title: Catalytic enantioselective allylation of ketimines by using palladium pincer complexes with chiral bis(imidazoline)s.
abstract: Get selective! Enantioselective allylation of ketimines derived from isatins by using chiral 1,3-bis(imidazolin-2-yl)benzene (Phebim)-Pd(II) complexes afforded products with good enantioselectivity (see scheme). The reaction was applied to a wide variety of ketimines. The obtained product can be converted to homoallylic amines and a spirocyclic amine without the loss of enantiopurity.
authors: Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan. snakamur@nitech.ac.jp
authors: Shuichi
authors: S
authors: Nakamura
authors: Kengo
authors: K
authors: Hyodo
authors: Masayuki
authors: M
authors: Nakamura
authors: Daisuke
authors: D
authors: Nakane
authors: Hideki
authors: H
authors: Masuda