title: Ionic conductivity of [Li+@C60](PF6(-)) in organic solvents and its electrochemical reduction to Li+@C60(·-).
abstract: The ionic conductivity of [Li(+)@C60](PF6(-)) was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of [Li(+)@C60](PF6(-)) without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic ESR signal and NIR absorption band.
authors.affiliation: Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Ueno
authors.forename: Ken
authors.initials: K
authors.lastname: Kokubo
authors.forename: Yuji
authors.initials: Y
authors.lastname: Nakamura
authors.forename: Kei
authors.initials: K
authors.lastname: Ohkubo
authors.forename: Naohiko
authors.initials: N
authors.lastname: Ikuma
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Moriyama
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
authors.forename: Takumi
authors.initials: T
authors.lastname: Oshima
mesh_terms: D002722:Chlorobenzenes / Q000737:chemistry; D055664:Electrochemical Techniques; D004573:Electrolytes / Q000737:chemistry; D004867:Equipment Design; D037741:Fullerenes / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008094:Lithium / Q000737:chemistry*; D008958:Models, Molecular; D010084:Oxidation-Reduction; D017553:Phosphorus Compounds / Q000737:chemistry*
chemical_list: D002722:Chlorobenzenes; D004573:Electrolytes; D037741:Fullerenes; D007477:Ions; D017553:Phosphorus Compounds; C004726:2-dichlorobenzene; D008094:Lithium