title: Dy(III) single-ion magnet showing extreme sensitivity to (de)hydration.
abstract: A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aobaku, Sendai 980-8578, Japan.
authors.forename: Min
authors.initials: M
authors.lastname: Ren
authors.forename: Dawid
authors.initials: D
authors.lastname: Pinkowicz
authors.forename: Minyoung
authors.initials: M
authors.lastname: Yoon
authors.forename: Kimoon
authors.initials: K
authors.lastname: Kim
authors.forename: Li-Min
authors.initials: LM
authors.lastname: Zheng
authors.forename: Brian K
authors.initials: BK
authors.lastname: Breedlove
authors.forename: Masahiro
authors.initials: M
authors.lastname: Yamashita