title: Nanocrystal shape and nanojunction effects on electron transport in nanocrystal-assembled bulks.
abstract: Bulk nanostructured materials are made from the assembly of octahedral PbSe nanocrystals. After thermal annealing, the artificial bulk demonstrates a large difference in behavior depending on the temperature, and a large variation of room-temperature resistivity of up to seven orders of magnitude. This variation originates from the high-indexed sharp edges of the octahedral nanocrystals. As the nanocrystals are arranged in the edge-to-edge configuration, which was observed in scanning electron microscopy images, the inter-nanocrystal capacitance is small due to the small parallel area between the nanocrystals. The small capacitance results in a high thermal fluctuation voltage and drives electron transport. The temperature-dependent resistivity and the electric field-dependent current are highly in agreement with the model of fluctuation-induced tunneling conduction. Thermal annealing reduces the inter-nanocrystal separation distance, creating a large variation in the electrical properties. Specifically, octahedral-shaped PbSe nanocrystals are employed in tailoring the electron transport in bulk nanostructured materials.
authors.affiliation: Department of Electrophysics, National Chiao Tung University, Hsinchu 30010, Taiwan, ROC.
authors.forename: Shao-Chien
authors.initials: SC
authors.lastname: Chiu
authors.forename: Jia-Sin
authors.initials: JS
authors.lastname: Jhang
authors.forename: Yen-Fu
authors.initials: YF
authors.lastname: Lin
authors.forename: Shih-Ying
authors.initials: SY
authors.lastname: Hsu
authors.forename: Jiye
authors.initials: J
authors.lastname: Fang
authors.forename: Wen-Bin
authors.initials: WB
authors.lastname: Jian