title: Direct arylation of primary and secondary sp3 C-H bonds with diarylhyperiodonium salts via Pd catalysis.
abstract: Palladium-catalyzed primary and secondary sp(3) C-H bond arylation is reported. The method using diarylhyperiodonium salts as arylation reagents shows good functional group tolerance and proceeds under mild reaction conditions. The KIE experiments show that the C-H bond activation is the rate-determining step.
authors.affiliation: Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Education, College of Chemistry and Green Chemistry Center, Peking University , Beijing 100871, China, and State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences , Shanghai 200032, China.
authors.forename: Fei
authors.initials: F
authors.lastname: Pan
authors.forename: Peng-Xiang
authors.initials: PX
authors.lastname: Shen
authors.forename: Li-Sheng
authors.initials: LS
authors.lastname: Zhang
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.forename: Zhang-Jie
authors.initials: ZJ
authors.lastname: Shi