title: Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions.
abstract: The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.
authors.affiliation: Graduate School of Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan.
authors.forename: Katsunori
authors.initials: K
authors.lastname: Yamanishi
authors.forename: Takeshi
authors.initials: T
authors.lastname: Yairi
authors.forename: Keisuke
authors.initials: K
authors.lastname: Suzuki
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Kondo
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry* / Q000378:metabolism; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D018360:Crystallography, X-Ray; D006900:Hydroxylation; D008024:Ligands; D008968:Molecular Conformation; D011166:Porphyrins / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D011166:Porphyrins; D002244:Carbon; D003300:Copper