title: Recycling and reuse of waste from electricity distribution networks as reinforcement agents in polymeric composites.
abstract: Of the waste generated from electricity distribution networks, wooden posts treated with chromated copper arsenate (CCA) and ceramic insulators make up the majority of the materials for which no effective recycling scheme has been developed. This study aims to recycle and reuse this waste as reinforcement elements in polymer composites and hybrid composites, promoting an ecologically and economically viable alternative for the disposal of this waste. The CCA wooden posts were cut, crushed and recycled via acid leaching using 0.2 and 0.4N H2SO4 in triplicate at 70°C and then washed and dried. The ceramic insulators were fragmented in a hydraulic press and separated by particle size using a vibrating sieve. The composites were mixed in a twin-screw extruder and injected into the test specimens, which were subjected to physical, mechanical, thermal and morphological characterization. The results indicate that the acid treatment most effective for removing heavy metals in the wood utilizes 0.4NH2SO4. However, the composites made from wood treated with 0.2NH2SO4 exhibited the highest mechanical properties of the composites, whereas the use of a ceramic insulator produces composites with better thermal stability and impact strength. This study is part of the research and development project of ANEEL (Agência Nacional de Energia Elétrica) and funded by CPFL (Companhia Paulista de Força e Luz).
authors.affiliation: Program of Postgraduate Studies in Process and Technology Engineering, University of Caxias do Sul, Rua Francisco Getúlio Vargas, 1130, 95070-560 Caxias do Sul, RS, Brazil. matheus.vgz@gmail.com
authors.forename: Matheus V G
authors.initials: MV
authors.lastname: Zimmermann
authors.forename: Ademir J
authors.initials: AJ
authors.lastname: Zattera
mesh_terms: D001149:Arsenates; D002516:Ceramics; D004560:Electricity; D004736:Energy-Generating Resources; D019216:Metals, Heavy / Q000302:isolation & purification; D011108:Polymers; D059027:Recycling; D012037:Refuse Disposal / Q000379:methods*; D013464:Sulfuric Acids / Q000737:chemistry; D014934:Wood
chemical_list: D001149:Arsenates; D019216:Metals, Heavy; D011108:Polymers; D013464:Sulfuric Acids; C040890:chromated copper arsenate; C033158:sulfuric acid