title: Palladium nanoparticles with high energy facets as a key factor in dissociating O2 in the solvent-free selective oxidation of alcohols.
abstract: Palladium (Pd) nanocatalysts with high energy facets {110} supported on flower-like hydroxyapatite (F-HAP) were successfully prepared. Based on the experimental data and theoretical calculations, it was found that the O2 dissociation on Pd {110} facets could be key to the performance of Pd nanoparticles in the solvent-free selective oxidation of alcohols.
authors.affiliation: School of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, 46# East of Construction Road, Xinxiang 453007, PR China.
authors.forename: Feifei
authors.initials: F
authors.lastname: Wang
authors.forename: Zhansheng
authors.initials: Z
authors.lastname: Lu
authors.forename: Lin
authors.initials: L
authors.lastname: Yang
authors.forename: Yanxing
authors.initials: Y
authors.lastname: Zhang
authors.forename: Qinghu
authors.initials: Q
authors.lastname: Tang
authors.forename: Yuming
authors.initials: Y
authors.lastname: Guo
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Ma
authors.forename: Zongxian
authors.initials: Z
authors.lastname: Yang
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D017886:Durapatite / Q000138:chemical synthesis* / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D000438:Alcohols; D010165:Palladium; D017886:Durapatite; D010100:Oxygen