title: NF-TiO₂ photocatalysis of amitrole and atrazine with addition of oxidants under simulated solar light: emerging synergies, degradation intermediates, and reusable attributes.
abstract: In order to investigate sustainable alternatives to current water treatment methods, the effect of NF-titania film thickness and subsequent photocatalysis in combination with oxidants was examined under simulated solar light. Such a combination presents a theoretical possibility for a synergistic interaction between the photocatalyst and the oxidant (activation of the oxidant by the catalyst under conditions under which it may not conventionally be activated). To investigate, peroxymonosulfate (PMS) and persulfate (PS) were used as oxidants, and two pesticides, amitrole and atrazine, were used as target contaminants. In the absence of a film, activation of PMS under simulated solar conditions is demonstrated by removal of atrazine, whereas PS provided minimal removal, suggesting inefficient activation. Combining photocatalytic films with PMS and PS manifested synergies for both oxidants. The effect was most pronounced for PS since PMS already underwent significant activation without the photocatalyst. Amitrole degradation results indicated a lack of removal of amitrole by activated PS alone, suggesting that this sulfate radical-based treatment technology may be ineffective for the removal of amitrole. The NF-TiO₂ films demonstrated reusability under solar light both with and without oxidants. Finally, the degradation intermediates were analyzed, and a new intermediate appeared upon incorporating oxidants into the system.
authors.affiliation: Environmental Engineering and Science Program, University of Cincinnati, Cincinnati, OH 45221-0071, USA.
authors.forename: Joel
authors.initials: J
authors.lastname: Andersen
authors.forename: Miguel
authors.initials: M
authors.lastname: Pelaez
authors.forename: Lisa
authors.initials: L
authors.lastname: Guay
authors.forename: Zhaohong
authors.initials: Z
authors.lastname: Zhang
authors.forename: Kevin
authors.initials: K
authors.lastname: O'Shea
authors.forename: Dionysios D
authors.initials: DD
authors.lastname: Dionysiou
mesh_terms: D000640:Amitrole / Q000737:chemistry*; D001280:Atrazine / Q000737:chemistry*; D002384:Catalysis; D002851:Chromatography, High Pressure Liquid; D002853:Chromatography, Liquid; D008027:Light; D013058:Mass Spectrometry; D008422:Materials Testing; D016877:Oxidants / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D010545:Peroxides / Q000737:chemistry; D010777:Photochemistry; D013431:Sulfates / Q000737:chemistry; D013472:Sunlight; D013696:Temperature; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
chemical_list: D016877:Oxidants; D010545:Peroxides; D013431:Sulfates; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; C038288:peroxymonosulfate; D014025:Titanium; D001280:Atrazine; D010100:Oxygen; D000640:Amitrole
keywords: Amitrole; Atrazine; NF-TiO(2); Peroxymonosulfate; Persulfate