title: Switching the regioselectivity via indium(III) and gold(I) catalysis: a post-Ugi intramolecular hydroarylation to azepino- and azocino-[c,d]indolones.
abstract: A post-Ugi indium(III)- and gold(I)-mediated regioselective intramolecular hydroarylation for the synthesis of azepino- and azocino-[c,d]indolones is described.
authors.affiliation: Laboratory for Organic & Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven (KU Leuven), Celestijnenlaan 200F, B-3001, Leuven, Belgium.
authors.forename: Amit
authors.initials: A
authors.lastname: Kumar
authors.forename: Zhenghua
authors.initials: Z
authors.lastname: Li
authors.forename: Sunil K
authors.initials: SK
authors.lastname: Sharma
authors.forename: Virinder S
authors.initials: VS
authors.lastname: Parmar
authors.forename: Erik V
authors.initials: EV
authors.lastname: Van der Eycken
mesh_terms: D001381:Azepines / Q000138:chemical synthesis*; D001392:Azocines / Q000138:chemical synthesis*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D007204:Indium / Q000737:chemistry*; D007211:Indoles / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D001381:Azepines; D001392:Azocines; D007211:Indoles; C540210:azepino(4,5-b)indolone; C557359:azocino(4,3-b)indole; D007204:Indium; D006046:Gold