title: Ready synthetic access to enantiopure allylic α(F)-branched fluoroalkenes.
abstract: Convenient access to homochiral fluoroalkenes is described via a Julia-Kocienski olefination reaction. The required homochiral fluorosulfone is synthesized by a Mitsunobu reaction from readily available enantiopure secondary alcohols.
authors: Laboratoire de Chimie Moleculaire et Thioorganique, UMR CNRS 6507 & FR3038, ENSICAEN, Universite de Caen Basse-Normandie , 6 Boulevard du Marechal Juin, 14050 Caen, France, and Chemistry, University of Southampton , Highfield, Southampton SO17 1BJ, U.K.
authors: Florent
authors: F
authors: Larnaud
authors: Julien
authors: J
authors: Malassis
authors: Emmanuel
authors: E
authors: Pfund
authors: Bruno
authors: B
authors: Linclau
authors: Thierry
authors: T
authors: Lequeux
mesh_terms: D000438:Alcohols / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D000478:Alkylation; D005459:Fluorides / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013464:Sulfuric Acids / Q000737:chemistry
chemical_list: D000438:Alcohols; D000475:Alkenes; D006845:Hydrocarbons, Fluorinated; D013464:Sulfuric Acids; C046106:fluorosulfonic acid; D005459:Fluorides