title: Tuning activities of K1.9Na0.1Ta2O6·2H2O nanocrystals in photocatalysis by controlling exposed facets.
abstract: Morphology-controlled synthesis of tantalates is a major challenge in the field of material science. Herein, an innovative strategy has been developed for controllably synthesizing K1.9Na0.1Ta2O6·2H2O (KNTO) nanocrystals shaped as octahedra and nanosheets without using any capping agents. The obtained nanocrystals show high activity in photocatalytic H2 evolution from CH3OH/H2O solution, and their performance closely depends on the exposed facets, in which the {111}-facet-bounded nanooctahedra exhibit more than 3 times higher activity than the nanosheets dominated with {101} facets. The influence of surface atomic structure and electronic band structure on the photocatalytic properties of the KNTO nanocrystals is systematically studied. This is the first report for the facet controllable synthesis of tantalate materials with highly regular shapes. The present approach is anticipated as a general strategy for controllable synthesis of tantalate materials and also provides feasibility for rational design and activity optimization of shape-controlled photocatalysts for H2 production.
authors.affiliation: Laboratory of Environmental Sciences and Technology, Xinjiang Technical Institute of Physics & Chemistry; Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, China.
authors.forename: Yingxuan
authors.initials: Y
authors.lastname: Li
authors.forename: Shuai
authors.initials: S
authors.lastname: Chen
authors.forename: Hongquan
authors.initials: H
authors.lastname: He
authors.forename: Ying
authors.initials: Y
authors.lastname: Zhang
authors.forename: Chuanyi
authors.initials: C
authors.lastname: Wang