title: Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.
abstract: Upon reaction with ligands A, 1 and 3 bearing the 2,5-bis(2-pyridyl)phosphole fragment, an unexpected conversion of Cu(II) metal centers to Cu(I) centers is observed affording either bimetallic complexes bearing a bridging phosphane coordination mode or hexametallic metallacycles.
authors.affiliation: Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS - Université de Rennes 1, 35042 Rennes Cedex, France.
authors.forename: Mehdi
authors.initials: M
authors.lastname: El Sayed Moussa
authors.forename: Fabian
authors.initials: F
authors.lastname: Friess
authors.forename: Wenting
authors.initials: W
authors.lastname: Shen
authors.forename: Muriel
authors.initials: M
authors.lastname: Hissler
authors.forename: Régis
authors.initials: R
authors.lastname: Réau
authors.forename: Christophe
authors.initials: C
authors.lastname: Lescop