title: Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].
abstract: The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H···H) bond within a hydrogenated FLP system.
authors.affiliation: Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, UK. dermot.ohare@chem.ox.ac.uk.
authors.forename: Hasna
authors.initials: H
authors.lastname: Zaher
authors.forename: Andrew E
authors.initials: AE
authors.lastname: Ashley
authors.forename: Mark
authors.initials: M
authors.lastname: Irwin
authors.forename: Amber L
authors.initials: AL
authors.lastname: Thompson
authors.forename: Matthias J
authors.initials: MJ
authors.lastname: Gutmann
authors.forename: Tobias
authors.initials: T
authors.lastname: Krämer
authors.forename: Dermot
authors.initials: D
authors.lastname: O'Hare