title: Enantioselective self-assembly of antiferromagnetic hexacopper(II) wheels with chiral amino acid oxamates.
abstract: The Cu(2+)-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.
authors.affiliation: Departament de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valéncia, 46980 Paterna, Valéncia, Spain.
authors.forename: Thais
authors.initials: T
authors.lastname: Grancha
authors.forename: Jesús
authors.initials: J
authors.lastname: Ferrando-Soria
authors.forename: Joan
authors.initials: J
authors.lastname: Cano
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve
authors.forename: Giovanni
authors.initials: G
authors.lastname: De Munno
authors.forename: Donatella
authors.initials: D
authors.lastname: Armentano
authors.forename: Emilio
authors.initials: E
authors.lastname: Pardo
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D060328:Magnetic Phenomena; D013237:Stereoisomerism; D014633:Valine / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D003300:Copper; D014633:Valine