title: A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage.
abstract: The new tungstatoiodate, α-[H5W18O59(IO3)](6-), containing I(V)O3(-) within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)](6-) by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I-O covalent bonds are broken.
authors.affiliation: WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, G12 8QQ, UK. Deliang.Long@glasgow.ac.uk Lee.Cronin@glasgow.ac.uk.
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Jun
authors.initials: J
authors.lastname: Yan
authors.forename: Andreu
authors.initials: A
authors.lastname: Ruiz de la Oliva
authors.forename: Christoph
authors.initials: C
authors.lastname: Busche
authors.forename: Haralampos N
authors.initials: HN
authors.lastname: Miras
authors.forename: R John
authors.initials: RJ
authors.lastname: Errington
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin