title: Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles.
abstract: The palladium-catalyzed three-component reactions of benzyl halides, activated olefins, and allyltributylstannane were successfully conducted to produce the corresponding benzylallylation products in satisfactory to high yields. The benzylallylation reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.
authors: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China.
authors: Xuan
authors: X
authors: Zhang
authors: Xiujuan
authors: X
authors: Feng
authors: Xiaoqiang
authors: X
authors: Yu
authors: Ren
authors: R
authors: He
authors: Ming
authors: M
authors: Bao
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000478:Alkylation; D001593:Benzyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013237:Stereoisomerism; D013499:Surface Properties
chemical_list: D000475:Alkenes; D001593:Benzyl Compounds; D009942:Organometallic Compounds; D010165:Palladium