title: A single-molecule magnet based on heptacyanomolybdate with the highest energy barrier for a cyanide compound.
abstract: Three trinuclear Mn2Mo molecules based on the orbitally degenerate [Mo(CN)7](4-) anion were prepared, one of which is the first single-molecule magnet (SMM) based on heptacyanomolybdate. The blocking temperature and the energy barrier (U = 40.5 cm(-1)) are records for a cyanide-based SMM. Wide hysteresis loops and sharp quantum tunneling steps were observed from single-crystal measurements.
authors: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, China.
authors: Kun
authors: K
authors: Qian
authors: Xing-Cai
authors: XC
authors: Huang
authors: Chun
authors: C
authors: Zhou
authors: Xiao-Zeng
authors: XZ
authors: You
authors: Xin-Yi
authors: XY
authors: Wang
authors: Kim R
authors: KR
authors: Dunbar