title: Catalytic asymmetric exo-selective [6+3] cycloaddition of iminoesters with fulvenes.
abstract: A novel exo-selective [6+3] cycloaddition approach for the highly enantioselective synthesis of polysubstituted piperidines was developed. The developed methodology was applied in a one-pot [6+3]-[4+2] dicycloaddition, allowing the construction of structurally and stereochemically rich polycyclic compounds from simple building blocks.
authors.affiliation: Max-Planck Institute of Molecular Physiology, Otto-Hahn Strasse 11, Dortmund 44227, Germany.
authors.forename: Marco
authors.initials: M
authors.lastname: Potowski
authors.forename: Andrey P
authors.initials: AP
authors.lastname: Antonchick
authors.forename: Herbert
authors.initials: H
authors.lastname: Waldmann
mesh_terms: D002384:Catalysis; D061565:Cycloaddition Reaction; D003517:Cyclopentanes / Q000737:chemistry*; D004952:Esters; D010880:Piperidines / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D003517:Cyclopentanes; D004952:Esters; D010880:Piperidines; C017332:fulvene