title: Synthesis, growth, structural, optical and thermal properties of an organic single crystal: 4-nitroaniline 4-aminobenzoic acid.
abstract: The organic single crystals of 4-nitroaniline 4-aminobenzoic acid (4NAABA) were grown from ethanol solvent. The lattice parameters of the grown crystal have been confirmed from single crystal XRD analysis. The powder XRD pattern shows the various planes of grown crystal. The FTIR and (1)H NMR spectral analysis confirm the presence of various functional groups and the placement of proton in 4NAABA compound respectively. The UV absorption was carried out which shows the cutoff wavelength around 459 nm. The optical band gap of the crystal has been evaluated from the transmission spectra and absorption coefficient by extrapolation technique. In addition, a fluorescence spectral analysis is carried out for 4NAABA crystals. The thermal properties of crystals were evaluated from thermogravimetrical analysis. It shows that the grown crystal is stable up to 160°C and the crystal has sharp melting point at 151°C.
authors.affiliation: Centre for Crystal Growth, SSN College of Engineering, Kalavakkam 603 110, India.
authors.forename: A
authors.initials: A
authors.lastname: Silambarasan
authors.forename: P
authors.initials: P
authors.lastname: Rajesh
authors.forename: P
authors.initials: P
authors.lastname: Ramasamy
mesh_terms: D010129:4-Aminobenzoic Acid / Q000737:chemistry*; D003460:Crystallization; D009682:Magnetic Resonance Spectroscopy; D055620:Optical Phenomena; D017785:Photons; D011208:Powders; D013050:Spectrometry, Fluorescence; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D019265:Spectroscopy, Near-Infrared; D013696:Temperature; D014961:X-Ray Diffraction; D062366:para-Aminobenzoates / Q000737:chemistry*
chemical_list: C000593889:4-nitroaniline 4-aminobenzoic acid; D011208:Powders; D062366:para-Aminobenzoates; D010129:4-Aminobenzoic Acid
keywords: Fluorescence analysis; Growth from solutions; Organic optical materials; Single crystal growth; Solubility; Thermal analysis