title: Across the structural re-entrant transition in BaFe2(PO4)2: influence of the two-dimensional ferromagnetism.
abstract: BaFe2(PO4)2 was recently prepared by hydrothermal synthesis and identified as the first two-dimensional (2D) Ising ferromagnetic oxide, in which honeycomb layers made up of edge-sharing FeO6 octahedra containing high-spin Fe(2+) ions (S = 2) are isolated by PO4 groups and Ba(2+) cations. BaFe2(PO4)2 has a trigonal R-3 structure at room temperature but adopts a triclinic P-1 structure below 140 K due to the Jahn-Teller (JT) instability arising from the (t2g)(4)(eg)(2) configuration. The triclinic crystal structure was refined to find significantly distorted Fe(2+)O6 octahedra in the honeycomb layers while the distortion amplitude QJT was estimated to 0.019 Å. The JT stabilization energy is estimated to be ∼7 meV per formula unit by DFT calculations. Below ∼70 K, very close to the ferromagnetic transition temperature Tc = 65.5 K, the structure of BaFe2(PO4)2 returns to a trigonal R-3 structure in the presence of significant ferromagnetic domains. This rare re-entrant structural transition is accompanied by a discontinuous change in the quadrupolar splitting of Fe(2+), as determined by Mössbauer spectroscopy. EPR measurements show the presence of magnetic domains well above Tc , as expected for a ferromagnetic 2D Ising system, and support that the magnetism of BaFe2(PO4)2 is uniaxial (g⊥ = 0).
authors: Université Lille Nord de France, UCCS, UMR-CNRS 8181, ENSCL-USTL, Villeneuve d'Ascq, France.
authors: Rénald
authors: R
authors: David
authors: Alain
authors: A
authors: Pautrat
authors: Dmitry
authors: D
authors: Filimonov
authors: Houria
authors: H
authors: Kabbour
authors: Hervé
authors: H
authors: Vezin
authors: Myung-Hwan
authors: MH
authors: Whangbo
authors: Olivier
authors: O
authors: Mentré