title: Halogen bonding in fluorine: experimental charge density study on intermolecular F···F and F···S donor-acceptor contacts.
abstract: The enigmatic type II C-F···F-C and C-F···S-C interactions in pentafluorophenyl 2,2'-bithiazole are shown to be realistic "σ-hole" interactions based on high resolution X-ray charge density analysis.
authors.affiliation: Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India.
authors.forename: Mysore S
authors.initials: MS
authors.lastname: Pavan
authors.forename: Karothu
authors.initials: K
authors.lastname: Durga Prasad
authors.forename: T N Guru
authors.initials: TN
authors.lastname: Row
mesh_terms: D001665:Binding Sites; D005461:Fluorine / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013455:Sulfur / Q000737:chemistry*; D013844:Thiazoles / Q000737:chemistry*
chemical_list: D013844:Thiazoles; D005461:Fluorine; D013455:Sulfur