title: Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction.
abstract: Neutron powder diffraction measurements were carried out on the evacuated and CO2-loaded Prussian blue analogue, Fe3[Co(CN)6]2, identifying two distinct CO2 adsorption sites: site A, in which CO2 uniquely bridges between two bare-metal sites, and site B, in which it interacts in a face capping motif. The saturation of site A at low loadings of CO2 demonstrates the favourable nature of the interaction of CO2 with bare-metal sites within the material.
authors.affiliation: School of Chemistry, The University of Sydney, NSW 2006, Australia. cameron.kepert@sydney.edu.au.
authors.forename: Stephen H
authors.initials: SH
authors.lastname: Ogilvie
authors.forename: Samuel G
authors.initials: SG
authors.lastname: Duyker
authors.forename: Peter D
authors.initials: PD
authors.lastname: Southon
authors.forename: Vanessa K
authors.initials: VK
authors.lastname: Peterson
authors.forename: Cameron J
authors.initials: CJ
authors.lastname: Kepert