title: A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies.
abstract: The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)·H2O () was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound .
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka, 816-8580, Japan. sato@cm.kyushu-u.ac.jp.
authors.forename: Zhao-Yang
authors.initials: ZY
authors.lastname: Li
authors.forename: Jing-Wei
authors.initials: JW
authors.lastname: Dai
authors.forename: Kevin J
authors.initials: KJ
authors.lastname: Gagnon
authors.forename: Hong-Ling
authors.initials: HL
authors.lastname: Cai
authors.forename: Takashi
authors.initials: T
authors.lastname: Yamamoto
authors.forename: Yasuaki
authors.initials: Y
authors.lastname: Einaga
authors.forename: Han-Hua
authors.initials: HH
authors.lastname: Zhao
authors.forename: Shinji
authors.initials: S
authors.lastname: Kanegawa
authors.forename: Osamu
authors.initials: O
authors.lastname: Sato
authors.forename: Kim R
authors.initials: KR
authors.lastname: Dunbar
authors.forename: Ren-Gen
authors.initials: RG
authors.lastname: Xiong