title: Exploring the scope of a novel ligand class: synthesis and catalytic examination of metal complexes with 'normal' 1,2,3-triazolylidene ligands.
abstract: Using new 'normal'-substituted 1,2,3-triazolylidene silver compounds as starting materials allowed for preparation of a series of molybdenum, ruthenium, rhodium, and palladium transition metal complexes bound to the new 1,2,3-triazolylidene ligand system. In this work, the first triazolylidene Mo compound is presented as well as the first structural investigation of a silver complex with a monodentate 1,2,3-triazolylidene. Furthermore, the triazolylidene Pd complex and the Mo complex were tested as precatalysts in Suzuki-Miyaura coupling and epoxidation catalysis, respectively.
authors: Catalysis Research Center, Technische Universität München, Ernst-Otto-Fischer-Strasse 1, D-85747 Garching bei München, Germany.
authors: Lars-Arne
authors: LA
authors: Schaper
authors: Lilian
authors: L
authors: Graser
authors: Xuhui
authors: X
authors: Wei
authors: Rui
authors: R
authors: Zhong
authors: Karl
authors: K
authors: Öfele
authors: Alexander
authors: A
authors: Pöthig
authors: Mirza
authors: M
authors: Cokoja
authors: Bettina
authors: B
authors: Bechlars
authors: Wolfgang A
authors: WA
authors: Herrmann
authors: Fritz E
authors: FE
authors: Kühn
mesh_terms: D002384:Catalysis; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; D012834:Silver