title: TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C═C double-bond cleavage.
abstract: A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C═C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.
authors.affiliation: State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Xue Yuan Rd. 38, Beijing 100191, China.
authors.forename: Teng
authors.initials: T
authors.lastname: Wang
authors.forename: Ning
authors.initials: N
authors.lastname: Jiao
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D003497:Cyclic N-Oxides / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*
chemical_list: D000475:Alkenes; D003497:Cyclic N-Oxides; D016877:Oxidants; D009584:Nitrogen; D010100:Oxygen; C003959:TEMPO