title: Composite poly(ethylene oxide) electrolytes plasticized by N-alkyl-N-butylpyrrolidinium bis(trifluoromethanesulfonyl)imide for lithium batteries.
abstract: We report a new class of quaternary polymer electrolyte membranes that comprise poly(ethylene oxide) (PEO), lithium trifluoromethanesulfonylimide (LiTFSI), N-alkyl-N-butylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PyrA,4 TFSI) as an ionic liquid, and a SiO₂ filler. The results of differential scanning calorimetry indicate that the addition of SiO₂ and different ionic liquids induces a decrease in the PEO melting enthalpy, which thereby increases the ionic conductivity and the Li transference number. The electrochemical stability is proved by using impedance spectroscopy and cyclic voltammetry. Galvanostatic cycling of Li/LiFePO₄ cells, which comprise the quaternary polymer electrolytes, revealed their superior performance compared to conventional PEO-Li salt electrolytes. In the course of this investigation, a synergistic effect of the combined ionic liquid-ceramic filler modification could be proved at temperatures close to 50 °C.
authors.affiliation: University of Münster, Institute of Physical Chemistry, Corrensstr. 46, 48149 Münster, Germany.
authors.forename: Morten
authors.initials: M
authors.lastname: Wetjen
authors.forename: Maria Assunta
authors.initials: MA
authors.lastname: Navarra
authors.forename: Stefania
authors.initials: S
authors.lastname: Panero
authors.forename: Stefano
authors.initials: S
authors.lastname: Passerini
authors.forename: Bruno
authors.initials: B
authors.lastname: Scrosati
authors.forename: Jusef
authors.initials: J
authors.lastname: Hassoun
mesh_terms: D011211:Electric Power Supplies; D004563:Electrochemistry; D007094:Imides / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D010968:Plasticizers / Q000737:chemistry*; D011092:Polyethylene Glycols / Q000737:chemistry*; D013696:Temperature
chemical_list: D007094:Imides; D010968:Plasticizers; D011092:Polyethylene Glycols; D008094:Lithium