title: Fused polycyclic compounds via cycloaddition of 4-(1'-cyclohexenyl)-5-iodo-1,2,3-triazoles with 4-phenyl-1,2,4-triazoline-3,5-dione: the importance of a sacrificial iodide leaving group.
abstract: 4-(1'-Cyclohexenyl)-5-iodo-1,2,3-triazole and 4-phenyl-1,2,4-triazoline-3,5-dione undergo a formal Diels-Alder reaction, which following an S(N)2' solvolysis process to displace the iodo group affords a fused polycyclic compound.
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306-4390, USA.
authors.forename: Heather A
authors.initials: HA
authors.lastname: Michaels
authors.forename: J Tyler
authors.initials: JT
authors.lastname: Simmons
authors.forename: Ronald J
authors.initials: RJ
authors.lastname: Clark
authors.forename: Lei
authors.initials: L
authors.lastname: Zhu
mesh_terms: D003500:Cyclization; D007454:Iodides / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry*
chemical_list: D007454:Iodides; D011083:Polycyclic Compounds; D014230:Triazoles