title: Regiodivergent N-C and N-N aryl coupling reactions of indoloterpenes and cycloether formation mediated by a single bacterial flavoenzyme.
authors.affiliation: Dept. of Biomolecular Chemistry, Leibniz Institute for Natural Product Research and Infection Biology, HKI, Beutenbergstr. 11a, 07745 Jena, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Baunach
authors.forename: Ling
authors.initials: L
authors.lastname: Ding
authors.forename: Torsten
authors.initials: T
authors.lastname: Bruhn
authors.forename: Gerhard
authors.initials: G
authors.lastname: Bringmann
authors.forename: Christian
authors.initials: C
authors.lastname: Hertweck
mesh_terms: D000470:Alkaloids; D000588:Amines; D002384:Catalysis; D004988:Ethers, Cyclic / Q000737:chemistry*; D005420:Flavoproteins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D013729:Terpenes / Q000737:chemistry*
chemical_list: D000470:Alkaloids; D000588:Amines; D004988:Ethers, Cyclic; D005420:Flavoproteins; D013729:Terpenes
keywords: alkaloids; aryl coupling; flavoproteins; indolosesquiterpenes; radicals