title: Efficient epoxidation of olefins by H2O2 catalyzed by iron "helmet" phthalocyanines.
abstract: High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2-2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.
authors.affiliation: Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, CNRS-Université Lyon 1, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France.
authors.forename: Igor Y
authors.initials: IY
authors.lastname: Skobelev
authors.forename: Evgeny V
authors.initials: EV
authors.lastname: Kudrik
authors.forename: Olga V
authors.initials: OV
authors.lastname: Zalomaeva
authors.forename: Florian
authors.initials: F
authors.lastname: Albrieux
authors.forename: Pavel
authors.initials: P
authors.lastname: Afanasiev
authors.forename: Oxana A
authors.initials: OA
authors.lastname: Kholdeeva
authors.forename: Alexander B
authors.initials: AB
authors.lastname: Sorokin
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D004852:Epoxy Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D015394:Molecular Structure; D011789:Quantum Theory
chemical_list: D000475:Alkenes; D004852:Epoxy Compounds; D005290:Ferric Compounds; D007211:Indoles; D054833:Isoindoles; D006861:Hydrogen Peroxide; C013647:phthalocyanine