title: Electrochemical formation of Mn(III)-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands.
abstract: A novel and efficient method for preparing [Mn(III)(O2)(L)](+) complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.
authors.affiliation: ICMMO, CNRS UMR 8182, Univ Paris-Sud, Bât. 420, 15 rue Georges Clemenceau, 91405 Orsay Cedex, France.
authors.forename: Sanae
authors.initials: S
authors.lastname: El Ghachtouli
authors.forename: H Y Vincent
authors.initials: HY
authors.lastname: Ching
authors.forename: Benedikt
authors.initials: B
authors.lastname: Lassalle-Kaiser
authors.forename: Régis
authors.initials: R
authors.lastname: Guillot
authors.forename: Domenick F
authors.initials: DF
authors.lastname: Leto
authors.forename: Swarup
authors.initials: S
authors.lastname: Chattopadhyay
authors.forename: Timothy A
authors.initials: TA
authors.lastname: Jackson
authors.forename: Pierre
authors.initials: P
authors.lastname: Dorlet
authors.forename: Elodie
authors.initials: E
authors.lastname: Anxolabéhère-Mallart
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D004563:Electrochemistry; D007093:Imidazoles / Q000737:chemistry*; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013481:Superoxides / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D007093:Imidazoles; D008024:Ligands; D011725:Pyridines; D013481:Superoxides; D008345:Manganese