title: Metal deposition by electroless plating on polydopamine functionalized micro- and nanoparticles.
abstract: A novel approach for the fabrication of metal coated micro- and nanoparticles by functionalization with a thin polydopamine layer followed by electroless plating is reported. The particles are initially coated with polydopamine via self-polymerization. The resulting polydopamine coated particles have a surface rich in catechols and amino groups, resulting in a high affinity toward metal ions. Thus, they provide an effective platform for selective electroless metal deposition without further activation and sensitization steps. The combination of a polydopamine-based functionalization with electroless plating ensures a simple, scalable, and cost-effective metal coating strategy. Silver-plated tungsten carbide microparticles, copper-plated tungsten carbide microparticles, and copper-plated alumina nanoparticles were successfully fabricated, showing also the high versatility of the method, since the polymerization of dopamine leads to the formation of an adherent polydopamine layer on the surface of particles of any material and size. The metal coated particles produced with this process are particularly well suited for the production of metal matrix composites, since the metal coating increases the wettability of the particles by the metal, promoting their integration within the matrix. Such composite materials are used in a variety of applications including electrical contacts, components for the automotive industries, magnets, and electromagnetic interference shielding.
authors.affiliation: Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, D-01069 Dresden, Germany. Electronic address: giovanni.mondin@chemie.tu-dresden.de.
authors.forename: Giovanni
authors.initials: G
authors.lastname: Mondin
authors.forename: Florian M
authors.initials: FM
authors.lastname: Wisser
authors.forename: Annika
authors.initials: A
authors.lastname: Leifert
authors.forename: Nasser
authors.initials: N
authors.lastname: Mohamed-Noriega
authors.forename: Julia
authors.initials: J
authors.lastname: Grothe
authors.forename: Susanne
authors.initials: S
authors.lastname: Dörfler
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
mesh_terms: D007211:Indoles / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D053758:Nanoparticles; D011108:Polymers / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D007211:Indoles; D008670:Metals; D011108:Polymers; C568283:polydopamine
keywords: Al(2)O(3); Copper; Electroless plating; Metal matrix composites; Nanoparticles; Polydopamine; Silver; WC