title: Colloid mobilization by fluid displacement fronts in channels.
abstract: Understanding colloid mobilization during transient flow in soil is important for addressing colloid and contaminant transport issues. While theoretical descriptions of colloid detachment exist for saturated systems, corresponding mechanisms of colloid mobilization during drainage and imbibition have not been considered in detail. In this work, theoretical force and torque analyses were performed to examine the interactive effects of adhesion, drag, friction, and surface tension forces on colloid mobilization and to outline conditions corresponding to the mobilization mechanisms such as lifting, sliding, and rolling. Colloid and substrate contact angles were used as variables to determine theoretical criteria for colloid mobilization mechanisms during drainage and imbibition. Experimental mobilization of hydrophilic and hydrophobic microspheres with drainage and imbibition fronts was investigated in hydrophilic and hydrophobic channels using a confocal microscope. Colloid mobilization differed between drainage and imbibition due to different dynamic contact angles and interfacial geometries on the contact line. Experimental results did not fully follow the theoretical criteria in all cases, which was explained with additional factors not included in the theory such as presence of aggregates and trailing films. Theoretical force and torque analyses resulted in similar mobilization predictions and suggested that all mobilization mechanisms contributed to the observed colloid mobilization.
authors.affiliation: Department of Plant and Soil Sciences, University of Delaware, Newark, DE 19716, USA. volha@udel.edu
authors.forename: Volha
authors.initials: V
authors.lastname: Lazouskaya
authors.forename: Lian-Ping
authors.initials: LP
authors.lastname: Wang
authors.forename: Dani
authors.initials: D
authors.lastname: Or
authors.forename: Gang
authors.initials: G
authors.lastname: Wang
authors.forename: Jeffrey L
authors.initials: JL
authors.lastname: Caplan
authors.forename: Yan
authors.initials: Y
authors.lastname: Jin
mesh_terms: D003102:Colloids / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D018613:Microscopy, Confocal; D008863:Microspheres; D008962:Models, Theoretical; D016062:Porosity; D013499:Surface Properties; D013500:Surface Tension
chemical_list: D003102:Colloids
keywords: AWI; Colloid transport; Contact angle; Contact line; DLVO; Derjaguin–Landau–Verwey–Overbeek theory; Drainage; Imbibition; Thin films; air–water interface