title: Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8-.
abstract: The two-electron reduced mixed-valence polyoxometalate [GeV14O40](8-) presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.
authors.affiliation: Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán No 2, 46980 Paterna, Spain. eugenio.coronado@uv.es.
authors.forename: Salvador
authors.initials: S
authors.lastname: Cardona-Serra
authors.forename: Juan M
authors.initials: JM
authors.lastname: Clemente-Juan
authors.forename: Alejandro
authors.initials: A
authors.lastname: Gaita-Ariño
authors.forename: Nicolas
authors.initials: N
authors.lastname: Suaud
authors.forename: Ondrej
authors.initials: O
authors.lastname: Svoboda
authors.forename: Eugenio
authors.initials: E
authors.lastname: Coronado