title: Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides.
abstract: An orthogonal set of catalyst systems has been developed for the Suzuki-Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.
authors.affiliation: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
authors.forename: Yang
authors.initials: Y
authors.lastname: Yang
authors.forename: Stephen L
authors.initials: SL
authors.lastname: Buchwald
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D006219:Halogens / Q000737:chemistry*; D007536:Isomerism; D008024:Ligands; D010165:Palladium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D001555:Benzene Derivatives; D001897:Boronic Acids; D006219:Halogens; D008024:Ligands; D010165:Palladium