title: Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acids.
abstract: A palladium-catalyzed method for the preparation of sulfonamides is described. The process exhibits significant functional group tolerance and allows for the preparation of a number of arylsulfonyl chlorides and sulfonamides under mild conditions.
authors.affiliation: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
authors.forename: J Robb
authors.initials: JR
authors.lastname: DeBergh
authors.forename: Nootaree
authors.initials: N
authors.lastname: Niljianskul
authors.forename: Stephen L
authors.initials: SL
authors.lastname: Buchwald
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000138:chemical synthesis; D054879:Halogenation; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis*; D010165:Palladium / Q000737:chemistry*; D013449:Sulfonamides / Q000138:chemical synthesis*
chemical_list: D001897:Boronic Acids; D002712:Chlorides; D006841:Hydrocarbons, Aromatic; D013449:Sulfonamides; D010165:Palladium