title: New trends in the kitchen: propellants assessment of edible food aerosol sprays used on food.
abstract: New products available for food creations include a wide variety of "supposed" food grade aerosol sprays. However, the gas propellants used cannot be considered as safe. The different legislations available did not rule any maximum residue limits, even though these compounds have some limits when used for other food purposes. This study shows a preliminary monitoring of propane, butane and dimethyl ether residues, in cakes and chocolate after spraying, when these gases are used as propellants in food aerosol sprays. Release kinetics of propane, butane and dimethyl ether were measured over one day with sprayed food, left at room temperature or in the fridge after spraying. The alkanes and dimethyl ether analyses were performed by headspace-gas chromatography-mass spectrometry/thermal conductivity detection, using monodeuterated propane and butane generated in situ as internal standards. According to the obtained results and regardingthe extrapolations of the maximum residue limits existing for these substances, different delays should be respected according to the storage conditions and the gas propellant to consume safely the sprayed food.
authors.affiliation: Forensic Toxicology and Chemistry Unit, University Center of Legal Medicine Lausanne - Geneva, CH-1011 Lausanne, Switzerland. vincent.varlet@chuv.ch
authors.forename: V
authors.initials: V
authors.lastname: Varlet
authors.forename: F
authors.initials: F
authors.lastname: Smith
authors.forename: M
authors.initials: M
authors.lastname: Augsburger
mesh_terms: D000336:Aerosols / Q000032:analysis*; D002073:Butanes / Q000737:chemistry*; D003296:Cooking / Q000295:instrumentation* / Q000331:legislation & jurisprudence; D005503:Food Additives / Q000737:chemistry*; D005506:Food Contamination / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D007700:Kinetics; D008738:Methyl Ethers / Q000737:chemistry*; D011407:Propane / Q000737:chemistry*
chemical_list: D000336:Aerosols; D002073:Butanes; D005503:Food Additives; D008738:Methyl Ethers; C046888:butane; C033413:dimethyl ether; D011407:Propane
keywords: Butane; Dimethyl ether; Food aerosol spray; Gas analysis; Propane; Propellants assessment