Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks.
Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ3-O)(CO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2.
Department of Chemistry, CHE205, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, USA.
Sameh K
SK
Elsaidi
Mona H
MH
Mohamed
Lukasz
L
Wojtas
Amy J
AJ
Cairns
Mohamed
M
Eddaoudi
Michael J
MJ
Zaworotko
D002245:Carbon Dioxide / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D006860:Hydrogen Bonding; D019216:Metals, Heavy / Q000737:chemistry*; D008958:Models, Molecular; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties
D002712:Chlorides; D019216:Metals, Heavy; D002245:Carbon Dioxide