title: Highly diastereoselective radical cyclisations of chiral sulfinimines.
abstract: Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines.
authors.affiliation: School of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK. Robert.stockman@nottingham.ac.uk.
authors.forename: Elise M
authors.initials: EM
authors.lastname: Rochette
authors.forename: William
authors.initials: W
authors.lastname: Lewis
authors.forename: Al G
authors.initials: AG
authors.lastname: Dossetter
authors.forename: Robert A
authors.initials: RA
authors.lastname: Stockman
mesh_terms: D000588:Amines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005609:Free Radicals / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013452:Sulfonium Compounds / Q000737:chemistry*
chemical_list: D000588:Amines; D005609:Free Radicals; D007097:Imines; D013452:Sulfonium Compounds; C522016:sulfinimine