title: In situ observations of gas phase dynamics during graphene growth using solid-state carbon sources.
abstract: A single-layer graphene has been uniformly grown on a Cu surface at elevated temperatures by thermal processing of a poly(methyl methacrylate) (PMMA) film in a rapid thermal annealing (RTA) system under vacuum. The detailed chemistry of the transition from solid-state carbon to graphene on the catalytic Cu surface was investigated by performing in situ residual gas analysis while PMMA/Cu-foil samples were being heated, in conjunction with interrupted growth studies to reconstruct ex situ the heating process. The data clearly show that the formation of graphene occurs by vaporizing hydrocarbon molecules from PMMA, such as methane and/or methyl radicals, which act as precursors, rather than by the direct graphitization of solid-state carbon. We also found that the temperature for vaporizing hydrocarbon molecules from PMMA and the length of time the gaseous hydrocarbon atmosphere is maintained, which are dependent on both the heating temperature profile and the amount of a solid carbon feedstock, are the dominant factors that determine the crystalline quality of the resulting graphene film. Under optimal growth conditions, the PMMA-derived graphene was found to have a carrier (hole) mobility as high as ∼2700 cm(2) V(-1) s(-1) at room temperature, which is superior to common graphene converted from solid carbon.
authors.affiliation: School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, South Korea.
authors.forename: Jinsung
authors.initials: J
authors.lastname: Kwak
authors.forename: Tae-Yang
authors.initials: TY
authors.lastname: Kwon
authors.forename: Jae Hwan
authors.initials: JH
authors.lastname: Chu
authors.forename: Jae-Kyung
authors.initials: JK
authors.lastname: Choi
authors.forename: Mi-Sun
authors.initials: MS
authors.lastname: Lee
authors.forename: Sung Youb
authors.initials: SY
authors.lastname: Kim
authors.forename: Hyung-Joon
authors.initials: HJ
authors.lastname: Shin
authors.forename: Kibog
authors.initials: K
authors.lastname: Park
authors.forename: Jang-Ung
authors.initials: JU
authors.lastname: Park
authors.forename: Soon-Yong
authors.initials: SY
authors.lastname: Kwon