title: A corrole-azafullerene dyad: synthesis, characterization, electronic interactions and photoinduced charge separation.
abstract: The preparation and characterization of the first corrole-azafullerene dyad are described. The photophysical and electrochemical properties of the new corrole-C59N dyad were examined and it was found that photoexcitation of the corrole unit leads to the formation of a charge separated state.
authors.affiliation: Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, Athens 11635, Greece. tagmatar@eie.gr.
authors.forename: Georgios
authors.initials: G
authors.lastname: Rotas
authors.forename: Georgios
authors.initials: G
authors.lastname: Charalambidis
authors.forename: Lukas
authors.initials: L
authors.lastname: Glätzl
authors.forename: Daniel T
authors.initials: DT
authors.lastname: Gryko
authors.forename: Axel
authors.initials: A
authors.lastname: Kahnt
authors.forename: Athanassios G
authors.initials: AG
authors.lastname: Coutsolelos
authors.forename: Nikos
authors.initials: N
authors.lastname: Tagmatarchis
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D055664:Electrochemical Techniques; D004583:Electrons; D037741:Fullerenes / Q000737:chemistry*; D008027:Light; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D013816:Thermodynamics
chemical_list: D001372:Aza Compounds; D037741:Fullerenes; D011166:Porphyrins; C431863:corrole