title: Tetramethoxypyrene-based biradical donors with tunable physical and magnetic properties.
abstract: Synthesis of 2,7-disubstituted tetramethoxypyrene-based neutral biradical donors is reported. The biradicals were characterized by EPR, UV-vis, CV, SQUID, and single-crystal X-ray diffraction, and their optical, electrochemical, and structural properties were compared and discussed. The experimental results are well supported by DFT calculations. Systematic tuning of magnetic exchange interactions was achieved by varying the radical moieties.
authors: Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
authors: Prince
authors: P
authors: Ravat
authors: Yoshikazu
authors: Y
authors: Ito
authors: Elena
authors: E
authors: Gorelik
authors: Volker
authors: V
authors: Enkelmann
authors: Martin
authors: M
authors: Baumgarten