title: Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand.
abstract: A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.
authors.affiliation: Center for Catalysis, Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA.
authors.forename: Gary L
authors.initials: GL
authors.lastname: Guillet
authors.forename: Forrest T
authors.initials: FT
authors.lastname: Sloane
authors.forename: David M
authors.initials: DM
authors.lastname: Ermert
authors.forename: Matthew W
authors.initials: MW
authors.lastname: Calkins
authors.forename: Marcus K
authors.initials: MK
authors.lastname: Peprah
authors.forename: Elisabeth S
authors.initials: ES
authors.lastname: Knowles
authors.forename: Erik
authors.initials: E
authors.lastname: Čižmár
authors.forename: Khalil A
authors.initials: KA
authors.lastname: Abboud
authors.forename: Mark W
authors.initials: MW
authors.lastname: Meisel
authors.forename: Leslie J
authors.initials: LJ
authors.lastname: Murray
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013696:Temperature
chemical_list: D001555:Benzene Derivatives; D005296:Ferrous Compounds; D007097:Imines; D008024:Ligands; D009942:Organometallic Compounds; D008345:Manganese