title: Thermal analysis and vibrational spectroscopic characterization of the boro silicate mineral datolite - CaBSiO4(OH).
abstract: The objective of this work is to determine the thermal stability and vibrational spectra of datolite CaBSiO4(OH) and relate these properties to the structure of the mineral. The thermal analysis of datolite shows a mass loss of 5.83% over a 700-775°C temperature range. This mass loss corresponds to 1 water (H2O) molecules pfu. A quantitative chemical analysis using electron probe was undertaken. The Raman spectrum of datolite is characterized by bands at 917 and 1077cm(-1) assigned to the symmetric stretching modes of BO and SiO tetrahedra. A very intense Raman band is observed at 3498cm(-1) assigned to the stretching vibration of the OH units in the structure of datolite. BOH out-of-plane vibrations are characterized by the infrared band at 782cm(-1). The vibrational spectra are based upon the structure of datolite based on sheets of four- and eight-membered rings of alternating SiO4 and BO3(OH) tetrahedra with the sheets bonded together by calcium atoms.
authors.affiliation: School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia. r.frost@qut.edu.au
authors.forename: Ray L
authors.initials: RL
authors.lastname: Frost
authors.forename: Yunfei
authors.initials: Y
authors.lastname: Xi
authors.forename: Ricardo
authors.initials: R
authors.lastname: Scholz
authors.forename: Rosa Malena Fernandes
authors.initials: RM
authors.lastname: Lima
authors.forename: Laura Frota Campos
authors.initials: LF
authors.lastname: Horta
authors.forename: Andres
authors.initials: A
authors.lastname: Lopez
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D004055:Differential Thermal Analysis; D007558:Italy; D008903:Minerals / Q000737:chemistry*; D017640:Silicates / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D013696:Temperature; D013818:Thermogravimetry; D014732:Vibration
chemical_list: D001896:Boron Compounds; D008903:Minerals; D017640:Silicates
keywords: Borate; Datolite; Silicate; Thermal analysis; Thermal stability; Vibrational spectroscopy