Efficient sensitization of dye-sensitized solar cells by novel triazine-bridged porphyrin-porphyrin dyads.
Two novel porphyrin-porphyrin dyads, the symmetrical Zn[Porph]-Zn[Porph] (2) and unsymmetrical Zn[Porph]-H2[Porph] (4), where Zn[Porph] and H2[Porph] are the metalated and free-base forms of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin, respectively, in which two porphyrin units are covalently bridged by 1,3,5-triazine, have been synthesized via the stepwise amination of cyanuric chloride. The dyads are also functionalized by a terminal carboxylic acid group of a glycine moiety attached to the triazine group. Photophysical measurements of 2 and 4 showed broaden and strengthened absorptions in their visible spectra, while electrochemistry experiments and density functional theory calculations revealed negligible interaction between the two porphyrin units in their ground states but appropriate frontier orbital energy levels for use in dye-sensitized solar cells (DSSCs). The 2- and 4-based solar cells have been fabricated and found to exhibit power conversion efficiencies (PCEs) of 3.61% and 4.46%, respectively (under an illumination intensity of 100 mW/cm(2) with TiO2 films of 10 μm thickness). The higher PCE value of the 4-based DSSC, as revealed by photovoltaic measurements (J-V curves) and incident photon-to-current conversion efficiency (IPCE) spectra of the two cells, is attributed to its enhanced short-circuit current (J(sc)) under illumination, high open-circuit voltage (V(oc)), and fill factor (FF) values. Electrochemical impedance spectra demonstrated shorter electron-transport time (τd), longer electron lifetime (τe), and high charge recombination resistance for the 4-based cell, as well as larger dye loading onto TiO2.
Laboratory of Bioinorganic Chemistry, Department of Chemistry, University of Crete, Voutes Campus, P.O. Box 2208, 71003 Heraklion, Crete, Greece.
Galateia E
GE
Zervaki
Mahesh S
MS
Roy
Manas K
MK
Panda
Panagiotis A
PA
Angaridis
Emmanouel
E
Chrissos
Ganesh D
GD
Sharma
Athanassios G
AG
Coutsolelos
D004396:Coloring Agents / Q000737:chemistry*; D011211:Electric Power Supplies; D055664:Electrochemical Techniques; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D011166:Porphyrins / Q000737:chemistry; D011789:Quantum Theory; D012993:Solar Energy; D014227:Triazines / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
C548833:5-(4-aminophenyl)-10,15,20-triphenylporphyrin; D004396:Coloring Agents; D008665:Metalloporphyrins; D011166:Porphyrins; D014227:Triazines; D015032:Zinc