title: Activated carbon prepared from coffee pulp: potential adsorbent of organic contaminants in aqueous solution.
abstract: The processing of coffee beans generates large amounts of solid and liquid residues. The solid residues (pulp, husk and parchment) represent a serious environmental problem and do not have an adequate disposal mechanism. In this work, activated carbons (ACs) for adsorption of organic compounds were prepared from coffee pulp by controlled temperature at different pulp/Na2HPO4 ratios (4:1, 2:1, 5:4 and 1:1). The N2 adsorption/desorption isotherms showed ACs with high quantities of mesopores and micropores and specific surface areas of 140, 150, 450 and 440 m(2)g(-1) for AC 4:1, AC 2:1, AC 5:4 and AC 1:1, respectively. The prepared material AC 5:4 showed a higher removal capacity of the organic contaminants methylene blue (MB), direct red (DR) and phenol than did a Merck AC. The maximum capacities for this AC are approximately 150, 120 and 120 mg g(-1) for MB, DR and phenol, respectively. Thus, a good adsorbent was obtained from coffee pulp, an abundant Brazilian residue.
authors.affiliation: Departamento de Química, Universidade Federal de Lavras, Caixa Postal 3037, CEP 37200-000, Lavras-MG, Brazil E-mail: maraisa_g@yahoo.com.br.
authors.forename: Maraisa
authors.initials: M
authors.lastname: Gonçalves
authors.forename: Mário César
authors.initials: MC
authors.lastname: Guerreiro
authors.forename: Paulize Honorato
authors.initials: PH
authors.lastname: Ramos
authors.forename: Luiz Carlos Alves
authors.initials: LC
authors.lastname: de Oliveira
authors.forename: Karim
authors.initials: K
authors.lastname: Sapag
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry*; D003069:Coffee / Q000737:chemistry*; D008751:Methylene Blue / Q000737:chemistry; D010636:Phenols / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
chemical_list: D003069:Coffee; D010636:Phenols; D014874:Water Pollutants, Chemical; D002606:Charcoal; D008751:Methylene Blue