title: Bent thorocene complexes with the cyanide, azide and hydride ligands.
abstract: Reaction of the linear thorocene with NC(-), N3(-) and H(-) led to the bent derivatives [(Cot)2Th(X)](-) (X = CN, N3) and the bimetallic [{(Cot)2Th}2(μ-H)](-), whereas only [(Cot)2U(CN)](-) could be formed from (Cot)2U.
authors.affiliation: CEA, IRAMIS, SIS2M, CNRS UMR 3299, CEA/Saclay, 91191 Gif-sur-Yvette, France.
authors.forename: Alexandre
authors.initials: A
authors.lastname: Hervé
authors.forename: Nicolas
authors.initials: N
authors.lastname: Garin
authors.forename: Pierre
authors.initials: P
authors.lastname: Thuéry
authors.forename: Michel
authors.initials: M
authors.lastname: Ephritikhine
authors.forename: Jean-Claude
authors.initials: JC
authors.lastname: Berthet
mesh_terms: D001386:Azides / Q000737:chemistry*; D003486:Cyanides / Q000737:chemistry*; D034242:Cyclooctanes / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry; D014501:Uranium / Q000737:chemistry
chemical_list: D001386:Azides; D003486:Cyanides; D034242:Cyclooctanes; D008024:Ligands; D009942:Organometallic Compounds; D014501:Uranium; D006859:Hydrogen; D012964:Sodium