title: cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV).
abstract: The mononuclear title complex, [VCl2O(C3H8S)2], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal-bipyramidal coordination environment defined by two Cl(-) and the S atoms of two (CH3CH2)(CH3)S ligands. In the crystal, pairs of mol-ecules form centrosymmetric dimers via C-H⋯O hydrogen bonds between the methyl C-H group and the oxidovanadium O atom of a neighbouring mol-ecule.
authors: Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-Okubo 255, Sakura-ku, Saitama 338-8570, Japan.
authors: Masatoshi
authors: M
authors: Matsuura
authors: Takashi
authors: T
authors: Fujihara
authors: Akira
authors: A
authors: Nagasawa
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