title: Experimental evidence for oxygen sublattice control in polar infinite layer SrCuO2.
abstract: A recent theoretical study [Phys. Rev. B 85, 121411(R) (2012)] predicted a thickness limit below which ideal polar cuprates turn nonpolar driven by the associated electrostatic instability. Here we demonstrate this possibility by inducing a structural transformation from the bulk planar to chainlike structure upon reducing the SrCuO2 repeat thickness in SrCuO2/SrTiO3 superlattices with unit-cell precision. Our results, based on structural investigation by x-ray diffraction and high resolution scanning transmission electron microscopy, demonstrate that the oxygen sublattice can essentially be built by design. In addition, the electronic structure of the chainlike structure, as studied by x-ray absorption spectroscopy, shows the signature for preferential hole occupation in the Cu 3d(3z2-r2) orbital, which is different from the planar case.
authors.affiliation: MESA+ Institute for Nanotechnology, University of Twente, Post Office Box 217, 7500AE Enschede, The Netherlands.
authors.forename: D
authors.initials: D
authors.lastname: Samal
authors.forename: Haiyan
authors.initials: H
authors.lastname: Tan
authors.forename: H
authors.initials: H
authors.lastname: Molegraaf
authors.forename: B
authors.initials: B
authors.lastname: Kuiper
authors.forename: W
authors.initials: W
authors.lastname: Siemons
authors.forename: Sara
authors.initials: S
authors.lastname: Bals
authors.forename: Jo
authors.initials: J
authors.lastname: Verbeeck
authors.forename: Gustaaf
authors.initials: G
authors.lastname: Van Tendeloo
authors.forename: Y
authors.initials: Y
authors.lastname: Takamura
authors.forename: Elke
authors.initials: E
authors.lastname: Arenholz
authors.forename: Catherine A
authors.initials: CA
authors.lastname: Jenkins
authors.forename: G
authors.initials: G
authors.lastname: Rijnders
authors.forename: Gertjan
authors.initials: G
authors.lastname: Koster