title: Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates.
abstract: An efficient protocol for the one-step synthesis of biologically relevant 1,1-diarylalkanes has been described. This reaction introduces two different aryl groups across the terminal end of simple feedstock alkenes such as ethylene and allylic carbonates. The propensity to generate π-benzylpalladium intermediates dictates the exclusive 1,1-regioselectivity observed in the product.
authors.affiliation: Department of Chemistry, University of Utah , 315 South 1400 East, Salt Lake City, Utah 84112, United States.
authors.forename: Vaneet
authors.initials: V
authors.lastname: Saini
authors.forename: Longyan
authors.initials: L
authors.lastname: Liao
authors.forename: Qiaofeng
authors.initials: Q
authors.lastname: Wang
authors.forename: Ranjan
authors.initials: R
authors.lastname: Jana
authors.forename: Matthew S
authors.initials: MS
authors.lastname: Sigman
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002254:Carbonates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D005030:Ethylenes / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium; D013237:Stereoisomerism
chemical_list: D000498:Allyl Compounds; D002254:Carbonates; D005030:Ethylenes; D010165:Palladium; C036216:ethylene
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