title: Change of the magnetic coupling of a metal-organic complex with the substrate by a stepwise ligand reaction.
abstract: The surface-assisted intramolecular ligand reaction of a porphyrin molecule adsorbed on Au(111) is studied by scanning tunneling microscopy and spectroscopy. The temperature-induced stepwise transformation of iron octaethylporphyrin proceeds via a concentric electrocyclic ring closure, with the final product iron tetrabenzoporphyrin being identified by its characteristic Kondo resonance. Along with the transformation of the organic ligand, changes in the magnetic fingerprint are observed, indicating an increasing coupling of the iron spin with the substrate electrons.
authors.affiliation: Institut für Experimentalphysik, Freie Universität Berlin , Arnimallee 14, 14195 Berlin, Germany.
authors.forename: Benjamin W
authors.initials: BW
authors.lastname: Heinrich
authors.forename: Gelavizh
authors.initials: G
authors.lastname: Ahmadi
authors.forename: Valentin L
authors.initials: VL
authors.lastname: Müller
authors.forename: Lukas
authors.initials: L
authors.lastname: Braun
authors.forename: José I
authors.initials: JI
authors.lastname: Pascual
authors.forename: Katharina J
authors.initials: KJ
authors.lastname: Franke
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D006046:Gold / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D060328:Magnetic Phenomena; D016252:Microscopy, Scanning Tunneling; D008958:Models, Molecular; D011166:Porphyrins / Q000737:chemistry* / Q000378:metabolism
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D011166:Porphyrins; D006046:Gold; D007501:Iron