title: Anti-Markovnikov hydrophosphoroselenoylation of alkenes using phosphorodiselenoic acid esters leading to the formation of phosphonoselenoic acid esters.
abstract: Phosphorodiselenoic acid esters with a binaphthyl group were reacted with alkenes in the presence of Bu3SnH and AIBN to give phosphonoselenoic acid esters in moderate to good yields. The addition of a phosphoroselenoyl group to alkenes proceeded in an anti-Markovnikov fashion. The diastereoselectivity was improved by the introduction of substituents to 3,3'-positions of a binaphthyl group.
authors.affiliation: Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. mtoshi@gifu-u.ac.jp.
authors.forename: Toshiaki
authors.initials: T
authors.lastname: Murai
authors.forename: Yuuki
authors.initials: Y
authors.lastname: Maekawa
authors.forename: Masaki
authors.initials: M
authors.lastname: Monzaki
authors.forename: Takafumi
authors.initials: T
authors.lastname: Ando
authors.forename: Toshifumi
authors.initials: T
authors.lastname: Maruyama