title: A single catalyst of aqueous CoIII for deodorization of mixture odor gases: a development and reaction pathway study at electro-scrubbing process.
abstract: A constant generation of aqueous Co(III) active catalyst and its utility on various odor gases deodorization at electro-scrubbing process is the primary investigation. The Co(III) activation and regeneration for continuous use is established by electrochemical undivided cell in H₂SO₄ medium. The generated aqueous Co(III) is then applied to simultaneous deodorization of simulated odor gases, namely, ammonia, trimethylamine, hydrogen sulfide, methyl mercaptan, and acetaldehyde, for municipal waste treatment plant emissions. The electro-scrubbing process results indicated that deodorization is almost complete at a low gas flow rate of 30 L min(-1). FTIR and pH studies demonstrated that amine compounds are removed via complex formation with H₂SO₄ and Co(III). In the case of sulfur compounds, deodorization of methyl mercaptan and hydrogen sulfide are removed by the Co(III)-MEO (Co(III)-mediated electrocatalytic oxidation) process via the formation of acetic acid as intermediate and SO₄(2-) as a product. Also, acetaldehyde deodorization results obtained by pH, total acidity and CO₂ analyses evidence the process follow Co(III)-MEO. The constant generation of aqueous active Co(III) and an electro-scrubbing process offers promise as a means of removing odorous waste gases from gaseous emissions.
authors.affiliation: Department of Chemical Engineering, Sunchon National University, 315 Maegok Dong, Suncheon 540-742, Chonnam, Republic of Korea.
authors.forename: Muthuraman
authors.initials: M
authors.lastname: Govindan
authors.forename: Il-Shik
authors.initials: IS
authors.lastname: Moon
mesh_terms: D000042:Absorption; D000079:Acetaldehyde / Q000737:chemistry; D000393:Air Pollutants / Q000032:analysis; D000641:Ammonia / Q000737:chemistry; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D004563:Electrochemistry; D004785:Environmental Pollutants; D004867:Equipment Design; D005740:Gases; D006862:Hydrogen Sulfide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D008744:Methylamines / Q000737:chemistry; D009812:Odorants; D012037:Refuse Disposal / Q000379:methods*; D017550:Spectroscopy, Fourier Transform Infrared; D013438:Sulfhydryl Compounds / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry; D013997:Time Factors; D064091:Waste Disposal Facilities
chemical_list: D000393:Air Pollutants; D004785:Environmental Pollutants; D005740:Gases; D008744:Methylamines; D013438:Sulfhydryl Compounds; C005231:methylmercaptan; D003035:Cobalt; D013455:Sulfur; D000641:Ammonia; D000079:Acetaldehyde; C023336:trimethylamine; D006862:Hydrogen Sulfide
keywords: Co(III)-MEO process; Combined deodorization; Electro-scrubbing; Electrogenerated Co(III)