title: Silver-mediated trifluoromethylation of aryldiazonium salts: conversion of amino group into trifluoromethyl group.
abstract: A novel strategy for aromatic trifluoromethylation by converting aromatic amino group into CF3 group is reported herein. This method, which can be considered as trifluoromethylation variation of the classic Sandmeyer reaction, uses readily available aromatic amines as starting materials and is performed under mild conditions.
authors.affiliation: Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China.
authors.forename: Xi
authors.initials: X
authors.lastname: Wang
authors.forename: Yan
authors.initials: Y
authors.lastname: Xu
authors.forename: Fanyang
authors.initials: F
authors.lastname: Mo
authors.forename: Guojing
authors.initials: G
authors.lastname: Ji
authors.forename: Di
authors.initials: D
authors.lastname: Qiu
authors.forename: Jiajie
authors.initials: J
authors.lastname: Feng
authors.forename: Yuxuan
authors.initials: Y
authors.lastname: Ye
authors.forename: Songnan
authors.initials: S
authors.lastname: Zhang
authors.forename: Yan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Jianbo
authors.initials: J
authors.lastname: Wang
mesh_terms: D003979:Diazonium Compounds / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D008745:Methylation; D015394:Molecular Structure; D012492:Salts / Q000737:chemistry; D012834:Silver / Q000737:chemistry*
chemical_list: D003979:Diazonium Compounds; D006845:Hydrocarbons, Fluorinated; D012492:Salts; D012834:Silver