title: Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group.
abstract: A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.
authors: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China. fsong@scu.edu.cn.
authors: Luo-Qiang
authors: LQ
authors: Zhang
authors: Shiping
authors: S
authors: Yang
authors: Xiaolei
authors: X
authors: Huang
authors: Jingsong
authors: J
authors: You
authors: Feijie
authors: F
authors: Song
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002227:Carbazoles / Q000737:chemistry*; D002384:Catalysis; D007211:Indoles / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D011758:Pyrroles / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D002227:Carbazoles; D007211:Indoles; D016877:Oxidants; D011758:Pyrroles; D012428:Ruthenium; D010100:Oxygen