title: Nucleation and growth study of nano-PbO2 on Ti in different additives for electrocatalytic oxidation process.
abstract: Electrocrystallization of PbO2 on Ti electrode was studied in different bath solutions using cyclic voltammetry (CV), chronoamperometry (CA), and scanning electron microscopy. The cyclic voltammetry studies revealed that the addition of methanol postponed the oxygen evolution region and made over potential nucleation of PbO2 on Ti. Oxidation of PbO2 is preferred in second cycle (a peak) in other studied bath solutions, except the Nafion and aniline containing solution. In the presence of the pyrrole, the PbO2 formed at under deposition potential with less in numbers. Nafion and aniline inclusion turn the process in to progressive nucleation and growth without inhibition. On the other hand, other solutions studied are revealed the instantaneous nucleation and growth or inhibition at high potentials. Surface morphology explained that approximately equal to 300 nm sizes PbO2 particles with vertical nucleation and growth phenomena evidenced the Nafion and aniline are the important dopants. The results indicated that large current density or high potential polarization can be obtained in presence of methanol, Nafion, and aniline, which is one of the most important and necessary factors for forming high surface area PbO2 with strong adherence towards mediated electro-oxidation process.
authors.affiliation: Department of Chemical Engineering, Sunchon National University, #413 Jungangno, Suncheon 540-742, Jeollanam-do, Republic of Korea.
authors.forename: G
authors.initials: G
authors.lastname: Muthuraman
authors.forename: Il-Shik
authors.initials: IS
authors.lastname: Moon