title: Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols.
abstract: Azatitanacyclopropanes (titanaziridines) are shown to be stereochemically labile under reaction conditions for reductive cross-coupling. This fundamental property has been employed to realize highly selective asymmetric coupling reactions with allylic alcohols that proceed by dynamic kinetic resolution.
authors: Department of Chemistry, Dartmouth College, Hanover, NH 03755, USA. glenn.c.micalizio@dartmouth.edu.
authors: Dexi
authors: D
authors: Yang
authors: Glenn C
authors: GC
authors: Micalizio
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D001388:Aziridines / Q000737:chemistry*; D003521:Cyclopropanes / Q000737:chemistry*; D010084:Oxidation-Reduction; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001372:Aza Compounds; D001388:Aziridines; D003521:Cyclopropanes; D020005:Propanols; C006463:allyl alcohol
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