title: Different crystallographic one-dimensional MnO2 nanomaterials and their superior performance in catalytic phenol degradation.
abstract: Three one-dimensional MnO2 nanoparticles with different crystallographic phases, α-, β-, and γ-MnO2, were synthesized, characterized, and tested in heterogeneous activation of Oxone for phenol degradation in aqueous solution. The α-, β-, and γ-MnO2 nanostructured materials presented in morphologies of nanowires, nanorods, and nanofibers, respectively. They showed varying activities in activation of Oxone to generate sulfate radicals for phenol degradation depending on surface area and crystalline structure. α-MnO2 nanowires exhibited the highest activity and could degrade phenol in 60 min at phenol concentrations ranging in 25-100 mg/L. It was found that phenol degradation on α-MnO2 followed first order kinetics with an activation energy of 21.9 kJ/mol. The operational parameters, such as MnO2 and Oxone loading, phenol concentration and temperature, were found to influence phenol degradation efficiency. It was also found that α-MnO2 exhibited high stability in recycled tests without losing activity, demonstrating itself to be a superior heterogeneous catalyst to the toxic Co3O4 and Co(2+).
authors: Department of Chemical Engineering and CRC for Contamination Assessment and Remediation of the Environment (CRC CARE), Curtin University, GPO Box U1987, Perth, WA 6845, Australia.
authors: Edy
authors: E
authors: Saputra
authors: Syaifullah
authors: S
authors: Muhammad
authors: Hongqi
authors: H
authors: Sun
authors: H M
authors: HM
authors: Ang
authors: M O
authors: MO
authors: Tadé
authors: Shaobin
authors: S
authors: Wang
mesh_terms: D000327:Adsorption; D002384:Catalysis; D003461:Crystallography; D017895:Manganese Compounds / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry; D049329:Nanostructures / Q000737:chemistry*; D043942:Nanotubes / Q000737:chemistry; D053770:Nanowires; D010087:Oxides / Q000737:chemistry*; D019800:Phenol / Q000737:chemistry*; D013431:Sulfates; D013464:Sulfuric Acids; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D017895:Manganese Compounds; D010087:Oxides; D013431:Sulfates; D013464:Sulfuric Acids; D014874:Water Pollutants, Chemical; D019800:Phenol; C027424:manganese oxide; C048813:potassium peroxymonosulfuric acid