title: Enhanced catalytic activity of titanosilicates controlled by hydrogen-bonding interactions.
abstract: A typical volcano-shaped curve has been found in heterogeneous catalytic systems containing titanosilicates for the first time. A new reactive intermediate with double H-bonds is proposed. Systematic results clearly evidence another H-bond formed between the high-electronegativity atom of the H-bond acceptor and the H(end) atom of Ti-Oα-Oβ-H(end).
authors.affiliation: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, China.
authors.forename: Xiujuan
authors.initials: X
authors.lastname: Deng
authors.forename: Shuo
authors.initials: S
authors.lastname: Zhang
authors.forename: Binshen
authors.initials: B
authors.lastname: Wang
authors.forename: Yuning
authors.initials: Y
authors.lastname: Wang
authors.forename: Haihong
authors.initials: H
authors.lastname: Wu
authors.forename: Yueming
authors.initials: Y
authors.lastname: Liu
authors.forename: Mingyuan
authors.initials: M
authors.lastname: He