title: Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides.
abstract: The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an intramolecular hydrogen transfer process.
authors.affiliation: College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, PR China.
authors.forename: Lu
authors.initials: L
authors.lastname: Wang
authors.forename: Chao
authors.initials: C
authors.lastname: Liu
authors.forename: Ruopeng
authors.initials: R
authors.lastname: Bai
authors.forename: Yani
authors.initials: Y
authors.lastname: Pan
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000499:Allylamine / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry; D007536:Isomerism; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D000577:Amides; D000499:Allylamine; D009532:Nickel; D006859:Hydrogen