title: Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.
authors.affiliation: Department of Chemistry, Stanford University, Stanford, CA 94305-5580, USA. bmtrost@stanford.edu
authors.forename: Barry M
authors.initials: BM
authors.lastname: Trost
authors.forename: Maksim
authors.initials: M
authors.lastname: Osipov
mesh_terms: D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D014363:Tryptamines / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D000470:Alkaloids; D009942:Organometallic Compounds; D014363:Tryptamines; C030820:tryptamine; D010165:Palladium; D002244:Carbon
keywords: alkaloids; allylic alkylation; asymmetric catalysis; palladium; quaternary stereocenters