Non-conventional methods and media for the activation and manipulation of carbon nanoforms.
Very often, chemical transformations require tedious and long procedures, which, sometimes, can be avoided using alternative methods and media. New protocols, enabling us to save time and solvents, allow us also to explore new reaction profiles. This Tutorial Review focuses on the physical and chemical behavior of carbon nanoforms, CNFs (fullerenes, nanotubes, nanohorns, graphene, etc.) when non-conventional methods and techniques, such as microwave irradiation, mechano-chemistry or highly ionizing radiations are employed. In addition, the reactivity of CNFs in non-conventional media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed.
Departamento de Química Orgánica, Facultad de Químicas-IRICA, Universidad de Castilla-La Mancha, Campus Universitario, 13071-Ciudad Real, Spain. ester.vazquez@uclm.es.
Ester
E
Vázquez
Francesco
F
Giacalone
Maurizio
M
Prato
D002244:Carbon; D005720:Gamma Rays; D006108:Graphite; D052578:Ionic Liquids; D008872:Microwaves; D049329:Nanostructures / Q000737:chemistry*; D037742:Nanotubes, Carbon; D012997:Solvents; D014867:Water
D052578:Ionic Liquids; D037742:Nanotubes, Carbon; D012997:Solvents; D014867:Water; D002244:Carbon; D006108:Graphite