title: Chemical adsorption enhanced CO2 capture and photoreduction over a copper porphyrin based metal organic framework.
abstract: Effective CO2 capture and activation is a prerequisite step for highly efficient CO2 reduction. In this study, we reported a case of Cu(2+) in a porphyrin based MOF promoted enhanced photocatalytic CO2 conversion to methanol. Compared with the sample without Cu(2+), the methanol evolution rate was improved as high as 7 times. In situ FT-IR results suggested that CO2 chemical adsorption and activation over Cu(2+) played an important role in improving the conversion efficiency.
authors.affiliation: State Key Lab of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China.
authors.forename: Yuanyuan
authors.initials: Y
authors.lastname: Liu
authors.forename: Yanmei
authors.initials: Y
authors.lastname: Yang
authors.forename: Qilong
authors.initials: Q
authors.lastname: Sun
authors.forename: Zeyan
authors.initials: Z
authors.lastname: Wang
authors.forename: Baibiao
authors.initials: B
authors.lastname: Huang
authors.forename: Ying
authors.initials: Y
authors.lastname: Dai
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: Qin
authors.forename: Xiaoyang
authors.initials: X
authors.lastname: Zhang