title: Radon emanation fractions from concretes containing fly ash and metakaolin.
abstract: Radon ((222)Rn) and progenies emanate from soil and building components and can create an indoor air quality hazard. In this study, nine concrete constituents, including the supplementary cementitious materials (SCMs) fly ash and metakaolin, were used to create eleven different concrete mixtures. We investigated the effect of constituent radium specific activity, radon effective activity and emanation fraction on the concrete emanation fraction and the radon exhalation rate. Given the serious health effects associated with radionuclide exposure, experimental results were coupled with Monte Carlo simulations to demonstrate predictive differences in the indoor radon concentration due to concrete mixture design. The results from this study show that, on average, fly ash constituents possessed radium specific activities ranging from 100 Bq/kg to 200 Bq/kg and emanation fractions ranging from 1.1% to 2.5%. The lowest emitting concrete mixture containing fly ash resulted in a 3.4% reduction in the concrete emanation fraction, owing to the relatively low emanation that exists when fly ash is part of concrete. On average, the metakaolin constituents contained radium specific activities ranging from 67 Bq/kg to 600 Bq/kg and emanation fractions ranging from 8.4% to 15.5%, and changed the total concrete emanation fraction by roughly ±5% relative to control samples. The results from this study suggest that SCMs can reduce indoor radon exposure from concrete, contingent upon SCM radionucleotide content and emanation fraction. Lastly, the experimental results provide SCM-specific concrete emanation fractions for indoor radon exposure modeling.
authors.affiliation: Department of Civil, Architectural, and Environmental Engineering, 1 University Station C1748, The University of Texas at Austin, Austin, TX 78712, USA. Electronic address: taylorlanges@utexas.edu.
authors.forename: Sarah C
authors.initials: SC
authors.lastname: Taylor-Lange
authors.forename: Maria C G
authors.initials: MC
authors.lastname: Juenger
authors.forename: Jeffrey A
authors.initials: JA
authors.lastname: Siegel
mesh_terms: D000396:Air Pollutants, Radioactive / Q000032:analysis*; D016902:Air Pollution, Indoor / Q000032:analysis*; D060729:Coal Ash / Q000032:analysis; D003252:Construction Materials / Q000032:analysis*; D004781:Environmental Exposure; D007616:Kaolin / Q000032:analysis; D009010:Monte Carlo Method; D011834:Radiation Monitoring; D011886:Radon / Q000032:analysis*
chemical_list: D000396:Air Pollutants, Radioactive; D060729:Coal Ash; D007616:Kaolin; D011886:Radon
keywords: Indoor air quality; Radioactive pollution; Specific activity; Supplementary cementitious materials