title: Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations.
abstract: We report the direct facile high-temperature synthesis and investigation of heterometallic rhenium-molybdenum cluster K6[Re3Mo3S8(CN)4(CN)2/2] (1) with a new {Re3Mo3S8} core. Dissolution of polymeric compound 1 resulted in subsequent oxidation and formation of stable 23e paramagnetic anionic cluster complex [Re3Mo3S8(CN)6](6-).
authors.affiliation: Nikolaev Institute of Inorganic Chemistry, 3, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia. naumov@niic.nsc.ru.
authors.forename: Yakov M
authors.initials: YM
authors.lastname: Gayfulin
authors.forename: Nikolay G
authors.initials: NG
authors.lastname: Naumov
authors.forename: Maxim R
authors.initials: MR
authors.lastname: Rizhikov
authors.forename: Anton I
authors.initials: AI
authors.lastname: Smolentsev
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Nadolinny
authors.forename: Yuri V
authors.initials: YV
authors.lastname: Mironov