title: Asymmetric construction of fluorinated imidazolidines via Cu(I)-catalyzed exo'-selective 1,3-dipolar cycloaddition of azomethine ylides with fluorinated imines.
abstract: Expedient access to optically active fluorinated 2,4-trans-imidazolidines was successfully developed via Cu(I)-catalyzed exo'-selective 1,3-DC of azomethine ylides with fluorinated imines.
authors.affiliation: College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
authors.forename: Qing-Hua
authors.initials: QH
authors.lastname: Li
authors.forename: Liang
authors.initials: L
authors.lastname: Wei
authors.forename: Xuan
authors.initials: X
authors.lastname: Chen
authors.forename: Chun-Jiang
authors.initials: CJ
authors.lastname: Wang
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D048289:Imidazolidines / Q000138:chemical synthesis* / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013882:Thiosemicarbazones / Q000737:chemistry*
chemical_list: D001391:Azo Compounds; D048289:Imidazolidines; D007097:Imines; D013882:Thiosemicarbazones; C512188:azomethine; D003300:Copper