title: A simple reduction process to synthesize MoO2/C composites with cage-like structure for high-performance lithium-ion batteries.
abstract: Large-scale MoO2/carbon composites with a cage-like nanostructure have been synthesized by a simple hydrothermal reduction process. During the hydrothermal process, ammonium molybdate tetrahydrate ((NH4)6Mo7O24·4H2O) was employed as starting material and ascorbic acid as a structure directing agent, reductive agent and carbon source. MoO2/C nanospheres with diameters of about 15-25 nm were interconnected to form a cage-like architecture. Time-dependent experiments illustrated that the cage-like structure was transformed from tightly packed MoO2 nanoparticles. Furthermore, with a water-soluble binder (sodium alginate), the cage-like MoO2/C composites exhibited a high discharge capacity and significantly improved cycling performance compared to previously reported MoO2-based anode materials. The electrodes with the MoO2/C composites can deliver a capacity of 692.5 mA h g(-1) after 80 charge-discharge cycles at a current density of 200 mA g(-1). After C-rate measurement, the battery still can maintain excellent cycling stability (about 550 mA h g(-1) reversible capacity retained even after 475 cycles). The excellent electrochemical performance can be ascribed to the cage-like structure, which integrates three advantages: porous structure, interconnected MoO2/C framework and small nano-crystals.
authors: Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China.
authors: Bing
authors: B
authors: Liu
authors: Xinyu
authors: X
authors: Zhao
authors: Yuan
authors: Y
authors: Tian
authors: Di
authors: D
authors: Zhao
authors: Changwen
authors: C
authors: Hu
authors: Minhua
authors: M
authors: Cao