title: A phenomenological model for particle retention in single, saturated fractures.
abstract: Fractured aquifers are some of the most poorly characterized subsurface environments despite posing one of the highest risks to the protection of potable groundwater. This research was designed to improve the understanding of the factors affecting particle transport through fractures by developing a phenomenological model based on laboratory-scale transport data. The model presented in this research employed data from over 70 particle tracer tests conducted in single, saturated, variable-aperture fractures that were obtained from the natural environment and fractured in the laboratory or cast from epoxy in the laboratory. The particles employed were Escherichia coli RS2-GFP and microspheres. The tracer experiments were conducted in natural (dolomitic limestone and granite) as well as epoxy replicas of the natural fractures. The multiple linear regression analysis revealed that the most important factors influencing particle retention in fractures are the ratio of the ionic strength of solution to collector charge, the ratio of particle to collector charge, and the ratio of advective to diffusive forces as described by the Peclet number. The model was able to reasonably (R(2)  = 0.64) predict the fraction of particles retained; however, it is evident that some factors not accounted for in the model also contributed to retention. This research presents a novel approach to understanding particle transport in fractures, and illustrates the relative importance of various factors affecting the transport mechanisms. The utility of this model lies in the increased understanding of particle transport in fractures, which is extremely useful for directing future research.
authors: McMaster University, 1280 Main St. W., Hamilton, ON L8S 4L7, Canada.
authors: Sandrina
authors: S
authors: Rodrigues
authors: Sarah
authors: S
authors: Dickson
mesh_terms: D004926:Escherichia coli; D060587:Groundwater / Q000737:chemistry*; D008863:Microspheres; D008956:Models, Chemical; D009994:Osmolar Concentration; D010316:Particle Size; D012996:Solutions; D013499:Surface Properties; D014872:Water Movements
chemical_list: D012996:Solutions