title: Synthesis and characterization of conjugated Dawson-type polyoxometalate-porphyrin copolymers.
abstract: Hybrid polyoxometalate-porphyrin copolymeric films were obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) in the presence of a Dawson type polyoxophosphovanadotungstate bearing two pyridyl groups (POM(py)2). The synthesis of a series of POM(py)2 consisting of [P2W15V3O62](9-) functionalized with diol-amide or triol moieties, as well as the characterization of the copolymers are presented.
authors.affiliation: UPMC Univ Paris 6, Institut Parisien de Chimie Moléculaire, CNRS UMR 7201, 4 Place Jussieu, 75005 Paris, France.
authors.forename: Iban
authors.initials: I
authors.lastname: Azcarate
authors.forename: Iftikhar
authors.initials: I
authors.lastname: Ahmed
authors.forename: Rana
authors.initials: R
authors.lastname: Farha
authors.forename: Michel
authors.initials: M
authors.lastname: Goldmann
authors.forename: Xiaoxia
authors.initials: X
authors.lastname: Wang
authors.forename: Hualong
authors.initials: H
authors.lastname: Xu
authors.forename: Bernold
authors.initials: B
authors.lastname: Hasenknopf
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Lacôte
authors.forename: Laurent
authors.initials: L
authors.lastname: Ruhlmann
mesh_terms: D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D009942:Organometallic Compounds; D011108:Polymers; D011166:Porphyrins; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates