title: A tetragonal prismatic {Co32} nanocage based on thiacalixarene.
abstract: A novel coordination nanocage was obtained with in situ-generated tetrazole ligands from the cobalt-thiacalix[4]arene system. Four in situ-generated 1,3-bis(2H-tetrazol-5-yl)benzene ligands bolster eight Co4-calix shuttle-cock-like secondary building units (SBUs) into a hollow tetragonal prism with a high surface area. The unprecedented {Co32} nanocage presents the highest nuclearity example.
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
authors.forename: Yanfeng
authors.initials: Y
authors.lastname: Bi
authors.forename: Shentang
authors.initials: S
authors.lastname: Wang
authors.forename: Mei
authors.initials: M
authors.lastname: Liu
authors.forename: Shangchao
authors.initials: S
authors.lastname: Du
authors.forename: Wuping
authors.initials: W
authors.lastname: Liao