title: Monophosphate tungsten bronzes with pentagonal tunnels: reinvestigation through the peephole of the superspace.
abstract: The large family of monophosphate tungsten bronzes with pentagonal tunnels (MPTBp), (PO2)4(WO3)2m with m ranging from 4 to 14, can be considered as modular structures via a description with (PO2)2(WO3)m modules related together by a symmetry operation and alternating along the z axis. Following the success of the application of the superspace for the description of the lillianites homologous series, a (3+1)-dimensional superspace model is efficiently defined to unify the structural analysis of the MPTBp. The (3+1)-dimensional model reveals hidden common characteristics such as the symmetry. An evaluation of the model for six well known members of the series was carried out from experimental data collected to this aim.
authors.affiliation: CRISMAT/ENSICAEN, UMR CNRS 6508, 6 Boulevard du Maréchal Juin, 14050 CEDEX 4, Caen, France.
authors.forename: Olivier
authors.initials: O
authors.lastname: Pérez
authors.forename: Luis
authors.initials: L
authors.lastname: Elcoro
authors.forename: J M
authors.initials: JM
authors.lastname: Pérez-Mato
authors.forename: Václav
authors.initials: V
authors.lastname: Petříček
keywords: modular structures; pentagonal tunnel homologous series; superspace formalism; tungsten bronzes