title: P-stereogenic phospholanes or phosphorinanes from o-biarylylphosphines: two bridges not too far.
abstract: The discovery of a concise regiodivergent asymmetric route to nonclassical P-stereogenic 5- or 6-membered benzophosphacycles, under conditions-dependent radical (oxidative addition) versus anionic (S(N)Ar) benzannulation, is reported.
authors: National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana, Slovenia. barbara.mohar@ki.si
authors: Barbara
authors: B
authors: Mohar
authors: Alen
authors: A
authors: Čusak
authors: Barbara
authors: B
authors: Modec
authors: Michel
authors: M
authors: Stephan
mesh_terms: D008958:Models, Molecular; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D009943:Organophosphorus Compounds; D010720:Phosphines