title: {N,N-Bis[bis-(2,2,2-tri-fluoro-eth-oxy)phosphan-yl]methyl-amine-κ(2) P,P'}bis-(η(5)-cyclo-penta-dien-yl)titanium(II).
abstract: The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η(2)-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis-[bis-(tri-fluoro-eth-oxy)phosphan-yl]methyl-amine, tfepma}. The Ti(II) atom is coordinated by two cyclo-penta-dienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetra-hedral geometry. The mol-ecule is located on a mirror plane.
authors.affiliation: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Haehnel
authors.forename: Sven
authors.initials: S
authors.lastname: Hansen
authors.forename: Anke
authors.initials: A
authors.lastname: Spannenberg
authors.forename: Torsten
authors.initials: T
authors.lastname: Beweries