title: Superarming of glycosyl donors by combined neighboring and conformational effects.
abstract: A novel glycosyl donor that combines the concepts of both conformational and electronic superarming has been synthesized. The reactivity and selectivity of the donor have been tested in competition experiments.
authors.affiliation: Department of Chemistry, University of Copenhagen , 2100 Copenhagen Ø, Denmark, and Department of Chemistry and Biochemistry, University of Missouri-St. Louis , One University Boulevard, St. Louis, Missouri 63121, United States.
authors.forename: Mads
authors.initials: M
authors.lastname: Heuckendorff
authors.forename: Hemali D
authors.initials: HD
authors.lastname: Premathilake
authors.forename: Papapida
authors.initials: P
authors.lastname: Pornsuriyasak
authors.forename: Anders Ø
authors.initials: AØ
authors.lastname: Madsen
authors.forename: Christian M
authors.initials: CM
authors.lastname: Pedersen
authors.forename: Mikael
authors.initials: M
authors.lastname: Bols
authors.forename: Alexei V
authors.initials: AV
authors.lastname: Demchenko
mesh_terms: D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry*; D006031:Glycosylation; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D006027:Glycosides