title: Synthesis of mono-fluorinated functionalized cyclopropanes and aziridines using the α-fluorovinyl diphenyl sulfonium salt.
abstract: The α-fluorovinyl diphenyl sulfonium salt 1 is attractive due to its high potential for the synthesis of mono-fluorinated cyclopropanes and aziridines as useful three-membered rings. The synthetically useful salt 1 is readily prepared from α-fluorovinyl phenyl sulfide and diphenyl iodonium salt in one step.
authors.affiliation: Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan. hanamoto@cc.saga-u.ac.jp.
authors.forename: Kensuke
authors.initials: K
authors.lastname: Hirotaki
authors.forename: Yui
authors.initials: Y
authors.lastname: Takehiro
authors.forename: Ryo
authors.initials: R
authors.lastname: Kamaishi
authors.forename: Yasunori
authors.initials: Y
authors.lastname: Yamada
authors.forename: Takeshi
authors.initials: T
authors.lastname: Hanamoto
mesh_terms: D001388:Aziridines / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D015394:Molecular Structure; D013440:Sulfides / Q000138:chemical synthesis / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D001388:Aziridines; D003521:Cyclopropanes; D013440:Sulfides; D014753:Vinyl Compounds; D005461:Fluorine