title: Iridium(I)-catalyzed vinylic C-H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron.
abstract: Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
authors.affiliation: Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan.
authors.forename: Ikuo
authors.initials: I
authors.lastname: Sasaki
authors.forename: Hana
authors.initials: H
authors.lastname: Doi
authors.forename: Toshiya
authors.initials: T
authors.lastname: Hashimoto
authors.forename: Takao
authors.initials: T
authors.lastname: Kikuchi
authors.forename: Hajime
authors.initials: H
authors.lastname: Ito
authors.forename: Tatsuo
authors.initials: T
authors.lastname: Ishiyama
mesh_terms: D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D001896:Boron Compounds; D002264:Carboxylic Acids; D009942:Organometallic Compounds; D007495:Iridium