title: Quantum chemistry study on the destruction mechanism of 2,3,7,8-TCDD by OH and O(3) radicals.
abstract: Due to its fundamental importance, the destruction mechanism of the dioxins, as exemplified by 2,3,7,8-TCDD, by OH and O3 radicals was investigated in detail employing Quantum Chemical Calculations in this paper. Theoretical results showed that, OH radical degraded 2,3,7,8-TCDD via substituting chlorine at the 2,3,7,8 positions, while O3 radical degraded 2,3,7,8-TCDD via destructing CC bonds and aromatic ring. Based on the mechanism study, the kinetic parameters of the reactions were also calculated by Transition State Theory. By comparing, the rate constant of the 2,3,7,8-TCDD destruction by OH was found to be much higher than that by O3, which indicated that OH radical have much stronger ability to degrade 2,3,7,8-TCDD than O3 radical. This finding was consistent with the standard electrode potential of OH and O3 radical. The theoretical results in this paper can be believed to supply important theory basis for the further investigation on dioxins removal by using the catalytic oxidation technology.
authors: College of Science, Hangzhou Dianzi University, Hangzhou 310018, China. wenzc@hdu.edu.cn
authors: Zhengcheng
authors: Z
authors: Wen
authors: Zhihua
authors: Z
authors: Wang
authors: Jiangrong
authors: J
authors: Xu
authors: Yang
authors: Y
authors: Liu
authors: Kefa
authors: K
authors: Cen
mesh_terms: D004785:Environmental Pollutants / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry*; D007700:Kinetics; D008958:Models, Molecular; D008968:Molecular Conformation; D010126:Ozone / Q000737:chemistry*; D000072317:Polychlorinated Dibenzodioxins / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: D004785:Environmental Pollutants; D000072317:Polychlorinated Dibenzodioxins; D017665:Hydroxyl Radical; D010126:Ozone