title: Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect.
abstract: A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
authors: Département de Chimie, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1. Pierre.Harvey@USherbrooke.ca.
authors: Antony
authors: A
authors: Lapprand
authors: Antoine
authors: A
authors: Bonnot
authors: Michael
authors: M
authors: Knorr
authors: Youann
authors: Y
authors: Rousselin
authors: Marek M
authors: MM
authors: Kubicki
authors: Daniel
authors: D
authors: Fortin
authors: Pierre D
authors: PD
authors: Harvey
mesh_terms: D001965:Bromides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D049408:Luminescent Agents / Q000737:chemistry; D008958:Models, Molecular; D011108:Polymers / Q000737:chemistry*; D017641:Zeolites / Q000737:chemistry*
chemical_list: D001965:Bromides; D006219:Halogens; D049408:Luminescent Agents; D011108:Polymers; D017641:Zeolites; D003300:Copper