title: Pd(0)-catalyzed sequential C-N bond formation via allylic and aromatic C-H amination of α-methylstyrenes with diaziridinone.
abstract: A novel Pd(0)-catalyzed sequential C-N bond formation process via allylic and aromatic C-H amination of α-methylstyrenes with di-tert-butyldiaziridinone, giving spirocyclic indolines in good yields, is described. Four C-N bonds and one spiro quaternary carbon are generated in a single operation.
authors.affiliation: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
authors.forename: Thomas A
authors.initials: TA
authors.lastname: Ramirez
authors.forename: Qian
authors.initials: Q
authors.lastname: Wang
authors.forename: Yingguang
authors.initials: Y
authors.lastname: Zhu
authors.forename: Huaiji
authors.initials: H
authors.lastname: Zheng
authors.forename: Xingao
authors.initials: X
authors.lastname: Peng
authors.forename: Richard G
authors.initials: RG
authors.lastname: Cornwall
authors.forename: Yian
authors.initials: Y
authors.lastname: Shi
mesh_terms: D000586:Amination; D001388:Aziridines / Q000737:chemistry*; D002384:Catalysis; D006860:Hydrogen Bonding; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013343:Styrenes / Q000737:chemistry*
chemical_list: D001388:Aziridines; D007211:Indoles; D013343:Styrenes; C527442:di-tert-butyldiaziridinone; C027142:vinyltoluene; D010165:Palladium
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