A porous Mn(V) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO2 sorption.
A new coordination framework material, [Zn{MnN(CN)4(H2O)}]·2H2O·MeOH, has been characterised crystallographically and the effect of a terminal nitride on the N2, H2 and CO2 sorption capacities of the material assessed through porosimetery measurements and DRIFTS.
School of Chemistry, The University of Sydney, NSW, 2006, Australia.
Michael J
MJ
Murphy
Deanna M
DM
D'Alessandro
Cameron J
CJ
Kepert
D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009570:Nitriles / Q000737:chemistry*; D010316:Particle Size; D010984:Platinum / Q000737:chemistry*; D016062:Porosity; D013455:Sulfur / Q000737:chemistry*; D013499:Surface Properties; D014867:Water / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D009570:Nitriles; D014867:Water; D002245:Carbon Dioxide; D008345:Manganese; D010984:Platinum; D013455:Sulfur; D015032:Zinc