title: Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature.
abstract: This communication describes the first phosphoramidate directing group for synthetically useful arylation. Remarkably, the nature of a new directing group drives selective C-H bond activation to afford diverse N-aryl phosphoramidates in good to excellent yields at room temperature.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
authors.forename: Bathoju Chandra
authors.initials: BC
authors.lastname: Chary
authors.forename: Sunggak
authors.initials: S
authors.lastname: Kim
authors.forename: Youngchul
authors.initials: Y
authors.lastname: Park
authors.forename: Jinsik
authors.initials: J
authors.lastname: Kim
authors.forename: Phil Ho
authors.initials: PH
authors.lastname: Lee