title: Hydrogen-bond mediated regio- and enantioselectivity in a C-H amination reaction catalysed by a supramolecular Rh(II) complex.
abstract: Enantioselective (up to 74% ee) and regioselective C-H amination reactions of 3-benzylquinolones were achieved with a chiral C2-symmetric Rh(II) complex exhibiting two lactam binding sites for substrate coordination via hydrogen bonds.
authors.affiliation: Department Chemie and Catalysis Research Center, Technische Universität München, 85747 Garching, Germany. thorsten.bach@ch.tum.de
authors.forename: Thorsten
authors.initials: T
authors.lastname: Höke
authors.forename: Eberhardt
authors.initials: E
authors.lastname: Herdtweck
authors.forename: Thorsten
authors.initials: T
authors.lastname: Bach