title: Spectral properties of a simple azine Schiff base and its sensing ability towards protic environment through hydrogen bonding interaction.
abstract: A simple azine linkage containing Schiff base p-N,N-diethylaminobenzaldazine (PDEAB) has been synthesized and its spectroscopic properties have been investigated using steady state absorption and fluorescence measurement. Both the absorption and emission studies indicate that the compound PDEAB forms intermolecular hydrogen bond with protic solvents. The formation of intermolecular hydrogen bond between PDEAB and protic solvents is further verified by Quantum chemical calculation using Density Functional Theory (DFT) (B3LYP/6-31++G(d,p)) and Natural Bond Orbital (NBO) analysis. The non-fluorescent nature (fluorescence off) of PDEAB in aprotic environment can be switched over to a fluorescent system (fluorescence on) in presence of protic solvents and hence this molecule can be used as highly sensitive fluorosensor for protic solvent in aprotic medium like ACN or DOX.
authors.affiliation: Department of Chemistry, University of Calcutta, 92 APC Road, Calcutta 700 009, India.
authors.forename: Debarati
authors.initials: D
authors.lastname: Ray
authors.forename: Sasanka
authors.initials: S
authors.lastname: Dalapati
authors.forename: Nikhil
authors.initials: N
authors.lastname: Guchhait
mesh_terms: D000042:Absorption; D006834:Hydrazines / Q000737:chemistry*; D006860:Hydrogen Bonding; D007700:Kinetics; D008968:Molecular Conformation; D011522:Protons; D012545:Schiff Bases / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013816:Thermodynamics
chemical_list: D006834:Hydrazines; D011522:Protons; D012545:Schiff Bases; D012997:Solvents
keywords: Aazine Schiff base; Fluorescence; Intermolecular hydrogen bonding; Protic solvent; p-N,N-diethylaminobenzaldazine