Rhodium(III)-catalyzed intermolecular N-chelator-directed aromatic C-H amidation with amides.
Rh(III)-catalyzed intermolecular direct aromatic C-H bond amidation with amides has been accomplished under mild reaction conditions. This protocol is applicable to a broad range of N-chelator-containing arenes amidated with aromatic and aliphatic sulfonamides. A possible mechanism is proposed according to the experimental results.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
Huaiqing
H
Zhao
Yaping
Y
Shang
Weiping
W
Su
D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D002614:Chelating Agents / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry; D013449:Sulfonamides / Q000737:chemistry
D000577:Amides; D002614:Chelating Agents; D013449:Sulfonamides; D012238:Rhodium