title: Exploiting dense shell/packing principles to invoke stereoselectivity in a reaction accelerated by a chiral dendrimer.
abstract: As dendrimers approach their dense shell or dense packed limit, a certain amount of conformational organization exists. Any substrate binding within the dendrimer's external layer will experience the same organizational effects. This paper describes how these effects can be exploited towards stereocontrol with respect to binding and reactivity.
authors.affiliation: Department of Chemistry, The University of Sheffield, Sheffield, S2 7HF, UK.
authors.forename: Adam
authors.initials: A
authors.lastname: Ellis
authors.forename: Melanie
authors.initials: M
authors.lastname: Wallace
authors.forename: Lance J
authors.initials: LJ
authors.lastname: Twyman
mesh_terms: D000588:Amines / Q000737:chemistry; D050091:Dendrimers / Q000737:chemistry*; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D000588:Amines; D050091:Dendrimers