title: Tetra-aceto-nitrile-lithium tetra-iso-thio-cyanato-borate.
abstract: The crystal structure of the title salt, [Li(CH3CN)4][B(NCS)4], is composed of discrete cations and anions. Both the Li and B atoms show a tetra-hedral coordination by four equal ligands. The aceto-nitrile and iso-thio-cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra-hedral value [108.92 (18)-109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)-113.70 (17)°].
authors.affiliation: Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany.
authors.forename: Jens Michael
authors.initials: JM
authors.lastname: Breunig
authors.forename: Ulrich
authors.initials: U
authors.lastname: Wietelmann
authors.forename: Hans-Wolfram
authors.initials: HW
authors.lastname: Lerner
authors.forename: Michael
authors.initials: M
authors.lastname: Bolte