title: Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH···F bonds.
abstract: Bis-pyridazine tectons support the structure of metallosupramolecular cavitand Cu2L4(4+), which is capable of selective encapsulation of SiF6(2-) anions by a set of multiple host-guest interactions.
authors: Inorganic Chemistry Dpt, Taras Shevchenko National University of Kyiv, Volodymyrska Str. 64/13, Kyiv 01601, Ukraine. dk@univ.kiev.ua.
authors: Anna S
authors: AS
authors: Degtyarenko
authors: Eduard B
authors: EB
authors: Rusanov
authors: Antonio
authors: A
authors: Bauzá
authors: Antonio
authors: A
authors: Frontera
authors: Harald
authors: H
authors: Krautscheid
authors: Alexander N
authors: AN
authors: Chernega
authors: Andriy A
authors: AA
authors: Mokhir
authors: Konstantin V
authors: KV
authors: Domasevitch
mesh_terms: D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D004988:Ethers, Cyclic / Q000737:chemistry*; D005459:Fluorides / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D011724:Pyridazines / Q000737:chemistry; D012118:Resorcinols / Q000737:chemistry*; D012824:Silicic Acid / Q000737:chemistry*
chemical_list: D000838:Anions; D004988:Ethers, Cyclic; D011724:Pyridazines; D012118:Resorcinols; C442939:cavitand; D012824:Silicic Acid; C004832:hexafluorosilicate; D005461:Fluorine; C062482:pyridazine; D005459:Fluorides