title: Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters.
abstract: The reactivity of a series of {Fe(NO)2}(9) dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)2}(10) complexes.
authors.affiliation: Department of Chemistry, Brown University, Providence, RI 02912, USA.
authors.forename: Jessica
authors.initials: J
authors.lastname: Fitzpatrick
authors.forename: Harris
authors.initials: H
authors.lastname: Kalyvas
authors.forename: Jason
authors.initials: J
authors.lastname: Shearer
authors.forename: Eunsuk
authors.initials: E
authors.lastname: Kim
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry*; D008968:Molecular Conformation; D009566:Nitrates / Q000737:chemistry*; D009603:Nitroso Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D011789:Quantum Theory; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D005296:Ferrous Compounds; D009566:Nitrates; D009603:Nitroso Compounds; D013438:Sulfhydryl Compounds; C028357:Roussin red methyl ester; D010100:Oxygen