title: Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects.
abstract: The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.
authors.affiliation: Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat 80161, Thailand. hdavid@wu.ac.th
authors.forename: David J
authors.initials: DJ
authors.lastname: Harding
authors.forename: Wasinee
authors.initials: W
authors.lastname: Phonsri
authors.forename: Phimphaka
authors.initials: P
authors.lastname: Harding
authors.forename: Ian A
authors.initials: IA
authors.lastname: Gass
authors.forename: Keith S
authors.initials: KS
authors.lastname: Murray
authors.forename: Boujemaa
authors.initials: B
authors.lastname: Moubaraki
authors.forename: John D
authors.initials: JD
authors.lastname: Cashion
authors.forename: Lujia
authors.initials: L
authors.lastname: Liu
authors.forename: Shane G
authors.initials: SG
authors.lastname: Telfer
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D012997:Solvents / Q000737:chemistry
chemical_list: D005290:Ferric Compounds; D012997:Solvents; C581450:iron(III) quinolylsalicylaldimine; D000432:Methanol