title: Thermal detrapping rates of atomic hydrogen and atomic deuterium trapped in double four-ring Si8O12 cages measured simultaneously using EPR.
abstract: Does atomic hydrogen or atomic deuterium escape faster from the D4R cage of Q8M8 in thermal detrapping? An isotope effect was clearly observed by a simultaneous measurement using EPR. Arrhenius parameters were obtained and allowed the application of the absolute rate theory to explain the process.
authors.affiliation: Kyushu University, Department of Chemistry, Graduate School of Sciences, Higashi-ku, Fukuoka, Japan.
authors.forename: Y
authors.initials: Y
authors.lastname: Hayashino
authors.forename: T
authors.initials: T
authors.lastname: Isobe
authors.forename: Y
authors.initials: Y
authors.lastname: Matsuda