title: Modeling the influence of raindrop size on the wash-off losses of copper-based fungicides sprayed on potato (Solanum tuberosum L.) leaves.
abstract: Modeling the pesticide wash-off by raindrops is important for predicting pesticide losses and the subsequent transport of pesticides to soil and in soil run-off. Three foliar-applied copper-based fungicide formulations, specifically the Bordeaux mixture (BM), copper oxychloride (CO), and a mixture of copper oxychloride and propylene glycol (CO-PG), were tested on potato (Solanum tuberosum L.) leaves using a laboratory raindrop simulator. The losses in the wash-off were quantified as both copper in-solution loss and copper as particles detached by the raindrops. The efficiency of the raindrop impact on the wash-off was modeled using a stochastic model based on the pesticide release by raindrops. In addition, the influence of the raindrop size, drop falling height, and fungicide dose was analyzed using a full factorial experimental design. The average losses per dose after 14 mm of dripped water for a crop with a leaf area index equal to 1 were 0.08 kg Cu ha(-1) (BM), 0.3 kg Cu ha(-1) (CO) and 0.47 kg Cu ha(-1) (CO-PG). The stochastic model was able to simulate the time course of the wash-off losses and to estimate the losses of both Cu in solution and as particles by the raindrop impacts. For the Cu-oxychloride fungicides, the majority of the Cu was lost as particles that detached from the potato leaves. The percentage of Cu lost increased with the decreasing raindrop size in the three fungicides for the same amount of dripped water. This result suggested that the impact energy is not a limiting factor in the particle detachment rate of high doses. The dosage of the fungicide was the most influential factor in the losses of Cu for the three formulations studied. The results allowed us to quantify the factors that should be considered when estimating the losses by the wash-off of copper-based fungicides and the inputs of copper to the soil by raindrop wash-off.
authors.affiliation: Área de Edafoloxía e Química Agrícola, Universidade de Vigo, Facultade de Ciencias, 32004 Ourense, Spain.
authors.forename: Paula
authors.initials: P
authors.lastname: Pérez-Rodríguez
authors.forename: Marcos
authors.initials: M
authors.lastname: Paradelo
authors.forename: Isabel
authors.initials: I
authors.lastname: Rodríguez-Salgado
authors.forename: David
authors.initials: D
authors.lastname: Fernández-Calviño
authors.forename: José Eugenio
authors.initials: JE
authors.lastname: López-Periago
mesh_terms: D003300:Copper / Q000737:chemistry; D005659:Fungicides, Industrial / Q000737:chemistry / Q000494:pharmacology*; D007700:Kinetics; D008962:Models, Theoretical; D018515:Plant Leaves / Q000187:drug effects* / Q000254:growth & development; D011891:Rain / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D011198:Solanum tuberosum / Q000187:drug effects* / Q000254:growth & development
chemical_list: D005659:Fungicides, Industrial; D012989:Soil Pollutants; C007120:copper oxychloride; D003300:Copper; C006788:Bordeaux mixture