title: Interfacial self-assembly and characterization of chiral coordination polymer multilayers with bidentate ligands of hydroquinine anthraquinone-1,4-diyl diether as linkers.
abstract: Chiral coordination polymers (CPs) have been prepared at the air-water interface by using the ligand of 1,4-bis(9-O-dihydroquininyl)anthraquinone [(DHQ)2AQN] and its enantiomer of 1,4-bis(9-O-dihydroquinidinyl)anthraquinone [(DHQD)2AQN] as linkers and AgNO3 as the connector. Surface pressure-area isotherms indicated that both ligands could form insoluble monomolecular layers on the pure water and AgNO3 subphase surfaces. Compared with the average molecular area on the pure water surface, that of the ligand increased about 10% when its monolayer was formed on the AgNO3 subphase surface due to the formation of Ag-(DHQ)2AQN and Ag-(DHQD)2AQN chiral CPs. These monolayers were deposited on the quartz, Si, and indium tin oxide (ITO) substrate surfaces via the Langmuir-Blodgett (LB) method. The as-prepared LB films were characterized by using UV-vis absorption and fluorescence spectroscopy, circular dichroism and X-ray photoelectron spectroscopy, as well as by using a scanning electron microscope and atomic force microscope. Broad fluorescence emissions were measured at about 365 and 525 nm for the ligands in the methanol solutions. The second emission red shifted to about 555 nm in the LB films of both pure ligands and their Ag-directed CPs. A couple of well-reversible redox waves were recorded and centered at about -0.2 ~ -0.3 V (vs Ag/AgCl) for the ITO electrode covered by the LB films of (DHQ)2AQN, (DHQD)2AQN, or of the Ag(+)-directed CPs, which were designated to one electron transfer process of the ligands. Small aggregates were observed for the LB films prepared at the lower surface pressures, which were compressed to form more uniform two-dimensional layers at the higher surface pressures.
authors: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
authors: Ying
authors: Y
authors: Tang
authors: Meng
authors: M
authors: Chen
authors: Dong-Jin
authors: DJ
authors: Qian
authors: Li
authors: L
authors: Zhang
authors: Minghua
authors: M
authors: Liu
mesh_terms: D000880:Anthraquinones / Q000737:chemistry*; D004987:Ethers; D008024:Ligands; D015394:Molecular Structure; D010316:Particle Size; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D000880:Anthraquinones; D004987:Ethers; D008024:Ligands; D011108:Polymers; C000592673:hydroquinine(anthraquinone-1,4-diyl)diether