title: Dichloridobis(1,3-diisopropyl-4,5-di-methyl-1H-imidazol-3-ium-2-thiol-ate-κS)copper(II).
abstract: The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-Cl = 142.84 (4)°, Cl-Cu-S = 94.80 (2) and 99.97 (2)°, and S-Cu-S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°.
authors: Department Chemie, Fakultät für Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, Germany.
authors: Ulrich
authors: U
authors: Flörke
authors: Aziza
authors: A
authors: Ahmida
authors: Jörg
authors: J
authors: Schröder
authors: Hans
authors: H
authors: Egold
authors: Gerald
authors: G
authors: Henkel
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677