title: Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine.
abstract: A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated Pd(II) cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.
authors.affiliation: Institute for Inorganic Chemistry, Georg-August University Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) http://www.clever-lab.de.
authors.forename: Marina
authors.initials: M
authors.lastname: Frank
authors.forename: Jakob
authors.initials: J
authors.lastname: Hey
authors.forename: Ilker
authors.initials: I
authors.lastname: Balcioglu
authors.forename: Yu-Sheng
authors.initials: YS
authors.lastname: Chen
authors.forename: Dietmar
authors.initials: D
authors.lastname: Stalke
authors.forename: Tomoyoshi
authors.initials: T
authors.lastname: Suenobu
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
authors.forename: Holm
authors.initials: H
authors.lastname: Frauendorf
authors.forename: Guido H
authors.initials: GH
authors.lastname: Clever
mesh_terms: D015394:Molecular Structure; D009930:Organic Chemicals / Q000737:chemistry*; D010084:Oxidation-Reduction; D010640:Phenothiazines / Q000737:chemistry*
chemical_list: D009930:Organic Chemicals; D010640:Phenothiazines; C031637:phenothiazine
keywords: cage compounds; interpenetration; phenothiazines; redox chemistry; supramolecular chemistry