title: New class of phosphine oxide donor-based supramolecular coordination complexes from an in situ phosphine oxidation reaction or phosphine oxide ligands.
abstract: A one-pot, multicomponent, coordination-driven self-assembly approach was used to synthesize the first examples of neutral bridging phosphine oxide donor-based supramolecular coordination complexes. The complexes were self-assembled from a fac-Re(CO)3 acceptor, an anionic bridging O donor, and a neutral soft phosphine or hard phosphine oxide donor.
authors.affiliation: Department of Chemistry, University of Delhi , Delhi 110 007, India.
authors.forename: Bhaskaran
authors.initials: B
authors.lastname: Shankar
authors.forename: Palani
authors.initials: P
authors.lastname: Elumalai
authors.forename: Ramasamy
authors.initials: R
authors.lastname: Shanmugam
authors.forename: Virender
authors.initials: V
authors.lastname: Singh
authors.forename: Dhanraj T
authors.initials: DT
authors.lastname: Masram
authors.forename: Malaichamy
authors.initials: M
authors.lastname: Sathiyendiran
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D046911:Macromolecular Substances; D010087:Oxides; D010720:Phosphines; C044646:phosphine