title: Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3-H for pyrrole synthesis.
abstract: The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp(3)-H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp(3)-H metallation step was a slow step.
authors.affiliation: College of Chemistry and Molecular Sciences, Wuhan University, P. R. China.
authors.forename: Lingkui
authors.initials: L
authors.lastname: Meng
authors.forename: Kun
authors.initials: K
authors.lastname: Wu
authors.forename: Chao
authors.initials: C
authors.lastname: Liu
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei
mesh_terms: D000475:Alkenes / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry; D007700:Kinetics; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D011789:Quantum Theory
chemical_list: D000475:Alkenes; D011758:Pyrroles; D010165:Palladium; D002244:Carbon; D006859:Hydrogen