title: Carbonylation of the simplest persistent diaminocarbene.
abstract: The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.
authors.affiliation: Institute of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, D-34132 Kassel, Germany.
authors.forename: Tim
authors.initials: T
authors.lastname: Schulz
authors.forename: Christian
authors.initials: C
authors.lastname: Färber
authors.forename: Michael
authors.initials: M
authors.lastname: Leibold
authors.forename: Clemens
authors.initials: C
authors.lastname: Bruhn
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Baumann
authors.forename: Detlef
authors.initials: D
authors.lastname: Selent
authors.forename: Timo
authors.initials: T
authors.lastname: Porsch
authors.forename: Max C
authors.initials: MC
authors.lastname: Holthausen
authors.forename: Ulrich
authors.initials: U
authors.lastname: Siemeling
mesh_terms: D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry; D004148:Dioxolanes / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: D000480:Alkynes; D004148:Dioxolanes; C504703:aminocarbene