title: Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides.
abstract: The cross-coupling reaction of cyclopropanol-derived ketone homoenolates bearing β-hydrogens with aryl and hetaryl bromides has been achieved for the first time. This reaction is high yielding, is broad in scope and uses a simple catalytic system. Notably, the proposed palladium homoenolates do not undergo β-hydride elimination to the corresponding α,β-unsaturated ketones.
authors: Department of Chemistry, York University, 4700 Keele Street, Toronto, ON M3J 1P3, Canada.
authors: David
authors: D
authors: Rosa
authors: Arturo
authors: A
authors: Orellana