title: Crystal growth, structure, polarization, and magnetic properties of cesium vanadate, Cs2V3O8: a structure-property study.
abstract: Cesium vanadate, Cs2V3O8, a member of the fresnoite-type structure, was synthesized via a hydrothermal route and structurally characterized by single-crystal X-ray diffraction. Cs2V3O8 crystallizes in a noncentrosymmetric polar space group, P4bm, with crystal data of a = 8.9448(4) Å, c = 6.0032(3) Å, V = 480.31(4) Å(3), and Z = 2. The material exhibits a two-dimensional layered crystal structure consisting of corner-shared V(5+)O4 and V(4+)O5 polyhedra. The layers are separated by the cesium cations. The alignment of the individual polyhedra results in a macroscopic polarity for Cs2V3O8. Frequency-dependent polarization measurements indicate that the material is not ferroelectric. A pyroelectric coefficient of -2.0 μC m(-2) K(-1) was obtained from pyroelectric measurements taken as a function of the temperature. The magnetic susceptibility data were measured as a function of the temperature and yielded an effective magnetic moment of 1.78 μB for the V(4+) cation. Short-range magnetic ordering was observed around 7 K. The susceptibility data were fit to the Heisenberg square-lattice model supporting that the short-range magnetic interactions are antiferromagnetic and two-dimensional. IR and thermal properties were also characterized.
authors: Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States.
authors: Jeongho
authors: J
authors: Yeon
authors: Athena S
authors: AS
authors: Sefat
authors: T Thao
authors: TT
authors: Tran
authors: P Shiv
authors: PS
authors: Halasyamani
authors: Hans-Conrad
authors: HC
authors: zur Loye