title: Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly.
abstract: Iron complexes derived from 6-diaminotriazyl-2,2'-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.
authors.affiliation: Department of Chemistry, University of California - Riverside, 501 Big Springs Rd., Riverside, CA 92521, USA.
authors.forename: Michael C
authors.initials: MC
authors.lastname: Young
authors.forename: Erica
authors.initials: E
authors.lastname: Liew
authors.forename: Jonathan
authors.initials: J
authors.lastname: Ashby
authors.forename: Kelsi E
authors.initials: KE
authors.lastname: McCoy
authors.forename: Richard J
authors.initials: RJ
authors.lastname: Hooley
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*
chemical_list: D005296:Ferrous Compounds; D011725:Pyridines