title: Aqua-carbon-yl(ferrocenyldi-thio-phos-phon-ato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II) dichloromethane mono-solvate.
abstract: The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η(5)-C5H4)(η(5)-C5H5)] and one CH2Cl2 solvent mol-ecule. The geometry around the Ru(II) atom is pseudo-octa-hedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2](2-) ligand via two S atoms. The average Ru-S and Ru-P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru-O and Ru-C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O-H⋯O hydrogen bonds link adjacent mol-ecules into dimers.
authors.affiliation: Department of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China.
authors.forename: Hang
authors.initials: H
authors.lastname: Zhu
authors.forename: Qing
authors.initials: Q
authors.lastname: Ma
authors.forename: Hua-Tian
authors.initials: HT
authors.lastname: Shi
authors.forename: Qun
authors.initials: Q
authors.lastname: Chen
authors.forename: Qian-Feng
authors.initials: QF
authors.lastname: Zhang