title: (2E)-1-(4-Bromo-phen-yl)-3-[3-(4-meth-oxy-phen-yl)-1-phenyl-1H-pyrazol-4-yl]prop-2-en-1-one.
abstract: The pyrazole ring in the title compound, C25H19BrN2O2, is almost planar (r.m.s. deviation = 0.003 Å) and forms dihedral angles of 7.56 (13) and 56.48 (13)° with the N- and C-bound benzene rings, respectively. The prop-2-en-1-one residue has an E conformation about the C=C double bond [1.328 (4) Å] and is almost coplanar with the pyrazole ring [C-C-C-C torsion angle = -174.4 (3)°]. A twist between the prop-2-en-1-one unit and the terminal benzene ring is evident [C-C-C-C torsion angle = -15.4 (4)°]. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by C-H⋯O, C-H⋯π and π-π [centroid-centroid separation = 3.7597 (16) Å] inter-actions.
authors.affiliation: Department of Chemistry, BITS, Pilani - K. K. Birla Goa Campus, Goa 403 726, India.
authors.forename: R
authors.initials: R
authors.lastname: Prasath
authors.forename: P
authors.initials: P
authors.lastname: Bhavana
authors.forename: Seik Weng
authors.initials: SW
authors.lastname: Ng
authors.forename: Edward R T
authors.initials: ER
authors.lastname: Tiekink
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o3105
references.pmid: 22220108