title: Efficient photocatalytic decolorization of some textile dyes using Fe ions doped polyaniline film on ITO coated glass substrate.
abstract: In this study, the photocatalytic decolorization of four commercial textile dyes with different structures has been investigated using electrochemically synthesized polyaniline and Fe ions doped polyaniline on ITO coated glass substrate as photocatalyst in aqueous solution under UV irradiation for the first time. Scanning electron microscopy, atomic force microscopy, FT-IR spectra, UV-vis spectroscopy measurements were used to characterize the electrochemically synthesized polymer film photocatalyst. Film hydrophilicity was assessed from contact angle measurements. The results show that both of the polymer films exhibit good photocatalytic performance. Surprisingly, it was determined that by using Fe(II) ions during polymerization, it is possible to modify the surface roughness and wettability of the produced polyaniline films which favors their photocatalytic activity in water-based solutions. All four of the used dyes (methylene blue, malachite green, methyl orange and methyl red) were completely decolorizated in 90 min of irradiation under UV light by using Fe ions doped polyaniline at the dye concentration of 1.5 × 10(-5)M, while the decolorization of those dyes were between 43% and 83% by using polyaniline as photocatalyst. Hence, it may be a viable technique for the safe disposal of textile wastewater into waste streams.
authors.affiliation: Department of Chemical Engineering, Selçuk University, Konya 42079, Turkey.
authors.forename: Bircan
authors.initials: B
authors.lastname: Haspulat
authors.forename: Ahmet
authors.initials: A
authors.lastname: Gülce
authors.forename: Handan
authors.initials: H
authors.lastname: Gülce
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry*; D004563:Electrochemistry; D005898:Glass; D007220:Industrial Waste; D007477:Ions; D007501:Iron / Q000737:chemistry*; D008751:Methylene Blue / Q000737:chemistry; D010777:Photochemistry; D011108:Polymers / Q000737:chemistry; D012394:Rosaniline Dyes / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013783:Textile Industry; D014865:Waste Disposal, Fluid / Q000379:methods; D014867:Water / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
chemical_list: D000814:Aniline Compounds; D001391:Azo Compounds; D004396:Coloring Agents; D007220:Industrial Waste; D007477:Ions; D011108:Polymers; D012394:Rosaniline Dyes; D014874:Water Pollutants, Chemical; C416807:polyaniline; D014867:Water; C005095:malachite green; C008492:methyl red; C100258:methyl orange; D007501:Iron; D008751:Methylene Blue
keywords: Malachite green; Methyl orange; Methyl red; Methylene blue; Photocatalysis; Polyaniline