Visible light photoredox atom transfer Ueno-Stork reaction.
A visible light-promoted atom transfer Ueno-Stork reaction was developed using Ir(ppy)2(dtb-bpy)PF6 as the sensitizer. 2-Iodoethyl propargyl ethers or 2-iodoethyl allyl ethers were used as the radical precursors to construct tetrahydrofuran-containing fused [6,5] and [5,5] bicyclic frameworks.
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering, and Materials Science, Soochow University, 199 RenAi Road, Suzhou, Jiangsu 215123, China. lipixu@suda.edu.cn yaoym@suda.edu.cn.
Xiangyong
X
Gu
Ping
P
Lu
Weigang
W
Fan
Pixu
P
Li
Yingming
Y
Yao
D018360:Crystallography, X-Ray; D003500:Cyclization; D004987:Ethers / Q000737:chemistry*; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D008027:Light; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D017319:Photosensitizing Agents / Q000737:chemistry*
D004987:Ethers; D005663:Furans; D017319:Photosensitizing Agents; C018674:tetrahydrofuran