title: Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs.
abstract: Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
authors.forename: Masakazu
authors.initials: M
authors.lastname: Saito
authors.forename: Takashi
authors.initials: T
authors.lastname: Toyao
authors.forename: Kozo
authors.initials: K
authors.lastname: Ueda
authors.forename: Takashi
authors.initials: T
authors.lastname: Kamegawa
authors.forename: Yu
authors.initials: Y
authors.lastname: Horiuchi
authors.forename: Masaya
authors.initials: M
authors.lastname: Matsuoka