Structures of the reaction products of the AZADO radical with TCNQF4 or thiourea.
While an addition product was formed by the reaction of AZADO (2-azaadamantane N-oxyl) with TCNQF4 (2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane), the reaction of AZADO with thiourea provided an inclusion compound, in which AZADO molecules are incorporated in cylindrical channels formed by thiourea molecules.
Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan, Tel: +81-791-58-0163; fax: +81-791-58-0164.
Hideto
H
Suzuki
Yuta
Y
Kawahara
Hiroki
H
Akutsu
Jun-Ichi
J
Yamada
Shin'ichi
S
Nakatsuji
TCNQF4; adduct; inclusion compound; nitroxide radical; thiourea