title: Leachate characteristics as influenced by application of anaerobic baffled reactor effluent to three soils: a soil column study.
abstract: A soil column study was undertaken in the laboratory with three contrasting soil types namely a sandy soil (Longlands (Typic Plinthaquult), E horizon), an organic soil (Inanda (Rhodic Hapludox), A horizon) and a clayey soil (Sepane (Aquic Haplustalf), A horizon). Anaerobic baffled reactor (ABR) effluent was leached through the soil and distilled water was concurrently used as a control. The effluent was slightly basic (pH 7.4-7.6), had heavy metal concentrations below permissible limits for irrigation purposes and contained plant nutrients such as P, S, Ca, Mg, and K. Results indicated that after application of 16 pore volumes, the concentrations of Ca(2+) and Mg(2+) were lower in the leachates than in the original effluent indicating adsorption by the soils and Mg(2+) was preferentially adsorbed to Ca(2+). Phosphorus was strongly adsorbed in all soils. While its adsorption in the Inanda could be attributed to organic matter and the presence of iron oxides and oxyhydroxides, the clay type and amount in the Sepane was likely responsible for P adsorption. The NO3(-)-N, which was initially low in the effluent, increased as leaching progressed while the NH4-N decreased. A chemical balance to ascertain loss or gain of major elements from the effluent application indicated P to be strongly immobilised from the effluent representing 41, 6 and 10 fold the fertilizer needs for maize in the Inanda, Longlands and Sepane, respectively. Results obtained indicated that the chemical composition of ABR effluent is significantly altered when leached through soils with distinct properties.
authors.affiliation: Soil Science, School of Agricultural, Earth and Environmental Sciences, University of KwaZulu-Natal, Private Bag X01, Scottsville 3209, South Africa. Electronic address: bongsiysi@gmail.com.
authors.forename: I B
authors.initials: IB
authors.lastname: Bame
authors.forename: J C
authors.initials: JC
authors.lastname: Hughes
authors.forename: L W
authors.initials: LW
authors.lastname: Titshall
authors.forename: C A
authors.initials: CA
authors.lastname: Buckley
mesh_terms: D000383:Agriculture; D000693:Anaerobiosis; D019149:Bioreactors; D004784:Environmental Monitoring; D006863:Hydrogen-Ion Concentration; D019216:Metals, Heavy / Q000032:analysis / Q000737:chemistry; D008956:Models, Chemical; D010758:Phosphorus / Q000032:analysis / Q000737:chemistry; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis* / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D019216:Metals, Heavy; D012987:Soil; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D010758:Phosphorus
keywords: ABR effluent; Chemical balance; Leachate; Macro-elements; Soil column