title: Large magnetoresistance and charge transfer between the conduction and magnetic electrons in layered oxyselenide BiOCu(0.96)Se.
abstract: The electrical and magnetic properties of slightly Cu-deficient BiOCu(0.96)Se have been investigated using neutron and X-ray diffraction, ac magnetic susceptibility, magnetization and electric resistivity measurements. The layered BiOCu(0.96)Se crystallizes into a tetragonal lattice with a P4/nmm symmetry. Thermal profiles of the electrical resistivity reveal a semiconductor type behavior, but depart from its course at low temperatures when antiferromagnetic coupling becomes thermally loosened at 140 K. Positive magnetoresistances are obtained at all temperatures studied. With an applied magnetic field of 0.5 kOe, the magnetoresistance reaches 235% at 2 K. It decreases with increasing temperature, but stabilizes to 70% above 60 K. Both ferromagnetic and antiferromagnetic coupling are detected between the Cu spins in the SeCu4 pyramidal blocks, which results in a non-collinear spin arrangement at low temperatures. The antiferromagnetic component becomes disordered above T(N) = 140 K, whereas the ferromagnetic moment persists up to T(C) = 300 K. Interlayer charge transfer between the conduction and magnetic electrons gives rise to an anomaly in the magnetic order parameter.
authors.affiliation: Department of Physics and Center for Neutron Beam Applications, National Central University, Jhongli 32001, Taiwan. whli@phy.ncu.edu.tw.
authors.forename: Sunil K
authors.initials: SK
authors.lastname: Karna
authors.forename: Chi-Hang
authors.initials: CH
authors.lastname: Hung
authors.forename: Chun-Ming
authors.initials: CM
authors.lastname: Wu
authors.forename: Chin-Wei
authors.initials: CW
authors.lastname: Wang
authors.forename: Wen-Hsien
authors.initials: WH
authors.lastname: Li
authors.forename: Raman
authors.initials: R
authors.lastname: Sankar
authors.forename: Fang Cheng
authors.initials: FC
authors.lastname: Chou
authors.forename: Maxim
authors.initials: M
authors.lastname: Avdeev