title: Fate of a giant {Mo72Fe30}-type polyoxometalate cluster in an aqueous solution at higher temperature: understanding related Keplerate chemistry, from molecule to material.
abstract: When the giant icosahedral {Mo72Fe30} cluster containing compound [Mo72Fe30O252(CH3COO)12{Mo2O7(H2O)}2{H2Mo2O8(H2O)}(H2O)91]·150H2O (1) is refluxed in water for 36 h, it results in the formation of nanoiron molybdate, Fe2(MoO4)3, in the form of a yellow precipitate; this simple approach not only generates nanoferric molybdate at a moderate temperature but also helps to understand the stability of {Mo72Fe30} in terms of the linker-pentagon complementary relationship.
authors: School of Chemistry, University of Hyderabad, P.O. Central University, Hyderabad 500046, India.
authors: Raju
authors: R
authors: Mekala
authors: Sabbani
authors: S
authors: Supriya
authors: Samar K
authors: SK
authors: Das
mesh_terms: D006358:Hot Temperature; D058085:Iron Compounds / Q000737:chemistry*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D017973:Tungsten Compounds / Q000737:chemistry*; D014867:Water / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D058085:Iron Compounds; D008982:Molybdenum; D017973:Tungsten Compounds; D014867:Water; C102296:polyoxometalate I; D000099294:Polyoxometalates; C044659:molybdate