A 3d-4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates.
A novel compound, Na2[Ce4(H2O)22(dpdo)5](Mn2HP2W15O56)2·8H2O (1) (dpdo = 4,4'-bipyridine-N,N'-dioxide) with 3d-4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated.
Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China. mahy017@163.com panghj116@163.com.
Tingting
T
Yu
Huiyuan
H
Ma
Chunjing
C
Zhang
Haijun
H
Pang
Shaobin
S
Li
Heng
H
Liu
D002384:Catalysis; D018360:Crystallography, X-Ray; D008280:Magnetics; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D009942:Organometallic Compounds; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates