title: Two solvatomorphic forms of a copper complex formulated as Cu(L(1))(ClO4)2·1.2H2O and Cu(L(1))(ClO4)2, where L(1) is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane.
abstract: Two copper complex solvatomorphs, namely (3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato-κO)copper(II) 1.2-hydrate, [Cu(ClO4)2(C18H40N4)]·1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato-κO)copper(II), [Cu(ClO4)2(C18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the Cu(II) cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices.
authors.affiliation: University of Chittagong, Chittagong 4331, Bangladesh.
authors.forename: Babul Chandra
authors.initials: BC
authors.lastname: Nath
authors.forename: Sebastián
authors.initials: S
authors.lastname: Suarez
authors.forename: Fabio
authors.initials: F
authors.lastname: Doctorovich
authors.forename: Tapashi G
authors.initials: TG
authors.lastname: Roy
authors.forename: Ricardo
authors.initials: R
authors.lastname: Baggio
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D012997:Solvents / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D012997:Solvents; D003300:Copper