title: Preparation of dicarboxylic acid-type gemini surfactant via Diels-Alder reaction & ozone oxidation.
abstract: We wish to report a novel preparation method for Gemsurf analogs as well as dicarboxylic acid-type Gemini surfactant from Diels-Alder adducts of 2-trimethylsilyloxy-1,3-butadiene, in which ozone oxidation is adopted to convert C=C double bond to dicarboxylic acid without any additional oxidant.
authors.affiliation: Kyoto Institute of Technology, Laboratory of Interface Materials Kyoto-shi, Japan.
authors.forename: Huynh N
authors.initials: HN
authors.lastname: Chau
authors.forename: Tokuzo
authors.initials: T
authors.lastname: Kawase
authors.forename: Tatsuo
authors.initials: T
authors.lastname: Oida
mesh_terms: D002070:Butadienes / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic / Q000379:methods; D061565:Cycloaddition Reaction; D003998:Dicarboxylic Acids / Q000737:chemistry*; D010084:Oxidation-Reduction; D010126:Ozone / Q000737:chemistry*; D013501:Surface-Active Agents / Q000138:chemical synthesis* / Q000737:chemistry*; D014297:Trimethylsilyl Compounds / Q000737:chemistry
chemical_list: D002070:Butadienes; D003998:Dicarboxylic Acids; D013501:Surface-Active Agents; D014297:Trimethylsilyl Compounds; D010126:Ozone