title: Copper-catalyzed B-H bond insertion reaction: a highly efficient and enantioselective C-B bond-forming reaction with amine-borane and phosphine-borane adducts.
abstract: A copper-catalyzed B-H bond insertion reaction with amine- and phosphine-borane adducts was realized with high yield and enantioselectivity under mild reaction conditions. The B-H bond insertion reaction provides a new C-B bond-forming methodology and an efficient approach to chiral organoboron compounds.
authors.affiliation: State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Qing-Qing
authors.initials: QQ
authors.lastname: Cheng
authors.forename: Shou-Fei
authors.initials: SF
authors.lastname: Zhu
authors.forename: Yong-Zhen
authors.initials: YZ
authors.lastname: Zhang
authors.forename: Xiu-Lan
authors.initials: XL
authors.lastname: Xie
authors.forename: Qi-Lin
authors.initials: QL
authors.lastname: Zhou