title: Iodine-mediated highly regio- and stereoselective iodoamination of ferrocenyl allene: an approach for the synthesis of ferrocene-containing allylic amines.
abstract: A straightforward and efficient protocol for the highly regio- and stereoselective synthesis of ferrocene-containing allylic amine derivatives via an iodine-mediated iodoamination of ferrocenyl allene was developed. The regio- and stereoselectivity of this reaction may be controlled by the steric effect of the bulky ferrocene group.
authors: College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, People's Republic of China. shufengchen@imu.edu.cn
authors: Shufeng
authors: S
authors: Chen
authors: Qing
authors: Q
authors: Yan
authors: Haiying
authors: H
authors: Zhao
authors: Baoguo
authors: B
authors: Li
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D005296:Ferrous Compounds / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D000075163:Metallocenes; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000498:Allyl Compounds; D000588:Amines; D005296:Ferrous Compounds; D000075163:Metallocenes; C025947:propadiene; D007455:Iodine; C004998:ferrocene