title: Base-stabilized boryl and cationic haloborylene complexes of iron.
abstract: The synthesis of base-stabilized boryl and borylene complexes is reported. An N-heterocyclic carbene (NHC)-stabilized iron-dihydroboryl complex was prepared by two different routes including methane liberation and salt elimination. A range of base-stabilized iron-dichloroboryl complexes was prepared by addition of Lewis bases to boryl complexes. Base-stabilized, cationic monochloroborylene complexes were synthesized from these boryl complexes by halide abstraction by using weakly coordinating anions.
authors: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg (Germany), Fax: (+49) 931-31-84623.
authors: Philipp
authors: P
authors: Bissinger
authors: Holger
authors: H
authors: Braunschweig
authors: Alexander
authors: A
authors: Damme
authors: Rian D
authors: RD
authors: Dewhurst
authors: Katharina
authors: K
authors: Kraft
authors: Thomas
authors: T
authors: Kramer
authors: Krzysztof
authors: K
authors: Radacki
keywords: boron; boryl complexes; borylene complexes; carbenes; iron