch membrane processes in series comprising ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) are used to purify the effluents exiting both the two-phase and tree-phase extraction processes to a grade compatible to the discharge in municipal sewer systems in Spain and Italy. However, one main problem in applying this technology to wastewater management issues is given by membrane fouling. In the last years, the threshold flux theory was introduced as a key tool to understand fouling problems, and threshold flux measurement can give valuable information regarding optimal membrane process design and operation. In the present manuscript, mathematical approach of threshold flux conditions for membranes operation is addressed, also implementing proper pretreatment processes such as pH-T flocculation and UV/TiO2 photocatalysis with ferromagnetic-core nanoparticles in order to reduce membranes fouling. Both influence the organic matter content as well as the particle size distribution of the solutes surviving in the wastewater stream, leading, when properly applied, to reduced fouling, higher rejection and recovery values, thus enhancing the economic feasibility of the process.
authors.affiliation: Department of Chemical Engineering, University of Granada, 18071 Granada, Spain. Electronic address: jmochandop@ugr.es.
authors.forename: J M
authors.initials: JM
authors.lastname: Ochando-Pulido
authors.forename: G
authors.initials: G
authors.lastname: Hodaifa
authors.forename: M D
authors.initials: MD
authors.lastname: Victor-Ortega
authors.forename: S
authors.initials: S
authors.lastname: Rodriguez-Vives
authors.forename: A
authors.initials: A
authors.lastname: Martinez-Ferez
mesh_terms: D005374:Filtration / Q000379:methods; D005427:Flocculation; D019649:Food Industry; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D008567:Membranes, Artificial; D000069463:Olive Oil; D010084:Oxidation-Reduction; D010782:Photolysis; D010938:Plant Oils; D013696:Temperature; D014025:Titanium / Q000737:chemistry / Q000528:radiation effects; D014466:Ultraviolet Rays; D014865:Waste Disposal, Fluid / Q000295:instrumentation / Q000379:methods*
chemical_list: D007220:Industrial Waste; D008567:Membranes, Artificial; D000069463:Olive Oil; D010938:Plant Oils; C009495:titanium dioxide; D014025:Titanium
keywords: Nanofiltration; Olive mill wastewater; Reverse osmosis; Threshold flux; Ultrafiltration; Wastewater reclamation