title: Detection of isomeric microscopic host-guest complexes. A time-evolving cucurbit[7]uril complex.
abstract: The formation of inclusion complexes between the cucurbit[7]uril host and a cationic guest containing ferrocenylmethyl and adamantyl residues connected to an ammonium nitrogen initially leads to an ~1:1 mixture of two isomeric microscopic complexes, which evolves as a function of time toward the thermodynamically stable mixture, dominated by the adamantyl-included complex.
authors.affiliation: Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, Florida 33124-0431, USA.
authors.forename: Mohammad Hossein
authors.initials: MH
authors.lastname: Tootoonchi
authors.forename: Song
authors.initials: S
authors.lastname: Yi
authors.forename: Angel E
authors.initials: AE
authors.lastname: Kaifer