title: Ag-carbenoid-initiated catalytic hydration cascades: rapid construction of functionalized bicyclo[3.3.1]nonanes.
abstract: Remarkable Ag-carbenoid-initiated enone cyclopropanation-hydrolytic fragmentation-competitive 1,2-vs-1,4 addition reaction cascades were uncovered on a range of propargylic esters tethered to cyclohexadienones, leading to the highly efficient and stereospecific construction of densely functionalized bicyclo[3.3.1]nonanes under mild conditions.
authors: Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Shenzhen Graduate School of Peking University , Shenzhen, China 518055.
authors: Lu
authors: L
authors: Wang
authors: Shunyou
authors: S
authors: Cai
authors: Xiangyou
authors: X
authors: Xing
authors: Ying
authors: Y
authors: Gao
authors: Tao
authors: T
authors: Wang
authors: David Zhigang
authors: DZ
authors: Wang
mesh_terms: D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D002384:Catalysis; D003521:Cyclopropanes / Q000737:chemistry*; D015394:Molecular Structure; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001643:Bridged Bicyclo Compounds; D003521:Cyclopropanes; D012834:Silver