title: Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures.
abstract: The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.
authors.affiliation: Department of Chemistry, Marquette University, 535 N. 14th St., Milwaukee, WI 53233, USA.
authors.forename: Amanda E
authors.initials: AE
authors.lastname: Baum
authors.forename: Sergey V
authors.initials: SV
authors.lastname: Lindeman
authors.forename: Adam T
authors.initials: AT
authors.lastname: Fiedler
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D006873:Hydroquinones / Q000737:chemistry*; D007501:Iron / Q000737:chemistry; D015394:Molecular Structure
chemical_list: D056831:Coordination Complexes; D005296:Ferrous Compounds; D006873:Hydroquinones; D007501:Iron