title: Enantiomeric differentiation by synthetic helical polymers.
abstract: Recent advances in the synthesis of helical polymers and their applications as chiral materials, in particular chiral stationary phases (CSPs), for high-performance liquid chromatography (HPLC) are reviewed with an emphasis on the key role of the helical conformations with one-handedness for the prominent chiral recognition of enantiomers. The historical background of artificial optically active helical polymers is also briefly described.
authors.affiliation: Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan, yashima@apchem.nagoya-u.ac.jp.
authors.forename: Eiji
authors.initials: E
authors.lastname: Yashima
authors.forename: Hiroki
authors.initials: H
authors.lastname: Iida
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Okamoto
mesh_terms: D000180:Acrylic Resins / Q000138:chemical synthesis / Q000302:isolation & purification; D003486:Cyanides / Q000138:chemical synthesis / Q000302:isolation & purification; D049673:History, 20th Century; D009696:Nucleic Acids / Q000138:chemical synthesis / Q000302:isolation & purification; D009904:Optical Rotation; D010455:Peptides / Q000138:chemical synthesis / Q000302:isolation & purification; D011108:Polymers / Q000138:chemical synthesis / Q000302:isolation & purification*; D011109:Polymethacrylic Acids / Q000138:chemical synthesis / Q000302:isolation & purification; D011134:Polysaccharides / Q000138:chemical synthesis / Q000302:isolation & purification; D053279:Polyynes / Q000138:chemical synthesis / Q000302:isolation & purification; D013237:Stereoisomerism; D000099166:Polyacrylamides
chemical_list: D000180:Acrylic Resins; D003486:Cyanides; D009696:Nucleic Acids; D010455:Peptides; D011108:Polymers; D011109:Polymethacrylic Acids; D011134:Polysaccharides; D053279:Polyynes; D000099166:Polyacrylamides; C030613:polymethacrylic acid