title: Bandgap engineering and shape control of colloidal Cd(x)Zn(1-x)O nanocrystals.
abstract: Bandgap engineering and shape control are important and advantageous for potential applications involving colloidal ZnO nanocrystals. Here we demonstrate the syntheses of high quality alloyed Cd(x)Zn(1-x)O nanocrystals with well-defined shapes, from faceted particles to tetrapods and ultrathin nanowires. By comparing the optical bandgaps of the pure ZnO, Cd(x)Zn(1-x)O and Mg(x)Zn(1-x)O nanocrystals with various dimensions, we conclude that bandgap engineering of colloidal ZnO nanocrystals via cadmium alloying effectively narrows the bandgaps. Our study may shed light on the design and syntheses of colloidal alloyed oxide nanocrystals with controlled band structures and shapes.
authors.affiliation: State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, People's Republic of China.
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.forename: Yizheng
authors.initials: Y
authors.lastname: Jin
authors.forename: Haiping
authors.initials: H
authors.lastname: He
authors.forename: Fan
authors.initials: F
authors.lastname: Yang
authors.forename: Yefeng
authors.initials: Y
authors.lastname: Yang
authors.forename: Zhizhen
authors.initials: Z
authors.lastname: Ye