title: Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones.
abstract: Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.
authors.affiliation: State Key Lab of Urban Water Resource and Environment (SKLUWRE) & Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang 150080, PR China. chenqian@hit.edu.cn
authors.forename: Qian
authors.initials: Q
authors.lastname: Chen
authors.forename: Chao
authors.initials: C
authors.lastname: Chen
authors.forename: Fang
authors.initials: F
authors.lastname: Guo
authors.forename: Wujiong
authors.initials: W
authors.lastname: Xia
mesh_terms: D001388:Aziridines / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry; D002384:Catalysis; D008024:Ligands; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001388:Aziridines; D001897:Boronic Acids; D008024:Ligands; D012238:Rhodium