title: The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters.
abstract: A novel and efficient procedure for the synthesis of δ,γ-alkenyl esters with complete E-stereochemistry by the 1,4-addition of alkenes to acrylate esters in the presence of a catalytic amount of palladium chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkenyl esters.
authors: Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin 541004, People's Republic of China.
authors: Pei
authors: P
authors: Liu
authors: Heng-shan
authors: HS
authors: Wang
authors: Ying-ming
authors: YM
authors: Pan
authors: Wei-long
authors: WL
authors: Dai
authors: Hong
authors: H
authors: Liang
authors: Zhen-Feng
authors: ZF
authors: Chen
mesh_terms: D000179:Acrylates / Q000138:chemical synthesis / Q000737:chemistry*; D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000138:chemical synthesis / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000179:Acrylates; D000475:Alkenes; D004952:Esters; D010165:Palladium; C036658:acrylic acid; C008756:palladium chloride