title: Sulfur(IV)-mediated transformations: from ylide transfer to metal-free arylation of carbonyl compounds.
abstract: The development of a direct ylide transfer to carbonyl derivatives and of a sulfoxide-mediated arylation is presented from a unified perspective. Mechanistic studies (including density functional calculations) support a common reaction pathway and showcase how subtle changes in reactant properties can lead to disparate and seemingly unrelated reaction outcomes.
authors: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany.
authors: Xueliang
authors: X
authors: Huang
authors: Mahendra
authors: M
authors: Patil
authors: Christophe
authors: C
authors: Farès
authors: Walter
authors: W
authors: Thiel
authors: Nuno
authors: N
authors: Maulide
mesh_terms: D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D011789:Quantum Theory; D013454:Sulfoxides / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
chemical_list: D006841:Hydrocarbons, Aromatic; D013454:Sulfoxides; D013455:Sulfur