title: A direct digital synthesis chirped pulse Fourier transform microwave spectrometer.
abstract: Chirped pulse Fourier transform microwave (CP-FTMW) spectrometers have become the instrument of choice for acquiring rotational spectra, due to their high sensitivity, fast acquisition rate, and large bandwidth. Here we present the design and capabilities of a recently constructed CP-FTMW spectrometer using direct digital synthesis (DDS) as a new method for chirped pulse generation, through both a suite of extensive microwave characterizations and deep averaging of the 10-14 GHz spectrum of jet-cooled acetone. The use of DDS is more suited for in situ applications of CP-FTMW spectroscopy, as it reduces the size, weight, and power consumption of the chirp generation segment of the spectrometer all by more than an order of magnitude, while matching the performance of traditional designs. The performance of the instrument was further improved by the use of a high speed digitizer with dedicated signal averaging electronics, which facilitates a data acquisition rate of 2.1 kHz.
authors.affiliation: Department of Chemistry, California Institute of Technology, Pasadena, California 91125, USA.
authors.forename: Ian A
authors.initials: IA
authors.lastname: Finneran
authors.forename: Daniel B
authors.initials: DB
authors.lastname: Holland
authors.forename: P Brandon
authors.initials: PB
authors.lastname: Carroll
authors.forename: Geoffrey A
authors.initials: GA
authors.lastname: Blake