title: Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets.
abstract: Pyrene-intercalated layered compounds, [{Ru2(O2CCF3)4}2(TCNQR(x))]·2(pyrene) (TCNQR(x) = 7,7,8,8-tetracyano-p-quinodimethane derivatives; R(x) = H4 and F4), were synthesized. Pyrene prohibits intralayer electron transfer of [Ru2(II,II)] → TCNQR(x), even in the compound with R(x) = F4, from occurring.
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors.forename: Masaki
authors.initials: M
authors.lastname: Nishio
authors.forename: Natsuko
authors.initials: N
authors.lastname: Motokawa
authors.forename: Miho
authors.initials: M
authors.lastname: Takemura
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Miyasaka