title: Bis{2,2'-[methyl-aza-nediylbis(methyl-ene)]bis-(4,6-dimethyl-phenolato)-κ(3) O,N,O'}titanium(IV) toluene sesquisolvate.
abstract: The title compound, [Ti(C19H23NO2)2]·1.5C7H8, crystallizes with one titanium complex mol-ecule per asymmetric unit together with one and a half toluene mol-ecules. The Ti(IV) atom is coordinated by two fully deprotonated O,N,O'-tridentate phen-oxy-amine ligands in a distorted octa-hedral environment. Within this arrangement the O atoms occupy the equatorial sites and the N atoms the axial sites. One of the toluene mol-ecules is disordered over two sets of sites in a 0.628 (18):0.372 (18) ratio.
authors: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea.
authors: Yongseog
authors: Y
authors: Chung
authors: Youngjo
authors: Y
authors: Kim
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