title: A crown-shaped 24-molybdate cluster constructed by organotriphosphonate ligand.
abstract: A crown-shaped organic-inorganic hybrid polyoxomolybdate, Na5[H7{N(CH2PO3)3}Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclearity of metal atoms in the area of organophosphonate-based polyoxometalates.
authors.affiliation: Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University Kaifeng, Henan 475004, People's Republic of China.
authors.forename: Lu
authors.initials: L
authors.lastname: Yang
authors.forename: Pengtao
authors.initials: P
authors.lastname: Ma
authors.forename: Zhen
authors.initials: Z
authors.lastname: Zhou
authors.forename: Jingping
authors.initials: J
authors.lastname: Wang
authors.forename: Jingyang
authors.initials: J
authors.lastname: Niu