title: Functionalized IRMOF-3: an efficient heterogeneous catalyst for the cycloaddition of allyl glycidyl ether and CO2.
abstract: Functionalized metal organic framework F-IRMOF-3 having quaternary ammonium group was prepared by a fast precipitation and solvothermal method. They showed good catalytic performance for the cycloaddition of allyl glycidyl ether (AGE) and carbon dioxide without any solvent. F-IRMOF-3 with a larger alkyl chain structure and more nucleophilic anion exhibited better reactivity for the cycloaddition reaction. The introduction of a defective ZnO to F-IRMOF-3 by the fast precipitation method becomes more advantageous than the conventional solvothermal method for the cycloaddition reaction due to acid-base bifunctional active sites. The F-IRMOF-3 can be easily recovered and reused without any considerable loss of initial activity.
authors.affiliation: Division of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Korea.
authors.forename: Yu-Jin
authors.initials: YJ
authors.lastname: Kim
authors.forename: Dae-Won
authors.initials: DW
authors.lastname: Park
mesh_terms: D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D061565:Cycloaddition Reaction; D004852:Epoxy Compounds / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D004852:Epoxy Compounds; D009930:Organic Chemicals; D002245:Carbon Dioxide; C054361:allyl glycidyl ether