title: A method for synthesis of homoallylic bromide.
abstract: Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People's Republic of China.
authors.forename: Wenke
authors.initials: W
authors.lastname: Qi
authors.forename: Peipei
authors.initials: P
authors.lastname: Wang
authors.forename: Liyuan
authors.initials: L
authors.lastname: Fan
authors.forename: Songlin
authors.initials: S
authors.lastname: Zhang
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis*; D001577:Benzophenones / Q000737:chemistry; D001966:Bromine / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D017905:Phosphites / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D001577:Benzophenones; D017905:Phosphites; C047723:benzophenone; D001966:Bromine