title: Dimensional crossover of hard parallel cylinders confined on cylindrical surfaces.
abstract: We derive, from the dimensional-crossover criterion, a fundamental-measure density functional for parallel hard curved rectangles moving on a cylindrical surface. We derive it from the density functional of circular arcs of length σ with centers of mass located on an external circumference of radius R(0). The latter functional in turn is obtained from the corresponding two-dimensional functional for a fluid of hard disks of radius R on a flat surface with centers of mass confined onto a circumference of radius R(0). Thus the curved length of closest approach between the two centers of mass of hard disks on this circumference is σ=2R(0)sin(-1)(R/R(0)), the length of the circular arcs. From the density functional of circular arcs, and by applying a dimensional expansion procedure to the spatial dimension orthogonal to the plane of the circumference, we finally obtain the density functional of curved rectangles of edge lengths σ and L. Along with the derivation, we show that, when the centers of mass of the disks are confined to the exterior circumference of a circle of radius R(0),(i) for R(0)>R, the exact Percus one-dimensional (1D) density functional of circular arcs of length 2R(0)sin(-1)(R/R(0)) is obtained, and (ii) for R(0)<R, the zero-dimensional limit (a cavity that can hold one particle at most) is recovered. We also show that, for R(0)>R, the obtained functional is equivalent to that of parallel hard rectangles on a flat surface of the same lengths, except that now the density profile of curved rectangles is a periodic function of the azimuthal angle, ρ(φ,z)=ρ(φ+2π,z). The phase behavior of a fluid of aligned curved rectangles is obtained by calculating the free-energy branches of smectic, columnar, and crystalline phases for different values of the ratio R(0)/R in the range 1<R(0)/R≤4; the smectic phase turns out to be the most stable except for R(0)/R=4, where the crystalline phase becomes reentrant in a small range of packing fractions. When R(0)/R<1 the transition is absent, since the density functional of curved rectangles reduces to the 1D Percus functional.
authors.affiliation: Grupo Interdisciplinar de Sistemas Complejos (GISC), Departamento de Matemáticas, Escuela Politécnica Superior, Universidad Carlos III de Madrid, Avenida de la Universidad 30, E-28911, Leganés, Madrid, Spain. yuri@math.uc3m.es
authors.forename: Yuri
authors.initials: Y
authors.lastname: Martínez-Ratón
authors.forename: Enrique
authors.initials: E
authors.lastname: Velasco
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003198:Computer Simulation; D008956:Models, Chemical; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012212:Rheology / Q000379:methods*
chemical_list: D003102:Colloids