title: Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of Ir(III) centres.
abstract: And, to round off … A series of Ir(III) 5-membered metallacycles with an Ir-CH2 bond, react with aq. NH2OH with formation of hydride 6-membered iridacyclic complexes, which contain an Ir-NH=CH- imine functionality (see scheme).
authors.affiliation: Instituto de Investigaciones Químicas (IIQ) and Departamento de Química Inorgánica. Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Av. Américo Vespucio, 49, Isla de la Cartuja, 41092 Sevilla, Spain.
authors.forename: Crispín
authors.initials: C
authors.lastname: Cristóbal
authors.forename: Joaquín
authors.initials: J
authors.lastname: López-Serrano
authors.forename: Ana M
authors.initials: AM
authors.lastname: Lozano-Vila
authors.forename: Margarita
authors.initials: M
authors.lastname: Paneque
authors.forename: Manuel L
authors.initials: ML
authors.lastname: Poveda
authors.forename: Florencia
authors.initials: F
authors.lastname: Vattier
authors.forename: Ángela
authors.initials: Á
authors.lastname: Vivancos
authors.forename: Eleuterio
authors.initials: E
authors.lastname: Álvarez
keywords: NH insertion; hydroxylamines; iridacycles; tautomerization; β elimination