title: 5-Bromo-4-(3,5-di-bromo-2-hy-droxy-phen-yl)-2-(piperidin-1-yl)-1,3-di-thiol-2-ylium bromide.
abstract: In the title salt, C14H13Br3NOS2 (+)·Br(-), synthesized by bromination of mesoionic 2-[2-(piperidin-1-yl)-1,3-di-thiol-2-ylium-4-yl]phenolate in glacial acetic acid, the dihedral angle between the 1,3-di-thiol-ium ring and the phenolic substituent ring is 45.9 (3)° due to the steric influence of the ortho-Br group on the 1,3-di-thiol-ium ring. The piperidine ring adopts a chair conformation. In the crystal, the cation and anion are linked by an O-H⋯Br hydrogen bond.
authors.affiliation: Department of Chemistry, University of Craiova, 107I Calea Bucuresti, Craiova, Romania.
authors.forename: Paul
authors.initials: P
authors.lastname: Chirita
authors.forename: Cristian G
authors.initials: CG
authors.lastname: Hrib
authors.forename: Lucian M
authors.initials: LM
authors.lastname: Birsa
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677