title: Management of agricultural biomass wastes: preliminary study on characterization and valorisation in clay matrix bricks.
abstract: In this work the feasibility of using woody agricultural biomass wastes as grapes and cherries seeds, sawdust, as pore forming agent, and sugar cane ash, as silica precursor, in bricks, were reported. Sawdust and grapes and cherries seeds, thanks to their organic substances content, during their combustion, bring an energetic support in the bricks firing phase and act as pore forming agent. Usually the addition of this kind of waste is limited to 10wt.% in order to reach an equilibrium between positive (weight and shrinkage decrease and porosity increase) and negative (increase of water absorption and mechanical resistance decrease) effects. The results show that grapes and cherries seeds, added in a percentage of 5wt.% to a brick formulation, have better influence with respect to the sawdust, maintaining the mechanical properties of the fired brick (950°C), showing modulus of rupture around 21-23MPa with a weight reduction of 3-10% (respect to the standard one). Regarding the sugar cane ash, the addition of 5wt.% improves the mechanical properties (modulus of rupture around 27MPa) and no weight decrease is observed. These results confirmed the role played by this kind of agricultural waste, which thanks to its high silica content (61wt.%) is capable to demonstrate a filler and plasticity reducing effect on the brick bodies. Tests carried out highlighted that the addition of these by-products (5wt.%) do not change negatively the main technological properties measured (water absorption, linear shrinkage, flexural resistance, etc.) and permit to hypothesize their use to obtain bricks with both insulating and higher mechanical properties using a pore agent forming or silica carrier alternative raw materials, respectively.
authors.affiliation: Dipartimento di Ingegneria "Enzo Ferrari", Università di Modena e Reggio Emilia, Via Vignolese 905/a, 41125 Modena, Italy.
authors.forename: Luisa
authors.initials: L
authors.lastname: Barbieri
authors.forename: Fernanda
authors.initials: F
authors.lastname: Andreola
authors.forename: Isabella
authors.initials: I
authors.lastname: Lancellotti
authors.forename: Rosa
authors.initials: R
authors.lastname: Taurino
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry; D018533:Biomass; D000077215:Clay; D003252:Construction Materials / Q000032:analysis*; D018556:Crops, Agricultural / Q000737:chemistry*; D005240:Feasibility Studies; D018505:Waste Management; D014866:Waste Products / Q000032:analysis*; D014934:Wood / Q000737:chemistry
chemical_list: D000538:Aluminum Silicates; D014866:Waste Products; D000077215:Clay
keywords: Biomass waste; Bricks; Building materials; Recycling