title: Acetate induced enhancement of photocatalytic hydrogen peroxide production from oxalic acid and dioxygen.
abstract: The addition of acetate ion to an O2-saturated mixed solution of acetonitrile and water containing oxalic acid as a reductant and 2-phenyl-4-(1-naphthyl)quinolinium ion (QuPh(+)-NA) as a photocatalyst dramatically enhanced the turnover number of hydrogen peroxide (H2O2) production. In this photocatalytic H2O2 production, a base is required to facilitate deprotonation of oxalic acid forming oxalate dianion, which acts as an actual electron donor, whereas a Brønsted acid is also necessary to protonate O2(•-) for production of H2O2 by disproportionation. The addition of acetate ion to a reaction solution facilitates both the deprotonation of oxalic acid and the protonation of O2(•-) owing to a pH buffer effect. The quantum yield of the photocatalytic H2O2 production under photoirradiation (λ = 334 nm) of an O2-saturated acetonitrile-water mixed solution containing acetate ion, oxalic acid and QuPh(+)-NA was determined to be as high as 0.34, which is more than double the quantum yield obtained by using oxalate salt as an electron donor without acetate ion (0.14). In addition, the turnover number of QuPh(+)-NA reached more than 340. The reaction mechanism and the effect of solvent composition on the photocatalytic H2O2 production were scrutinized by using nanosecond laser flash photolysis.
authors: Department of Material and Life Science, Graduate School of Engineering, Osaka University , ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan.
authors: Yusuke
authors: Y
authors: Yamada
authors: Akifumi
authors: A
authors: Nomura
authors: Takamitsu
authors: T
authors: Miyahigashi
authors: Kei
authors: K
authors: Ohkubo
authors: Shunichi
authors: S
authors: Fukuzumi
mesh_terms: D019342:Acetic Acid / Q000737:chemistry*; D000097:Acetonitriles / Q000737:chemistry; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008027:Light; D019815:Oxalic Acid / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010782:Photolysis; D011806:Quinolinium Compounds / Q000737:chemistry; D026082:Singlet Oxygen / Q000737:chemistry; D012996:Solutions; D014867:Water / Q000737:chemistry
chemical_list: D000097:Acetonitriles; D011806:Quinolinium Compounds; D012996:Solutions; D014867:Water; D026082:Singlet Oxygen; D019815:Oxalic Acid; D006861:Hydrogen Peroxide; D019342:Acetic Acid; D010100:Oxygen; C032159:acetonitrile