title: In-situ assessment of metal contamination via portable X-ray fluorescence spectroscopy: Zlatna, Romania.
abstract: Zlatna, Romania is the site of longtime mining/smelting operations which have resulted in widespread metal pollution of the entire area. Previous studies have documented the contamination using traditional methods involving soil sample collection, digestion, and quantification via inductively coupled plasma atomic emission spectroscopy or atomic absorption. However, field portable X-ray fluorescence spectroscopy (PXRF) can accurately quantify contamination in-situ, in seconds. A PXRF spectrometer was used to scan 69 soil samples in Zlatna across multiple land use types. Each site was georeferenced with data inputted into a geographic information system for high resolution spatial interpolations. These models were laid over contemporary aerial imagery to evaluate the extent of pollution on an individual elemental basis. Pb, As, Co, Cu, and Cd exceeded governmental action limits in >50% of the sites scanned. The use of georeferenced PXRF data offers a powerful new tool for in-situ assessment of contaminated soils.
authors.affiliation: Texas Tech University, Department of Plant and Soil Sciences, Lubbock, TX, USA. Electronic address: david.weindorf@ttu.edu.
authors.forename: David C
authors.initials: DC
authors.lastname: Weindorf
authors.forename: Laura
authors.initials: L
authors.lastname: Paulette
authors.forename: Titus
authors.initials: T
authors.lastname: Man
mesh_terms: D004784:Environmental Monitoring / Q000379:methods*; D004787:Environmental Pollution / Q000706:statistics & numerical data; D008670:Metals / Q000032:analysis*; D008906:Mining; D012383:Romania; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis*; D013052:Spectrometry, X-Ray Emission
chemical_list: D008670:Metals; D012987:Soil; D012989:Soil Pollutants
keywords: Arsenic; Lead; Metals; Spatial variability; Zlatna