title: Polyvinylferrocene for noncovalent dispersion and redox-controlled precipitation of carbon nanotubes in nonaqueous media.
abstract: We report noncovalent dispersion of carbon nanotubes (CNTs) in organic liquids with extremely high loading (∼2 mg mL(-1)) using polyvinylferrocene (PVF). In contrast to common dispersants, PVF does not contain any conjugated structures or ionic moieties. PVF is also shown to be effective in controlling nanotube dispersion and reprecipitation because it exhibits redox-switchable affinity for solvents, while maintaining stable physical attachment to CNTs during redox transformation. This switchability provides a novel approach to creating CNT-functionalized surfaces. The material systems described here offer new opportunities for applications of CNTs in nonaqueous media, such as nanotube-polymer composites and organic liquid-based optical limiters, and expand the means of tailoring nanotube dispersion behavior via external stimuli, with potential applications in switching devices. The PVF/CNT hybrid system with enhanced redox response of ferrocene may also find applications in high-performance biosensors and pseudocapacitors.
authors.affiliation: Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.
authors.forename: Xianwen
authors.initials: X
authors.lastname: Mao
authors.forename: Gregory C
authors.initials: GC
authors.lastname: Rutledge
authors.forename: T Alan
authors.initials: TA
authors.lastname: Hatton
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D010084:Oxidation-Reduction; D010316:Particle Size; D011145:Polyvinyls / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties
chemical_list: D005296:Ferrous Compounds; D037742:Nanotubes, Carbon; D009930:Organic Chemicals; D011145:Polyvinyls; D012997:Solvents; C451099:polyvinylferrocenium