title: Carboxylation of alkynylsilanes with carbon dioxide mediated by cesium fluoride in DMSO.
abstract: The facile syntheses of a variety functionalized propiolic acids were achieved by carboxylation of alkynylsilanes with carbon dioxide mediated by cesium fluoride under ambient conditions.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan.
authors.forename: Misato
authors.initials: M
authors.lastname: Yonemoto-Kobayashi
authors.forename: Kiyofumi
authors.initials: K
authors.lastname: Inamoto
authors.forename: Yoshiyuki
authors.initials: Y
authors.lastname: Tanaka
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Kondo
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D002586:Cesium / Q000737:chemistry*; D004121:Dimethyl Sulfoxide / Q000737:chemistry*; D005459:Fluorides / Q000737:chemistry*; D011422:Propionates / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
chemical_list: D000480:Alkynes; D011422:Propionates; D012821:Silanes; D002245:Carbon Dioxide; D002586:Cesium; C011537:propiolic acid; D005459:Fluorides; C027754:cesium fluoride; D004121:Dimethyl Sulfoxide