title: Effect of linear nonionic polymer additives on the kinetic stability of dispersions of poly(diallyldimethylammonium chloride)/sodium dodecylsulfate nanoparticles.
abstract: In this article, the impact of different neutral polymers on the kinetic stability of charge-stabilized poly(diallyldimethylammonium chloride) (PDADMAC)/sodium dodecylsulfate (SDS) colloidal dispersions is analyzed using dynamic light scattering, electrophoretic mobility, turbidity, and coagulation kinetics measurements. Poly(ethyleneoxide) (PEO), poly(vinylpyrrolidone) (PVP), and dextran of comparable molecular masses as well as a higher-molecular-weight dextran sample were tested as nonionic additives. The light scattering and mobility data indicate that the PEO and PVP molecules may adsorb on the surface of the PDADMAC/SDS nanoparticles formed in the presence of excess surfactant. The primary effect of these additives is manifested in enhanced coagulation of the PDADMAC/SDS nanoparticles due to bridging at lower polymer concentrations and depletion flocculation at higher polymer concentrations. These findings are in sharp contrast to the earlier published effect of the same nonionic polymers on the poly(ethyleneimine) (PEI)/SDS colloidal dispersions, which can be sterically stabilized at appropriate PEO or PVP concentrations. However, the adsorption of the investigated dextran samples is negligible on the PDADMAC/SDS nanoparticles. Therefore, dextran molecules may cause only depletion flocculation in the PDADMAC/SDS system in the vicinity of the critical overlap concentration.
authors.affiliation: Laboratory of Interfaces and Nanosized Systems, Institute of Chemistry, Eötvös Loránd University, 1117 Budapest, Pázmány Péter Sétány 1/A, Hungary.
authors.forename: Katalin
authors.initials: K
authors.lastname: Pojják
authors.forename: Edit
authors.initials: E
authors.lastname: Fegyver
authors.forename: Róbert
authors.initials: R
authors.lastname: Mészáros
mesh_terms: D007700:Kinetics; D053758:Nanoparticles / Q000737:chemistry*; D011095:Polyethylenes / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry*; D012996:Solutions
chemical_list: D011095:Polyethylenes; D000644:Quaternary Ammonium Compounds; D012996:Solutions; C041004:poly-N,N-dimethyl-N,N-diallylammonium chloride; D012967:Sodium Dodecyl Sulfate