title: Stereoselective synthesis of dienyl-carboxylate building blocks: formal synthesis of inthomycin C.
abstract: A direct synthesis of stereodefined halodienes is reported. Those key building blocks enable a concise access to polyenic products, as demonstrated in a modular synthesis of Inthomycin C.
authors.affiliation: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany.
authors.forename: Caroline
authors.initials: C
authors.lastname: Souris
authors.forename: Frédéric
authors.initials: F
authors.lastname: Frébault
authors.forename: Ashay
authors.initials: A
authors.lastname: Patel
authors.forename: Davide
authors.initials: D
authors.lastname: Audisio
authors.forename: K N
authors.initials: KN
authors.lastname: Houk
authors.forename: Nuno
authors.initials: N
authors.lastname: Maulide
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002264:Carboxylic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D006846:Hydrocarbons, Halogenated / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010080:Oxazoles / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D002264:Carboxylic Acids; D006846:Hydrocarbons, Halogenated; D010080:Oxazoles; C554877:inthomycin C