title: Cu-catalyzed cross-dehydrogenative coupling reactions of (benzo)thiazoles with cyclic ethers.
abstract: Copper-catalyzed cross-dehydrogenative coupling (CDC) reactions of (benzo)thiazoles with cyclic ethers were developed under mild conditions. In particular, the formation of C-C bonds via the CDC reactions between non-benzo-fused azoles and ethers are reported for the first time. In addition, the acetals, known as the masked 2-thiazolecarboxaldehydes, could be successfully obtained by this CDC reaction. The preliminary mechanism and supportive DFT calculations are discussed as well.
authors: Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, PR China, 210093.
authors: Zengyang
authors: Z
authors: Xie
authors: Yuping
authors: Y
authors: Cai
authors: Hongwen
authors: H
authors: Hu
authors: Chen
authors: C
authors: Lin
authors: Juli
authors: J
authors: Jiang
authors: Zhaoxu
authors: Z
authors: Chen
authors: Leyong
authors: L
authors: Wang
authors: Yi
authors: Y
authors: Pan