title: High-pressure carbon dioxide uptake for porous organic cages: comparison of spectroscopic and manometric measurement techniques.
abstract: A chemoselective spectroscopic method for measuring CO2 sorption isotherms at pressures up to 14 MPa (140 bar) is validated against manometric measurements and molecular simulations, giving insights into the preferred sorption sites in various crystalline porous organic cages.
authors.affiliation: University of Liverpool, Department of Chemistry and Centre for Materials Discovery, Liverpool L69 7ZD, UK. aicooper@liverpool.com.
authors.forename: Tom
authors.initials: T
authors.lastname: Hasell
authors.forename: Jayne A
authors.initials: JA
authors.lastname: Armstrong
authors.forename: Kim E
authors.initials: KE
authors.lastname: Jelfs
authors.forename: Feng H
authors.initials: FH
authors.lastname: Tay
authors.forename: K Mark
authors.initials: KM
authors.lastname: Thomas
authors.forename: Sergei G
authors.initials: SG
authors.lastname: Kazarian
authors.forename: Andrew I
authors.initials: AI
authors.lastname: Cooper
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D002623:Chemistry Techniques, Analytical / Q000379:methods*; D003500:Cyclization; D007097:Imines / Q000737:chemistry; D008365:Manometry; D016062:Porosity; D017550:Spectroscopy, Fourier Transform Infrared; D013057:Spectrum Analysis / Q000592:standards*
chemical_list: D007097:Imines; D002245:Carbon Dioxide