title: Evaluations of the TiO2/simulated solar UV degradations of XAD fractions of natural organic matter from a bog lake using size-exclusion chromatography.
abstract: This work reports on the changes in compositions of humic acids (HAs) and fulvic acids (FAs) during photocatalytic degradation. The HAs and FAs were obtained from the XAD-resin fractionation of natural-organic matter (NOM) from a bog lake (Lake Hohloh, Black Forest, Germany). Degussa P-25 titanium dioxide (TiO2) in a suspension and a solar UV simulator (batch reactor) were used in the experiments. The photocatalytic degradation of the HAs and FAs were monitored using size-exclusion chromatography (SEC) equipped with dissolved organic carbon (DOC) and ultraviolet (UV254) detection (SEC-DOC and SEC-UV254) and UV-Vis spectrophotometry. The evolutions of the photocatalytic degradations of the HA and FA fractions were selective. The photocatalytic degradation started with the degradations of high molecular weight compounds with relatively high UV254 absorbances in the HA and FA fractions to yield low molecular weight compounds showing less specific UV254 absorbances. Observance of the same tendency for the original NOM from Lake Hohloh indicates that these XAD-fractions still having complex compound mixtures. However, the larger molecular weight fractions of the FAs showed higher preferential adsorptions onto TiO2, which caused their faster degradation rates. Furthermore, FAs showed a greater reduction of the total THM formation potential (TTHMFP) and the organic halogen compounds adsorbable on activated carbon formation potential (AOXFP), in comparison with the HAs.
authors.affiliation: Grupo Procesos Fisicoquímicos Aplicados, Facultad de Ingeniería, Universidad de Antioquia, SIU/UdeA, Calle 70 No. 52-21 Medellín, Colombia. hvalens@gmail.com
authors.forename: Sergio
authors.initials: S
authors.lastname: Valencia
authors.forename: Juan M
authors.initials: JM
authors.lastname: Marín
authors.forename: Gloria
authors.initials: G
authors.lastname: Restrepo
authors.forename: Fritz H
authors.initials: FH
authors.lastname: Frimmel
mesh_terms: D000327:Adsorption; D001578:Benzopyrans / Q000737:chemistry*; D005591:Chemical Fractionation / Q000379:methods*; D002850:Chromatography, Gel / Q000379:methods*; D004203:Disinfection; D005858:Germany; D054879:Halogenation; D006812:Humic Substances; D060106:Lakes; D008970:Molecular Weight; D010777:Photochemistry / Q000379:methods*; D010782:Photolysis; D013056:Spectrophotometry, Ultraviolet; D013472:Sunlight; D014025:Titanium; D014466:Ultraviolet Rays; D053833:Wetlands
chemical_list: D001578:Benzopyrans; D006812:Humic Substances; C009495:titanium dioxide; D014025:Titanium; C005023:fulvic acid
keywords: Fulvic acids; Heterogenous photocatalysis; Humic acids; Natural-organic matter; Size-exclusion chromatography; XAD-fractionation