title: Well-dispersed Pt cubes on porous Cu foam: high-performance catalysts for the electrochemical oxidation of glucose in neutral media.
abstract: The investigation of highly efficient catalysts for the electrochemical oxidation of glucose is the most critical challenge to commercialize nonenzymatic glucose sensors, which display a few attractive superiorities including the sufficient stability of their properties and the desired reproducibility of results over enzyme electrodes. Herein we propose a new and very promising catalyst: Pt cubes well-dispersed on the porous Cu foam, for the the electrochemical oxidation reaction of glucose in neutral media. The catalyst is fabricated in situ on a homemade screen-printed carbon electrode (SPCE) substrate through initially synthesizing the three-dimensional (3D) porous Cu foam using a hydrogen evolution assisted electrodeposition strategy, followed by electrochemically reducing the platinic precursor simply and conveniently. Field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) proofs demonstrate that Pt cubes, with an average size (the distance of opposite faces) of 185.1 nm, highly dispersed on the macro/nanopore integrated Cu foam support can be reproducibly obtained. The results of electrochemical tests indicate that the cubic Pt-based catalyst exhibits significant enhancement on the catalytic activity towards the electrooxidation of glucose in the presence of chloride ions, providing a specific activity 6.7 times and a mass activity 5.3 times those of commercial Pt/C catalysts at -0.4 V (vs. Ag/AgCl). In addition, the proposed catalyst shows excellent stability of performance, with only a 2.8% loss of electrocatalytic activity after 100 repetitive measurements.
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai 200237, P.R. China.
authors.forename: Xiangheng
authors.initials: X
authors.lastname: Niu
authors.forename: Minbo
authors.initials: M
authors.lastname: Lan
authors.forename: Hongli
authors.initials: H
authors.lastname: Zhao
authors.forename: Chen
authors.initials: C
authors.lastname: Chen
mesh_terms: D015374:Biosensing Techniques / Q000379:methods; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D005947:Glucose / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D010084:Oxidation-Reduction; D010984:Platinum / Q000737:chemistry*; D016062:Porosity; D015203:Reproducibility of Results
chemical_list: D010984:Platinum; D002244:Carbon; D003300:Copper; D005947:Glucose
keywords: catalytic activity; electrooxidation; platinum; porous foam; sensors