title: B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.
abstract: Heterolytic B-H activation and H-H formation on an Os-SH bond give borylthiolate-dihydrogen derivatives. These species exchange borylthiol by borane to afford σ-borane derivatives or release H2 and undergo a hydride-boryl exchange to yield boryl-hydrogensulfide complexes depending on the boryl group bonded to the sulfur atom.
authors.affiliation: Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain. maester@unizar.es
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Esteruelas
authors.forename: Ana M
authors.initials: AM
authors.lastname: López
authors.forename: Malka
authors.initials: M
authors.lastname: Mora
authors.forename: Enrique
authors.initials: E
authors.lastname: Oñate
mesh_terms: D001895:Boron / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D006862:Hydrogen Sulfide / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D009992:Osmium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D009992:Osmium; D006859:Hydrogen; D001895:Boron; D006862:Hydrogen Sulfide