title: NH/PH isomerization and a Lewis pair for carbon dioxide capture.
abstract: Bis(di-i-propylphosphino)amine 1 reacts with B(C6F5)3 to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide. An attempt to prepare an anionic derivative resulted in the formation of a novel heterocycle derived from the PNP ligand and B(C6F5)3.
authors.affiliation: Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131, United States.
authors.forename: Brian M
authors.initials: BM
authors.lastname: Barry
authors.forename: Diane A
authors.initials: DA
authors.lastname: Dickie
authors.forename: Luke J
authors.initials: LJ
authors.lastname: Murphy
authors.forename: Jason A C
authors.initials: JA
authors.lastname: Clyburne
authors.forename: Richard A
authors.initials: RA
authors.lastname: Kemp