title: Iodine recycling via 1,3-migration in iodoindoles under metal catalysis.
abstract: 3-Substituted (indol-2-yl)-α-allenols show divergent patterns of reactivity under metal catalysis. An unprecedented intramolecular 1,3-iodine migration is described.
authors.affiliation: Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain. alcaideb@quim.ucm.es
authors.forename: Benito
authors.initials: B
authors.lastname: Alcaide
authors.forename: Pedro
authors.initials: P
authors.lastname: Almendros
authors.forename: José M
authors.initials: JM
authors.lastname: Alonso
authors.forename: Sara
authors.initials: S
authors.lastname: Cembellín
authors.forename: Israel
authors.initials: I
authors.lastname: Fernández
authors.forename: Teresa Martínez
authors.initials: TM
authors.lastname: del Campo
authors.forename: M Rosario
authors.initials: MR
authors.lastname: Torres
mesh_terms: D002227:Carbazoles / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D002412:Cations / Q000737:chemistry; D018360:Crystallography, X-Ray; D003500:Cyclization; D007455:Iodine / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D008968:Molecular Conformation
chemical_list: D002227:Carbazoles; D002412:Cations; D008670:Metals; D007455:Iodine