title: A three-dimensional manganese(II) metal-organic framework based on 5-methoxybenzene-1,3-dicarboxylic acid and exhibiting a pts net.
abstract: The solvothermal reaction of MnCl2·H2O and 5-methoxybenzene-1,3-dicarboxylic acid (MeO-m-H2BDC) led to a three-dimensional Mn(II) metal-organic framework, namely poly[(dimethylformamide-κO)(μ4-5-methoxybenzene-1,3-dicarboxylato-κ(4)O(1):O(1'):O(3),O(3'):O(3))manganese(II)], [Mn(C9H6O5)(C3H7NO)]n or [Mn(MeO-m-BDC)(DMF)]n (DMF is dimethylformamide). The Mn(II) atom is six-coordinated and exhibits a distorted octahedral geometry formed by five carboxylate O atoms from four different MeO-m-BDC(2-) anionic ligands and by one DMF O atom. The three-dimensional framework of (I) formed by the bridging MeO-m-BDC(2-) ligands and the Mn(II) atoms exhibits a pts topological network when MeO-m-BDC(2-) and Mn(II) are viewed as four-connected nodes.
authors: Department of Chemistry, Ningde Normal University, Ningde, Fujian 352100, People's Republic of China. huangxh45@126.com
authors: Xiao-Hui
authors: XH
authors: Huang
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003998:Dicarboxylic Acids / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular
chemical_list: C583147:5-methoxybenzene-1,3-dicarboxylic acid; D001555:Benzene Derivatives; D003998:Dicarboxylic Acids; D008024:Ligands; D008345:Manganese