title: [Fractions and adsorption characteristics of phosphorus on sediments and soils in water level fluctuating zone of the Pengxi River, a tributary of the Three Gorges Reservoir].
abstract: The sediment, one of the key factors leading to the eutrophication of water bodies, is an important ecological component of natural water body. In order to investigate the morphological characteristics and moving-transiting rule of phosphorus in the sediments of the Pengxi River, a tributary of the Three Gorges Reservoir, the distributions of different phosphorus forms on the three cross-section in the sediments and three soil types of riparian zone were investigated using the sequential extraction method. The characteristics of phosphorus adsorption on the sediments were also investigated by batch experiments. The equilibrium phosphorus concentrations at zero adsorption (EPC0) on those sediments were estimated using the Henry linear models. The results show that the total phosphorus (TP) contents of these sediments and soils of riparian zone were 0.80-1.45 g x kg(-1) and 0.65-1.16 g x kg(-1), respectively. Phosphorus in sediments and soils were divided into inorganic phosphorus (IP) and organic phosphorus (Or-P), and the inorganic phosphorus was the dominant component of TP. Of the inorganic phosphorus fractions, the percentages of phosphorus bounded to calcium (Ca-P) and occluded phosphorus (O-P) from sediments were higher than 80%, implying that the contents of phosphorus were mainly influenced by their bedrocks and the sedimentary environmental conditions, not by the activities of human beings. The fractions of Ca-P and O-P were the dominant components of inorganic phosphorus in alluvial soil and purple soil, while the fraction of O-P was the highest in the paddy soil. The EPC0 values of the sediments from the sections of Huangshi, Shuangjiang and Gaoyang were 0.08, 0.13 and 0.11 mg x L(-1) respectively, but the EPC0 values of the alluvial soil, purple soil and paddy soil located in riparian zone were 0.08, 0.09 and 0.04 mg x L(-1), respectively. Correlation analysis shows that the values of EPC0 positively related to the contents of total phosphorus and clay content, and significantly related to the content of Ca-P and pH values. According to the phosphorus concentration in the water of Pengxi River, it concludes that sediments and soils in the zone of fluctuating water level of the Pengxi river can be the sink of phosphorus in summer and autumn, while can be the source of phosphorus in the spring and winter. Therefore, the inherent phosphorus present in sediments and soils would be a major threat to the water quality and ecosystem reservation in the watershed of the Pengxi River.
authors.affiliation: Key Laboratory of Eco-Environments in Three Gorges Reservoir Region, Ministry of Education, College of Resources and Environment, Southwest University, Chongqing 400715, China. qqlswb@126.com
authors.forename: Wen-Bin
authors.initials: WB
authors.lastname: Sun
authors.forename: Bin
authors.initials: B
authors.lastname: Du
authors.forename: Xiu-Lan
authors.initials: XL
authors.lastname: Zhao
authors.forename: Bing-Hui
authors.initials: BH
authors.lastname: He
mesh_terms: D000327:Adsorption; D001673:Biodegradation, Environmental; D002681:China; D017753:Ecosystem; D004784:Environmental Monitoring; D005068:Eutrophication; D019015:Geologic Sediments / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry / Q000302:isolation & purification*; D045483:Rivers; D012987:Soil / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D014881:Water Supply
chemical_list: D012987:Soil; D014874:Water Pollutants, Chemical; D010758:Phosphorus