title: Solid-state NMR concepts for the investigation of supported transition metal catalysts and nanoparticles.
abstract: In recent years, solid-state NMR spectroscopy has evolved into an important characterization tool for the study of solid catalysts and chemical processes on their surface. This interest is mainly triggered by the need of environmentally benign organic transformations ("green chemistry"), which has resulted in a large number of new catalytically active hybrid materials, which are organized on the meso- and nanoscale. Typical examples of these catalysts are supported homogeneous transition metal catalysts or transition metal nanoparticles (MNPs). Solid-state NMR spectroscopy is able to characterize both the structures of these materials and the chemical processes on the catalytic surface. This article presents recent trends both on the characterization of immobilized homogeneous transition metal catalysts and on the characterization of surface species on transition metal surfaces.
authors: Institute of Physical Chemistry, Technical University Darmstadt, Petersenstrasse 22, D-64287 Darmstadt, Germany.
authors: Torsten
authors: T
authors: Gutmann
authors: Anna
authors: A
authors: Grünberg
authors: Niels
authors: N
authors: Rothermel
authors: Mayke
authors: M
authors: Werner
authors: Mohamad
authors: M
authors: Srour
authors: Safaa
authors: S
authors: Abdulhussain
authors: Shulin
authors: S
authors: Tan
authors: Yeping
authors: Y
authors: Xu
authors: Hergen
authors: H
authors: Breitzke
authors: Gerd
authors: G
authors: Buntkowsky
keywords: (2)H solid-state NMR; Heterogeneous catalysis; Immobilized catalyst; Solid state NMR; Transition metal nanoparticles