title: Adsorption-desorption and leaching of pyraclostrobin in Indian soils.
abstract: Pyraclostrobin is a new broad-spectrum foliar applied and seed protectant fungicide of the strobilurin group. In this paper, adsorption-desorption of pyraclostrobin has been investigated in three different soils viz. Inceptisol (sandy loam, Delhi), Vertisol (sandy clay, Hyderabad) and Ultisol (sandy clay loam, Thrissur). Effect of organic matter and clay content on sorption was also studied in Inceptisol of Delhi. Leaching potential of pyraclostrobin as influenced by rainfall was studied in intact soil columns to confirm the results of adsorption-desorption studies. The adsorption studies were carried out at initial concentrations of 0.05, 0.1, 0.5, 1 and 1.5 μg mL(-1). The distribution coefficient (Kd) values in three test soils ranged from 4.91 to 18.26 indicating moderate to high adsorption. Among the three test soils, adsorption was the highest in Ultisol (Kd 18.26), followed by Vertisol (Kd 9.87) and Inceptisol (Kd 4.91). KF value was also highest for Ultisol soil (66.21), followed by Vertisol (40.88) and Inceptisol (8.59). S-type adsorption isotherms were observed in all the three test soils. Kd values in organic carbon-removed soil and clay-removed soil were 3.57 and 2.83 respectively, indicating lower adsorption than normal Inceptisol. Desorption studies were carried out at initial concentrations of 0.5, 1 and 1.5 μg mL(-1). Desorption was the greatest in Inceptisol, followed by Vertisol and Ultisol. Amounts of pyraclostrobin desorbed in three desorption cycles for different concentrations were 23.1-25.3%, 9.4-20.7% and 8.1-13.6% in Inceptisol, Vertisol and Ultisol respectively. Desorption was higher in clay fraction-removed and organic carbonremoved soils than normal Inceptisol. Desorption was slower than adsorption in all the test soils, indicating hysteresis effect (with hysteresis coefficient values varying from 0.05 to 0.20). Low values of hysteresis coefficient suggest high hysteresis effect indicating easy and strong adsorption, and slow desorption, of pyraclostrobin in soils. Higher hysteresis coefficient values in organic carbon removed soil (0.25-0.30) and clay fraction removed soil (0.28-0.36) as compared to normal Inceptisol soil suggest relatively weak adsorption and easy desorption of pyraclostrobin. Results of regression analysis suggest that the organic matter and pH of the soil play a major role in adsorption of pyraclostrobin. Leaching studies were carried out in intact soil columns in Inceptisol. The columns were leached with different amounts of water simulating different amounts of rainfall. The results suggest that most of the pyraclostrobin residues will remain present in the top soil layers even under high rainfall conditions and chances of pyraclostrobin moving to lower soil depth are almost negligible.
authors.affiliation: Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, India.
authors.forename: S Navakishore
authors.initials: SN
authors.lastname: Reddy
authors.forename: Suman
authors.initials: S
authors.lastname: Gupta
authors.forename: Vijay T
authors.initials: VT
authors.lastname: Gajbhiye
mesh_terms: D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry; D002219:Carbamates / Q000737:chemistry*; D000077215:Clay; D004784:Environmental Monitoring; D005659:Fungicides, Industrial / Q000737:chemistry*; D007194:India; D011720:Pyrazoles / Q000737:chemistry*; D011891:Rain; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D000073739:Strobilurins
chemical_list: D000538:Aluminum Silicates; D002219:Carbamates; D005659:Fungicides, Industrial; D011720:Pyrazoles; D012987:Soil; D012989:Soil Pollutants; D000073739:Strobilurins; C513428:pyrachlostrobin; D000077215:Clay