title: Non-enzymatic acylative kinetic resolution of primary allylic amines.
abstract: A non-enzymatic acetyl transfer-based kinetic resolution of primary allylic amines is reported. The process involves the use of (1S,2S)- in conjunction with a supported ammonium salt and affords the corresponding enantio-enriched N-acetylated allylic amines with unprecedented levels of selectivity (s-factors up to 34).
authors.affiliation: Laboratoire de Chimie Organique, ESPCI ParisTech, CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France. stellios.arseniyadis@espci.fr janine.cossy@espci.fr.
authors.forename: Amandine
authors.initials: A
authors.lastname: Kolleth
authors.forename: Martin
authors.initials: M
authors.lastname: Cattoen
authors.forename: Stellios
authors.initials: S
authors.lastname: Arseniyadis
authors.forename: Janine
authors.initials: J
authors.lastname: Cossy
mesh_terms: D000588:Amines / Q000737:chemistry*; D007700:Kinetics; D012997:Solvents / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000588:Amines; D012997:Solvents