title: Colorimetric and ratiometric fluorescent detection of sulfite in water via cationic surfactant-promoted addition of sulfite to α,β-unsaturated ketone.
abstract: Three fluorescent probes were constructed by incorporating an α,β-unsaturated ketone to a coumarin fluorophore. The selective addition of sulfite to the alkene of TSP assisted by cetyltrimethyl ammonium bromide (CTAB) micelle can be visualized by dramatic color and ratiometric fluorescence changes. In CTAB-PBS system, the fluorescence intensity ratio at 465 nm and 592 nm (I465/I592) and the absorbance ratio at 390 nm and 470 nm (A390/A470) were linearly proportional to sulfite concentration in the range of 0.5-150 μM, and the detection limit was 0.2 μM. Good selectivity and competition of TSP1 towards sulfite over several anions and biological thiols were acquired. Probe TSP1 was used to detect sulfite in three realistic samples (mineral water, sugar and white wine) with good recovery.
authors.affiliation: Shanghai Key Laboratory of Functional Materials Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.
authors.forename: Haiyu
authors.initials: H
authors.lastname: Tian
authors.forename: Junhong
authors.initials: J
authors.lastname: Qian
authors.forename: Qian
authors.initials: Q
authors.lastname: Sun
authors.forename: Hongyan
authors.initials: H
authors.lastname: Bai
authors.forename: Weibing
authors.initials: W
authors.lastname: Zhang
mesh_terms: D002412:Cations / Q000737:chemistry; D000077286:Cetrimonium; D002593:Cetrimonium Compounds; D003124:Colorimetry / Q000379:methods*; D004396:Coloring Agents; D003374:Coumarins; D019422:Dietary Sucrose / Q000032:analysis; D005453:Fluorescence; D005456:Fluorescent Dyes / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007659:Ketones / Q000737:chemistry*; D008823:Micelles; D008900:Mineral Waters / Q000032:analysis; D013438:Sulfhydryl Compounds; D013447:Sulfites / Q000032:analysis*; D013501:Surface-Active Agents / Q000737:chemistry*; D014920:Wine / Q000032:analysis
chemical_list: D002412:Cations; D002593:Cetrimonium Compounds; D004396:Coloring Agents; D003374:Coumarins; D019422:Dietary Sucrose; D005456:Fluorescent Dyes; D007659:Ketones; D008823:Micelles; D008900:Mineral Waters; D013438:Sulfhydryl Compounds; D013447:Sulfites; D013501:Surface-Active Agents; C030123:coumarin; D000077286:Cetrimonium
keywords: Fluorescence probe; Sulfite; Surfactant; α,β-unsaturated ketone