title: Reversible hydrogen desorption from LiBH4 catalyzed by graphene supported Pt nanoparticles.
abstract: The thermally induced de-/rehydrogenation performance of the graphene supported Pt nanoparticles (Pt/G) doped LiBH4 was greatly improved even at very low catalyst content due to a synergetic effect of Pt addition and nanoconfinement in graphene. For the 5 wt% Pt/G doped LiBH4 sample, the onset hydrogen desorption temperature is about 140 °C lower than that of the pure LiBH4. With increasing loading of the Pt/G catalysts in LiBH4 samples, the onset dehydrogenation temperature and the two main desorption peaks from LiBH4 were found to decrease while the hydrogen release amount increased. About 17.8 wt% can be released from the 50 wt% Pt/G doped LiBH4 sample below 500 °C. Moreover, variation of the equilibrium pressure (350-450 °C) indicates that the dehydrogenation enthalpy is reduced from 74 kJ mol(-1) H2 for the pure LiBH4 to ca. 48 kJ mol(-1) H2 for the 10 wt% Pt/G doped LiBH4, showing improved thermodynamic properties. More importantly, a reversible capacity of ca. 8.1 wt% in the 30th de-/rehydrogenation cycle was achieved under 3 MPa H2 at 400 °C for 10 h, indicating that the Pt/G catalysts play a crucial role in the improvement of the hydrogen uptake reversibility of LiBH4 at lower temperature and pressure conditions. Especially, LiBH4 was reformed and a new product, Li2B10H10, was detected after the rehydrogenation process.
authors.affiliation: Jiangsu Key Laboratory for Solar Cell Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China. zdchen.lab@gmail.com.
authors.forename: Juan
authors.initials: J
authors.lastname: Xu
authors.forename: Zhongqing
authors.initials: Z
authors.lastname: Qi
authors.forename: Jianyu
authors.initials: J
authors.lastname: Cao
authors.forename: Rongrong
authors.initials: R
authors.lastname: Meng
authors.forename: Xiaofang
authors.initials: X
authors.lastname: Gu
authors.forename: Wenchang
authors.initials: W
authors.lastname: Wang
authors.forename: Zhidong
authors.initials: Z
authors.lastname: Chen