title: Synthesis of binuclear phenoxyimino organoaluminum complexes and their use as the catalyst precursors for efficient ring-opening polymerisation of ε-caprolactone.
abstract: A series of novel binuclear phenoxyimino organoaluminum complexes of the type [(RN=CH)C6H3OAlMe2]2 [R = C6H5 (2a), 2,6-(i)Pr2C6H3 (2b), 2,6-Ph2C6H3 (2c), adamantyl (2d), (t)Bu (2e)] have been prepared in high yields, and these complexes were identified by (1)H, (13)C NMR and elemental analysis. Structural analysis for 2a-e revealed that these complexes have a distorted tetrahedral geometry around Al and both the Al-O and the Al-N bond distances were considerably influenced by substituents in the imino groups. The complexes were tested as catalyst precursors for ring-opening polymerisation (ROP) of ε-caprolactone (CL) in the presence of BnOH, and their catalytic activities were strongly affected by the catalyst structures and polymerisation conditions. An efficient living ROP has been achieved using the 2b/BnOH system.
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
authors.forename: Hong-Ling
authors.initials: HL
authors.lastname: Han
authors.forename: Yan
authors.initials: Y
authors.lastname: Liu
authors.forename: Jing-Yu
authors.initials: JY
authors.lastname: Liu
authors.forename: Kotohiro
authors.initials: K
authors.lastname: Nomura
authors.forename: Yue-Sheng
authors.initials: YS
authors.lastname: Li
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D002208:Caproates / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007783:Lactones / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D058105:Polymerization
chemical_list: D002208:Caproates; D056831:Coordination Complexes; D007783:Lactones; D009942:Organometallic Compounds; C121056:caprolactone; D000535:Aluminum