title: Merging organocatalysis with transition metal catalysis and using O2 as the oxidant for enantioselective C-H functionalization of aldehydes.
abstract: A new catalytic Saegusa oxidation-Michael addition cascade reaction has been developed for the enantioselective β-functionalization of aldehydes. The feature of this research is the combination of organocatalysis and transition-metal catalysis for the asymmetric C-H functionalization which remains an underdeveloped research topic.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry and College of Chemistry & Chemical Engineering, Lanzhou University, Lanzhou 730000, P.R. China.
authors.forename: Yong-Long
authors.initials: YL
authors.lastname: Zhao
authors.forename: Yao
authors.initials: Y
authors.lastname: Wang
authors.forename: Xiu-Qin
authors.initials: XQ
authors.lastname: Hu
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Xu
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D009942:Organometallic Compounds; D016877:Oxidants; D010165:Palladium; D010100:Oxygen