title: Second generation synthesis of the neo-clerodane diterpenoid methyl barbascoate.
abstract: The second generation total synthesis of the neo-clerodane diterpenoid, methyl barbascoate, was accomplished in seven or nine linear steps via double enol triflation and subsequent palladium catalyzed double carbonylation, followed by regioselective samarium diiodide mediated conjugate reduction.
authors: Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Nishi-ku, Niigata 950-2181, Japan. hagiwara@gs.niigata-u.ac.jp
authors: Hisahiro
authors: H
authors: Hagiwara
authors: Naomi
authors: N
authors: Honma
authors: Kimihiko
authors: K
authors: Kinugawa
authors: Shota
authors: S
authors: Sato
authors: Takashi
authors: T
authors: Hoshi
authors: Toshio
authors: T
authors: Suzuki
mesh_terms: D005663:Furans / Q000138:chemical synthesis*; D006575:Heterocyclic Compounds, 3-Ring / Q000138:chemical synthesis*
chemical_list: D005663:Furans; D006575:Heterocyclic Compounds, 3-Ring; C500921:methyl barbascoate