title: Rotational spectrum and structure of cyclohexene oxide and the argon-cyclohexene oxide van der Waals complex.
abstract: The rotational spectra of cyclohexene oxide and its van der Waals complex with argon have been observed with a Balle-Flygare type pulsed jet Fourier transform microwave spectrometer in the 6 to 20 GHz region. This work improves the existing rotational and quartic centrifugal distortion constants of cyclohexene oxide, its six singly substituted (13)C, and the (18)O isotopologue. In addition, the (17)O isotopologue was observed in natural abundance. The quadrupole coupling constants for the (17)O isotopologue are χ(aa) = 8.855(5), χ(bb) = -4.560(4), and χ(cc) = -4.296(4) MHz. The argon-(12)C6H10(16)O complex has rotational constants of A = 2146.4825(2), B = 908.64292(8), and C = 859.00320(8) MHz. Additionally, the six unique singly substituted (13)C isotopologues of the argon complex are reported here. The position of the argon that is consistent with the parent and six (13)C complex rotational constants is above the ring on the side opposite the epoxide.
authors.affiliation: Department of Chemistry, Wesleyan University , 52 Lawn Avenue, Middletown, Connecticut 06459-0180, United States.
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Frohman
authors.forename: Stewart E
authors.initials: SE
authors.lastname: Novick
authors.forename: Wallace C
authors.initials: WC
authors.lastname: Pringle