title: Synthesis of stachybotrin C and all of its stereoisomers: structure revision.
abstract: We disclose the first total synthesis of stachybotrin C, a potent neuroprotective natural compound. All of the four stereoisomers have been prepared and fully characterized with the aim to attribute the absolute configuration of the two adjacent stereocenters of the stachybotrin C.
authors.affiliation: Université de Rennes 1, UMR 6226, Institut des Sciences Chimiques de Rennes, Equipe PNSCM, UFR des Sciences Biologiques et Pharmaceutiques, 2 avenue du Prof Léon Bernard, F-35043 Rennes Cedex, France.
authors.forename: Maiwenn
authors.initials: M
authors.lastname: Jacolot
authors.forename: Mickael
authors.initials: M
authors.lastname: Jean
authors.forename: Naresh
authors.initials: N
authors.lastname: Tumma
authors.forename: Arnaud
authors.initials: A
authors.lastname: Bondon
authors.forename: Srivari
authors.initials: S
authors.lastname: Chandrasekhar
authors.forename: Pierre
authors.initials: P
authors.lastname: van de Weghe
mesh_terms: D001578:Benzopyrans / Q000138:chemical synthesis* / Q000737:chemistry; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D001578:Benzopyrans; D007211:Indoles; C108546:stachybotrin C