title: Length-dependent thermopower of highly conducting Au-C bonded single molecule junctions.
abstract: We report the simultaneous measurement of conductance and thermopower of highly conducting single-molecule junctions using a scanning tunneling microscope-based break-junction setup. We start with molecular backbones (alkanes and oligophenyls) terminated with trimethyltin end groups that cleave off in situ to create junctions where terminal carbons are covalently bonded to the Au electrodes. We apply a thermal gradient across these junctions and measure their conductance and thermopower. Because of the electronic properties of the highly conducting Au-C links, the thermoelectric properties and power factor are very high. Our results show that the molecular thermopower increases nonlinearly with the molecular length while conductance decreases exponentially with increasing molecular length. Density functional theory calculations show that a gateway state representing the Au-C covalent bond plays a key role in the conductance. With this as input, we analyze a series of simplified models and show that a tight-binding model that explicitly includes the gateway states and the molecular backbone states accurately captures the experimentally measured conductance and thermopower trends.
authors.affiliation: Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York, USA.
authors.forename: J R
authors.initials: JR
authors.lastname: Widawsky
authors.forename: W
authors.initials: W
authors.lastname: Chen
authors.forename: H
authors.initials: H
authors.lastname: Vázquez
authors.forename: T
authors.initials: T
authors.lastname: Kim
authors.forename: R
authors.initials: R
authors.lastname: Breslow
authors.forename: M S
authors.initials: MS
authors.lastname: Hybertsen
authors.forename: L
authors.initials: L
authors.lastname: Venkataraman