title: Free-radical variant for the synthesis of functionalized 1,5-diketones.
abstract: A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , Singapore 637371, Singapore, and Laboratoire de Synthèse Organique, CNRS UMR 7652 Ecole Polytechnique , 91128 Palaiseau Cedex, France.
authors.forename: Kelvin Kau Kiat
authors.initials: KK
authors.lastname: Goh
authors.forename: Sunggak
authors.initials: S
authors.lastname: Kim
authors.forename: Samir Z
authors.initials: SZ
authors.lastname: Zard
mesh_terms: D000473:Alkanes / Q000737:chemistry; D005609:Free Radicals; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D011725:Pyridines / Q000138:chemical synthesis / Q000737:chemistry; D014970:Xanthines / Q000737:chemistry
chemical_list: D000473:Alkanes; D005609:Free Radicals; D007659:Ketones; D063065:Organophosphonates; D011725:Pyridines; D014970:Xanthines