title: 3-({[Bis(2-methyl-prop-yl)carbamo-thio-yl]amino}-carbon-yl)benzamide.
abstract: In the title compound, C17H25N3O2S, the terminal and central amide groups are, respectively, twisted and coplanar with the attached benzene ring [O-C-C-C torsion angles = 22.7 (3) and 5.4 (3)°]. In the central part of the mol-ecule, the amide and thio-amide residues are approximately perpendicular [C-N-C-S torsion angle = -104.98 (18)°]. Supra-molecular layers with a zigzag topology are formed in the crystal packing by N-H⋯O, N-H⋯S and C-H⋯O inter-actions; these stack along c, being separated by hydro-phobic inter-actions.
authors.affiliation: Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, India.
authors.forename: N
authors.initials: N
authors.lastname: Selvakumaran
authors.forename: R
authors.initials: R
authors.lastname: Karvembu
authors.forename: Seik Weng
authors.initials: SW
authors.lastname: Ng
authors.forename: Edward R T
authors.initials: ER
authors.lastname: Tiekink
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 29;69(Pt 7):o1184-5
references.pmid: 24046724