title: PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides.
abstract: The unsaturated side chain of l-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligopeptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.
authors.affiliation: TU Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Petersenstr. 20, Darmstadt, Germany.
authors.forename: Marco
authors.initials: M
authors.lastname: Körner
authors.forename: Grit
authors.initials: G
authors.lastname: Sauer
authors.forename: Andreas
authors.initials: A
authors.lastname: Heil
authors.forename: Daichi
authors.initials: D
authors.lastname: Nasu
authors.forename: Martin
authors.initials: M
authors.lastname: Empting
authors.forename: Daniel
authors.initials: D
authors.lastname: Tietze
authors.forename: Stephan
authors.initials: S
authors.lastname: Voigt
authors.forename: Heiko
authors.initials: H
authors.lastname: Weidler
authors.forename: Torsten
authors.initials: T
authors.lastname: Gutmann
authors.forename: Olga
authors.initials: O
authors.lastname: Avrutina
authors.forename: Harald
authors.initials: H
authors.lastname: Kolmar
authors.forename: Tomasz
authors.initials: T
authors.lastname: Ratajczyk
authors.forename: Gerd
authors.initials: G
authors.lastname: Buntkowsky
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D000595:Amino Acid Sequence; D002384:Catalysis; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D006865:Hydrogenation; D009682:Magnetic Resonance Spectroscopy; D009842:Oligopeptides / Q000138:chemical synthesis* / Q000737:chemistry; D013438:Sulfhydryl Compounds / Q000737:chemistry
chemical_list: D000480:Alkynes; D009842:Oligopeptides; D013438:Sulfhydryl Compounds; C009055:propargylglycine; D006859:Hydrogen; D005998:Glycine