Mechanistic insight into the nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids: potassium phosphate is not a spectator base but is involved in the transmetalation step in the Suzuki-Miyaura reaction.
Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Department of Chemistry, Xiamen University, Xiamen, 361005 (China) http://chem.xmu.edu.cn/group/yfzhao/zhao-home.html.
Liu Leo
LL
Liu
Shuangyan
S
Zhang
Hu
H
Chen
Ye
Y
Lv
Jun
J
Zhu
Yufen
Y
Zhao
D001897:Boronic Acids / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D007536:Isomerism; D008968:Molecular Conformation; D009532:Nickel / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D017680:Potassium Compounds / Q000737:chemistry*; D013816:Thermodynamics
D001897:Boronic Acids; D010710:Phosphates; D017680:Potassium Compounds; D002244:Carbon; D009532:Nickel; C013216:potassium phosphate
Suzuki-Miyaura reaction; cross-coupling; density functional calculations; nickel; reaction mechanisms