Synthesis of symmetrical and nonsymmetrical bisthienylcyclopentenes.
Diarylethenes possess unique structural properties, which enabled them to find widespread applications in the field of photochromism. Nowadays, bisthienylcyclopentenes (BTCs) present the most popular subfamily of these compounds, which are widely used as P-type chromophores. This minireview summarises the main strategies for the synthesis of symmetrical and nonsymmetrical BTCs. In addition, attention is drawn to desymmetrisations achieved by monosubstitutions, which is not frequently utilised, although it can be highly advantageous. This is supported with some of the authors' latest results.
Institut des Sciences Moléculaires, Université Bordeaux 1, 351 Cours de la Libération, 33405, Talence, France. g.szaloki@ism.u-bordeaux1.fr
György
G
Szalóki
Jean-Luc
JL
Pozzo
bisthienylcyclopentenes; diarylethenes; dithienylcyclopentenes; dithienylperfluorocyclopentenes; nonsymmetrical diarylethenes; photochromism