title: 1,3-Diiodo-azulene-2-carbonitrile.
abstract: In the title compound, C11H5I2N, the two iodine-atom substitutents with their large atomic sizes lead to short intra-molecular I⋯H distances (3.01 Å). In the crystal, the tris-ubstituted azulene system forms π-stacks [centroid-centroid distance = 3.6343 (11) Å] along the a-axis direction, showing the characteristic azulene inter-action mode between the electron-rich five-membered ring and the electron-deficient seven-membered ring. I⋯I [3.9129 (2) Å] non-covalent contacts are observed along with weak C-H⋯N and C-H⋯π. bonds.
authors.affiliation: Institut für Organische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachsen, Germany.
authors.forename: Sebastian
authors.initials: S
authors.lastname: Förster
authors.forename: Wilhelm
authors.initials: W
authors.lastname: Seichter
authors.forename: Edwin
authors.initials: E
authors.lastname: Weber