title: Behavior of MCPA in four intensive cropping soils amended with fresh, composted, and aged olive mill waste.
abstract: An evaluation was made of the impact of olive mill waste and its organic matter transformation on the sorption, desorption, leaching, and degradation of the herbicide MCPA when the waste was applied to four Mediterranean soils. The soils were amended in the laboratory with fresh, composted, and field-aged olive mill waste (OW, COW, and AOW treatments, respectively). It was found that the greater the amount of OW applied to the soils, but especially the greater its organic matter maturity, the greater the adsorption of MCPA. Compared with unamended soils, at the 5% rate of application the adsorption capacity increased by between 9.8% and 40%, 148% and 224%, and by 258% for the OW, COW, and AOW amended soils, respectively. The hysteresis coefficients were significantly lower in the OW-amended soils than in AOW or COW-amended soils, indicating that the adsorbed MCPA could be easily desorbed in OW-amended soils if the amendment is not aged or composted. While the OW addition greatly extended the persistence of MCPA, the application of COW enhanced MCPA degradation in all the soils, as corresponded to the increased soil microbial activity indicated by the higher levels of soil dehydrogenase activity. Fresh OW amendment significantly increased the amount of MCPA leached (from 13.7% in the most alkaline soil to 36.7% in the most acidic, at the 5% rate of application), favored by the higher levels of water soluble organic carbon content. However, leaching losses of the herbicide were reduced by up to 39.9% and 55.3% in the COW- and AOW-amended soils at the 5% loading rate, respectively. The use of OW with a high degree of organic matter maturity may be regarded as a potentially useful management practice to reduce MCPA leaching in soils with low organic matter content. The application of fresh OW, however, could well increase the risk of groundwater contamination by this herbicide, especially in acidic soils.
authors.affiliation: Área de Edafología y Química Agrícola, Facultad de Ciencias, Universidad de Extremadura, Avda de Elvas s/n, 06071-Badajoz, Spain. pineiro@unex.es
authors.forename: Antonio
authors.initials: A
authors.lastname: López-Piñeiro
authors.forename: David
authors.initials: D
authors.lastname: Peña
authors.forename: Angel
authors.initials: A
authors.lastname: Albarrán
authors.forename: Javier
authors.initials: J
authors.lastname: Sánchez-Llerena
authors.forename: Daniel
authors.initials: D
authors.lastname: Becerra
mesh_terms: D008456:2-Methyl-4-chlorophenoxyacetic Acid / Q000032:analysis*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D031658:Olea; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D012989:Soil Pollutants; D008456:2-Methyl-4-chlorophenoxyacetic Acid
keywords: Adsorption; Dehydrogenase activity; Leaching; MCPA; Olive mill waste; Persistence