title: Providing power for miniaturized medical implants: triplet sensitization of semiconductor surfaces.
abstract: Here, we recognize the growing significance of miniaturized devices as medical diagnostic tools and highlight the need to provide a convenient means of powering such instruments when implanted into the body. One of the most promising approaches to this end involves using a light-collection facility to absorb incident white light and transfer the photonic energy to a tiny semiconductor embedded on the device. Although fluorescent organic molecules offer strong potential as modules for such solar collectors, we emphasize the promise offered by transition metal complexes. Thus, an extended series of binuclear Ru(II)/Os(II) poly(pyridine) complexes has been shown to be highly promising sensitizers for amorphous silicon solar cells. These materials absorb a high fraction of visible light while the Ru(II)-based units possess triplet energies that are comparable to those of the naphthalene-based bridge. The metal complex injects a triplet exciton into the bridge and this, in turn, is trapped by the Os(II)-based terminal. The result is extremely efficacious triplet-energy transfer; at room temperature the rate of energy transfer is independent of distance over some 6 nm and only weakly dependent on temperature.
authors.affiliation: Molecular Photonics Laboratory, School of Chemistry, Newcastle University, Bedson Building, Newcastle upon Tyne NE1 7RU, UK.
authors.forename: Andrew C
authors.initials: AC
authors.lastname: Benniston
authors.forename: Anthony
authors.initials: A
authors.lastname: Harriman
authors.forename: Songjie
authors.initials: S
authors.lastname: Yang
mesh_terms: D001674:Bioelectric Energy Sources; D011211:Electric Power Supplies; D019544:Equipment Failure Analysis; D008027:Light; D008904:Miniaturization; D019736:Prostheses and Implants; D011474:Prosthesis Design; D012666:Semiconductors
keywords: energy transfer; metal poly(pyridine) complexes; nanoparticles; photophysics; triplet state