title: Desymmetrization of meso-2,5-diallylpyrrolidinyl ureas through asymmetric palladium-catalyzed carboamination: stereocontrolled synthesis of bicyclic ureas.
authors.affiliation: Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109-1055, USA.
authors.forename: Nicholas R
authors.initials: NR
authors.lastname: Babij
authors.forename: John P
authors.initials: JP
authors.lastname: Wolfe
mesh_terms: D000586:Amination; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011759:Pyrrolidines / Q000138:chemical synthesis* / Q000737:chemistry; D014508:Urea / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D009942:Organometallic Compounds; D011759:Pyrrolidines; D010165:Palladium; D014508:Urea
keywords: alkaloids; asymmetric catalysis; desymmetrization; heterocycles; palladium