Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl.
The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene.
University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK. Stephen.Faulkner@chem.ox.ac.uk TJS@chem.ku.dk.
Leila R
LR
Hill
Octavia A
OA
Blackburn
Michael W
MW
Jones
Manuel
M
Tropiano
Thomas Just
TJ
Sørensen
Stephen
S
Faulkner