title: Temperature influences epimerization and composition of flavanol monomers, dimers and trimers during cocoa bean roasting.
abstract: Cocoa consumption is suggested to promote many health benefits, since cocoa is a rich source of flavanols; but amounts and profiles of flavanols depend strongly on the bean type, origin and manufacturing process. Roasting is known as a crucial step in technical treatment of cocoa, which leads to flavanol losses and modifications, especially the epimerization of (-)-epicatechin to (-)-catechin. This study monitors the influence of cocoa bean roasting on the composition of flavanol monomers to trimers, with special focus on epimerization, which was quantified for procyanidin dimers, and also observed for trimers for the first time. Five dimeric and two trimeric potential epimerization products were detected and the extent of epimerization during cocoa roasting was shown to be a function of temperature. The data also showed remarkable variations in the change of flavanol content. The quantified flavanols decreased about 50% in Java beans and increased about 30% in Ivory Coast beans, despite being roasted under equal conditions.
authors.affiliation: Department of Nutrition and Food Sciences - Food Chemistry, University of Bonn, Endenicher Allee 11-13, 53115 Bonn, Germany.
authors.forename: Lisa
authors.initials: L
authors.lastname: Kothe
authors.forename: Benno F
authors.initials: BF
authors.lastname: Zimmermann
authors.forename: Rudolf
authors.initials: R
authors.lastname: Galensa
mesh_terms: D002099:Cacao / Q000737:chemistry*; D003296:Cooking / Q000379:methods*; D005419:Flavonoids / Q000737:chemistry*; D006358:Hot Temperature; D010936:Plant Extracts / Q000737:chemistry*
chemical_list: D005419:Flavonoids; D010936:Plant Extracts
keywords: Capillary electrophoresis; Cocoa; Epimerization; Flavanols; Procyanidins; Roasting; Stereochemistry; UHPLC-MS/MS