title: Free impinging jet microreactors: controlling reactive flows via surface tension and fluid viscoelasticity.
abstract: We investigate the use of impinging free liquid jets as wall-free continuous microreactors. The collision of two reactant jets forming a free-standing thin liquid sheet allows us to perform rapid precipitation reactions to form colloidal particles, enhance micromixing, and master challenging reactions with very fast kinetics. To control the shape, size, and hydrodynamics of the impingement zone between the two liquid streams, it is crucial to understand the interplay among surface tension, fluid viscoelasticity, and reaction kinetics. Here, we study these aspects using model fluids, each illustrating a different physical effect of surface and bulk fluid properties. First, solutions of sodium dodecyl sulfate below, near, and above the critical micelle concentration are used to assess the role of static and dynamic surface tension. Second, we demonstrate how dilute solutions of high-molecular-weight polymers can be used to control the morphology of the free surface flow. If properly controlled, these effects can enhance the micromixing time scales to the extent that very rapid reactions can be performed with outstanding selectivity. We quantitatively assess the interplay between the free surface flow and reaction kinetics using parallel-competitive reactions and demonstrate how these results can be used to control the particle size in precipitation processes.
authors.affiliation: Materials Science Department, Research Division, Firmenich SA, Meyrin 2 Geneva, Switzerland. philipp.erni@firmenich.com
authors.forename: Philipp
authors.initials: P
authors.lastname: Erni
authors.forename: Amal
authors.initials: A
authors.lastname: Elabbadi