"Fibonacci's route" to regioregular oligo(3-hexylthiophene)s.
We describe a new synthetic approach to regioregular monodisperse oligo(3-alkylthiophene)s allowing for simple separation of regioregular material in gram quantities. The number of repeat units follows the Fibonacci numbers up to a length of 21. In a small adaption of this approach, introduction of a protecting group was used to synthesize an oligo(3-hexylthiophene) with 36 repeating units, the longest regioregular 3-hexylthiophene oligomer synthesized to date.
Department of Materials, Eidgenössische Technische Hochschule (ETH) Zürich , Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.
Felix P V
FP
Koch
Paul
P
Smith
Martin
M
Heeney