title: Modification of electrical properties of graphene by substrate-induced nanomodulation.
abstract: A periodically modulated graphene (PMG) generated by nanopatterned surfaces is reported to profoundly modify the intrinsic electronic properties of graphene. The temperature dependence of the sheet resistivity and gate response measurements clearly show a semiconductor-like behavior. Raman spectroscopy reveals significant shifts of the G and the 2D modes induced by the interaction with the underlying grid-like nanostructure. The influence of the periodic, alternating contact with the substrate surface was studied in terms of strain caused by bending of graphene and doping through chemical interactions with underlying substrate atoms. Electronic structure calculations performed on a model of PMG reveals that it is possible to tune a band gap within 0.14-0.19 eV by considering both the periodic mechanical bending and the surface coordination chemistry. Therefore, the PMG can be regarded as a further step toward band gap engineering of graphene devices.
authors.affiliation: School of Electrical Engineering, WCU on Flexible Nanosystems, Korea University, Seoul, Korea.
authors.forename: Jong-Kwon
authors.initials: JK
authors.lastname: Lee
authors.forename: Shiro
authors.initials: S
authors.lastname: Yamazaki
authors.forename: Hoyeol
authors.initials: H
authors.lastname: Yun
authors.forename: Jinwoo
authors.initials: J
authors.lastname: Park
authors.forename: Gary P
authors.initials: GP
authors.lastname: Kennedy
authors.forename: Gyu-Tae
authors.initials: GT
authors.lastname: Kim
authors.forename: Oswald
authors.initials: O
authors.lastname: Pietzsch
authors.forename: Roland
authors.initials: R
authors.lastname: Wiesendanger
authors.forename: SangWook
authors.initials: S
authors.lastname: Lee
authors.forename: Suklyun
authors.initials: S
authors.lastname: Hong
authors.forename: Urszula
authors.initials: U
authors.lastname: Dettlaff-Weglikowska
authors.forename: Siegmar
authors.initials: S
authors.lastname: Roth