title: Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates.
abstract: New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar = o-, m-, p-CH3C6H4 and p-Cl-m-CH3C6H3; n = 1, L = N2C12H8, N2C10H8; n = 2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, thermogravimetric, cyclic voltammetry, and spectral analyses including ESI mass spectrometry, IR, and UV-visible. The presence of a four-and-six coordinated Mn atoms has been established in the complexes and adducts, respectively. Antimicrobial screening of the complexes against gram negative bacteria E. coli, K. pneumonia, and P. aeruginosa and fungus S. rolfsii has shown potential bioactivity.
authors: Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu and Kashmir 180 006, India.
authors: Ruchi
authors: R
authors: Khajuria
authors: Atiya
authors: A
authors: Syed
authors: Sandeep
authors: S
authors: Kumar
authors: Sushil K
authors: SK
authors: Pandey
references: J Nanosci Nanotechnol. 2009 Apr;9(4):2682-91
references: 19438021
references: Phytopathology. 1968 Nov;58(11):1522-31
references: 5693314
references: Biochemistry. 1997 Aug 12;36(32):9847-58
references: 9245417