title: Construction of 2-substituted-3-functionalized benzofurans via intramolecular Heck coupling: application to enantioselective total synthesis of daphnodorin B.
abstract: A novel approach was developed for the synthesis of 2-substituted-3-functionalized benzofurans, using an intramolecular Heck reaction which was further applied in the first enantioselective total synthesis of Daphnodorin B.
authors.affiliation: Department of Phytochemistry, School of Pharmacy, Second Military Medical University , Shanghai 200433, China, School of Pharmacy, Shanghai Jiao Tong University , Shanghai 200240, China, and Department of Organic Chemistry, School of Pharmacy, Second Military Medical University , Shanghai 200433, China.
authors.forename: Hu
authors.initials: H
authors.lastname: Yuan
authors.forename: Kai-Jian
authors.initials: KJ
authors.lastname: Bi
authors.forename: Bo
authors.initials: B
authors.lastname: Li
authors.forename: Rong-Cai
authors.initials: RC
authors.lastname: Yue
authors.forename: Ji
authors.initials: J
authors.lastname: Ye
authors.forename: Yun-Heng
authors.initials: YH
authors.lastname: Shen
authors.forename: Lei
authors.initials: L
authors.lastname: Shan
authors.forename: Hui-Zi
authors.initials: HZ
authors.lastname: Jin
authors.forename: Qing-Yan
authors.initials: QY
authors.lastname: Sun
authors.forename: Wei-Dong
authors.initials: WD
authors.lastname: Zhang
mesh_terms: D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry; D001578:Benzopyrans / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D001572:Benzofurans; D001578:Benzopyrans; D010165:Palladium; C055028:daphnodorin B