title: Outstanding luminescence from neutral copper(I) complexes with pyridyl-tetrazolate and phosphine ligands.
abstract: Strongly luminescent, neutral copper(I) complexes bearing 5-(2-pyridyl)tetrazolate and various phosphine ligands were synthesized. While the cationic copper(I) precursors 1b-4b do not exceed photoluminescence quantum yields (PLQY) of 4-46%, the neutral complexes 1a-4a show PLQYs of up to 89%.
authors: Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany.
authors: Larissa
authors: L
authors: Bergmann
authors: Jana
authors: J
authors: Friedrichs
authors: Mathias
authors: M
authors: Mydlak
authors: Thomas
authors: T
authors: Baumann
authors: Martin
authors: M
authors: Nieger
authors: Stefan
authors: S
authors: Bräse
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D010720:Phosphines / Q000737:chemistry*; D013777:Tetrazoles / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D010720:Phosphines; D013777:Tetrazoles; D003300:Copper