title: Unique coordination-based heterometallic approach for the stoichiometric inclusion of high-valent metal ions in a porous metal-organic framework.
abstract: A heterometallic metal-organic framework incorporating Zn(2+) and Ti(4+) is successfully synthesized. The unique coordination mode of each metal ion to 2-oxido-1,4-benzenedicarboxylate leads to Zn6Ti2 building blocks, which extend to form a double-walled primitive cubic net. This material possesses a permanent porosity and long-term stability.
authors: Department of Applied Chemistry, College of Science and Technology, Hanyang University, 55 Hanyangdaehak-ro, Ansan 426-791, Republic of Korea.
authors: Keunil
authors: K
authors: Hong
authors: Woojeong
authors: W
authors: Bak
authors: Hyungphil
authors: H
authors: Chun
mesh_terms: D018360:Crystallography, X-Ray; D007477:Ions / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D007477:Ions; D009942:Organometallic Compounds; D014025:Titanium; D015032:Zinc