title: Environmentally friendly electroless plating for Ag/TiO2-coated core-shell magnetic particles using ultrasonic treatment.
abstract: In this work, high-reflectance brilliant white color magnetic microspheres comprising a Fe/TiO2/Ag core-shell structure with a continuous, uniform compact silver layer were successfully fabricated by TiO2-assisted electroless plating in a simple and eco-friendly method. The coating procedure for TiO2 and Ag involved a sol-gel reaction and electroless plating with ultrasound treatment. The electroless plating step was carried out in an eco-friendly manner in a single process without environmentally toxic additives. The TiO2 layer was used as a modification layer between the Fe microspheres and the silver layer to improve adhesion. A continuous and compact silver layer could be formed with a high degree of morphological control by introducing ultrasonication and adjusting the ammonium hydroxide concentration.
authors.affiliation: Department of Anticounterfeit Center, Korea Minting, Security Printing & ID Card Operating Corp., Daejeon 305-713, South Korea.
authors.forename: Soo-Dong
authors.initials: SD
authors.lastname: Kim
authors.forename: Won-Gyun
authors.initials: WG
authors.lastname: Choe
authors.forename: Jong-Ryul
authors.initials: JR
authors.lastname: Jeong