title: The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.
authors.affiliation: Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637, USA.
authors.forename: Jiajing
authors.initials: J
authors.lastname: Tan
authors.forename: Matsujiro
authors.initials: M
authors.lastname: Akakura
authors.forename: Hisashi
authors.initials: H
authors.lastname: Yamamoto
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D008968:Molecular Conformation; D010455:Peptides / Q000138:chemical synthesis / Q000737:chemistry; D061065:Polyketides / Q000138:chemical synthesis / Q000737:chemistry; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D002264:Carboxylic Acids; D010455:Peptides; D061065:Polyketides; C116609:3-hydroxybutanal; D012825:Silicon
keywords: Mannich reaction; aldol reactions; carboxy groups; photodeprotection; protecting groups