title: Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enones.
authors.affiliation: Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.
authors.forename: Jennifer A
authors.initials: JA
authors.lastname: Dabrowski
authors.forename: Matthew T
authors.initials: MT
authors.lastname: Villaume
authors.forename: Amir H
authors.initials: AH
authors.lastname: Hoveyda
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C030011:carbene; D002244:Carbon; D003300:Copper; D000535:Aluminum; D008697:Methane
keywords: N-heterocyclic carbenes; copper; enantioselective conjugate additions; organoaluminums; quaternary carbons