title: Interaction of aromatic amines with iron oxides: implications for prebiotic chemistry.
abstract: The interaction of aromatic amines (aniline, p-chloroaniline, p-toludine and p-anisidine) with iron oxides (goethite, akaganeite and hematite) has been studied. Maximum uptake of amines was observed around pH 7. The adsorption data obtained at neutral pH were found to follow Langmuir adsorption. Anisidine was found to be a better adsorbate probably due to its higher basicity. In alkaline medium (pH > 8), amines reacted on goethite and akaganeite to give colored products. Analysis of the products by GC-MS showed benzoquinone and azobenzene as the reaction products of aniline while p-anisidine afforded a dimer. IR analysis of the amine-iron oxide hydroxide adduct suggests that the surface acidity of iron oxide hydroxides is responsible for the interaction. The present study suggests that iron oxide hydroxides might have played a role in the stabilization of organic molecules through their surface activity and in prebiotic condensation reactions.
authors.affiliation: Department of Chemistry, Dr B R Ambedkar National Institute of Technology Jalandhar, Jalandhar, 144011, Punjab, India. umaorganic29@gmail.com
authors.forename: Uma
authors.initials: U
authors.lastname: Shanker
authors.forename: Gurinder
authors.initials: G
authors.lastname: Singh
authors.lastname: Kamaluddin
mesh_terms: D000588:Amines / Q000737:chemistry*; D019418:Evolution, Chemical; D005290:Ferric Compounds / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry; D008903:Minerals / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*
chemical_list: D000588:Amines; D005290:Ferric Compounds; D058085:Iron Compounds; D008903:Minerals; D010087:Oxides; C473845:akaganeite; C094886:goethite; C000499:ferric oxide