title: Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates.
abstract: A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions.
authors.affiliation: Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China.
authors.forename: Saiwen
authors.initials: S
authors.lastname: Liu
authors.forename: Yang
authors.initials: Y
authors.lastname: Bai
authors.forename: Xiangxiang
authors.initials: X
authors.lastname: Cao
authors.forename: Fuhong
authors.initials: F
authors.lastname: Xiao
authors.forename: Guo-Jun
authors.initials: GJ
authors.lastname: Deng
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry*; D013441:Sulfinic Acids / Q000737:chemistry*
chemical_list: D000480:Alkynes; D009942:Organometallic Compounds; D013441:Sulfinic Acids; D010165:Palladium; D012964:Sodium