title: Palladium(III)-catalyzed fluorination of arylboronic acid derivatives.
abstract: A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Anthony R
authors.initials: AR
authors.lastname: Mazzotti
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Michael G
authors.initials: MG
authors.lastname: Campbell
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Pingping
authors.initials: P
authors.lastname: Tang
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Jennifer M
authors.initials: JM
authors.lastname: Murphy
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Tobias
authors.initials: T
authors.lastname: Ritter
mesh_terms: D001555:Benzene Derivatives / Q000138:chemical synthesis*; D001897:Boronic Acids / Q000138:chemical synthesis*; D002384:Catalysis; D005461:Fluorine / Q000737:chemistry*; D054879:Halogenation; D010165:Palladium
chemical_list: D001555:Benzene Derivatives; D001897:Boronic Acids; D005461:Fluorine; D010165:Palladium
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