title: Polymer-supported siloxane transfer agents for Pd-catalyzed cross-coupling reactions.
abstract: The design, synthesis, and validation of a ring-opening metathesis polymerization (ROMP) polymer supporting siloxane transfer agents have been achieved that permit efficient palladium-catalyzed cross-coupling reactions. The solubility properties of the polymer facilitate not only product purification but also polymer recycling without significant loss of cross-coupling activity.
authors.affiliation: Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
authors.forename: Minh H
authors.initials: MH
authors.lastname: Nguyen
authors.forename: Amos B
authors.initials: AB
authors.lastname: Smith
mesh_terms: D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D015394:Molecular Structure; D058105:Polymerization; D011108:Polymers / Q000737:chemistry*; D012833:Siloxanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003432:Cross-Linking Reagents; D011108:Polymers; D012833:Siloxanes
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