title: Efficient C-H/C-N and C-H/C-CO-N conversion via decatungstate-photoinduced alkylation of diisopropyl azodicarboxylate.
abstract: Tetrabutylammonium decatungstate (TBADT) accelerated the addition of C-H bonds to the N═N double bond of diisopropyl azodicarboxylate (DIAD) under irradiation conditions. The photoinduced three-component coupling between cyclic alkanes, CO, and DIAD was also achieved to give the corresponding acyl hydrazides.
authors: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan, and PhotoGreen Lab, Department of Chemistry, University of Pavia , Viale Taramelli 12, 27100 Pavia, Italy.
authors: Ilhyong
authors: I
authors: Ryu
authors: Akihiro
authors: A
authors: Tani
authors: Takahide
authors: T
authors: Fukuyama
authors: Davide
authors: D
authors: Ravelli
authors: Sara
authors: S
authors: Montanaro
authors: Maurizio
authors: M
authors: Fagnoni
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000478:Alkylation; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D006860:Hydrogen Bonding; D015394:Molecular Structure; D011407:Propane / Q000031:analogs & derivatives* / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D001391:Azo Compounds; D000644:Quaternary Ammonium Compounds; D017973:Tungsten Compounds; C009405:tetrabutylammonium; D011407:Propane