title: Unusual inner C-alkylation of 2-N-substituted N-confused porphyrin cobalt complexes in toluene and p-xylene.
abstract: The inner C-benzyl- and C-p-xylyl-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized from the reaction of 2-NCH2COOCH2C6H5NCTPPH (1) and CoCl2·6H2O in toluene (or p-xylene), and the structures were revealed by single-crystal X-ray analysis.
authors.affiliation: Department of Chemistry, National Chung Hsing University , Taichung 40227, Taiwan.
authors.forename: Yu-Cheng
authors.initials: YC
authors.lastname: Wang
authors.forename: Jyh-Horung
authors.initials: JH
authors.lastname: Chen
authors.forename: Shin-Shin
authors.initials: SS
authors.lastname: Wang
authors.forename: Jo-Yu
authors.initials: JY
authors.lastname: Tung
mesh_terms: D000478:Alkylation; D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D014050:Toluene / Q000737:chemistry*; D014992:Xylenes / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D011166:Porphyrins; D014992:Xylenes; D014050:Toluene; D003035:Cobalt; C031286:4-xylene