title: Poly[(aceto-nitrile-κN)-μ3-thio-cyanato-κ(3) N:S:S-μ2-thio-cyanato-κ(2) N:S-cadmium].
abstract: The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)] n , consists of one Cd(II) cation, two thio-cyanate anions and one aceto-nitrile ligand, all in general positions. The Cd(II) cation is coordinated by three N atoms of two thio-cyanate anions and one aceto-nitrile ligand, as well as three S atoms of symmetry-related thio-cyanate anions within a slightly distorted octa-hedral coordination environment. The Cd(II) cations are linked by μ-1,3(N,S) and μ-1,1,3(S,S,N) thio-cyanate anions into layers that are located in the ab plane.
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.
authors.forename: Thorben
authors.initials: T
authors.lastname: Reinert
authors.forename: Inke
authors.initials: I
authors.lastname: Jess
authors.forename: Christian
authors.initials: C
authors.lastname: Näther
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: Dalton Trans. 2010 Dec 7;39(45):11019-26
references.pmid: 20949144
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 05;67(Pt 3):m309
references.pmid: 21522245
references.citation: Chem Commun (Camb). 2011 Jul 7;47(25):7104-6
references.pmid: 21617809