title: Morphology dependent oxygen reduction activity of titanium carbide: bulk vs. nanowires.
abstract: Titanium carbide (TiC) possesses fascinating properties like high electrical conductivity and high mechanical strength coupled with high corrosion resistance and stability in acidic and alkaline environments. The present study demonstrates the tunability of mechanistic aspects of oxygen reduction reaction (ORR) using TiC nanostructures. One dimensional TiC nanostructures (TiC-NW) have been synthesized using a simple, hydrothermal method and used as a catalyst for ORR. Shape dependent electroactivity is demonstrated by comparing the activity of TiC-NW with its bulk counterparts. Comparative studies reveal higher ORR activities in the case of 1D TiC-NW involving ~4 electrons showing efficient reduction of molecular oxygen. Excellent stability and high methanol tolerance with good selectivity for ORR is reported.
authors: Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
authors: Vankayala
authors: V
authors: Kiran
authors: Kancharlapalli
authors: K
authors: Srinivasu
authors: Srinivasan
authors: S
authors: Sampath
mesh_terms: D053770:Nanowires / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
chemical_list: C096521:titanium carbide; D014025:Titanium; D010100:Oxygen