title: 2-[3-(4-Chloro-phen-yl)-5-(4-fluoro-phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia-zole.
abstract: In the title compound, C24H17ClFN3S, the pyrazole ring is almost planar (r.m.s. deviation = 0.030 Å). With the exception of the methine-bound benzene ring, which forms a dihedral angle of 85.77 (13)° with the pyrazole ring, the remaining non-C atoms lie in an approximate plane (r.m.s. deviation = 0.084 Å) so that overall the mol-ecule has a T-shape. In the crystal, centrosymmetrically related mol-ecules are connected via π-π inter-actions between pyrazole rings [centroid-centroid distance = 3.5370 (15) Å] and these stack along the a axis with no specific inter-actions between them.
authors: Applied Organic Chemistry Department, National Research Centre, Dokki, 12622 Giza, Egypt.
authors: Bakr F
authors: BF
authors: Abdel-Wahab
authors: Seik Weng
authors: SW
authors: Ng
authors: Edward R T
authors: ER
authors: Tiekink
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