title: Degradation of chlorophenoxy herbicides by coupled Fenton and biological oxidation.
abstract: A combined treatment for the degradation of the chlorophenoxy herbicides 2,4-D and MCPA in water by means of Fenton and biological oxidation has been studied. The chemical oxidation step was necessary to achieve an efficient removal of these pollutants due to their toxicity and low biodegradability. Aqueous herbicide solutions (180mgL(-1)) were subjected to Fenton oxidation upon different H2O2 doses (from the theoretical stoichiometric amount referred to initial COD to 20% of this value). The toxicity and biodegradability tests of the Fenton effluents suggested that the ones resulting upon treatment with 80% and 60% of stoichiometric H2O2 were the optimal for subsequent biological treatment dealing with 2,4-D and MCPA, respectively. These effluents were treated in a sequencing batch reactor achieving nearly 90% conversion of organic matter measured as COD.
authors.affiliation: Seccion Departamental de Ingenieria Quimica, Universidad Autonoma de Madrid, Madrid 28049, Spain. sonia.sanchis@uam.es
authors.forename: Sonia
authors.initials: S
authors.lastname: Sanchis
authors.forename: Alicia M
authors.initials: AM
authors.lastname: Polo
authors.forename: Montserrat
authors.initials: M
authors.lastname: Tobajas
authors.forename: Juan J
authors.initials: JJ
authors.lastname: Rodriguez
authors.forename: Angel F
authors.initials: AF
authors.lastname: Mohedano
mesh_terms: D015084:2,4-Dichlorophenoxyacetic Acid / Q000737:chemistry* / Q000378:metabolism* / Q000633:toxicity; D008456:2-Methyl-4-chlorophenoxyacetic Acid / Q000737:chemistry* / Q000378:metabolism* / Q000633:toxicity; D048908:Aliivibrio fischeri / Q000187:drug effects; D054750:Ecotoxicology; D004785:Environmental Pollutants / Q000737:chemistry / Q000378:metabolism / Q000633:toxicity; D006540:Herbicides / Q000737:chemistry* / Q000378:metabolism* / Q000633:toxicity; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D018505:Waste Management
chemical_list: D004785:Environmental Pollutants; C045076:Fenton's reagent; D006540:Herbicides; D015084:2,4-Dichlorophenoxyacetic Acid; D006861:Hydrogen Peroxide; D008456:2-Methyl-4-chlorophenoxyacetic Acid; D007501:Iron
keywords: 2,4-D; Biodegradability; Ecotoxicity; Fenton process; MCPA; Sequencing batch reactor