Haloacylation of the quintuple-bonded group VI metal amidinate dimers and disproportionation of acyl groups to form carbynes.
Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013 (Taiwan).
Han-Gung
HG
Chen
Hsiang-Wen
HW
Hsueh
Ting-Shen
TS
Kuo
Yi-Chou
YC
Tsai
D000215:Acylation; D000578:Amidines / Q000737:chemistry*; D002219:Carbamates / Q000737:chemistry*; D019281:Dimerization; D006219:Halogens / Q000737:chemistry*; D008982:Molybdenum / Q000737:chemistry*
D000578:Amidines; D002219:Carbamates; D006219:Halogens; C004359:barban; D008982:Molybdenum
Friedel-Crafts addition; acyl halide; carbyne; molybdenum; quintuple bond