title: Rhodium(III)-catalyzed azacycle-directed intermolecular insertion of arene C-H bonds into α-diazocarbonyl compounds.
abstract: Cp*Rh(III)-catalyzed intermolecular C-C couplings between activated α-diazocarbonyl compounds and arenes bearing a range of azacyclic directing groups have been achieved. This catalytic alkylation reaction operates under mild conditions with good functional group tolerance.
authors.affiliation: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
authors.forename: Xinzhang
authors.initials: X
authors.lastname: Yu
authors.forename: Songjie
authors.initials: S
authors.lastname: Yu
authors.forename: Jian
authors.initials: J
authors.lastname: Xiao
authors.forename: Boshun
authors.initials: B
authors.lastname: Wan
authors.forename: Xingwei
authors.initials: X
authors.lastname: Li
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001555:Benzene Derivatives / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D001372:Aza Compounds; D001391:Azo Compounds; D001555:Benzene Derivatives; D009942:Organometallic Compounds; D012238:Rhodium