title: Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex.
abstract: A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.
authors: Department of Chemistry, The University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS, USA.
authors: Domenick F
authors: DF
authors: Leto
authors: Rena
authors: R
authors: Ingram
authors: Victor W
authors: VW
authors: Day
authors: Timothy A
authors: TA
authors: Jackson
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013057:Spectrum Analysis; D014961:X-Ray Diffraction
chemical_list: D056831:Coordination Complexes; D008345:Manganese; D010100:Oxygen