title: Free-radical carbo-alkenylation of enamides and ene-carbamates.
abstract: The addition of xanthates and vinyldisulfones across the double bond of enamides and ene-carbamates provides access to the corresponding three-component adducts in good to excellent yields with a high level of diastereocontrol in cyclic systems. This strategy illustrates a complementary reactivity for these versatile olefins and extends their scope of application.
authors.affiliation: Institut des Sciences Moléculaires, Université de Bordeaux, UMR-CNRS 5255, 351, cours de la libération, 33405 Talence Cedex, France.
authors.forename: Clément
authors.initials: C
authors.lastname: Poittevin
authors.forename: Virginie
authors.initials: V
authors.lastname: Liautard
authors.forename: Redouane
authors.initials: R
authors.lastname: Beniazza
authors.forename: Frédéric
authors.initials: F
authors.lastname: Robert
authors.forename: Yannick
authors.initials: Y
authors.lastname: Landais
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002219:Carbamates / Q000737:chemistry*; D005609:Free Radicals; D015394:Molecular Structure; D013237:Stereoisomerism; D013871:Thiones / Q000737:chemistry*; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D000475:Alkenes; D000577:Amides; D002219:Carbamates; D005609:Free Radicals; D013871:Thiones; D014753:Vinyl Compounds