title: Superhydrophobic lignocellulosic wood fiber/mineral networks.
abstract: Lignocellulosic wood fibers and mineral fillers (calcium carbonate, talc, or clay) were used to prepare paper samples (handsheets), which were then subjected to a fluorocarbon plasma treatment. The plasma treatment was performed in two steps: first using oxygen plasma to create nanoscale roughness on the surface of the handsheet, and second fluorocarbon deposition plasma to add a layer of low surface energy material. The wetting behavior of the resulting fiber/mineral network (handsheet) was determined. It was found the samples that were subjected to oxygen plasma etching prior to fluorocarbon deposition exhibit superhydrophobicity with low contact angle hysteresis. On the other hand, those that were only treated by fluorocarbon plasma resulted in "sticky" hydrophobicity behavior. Moreover, as the mineral content in the handsheet increases, the hydrophobicity after plasma treatment decreases. Finally, it was found that although the plasma-treated handsheets show excellent water repellency they are not good water vapor barriers.
authors: Department of Chemical and Biological Engineering and Pulp and Paper Centre, The University of British Columbia , 2360 East Mall, Vancouver, BC V6T 1Z3, Canada.
authors: Mehr Negar
authors: MN
authors: Mirvakili
authors: Savvas G
authors: SG
authors: Hatzikiriakos
authors: Peter
authors: P
authors: Englezos