title: Role of molecular structure on bioelectrochemical reduction of mononitrophenols from wastewater.
abstract: The effect of nitro-substituent on mononitrophenol (o-nitrophenol (ONP), m-nitrophenol (MNP) and p-nitrophenol (PNP)) reduction in a bioelectrochemical system (BES) was investigated in this study. The results show that the removal of all three nitrophenols was significantly enhanced with more negative cathode potential and shortened hydraulic retention time in the BESs. Moreover, the reduction of the three nitrophenols followed in the order of ONP > MNP > PNP in the BESs. Both quantum chemical calculation using density function theory and cyclic voltammetry analysis confirmed the reductive sequence of the three nitrophenols. In addition, the acute toxicity of nitrophenol effluent significantly decreased while its biodegradability was enhanced after treatment in the BES. Therefore, the BES technology offers bright prospects for efficient treatment of nitrophenol-containing wastewater.
authors.affiliation: Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu Province, China. Electronic address: shenjinyou-1981@163.com.
authors.forename: Jinyou
authors.initials: J
authors.lastname: Shen
authors.forename: Yanyan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Xiaopeng
authors.initials: X
authors.lastname: Xu
authors.forename: Congxin
authors.initials: C
authors.lastname: Hua
authors.forename: Xiuyun
authors.initials: X
authors.lastname: Sun
authors.forename: Jiansheng
authors.initials: J
authors.lastname: Li
authors.forename: Yang
authors.initials: Y
authors.lastname: Mu
authors.forename: Lianjun
authors.initials: L
authors.lastname: Wang
mesh_terms: D001673:Biodegradation, Environmental; D004563:Electrochemistry / Q000379:methods*; D015394:Molecular Structure; D009596:Nitrophenols / Q000737:chemistry*; D014865:Waste Disposal, Fluid; D062065:Wastewater / Q000737:chemistry*
chemical_list: D009596:Nitrophenols; D062065:Wastewater; C049017:3-nitrophenol; C024836:4-nitrophenol
keywords: Bioelectrochemical system; Cathode; Nitrophenols; Reduction