title: Aminoalcohol functionalized zirconium phosphate as versatile filler for starch-based composite membranes.
abstract: Microcrystalline zirconium phosphate was exfoliated by treatment with aqueous solutions of α,ω-alkylaminoalcohols and employed for the fabrication of potato starch composite membranes. Glycerol-based and glycerol-free composite membranes, containing 5 wt% of filler, were prepared from gelatinized starch and characterized for their physico-chemical properties. Despite of a partial filler reaggregation, as revealed by XRD and SEM analysis, all the composites exhibited a significant increase in the Young's modulus with respect to the glycerol-starch membrane, up to 80% and 190% for the glycerol-based and the glycerol-free composites, respectively. For both kinds of membranes the filler delays to a large extent the starch decomposition above about 300°C. A significant reduction in the water uptake of the composites was also observed with respect to the neat glycerol-based membrane, up to about 70% for the glycerol-free composites.
authors.affiliation: Perugia University, Department of Chemistry, Via Elce di Sotto 8, 06123 Perugia, Italy. monica.pica@unipg.it
authors.forename: Monica
authors.initials: M
authors.lastname: Pica
authors.forename: Anna
authors.initials: A
authors.lastname: Donnadio
authors.forename: Valentina
authors.initials: V
authors.lastname: Bianchi
authors.forename: Sacha
authors.initials: S
authors.lastname: Fop
authors.forename: Mario
authors.initials: M
authors.lastname: Casciola