title: Palladium and organocatalysis: an excellent recipe for asymmetric synthesis.
abstract: The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric a-allylation of carbonyl compounds, a-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology.
authors: Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, Madrid 28049, Spain.
authors: M Angeles
authors: MA
authors: Fernández-Ibañez
authors: Beatriz
authors: B
authors: Maciá
authors: Diego A
authors: DA
authors: Alonso
authors: Isidro M
authors: IM
authors: Pastor
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D000478:Alkylation; D000498:Allyl Compounds / Q000138:chemical synthesis*; D002384:Catalysis; D054879:Halogenation; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis*; D008956:Models, Chemical; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D000498:Allyl Compounds; D006845:Hydrocarbons, Fluorinated; D010165:Palladium
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