title: The Lewis Base Stabilized Parent Arsanylborane H2AsBH2⋅NMe3.
abstract: Exclusively hydrogen-substituted arsanylboranes: The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H2AsBH2⋅NMe3 was achieved in a one-pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H2AsBH2⋅NMe3 to show its broad reactivity pattern.
authors.affiliation: Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg (Germany), Fax: (+49) 941-9434439.
authors.forename: Christian
authors.initials: C
authors.lastname: Marquardt
authors.forename: Ariane
authors.initials: A
authors.lastname: Adolf
authors.forename: Andreas
authors.initials: A
authors.lastname: Stauber
authors.forename: Michael
authors.initials: M
authors.lastname: Bodensteiner
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Virovets
authors.forename: Alexey Y
authors.initials: AY
authors.lastname: Timoshkin
authors.forename: Manfred
authors.initials: M
authors.lastname: Scheer
mesh_terms: D001151:Arsenic / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry*; D058115:Lewis Bases / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D001880:Boranes; D058115:Lewis Bases; D009942:Organometallic Compounds; D001151:Arsenic
keywords: Group 13/15 compounds; Lewis acid base adducts; arsenic; boron; phosphorus; primary arsine