Direct formation of tethered Ru(II) catalysts using arene exchange.
An 'arene exchange' approach has been successfully applied for the first time to the synthesis of Ru(II)-based 'tethered' reduction catalysts directly from their ligands in one step. This provides an alternative method for the formation of known complexes, and a route to a series of novel complexes. The novel complexes are highly active in both asymmetric transfer and pressure hydrogenation of ketones.
Department of Chemistry, The University of Warwick , Coventry, CV4 7AL, U.K.
Rina
R
Soni
Katherine E
KE
Jolley
Guy J
GJ
Clarkson
Martin
M
Wills