title: Graphene nanosheets and graphite oxide as promising adsorbents for removal of organic contaminants from aqueous solution.
abstract: Graphenes are an emerging class of carbon nanomaterials whose adsorption properties toward organic compounds have not been well understood. In the present study, graphene nanosheets were prepared by reoxidation and abrupt heating of graphite oxide, which was prepared by sequential chemical oxidation of commercial nonporous graphite powder. Adsorption properties of three aromatic compounds (naphthalene, 2-naphthol, and 1-naphthylamine) and one pharmaceutical compound (tylosin) on graphene nanosheets and graphite oxide were examined to explore the potential of these two adsorbents for the removal of organic contaminants from aqueous solutions. Compared with the literature data of adsorption on carbon nanotubes, adsorption of bulky, flexible tylosin on graphene nanosheets exhibited markedly faster adsorption kinetics, which can be attributed to their opened-up layer structure. Graphene nanosheets and graphite oxide showed similar sequences of adsorption affinity: 1-naphthylamine > 2-naphthol > tylosin > naphthalene (with much larger differences observed on graphite oxide). It was proposed that the strong adsorption of the three aromatic compounds was mainly due to π-π electron donor-acceptor interactions with the graphitic surfaces of adsorbents. Additionally, Lewis acid-base interaction was likely an important factor contributing to the strong adsorption of 1-naphthylamine and tylosin, especially for the O-functionality-abundant graphite oxide. After being normalized on the basis of adsorbent surface area, adsorption affinities of all four tested adsorbates on graphene nanosheets were very close to those on nonporous graphite powder, reflecting complete accessibility of the adsorbent surface area in adsorption.
authors.forename: Liangliang
authors.initials: L
authors.lastname: Ji
authors.forename: Wei
authors.initials: W
authors.lastname: Chen
authors.forename: Zhaoyi
authors.initials: Z
authors.lastname: Xu
authors.forename: Shourong
authors.initials: S
authors.lastname: Zheng
authors.forename: Dongqiang
authors.initials: D
authors.lastname: Zhu
mesh_terms: D000327:Adsorption; D006108:Graphite; D006863:Hydrogen-Ion Concentration; D037742:Nanotubes, Carbon / Q000737:chemistry; D009930:Organic Chemicals; D010087:Oxides
chemical_list: D037742:Nanotubes, Carbon; D009930:Organic Chemicals; D010087:Oxides; D006108:Graphite