Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine).
Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.
Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ 08854, USA.
Ren
R
Zhang
Qihan
Q
Gong
Thomas J
TJ
Emge
Debasis
D
Banerjee
Jing
J
Li
D001966:Bromine / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015195:Drug Design; D006859:Hydrogen / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010795:Phthalic Acids / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis*
D010795:Phthalic Acids; D011108:Polymers; C059768:isophthalate; D003300:Copper; D006859:Hydrogen; D001966:Bromine