title: Inverting pump-probe spectroscopy for state tomography of excitonic systems.
abstract: We propose a two-step protocol for inverting ultrafast spectroscopy experiments on a molecular aggregate to extract the time-evolution of the excited state density matrix. The first step is a deconvolution of the experimental signal to determine a pump-dependent response function. The second step inverts this response function to obtain the quantum state of the system, given a model for how the system evolves following the probe interaction. We demonstrate this inversion analytically and numerically for a dimer model system, and evaluate the feasibility of scaling it to larger molecular aggregates such as photosynthetic protein-pigment complexes. Our scheme provides a direct alternative to the approach of determining all Hamiltonian parameters and then simulating excited state dynamics.
authors: Department of Physics, University of California, Berkeley, California 94720, USA. shoyer@berkeley.edu
authors: Stephan
authors: S
authors: Hoyer
authors: K Birgitta
authors: KB
authors: Whaley
mesh_terms: D011789:Quantum Theory; D013057:Spectrum Analysis