title: Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes.
abstract: Cyclic voltammetry (CV), synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and near edge X-ray absorption fine structure (NEXAFS) show that oxidation of ferrocene tagged PVC induces an accumulation of high molecular weight polymer at the buried interface between the substrate electrode and the plasticized membrane.
authors.affiliation: Faculty of Science, Health, Education and Engineering, University of the Sunshine Coast, 90 Sippy Downs Drive, Sippy Downs, Queensland 4556, Australia.
authors.forename: Manzar
authors.initials: M
authors.lastname: Sohail
authors.forename: Roland
authors.initials: R
authors.lastname: De Marco
authors.forename: Muhammad Tanzirul
authors.initials: MT
authors.lastname: Alam
authors.forename: Marcin
authors.initials: M
authors.lastname: Pawlak
authors.forename: Eric
authors.initials: E
authors.lastname: Bakker
mesh_terms: D001692:Biological Transport / Q000502:physiology; D004566:Electrodes; D005296:Ferrous Compounds / Q000032:analysis / Q000378:metabolism*; D000075163:Metallocenes; D056951:Photoelectron Spectroscopy / Q000379:methods; D010968:Plasticizers / Q000737:chemistry*; D011143:Polyvinyl Chloride / Q000032:analysis / Q000378:metabolism*
chemical_list: D005296:Ferrous Compounds; D000075163:Metallocenes; D010968:Plasticizers; D011143:Polyvinyl Chloride; C004998:ferrocene