Synthesis and reactivity of Zn-biphenyl metal-organic frameworks, introducing a diphenylphosphino functional group.
Structural features, synthesis, and reactivity of Zn-biphenyl metal-organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn-biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.
Laboratory of Catalysis and Sustainable Chemistry Paul Scherrer Institute CH-5232 Villigen PSI, Switzerland. marco.ranocchiari@psi.ch
Marco
M
Ranocchiari
Jeroen Anton
JA
van Bokhoven
D001713:Biphenyl Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000494:pharmacology*; D063065:Organophosphonates / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D001713:Biphenyl Compounds; D009942:Organometallic Compounds; D063065:Organophosphonates; D015032:Zinc; C010574:biphenyl