title: Towards high conductivity in anion-exchange membranes for alkaline fuel cells.
abstract: Quaternized poly(2,6-dimethylphenylene oxide) materials (PPOs) containing clicked 1,2,3-triazoles were first prepared through Cu(I) -catalyzed "click chemistry" to improve the anion transport in anion-exchange membranes (AEMs). Clicked 1,2,3-triazoles incorporated into AEMs provided more sites to form efficient and continuous hydrogen-bond networks between the water/hydroxide and the triazole for anion transport. Higher water uptake was observed for these triazole membranes. Thus, the membranes showed an impressive enhancement of the hydroxide diffusion coefficient and, therefore, the anion conductivities. The recorded hydroxide conductivity was 27.8-62 mS cm(-1) at 20 °C in water, which was several times higher than that of a typical PPO-based AEM (TMA-20) derived from trimethylamine (5 mS cm(-1) ). Even at reduced relative humidity, the clicked membrane showed superior conductivity to a trimethylamine-based membrane. Moreover, similar alkaline stabilities at 80 °C in 1 M NaOH were observed for the clicked and non-clicked membranes. The performance of a H2 /O2 single cell assembled with a clicked AEM was much improved compared to that of a non-clicked TMA-20 membrane. The peak power density achieved for an alkaline fuel cell with the synthesized membrane 1a(20) was 188.7 mW cm(-2) at 50 °C. These results indicated that clicked AEM could be a viable strategy for improving the performance of alkaline fuel cells.
authors.affiliation: Institute of Chemistry, Chair of Macromolecular Chemistry, Division of Technical and Macromolecular Chemistry, Faculty of Natural Sciences II, Chemistry, Physics and Mathematics, Martin-Luther-University Halle-Wittenberg, Halle 06120 Germany. linanwen@gmail.com
authors.forename: Nanwen
authors.initials: N
authors.lastname: Li
authors.forename: Michael D
authors.initials: MD
authors.lastname: Guiver
authors.forename: Wolfgang H
authors.initials: WH
authors.lastname: Binder
mesh_terms: D002384:Catalysis; D057930:Click Chemistry; D003300:Copper / Q000737:chemistry; D004553:Electric Conductivity; D011211:Electric Power Supplies; D019791:Guanidine / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007474:Ion Exchange; D008567:Membranes, Artificial; D010100:Oxygen / Q000737:chemistry; D010647:Phenyl Ethers / Q000138:chemical synthesis / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D008567:Membranes, Artificial; D010647:Phenyl Ethers; D011108:Polymers; D014230:Triazoles; C488462:poly(2,6-dimethyl-1,4-phenylene oxide); D014867:Water; D003300:Copper; D006859:Hydrogen; D019791:Guanidine; D010100:Oxygen
keywords: 1,2,3-triazole; click chemistry; fuel cells; hydrogen bonds; ion exchange