title: Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II).
abstract: cis-[(Cy3P)2Pt{B(OMe)2}2] (1) was obtained in quantitative yield and fully characterised. The thermal stability of 1 was investigated in solution using multinuclear NMR spectroscopy revealing a hitherto unknown temperature-dependent equilibrium between 1 and the corresponding starting materials [Pt(PCy3)2] and free B2(OMe)4.
authors: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@uni-wuerzburg.de
authors: Holger
authors: H
authors: Braunschweig
authors: Alexander
authors: A
authors: Damme
mesh_terms: D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009944:Organoplatinum Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013816:Thermodynamics
chemical_list: D009944:Organoplatinum Compounds