title: Diisopinocampheylborane-mediated reductive aldol reactions: highly enantio- and diastereoselective synthesis of syn aldols from N-acryloylmorpholine.
authors.affiliation: Department of Chemistry, The Scripps Research Institute, 130 Scripps Way, 3A2, Jupiter, FL 33458, USA.
authors.forename: Philippe
authors.initials: P
authors.lastname: Nuhant
authors.forename: Christophe
authors.initials: C
authors.lastname: Allais
authors.forename: William R
authors.initials: WR
authors.lastname: Roush
mesh_terms: D000180:Acrylic Resins / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000180:Acrylic Resins; D000447:Aldehydes; D000577:Amides; D001896:Boron Compounds; C015460:poly(acryloylmorpholine); C034666:propionamide
keywords: aldol reaction; boranes; diastereoselectivity; enantioselectivity; morpholine amides