title: Palladium-catalyzed Hiyama-type cross-coupling reactions of arenesulfinates with organosilanes.
abstract: Palladium-catalyzed Hiyama-type cross-coupling reactions of various arenesulfinates with organosilanes were achieved in good to excellent yields under aerobic conditions at 70 °C. Fluoride is essential, and tetrabutylammonium fluoride (TBAF) was shown to be the most efficient additive for these cross-coupling reactions. These cross-coupling reactions of the arenesulfinates provide high yields and show wide functional group tolerance, making them attractive alternative transformations to traditional cross-coupling approaches for carbon-carbon bond construction.
authors: Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, People's Republic of China.
authors: Kai
authors: K
authors: Cheng
authors: Sai
authors: S
authors: Hu
authors: Baoli
authors: B
authors: Zhao
authors: Xian-Man
authors: XM
authors: Zhang
authors: Chenze
authors: C
authors: Qi
mesh_terms: D001190:Arylsulfonates / Q000737:chemistry*; D002384:Catalysis; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
chemical_list: D001190:Arylsulfonates; D006841:Hydrocarbons, Aromatic; D009942:Organometallic Compounds; D012821:Silanes; D010165:Palladium