title: Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity.
abstract: The palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclohexene with a variety of heteroarenes gives rise in to a new family of 1,2-di(heteroaryl)perfluorocyclohexenes. These derivatives do not exhibit photoreactivity and this unexpected outcome is explained by calculations demonstrating the lack of reactive isomers.
authors.affiliation: Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1 Organométalliques, Matériaux et Catalyse, 35042 Rennes Cedex, France.
authors.forename: Kedong
authors.initials: K
authors.lastname: Yuan
authors.forename: Julien
authors.initials: J
authors.lastname: Boixel
authors.forename: Hubert
authors.initials: H
authors.lastname: Le Bozec
authors.forename: Abdou
authors.initials: A
authors.lastname: Boucekkine
authors.forename: Henri
authors.initials: H
authors.lastname: Doucet
authors.forename: Véronique
authors.initials: V
authors.lastname: Guerchais
authors.forename: Denis
authors.initials: D
authors.lastname: Jacquemin