title: A novel hexairon cluster with one disulfide and two Ph2PCS(3-) ligands.
abstract: The title compound, hexadecacarbonylbis{μ3-[(diphenylphosphanyl)methanediidyl]sulfanido}-μ4-disulfido(2-)-hexairon(4 Fe-Fe), [Fe6(C13H10PS)2(S2)(CO)16], contains two inversion-related [Fe3(Ph2PCS)(CO)8] subclusters linked by an equatorial disulfide bond [S-S = 2.1490 (9) Å]. Each Ph2PCS(3-) ligand is coordinated to a triiron core in a μ3-κP:κ(2)C:κ(2)S fashion.
authors.affiliation: College of Chemistry and Chemical Engineering, Yangzhou University, 180 SiWangTing Road, Yangzhou 225002, People's Republic of China.
authors.forename: Yao-Cheng
authors.initials: YC
authors.lastname: Shi
authors.forename: Huan-Ren
authors.initials: HR
authors.lastname: Cheng
authors.forename: Da-Cong
authors.initials: DC
authors.lastname: Cheng
mesh_terms: D001713:Biphenyl Compounds / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004220:Disulfides / Q000737:chemistry; D007501:Iron / Q000737:chemistry; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure
chemical_list: D001713:Biphenyl Compounds; D056831:Coordination Complexes; D004220:Disulfides; D008024:Ligands; D007501:Iron