title: [2-(2,2':4',2''-Terpyridin-6'-yl-κ(2) N (1),N (1'))benzoato-κO]manganese(II) trihydrate.
abstract: In the title complex, [Mn(C22H14N3O2)2]·3H2O, the Mn(II) ion is coordinated by two N,N',O-tridentate 2-(2,2':4',2''-terpyridin-6'-yl-κ(2) N (1),N (1'))benzoate ligands in a distorted cis-MnO2N4 octa-hedral geometry. In one ligand, the dihedral angles between the central pyridine ring, the other bonded pyridine ring, the terminal pyridine ring and the benzene ring are 14.3 (15), 18.3 (18) and 43.9 (16)°, respectively. The equivalent angles in the second ligand are 5.8 (18), 6.3 (18), and 47.0 (17)°, respectively. In the crystal, the complex molecules and lattice water molecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generating a three-dimensional network.
authors: Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Qilu Normal University, Shandong 250013, People's Republic of China.
authors: Xinzheng
authors: X
authors: Liu
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677