title: [Preparation of porous ceramics based on waste ceramics and its Ni2+ adsorption characteristics].
abstract: The preparation conditions of porous ceramics were determined by SEM, XRD and FT-IR characterizations as well as the nickel removal ability of porous ceramics to be: the mass fraction w of sesbania powder doped was 4%, and the calcination temperature was 800 degrees C. SEM and pore structure characterization illustrated that calcination caused changes in the structure and morphology of waste ceramics. With the increase of calcination temperature, the specific surface area and pore volume decreased, while the aperture increased. EDS analyses showed that the main elements of both the original waste porcelain powder and the porous ceramics were Si, Al and O. The SEM, XRD and FT-IR characterization of porous ceramics illustrated that the structure of porous ceramics was stable before and after adsorption. The series of experiments of Ni2+ adsorption using these porous ceramics showed that when the dosage of porous ceramics was 10 g x L(-1), the adsorption time was 60 min, the pH value was 6.32, and the concentration of nickel-containing wastewater was below 100 mg x L(-1), the Ni2+ removal of wastewater reached 89.7%. Besides, the porous ceramics showed higher removal efficiency on nickel in the wastewater. The Ni(2+)-containing wastewater was processed by the porous ceramics prepared, and the adsorption dynamics and adsorption isotherms of Ni2+ in wastewater by porous ceramics were investigated. The research results showed that the Ni2+ adsorption process of porous ceramics was in accordance with the quasi second-order kinetic model (R2 = 0.999 9), with Q(e) of 9.09 mg x g(-1). The adsorption process can be described by the Freundlich equation and Langmuir equation, and when the temperature increased from 20 degrees C to 40 degrees C, the maximum adsorption capacity Q(m) increased from 14.49 mg x g(-1) to 15.38 mg x g(-1).
authors.affiliation: Department of Chemistry, Hanshan Normal University, Chaozhou 521041, China. zhang024@hstc.edu.cn
authors.forename: Yong-Li
authors.initials: YL
authors.lastname: Zhang
authors.forename: Cheng-Zhi
authors.initials: CZ
authors.lastname: Wang
authors.forename: Ce
authors.initials: C
authors.lastname: Shi
authors.forename: Ling-Ling
authors.initials: LL
authors.lastname: Shang
authors.forename: Rui
authors.initials: R
authors.lastname: Ma
authors.forename: Wan-Li
authors.initials: WL
authors.lastname: Dong
mesh_terms: D000327:Adsorption; D002516:Ceramics / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry / Q000302:isolation & purification*; D016062:Porosity; D012037:Refuse Disposal / Q000379:methods; D014865:Waste Disposal, Fluid / Q000379:methods*; D062065:Wastewater / Q000737:chemistry*
chemical_list: D009532:Nickel; D062065:Wastewater