title: Resolution and characterization of helicate dimer and trimer complexes of 1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane with copper(I).
abstract: Complexation of copper(I) with the binucleating ligand, 1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane, mphenpr, result in formation of helical dimers, [Cu2(mphenpr)2](2+). The resolution of the enantiomeric forms of the dimers has been carried out with Δ-[As(cat)3](-) as resolving agent and X-ray structures for two compounds, P-[Cu2(mphenpr)2](Δ-[As(cat)3])2 and P-[Cu2(mphenpr)2](Δ-[As(cat)3])2·4(CH3CN), are reported. The rate of racemization in poorly-coordinating solvents has been examined by (1)H NMR, and is slow. At saturating concentrations of [[Cu2(mphenpr)2](2+)] in acetonitrile, crystals of the helical trimeric complex [Cu3(mphenpr)3](ClO4)3 are obtained. The X-ray structure of the trimer is reported. This species has also been resolved. As with the helical dimer, racemization in poorly-coordinating solvents is slow, and circular dichroism and (1)H NMR spectra are reported. The absolute configuration of the resolved complex, P-[Cu3(mphenpr)3](Δ-[As(cat)3])3, has been determined by X-ray crystallography.
authors.affiliation: Facultad de Química y Biología, Universidad de Santiago de Chile, Santiago, Chile. luis.lemus@usach.cl
authors.forename: Luis
authors.initials: L
authors.lastname: Lemus
authors.forename: Juan
authors.initials: J
authors.lastname: Guerrero
authors.forename: Juan
authors.initials: J
authors.lastname: Costamagna
authors.forename: Romina
authors.initials: R
authors.lastname: Lorca
authors.forename: Danilo H
authors.initials: DH
authors.lastname: Jara
authors.forename: Guillermo
authors.initials: G
authors.lastname: Ferraudi
authors.forename: Allen
authors.initials: A
authors.lastname: Oliver
authors.forename: A Graham
authors.initials: AG
authors.lastname: Lappin