Difluorodioxophosphate-based hollow hexanuclear lanthanide(III) clusters decorated with tetrathiafulvalene ligands.
The galvanostatic reaction of the [4,5-bis(2-pyridyl-N-oxidemethylthio)]-4',5'-methyldithiotetrathiafulvalene ligand with lanthanide ions in the presence of hexafluorophosphate (PF6(-)) anions afforded the highest-nuclearity lanthanide clusters decorated by tetrathiafulvalene-based ligands thanks to the original partial hydrolysis of the PF6(-) anions in difluorodioxophosphate (PO2F2(-)) bridging ligands.
Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1 , 263 Avenue du Général Leclerc, 35042 Rennes Cedex, France.
Tamyris T
TT
da Cunha
Fabrice
F
Pointillart
Boris
B
Le Guennic
Cynthia L M
CL
Pereira
Stéphane
S
Golhen
Olivier
O
Cador
Lahcène
L
Ouahab