title: Rheology and synergy of κ-carrageenan/locust bean gum/konjac glucomannan gels.
abstract: The rheology and melting of mixed polysaccharide gels containing konjac glucomannan (KGM), locust bean gum (LBG) and κ-carrageenan (KC) were studied. Synergy-type peaks in the Young's modulus at optimal mixing ratios were found for both KC/LBG and KC/KGM binary gels at a fixed total polysaccharide content (1:5.5 for LBG:KC and 1:7 for KGM:KC). The Young's modulus peak for KC/KGM was higher than for KC/LBG gels. The same stoichiometric mixing ratios were found when either LBG or KGM was added to KC at a fixed KC concentration, where the Young's modulus increased up to additions at the stoichiometric ratio, but leveled off at higher LBG or KGM additions. Addition of KGM or LBG to the 2-component gels beyond the stoichiometric (optimal) mixing ratio at a fixed total polysaccharide content led to a decrease in the Young's modulus and an increase in the rupture strain and stress in extension, and both trends were stronger for KGM than for LBG. Differential scanning calorimetry of the gels revealed the development of a second melting peak for the KC/KGM gels that increased with KGM addition up to higher KGM contents than the stoichiometric ratio. For the KC/LBG gels, only a slight broadening and shift to a higher temperature were observed. When the three polysaccharides were mixed, the DSC endotherms reflected only the main features of the interaction between KC and KGM, and the same was true for the fracture in extension. The different trends led to higher Young's moduli at intermediate KC concentrations when a 1:1 addition of LBG:KGM was used than when either only KGM or LBG was added at a fixed total polysaccharide concentration. This suggests that no special interactions arise when the three polysaccharides are mixed and the binding mechanisms are simply a sum of the bindings observed for KC/KGM and KC/LBG two-component gels.
authors.affiliation: Graduate School of Human Life Science, Osaka City University, Osaka, Japan. physicalchemistrytom@gmail.com
authors.forename: Tom
authors.initials: T
authors.lastname: Brenner
authors.forename: Zheng
authors.initials: Z
authors.lastname: Wang
authors.forename: Piyada
authors.initials: P
authors.lastname: Achayuthakan
authors.forename: Tetsuya
authors.initials: T
authors.lastname: Nakajima
authors.forename: Katsuyoshi
authors.initials: K
authors.lastname: Nishinari
mesh_terms: D002351:Carrageenan / Q000737:chemistry*; D005685:Galactans / Q000737:chemistry*; D005782:Gels; D008351:Mannans / Q000737:chemistry*; D055595:Mechanical Phenomena; D053149:Plant Gums / Q000737:chemistry*; D012212:Rheology
chemical_list: D005685:Galactans; D005782:Gels; D008351:Mannans; D053149:Plant Gums; C022901:(1-6)-alpha-glucomannan; D002351:Carrageenan; C017471:locust bean gum
keywords: Heterotypic binding; Konjac glucomannan; Locust bean gum; Mixed gels; Synergy; κ-Carrageenan