title: Carboxylated multiwalled carbon nanotubes/polydimethylsiloxane, a new coating for 96-blade solid-phase microextraction for determination of phenolic compounds in water.
abstract: A new thin-film, carboxylated multiwalled carbon nanotubes/polydimethylsiloxane (MWCNTs-COOH/PDMS) coating was developed for 96-blade solid-phase microextraction (SPME) system followed by high performance liquid chromatography with ultraviolet detection (HPLC-UV). The method provided good extraction efficiency (64-90%) for three spiked levels, with relative standard deviations (RSD)≤6%, and detection limits between 1 and 2 μg/L for three phenolic compounds. The MWCNTs-COOH/PDMS 96-blade SPME system presents advantages over traditional methods due to its simplicity of use, easy coating preparation, low cost and high sample throughput (2.1 min per sample). The developed coating is reusable for a minimum of 110 extractions with good extraction efficiency. The coating provided higher extraction efficiency (3-8 times greater) than pure PDMS coatings.
authors: Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1, Canada; School of Science, Walailak University, Thasala, Nakhon Si Thammarat 80161, Thailand.
authors: Pamornrat
authors: P
authors: Kueseng
authors: Janusz
authors: J
authors: Pawliszyn
mesh_terms: D002851:Chromatography, High Pressure Liquid; D004129:Dimethylpolysiloxanes / Q000737:chemistry*; D017743:Equipment Reuse; D006863:Hydrogen-Ion Concentration; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010636:Phenols / Q000032:analysis* / Q000737:chemistry / Q000302:isolation & purification*; D015203:Reproducibility of Results; D045483:Rivers / Q000737:chemistry*; D052617:Solid Phase Microextraction / Q000295:instrumentation* / Q000379:methods; D013995:Time
chemical_list: D004129:Dimethylpolysiloxanes; D037742:Nanotubes, Carbon; D010636:Phenols; C013830:baysilon
keywords: Carboxylated multiwalled carbon nanotubes; Phenolic compounds; Polydimethylsiloxane; Solid-phase microextraction