title: Hydrogenation and disorder in engineered black TiO2.
abstract: A new form of TiO2 which is black in color has been shown to exhibit high efficiency for photocatalytic reactions under solar radiation [X. Chen, L. Liu, P. Y. Yu, and S. S. Mao, Science 331, 746 (2011)]. However, the mechanism behind this disorder-engineering process is not fully understood. In this Letter, based on density functional theory, we describe the role of hydrogen in producing lattice disorder in the anatase nanocrystals. We clarify further that the highly localized nature of the midgap states results in spatial separation of photoexcited electrons and holes in black TiO2, and that accounts for its high photocatalytic efficiency.
authors: State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, No. 3888 Dongnanhu Road, Changchun 130033, People's Republic of China.
authors: Lei
authors: L
authors: Liu
authors: Peter Y
authors: PY
authors: Yu
authors: Xiaobo
authors: X
authors: Chen
authors: Samuel S
authors: SS
authors: Mao
authors: D Z
authors: DZ
authors: Shen