title: One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition.
abstract: A series of poly(3-hexylthiophene)-b-poly(hexadecyloxylallene) copolymers has been synthesized in one pot via sequential monomer addition by using Ni(dppp)Cl2 as a single catalyst. The copolymerization has been revealed to proceed by a controlled chain extension mechanism and the block copolymer can self-assemble into a well-defined supramolecular structure in solution and exhibit microphase separation in the solid state.
authors.affiliation: Department of Polymer Science and Engineering, School of Chemical Engineering, Hefei University of Technology and Key Laboratory of Advanced Functional Materials and Devices, Anhui Province, Anhui, China. zqwu@hfut.edu.cn
authors.forename: Zong-Quan
authors.initials: ZQ
authors.lastname: Wu
authors.forename: Yu
authors.initials: Y
authors.lastname: Chen
authors.forename: Ying
authors.initials: Y
authors.lastname: Wang
authors.forename: Xiao-Yue
authors.initials: XY
authors.lastname: He
authors.forename: Yun-Sheng
authors.initials: YS
authors.lastname: Ding
authors.forename: Na
authors.initials: N
authors.lastname: Liu