title: Rapid synthesis of unsaturated alcohols under mild conditions by highly selective hydrogenation.
abstract: Ir-ReOx/SiO2 acted as a highly active and selective heterogeneous catalyst for the hydrogenation of unsaturated aldehydes to unsaturated alcohols in water at low H2 pressure (0.8 MPa) and low temperature (303 K). The catalysis is derived from the synergy between Ir metal and ReOx.
authors.affiliation: Graduate School of Engineering, Tohoku University, Aoba 6-6-07, Aramaki, Sendai, 980-8579, Japan.
authors.forename: Masazumi
authors.initials: M
authors.lastname: Tamura
authors.forename: Kensuke
authors.initials: K
authors.lastname: Tokonami
authors.forename: Yoshinao
authors.initials: Y
authors.lastname: Nakagawa
authors.forename: Keiichi
authors.initials: K
authors.lastname: Tomishige
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis / Q000737:chemistry*; D000447:Aldehydes / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry; D006865:Hydrogenation; D007495:Iridium / Q000737:chemistry; D011312:Pressure; D012211:Rhenium / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D000438:Alcohols; D000447:Aldehydes; D014867:Water; C015428:perrhenate; D007495:Iridium; D012211:Rhenium; D012822:Silicon Dioxide; D006859:Hydrogen