Dissipation and residues of clethodim and its oxidation metabolites in a rape-field ecosystem using QuEChERS and liquid chromatography/tandem mass spectrometry.
A rapid, sensitive and selective method using Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) procedure for simultaneous determination of clethodim and its oxidation metabolites (clethodim sulfoxide and clethodim sulphone) in soil, rape plant and rape seed was developed using high-performance liquid chromatography coupled with tandem mass spectrometry (HPLC-MS/MS). The limits of detection (LODs) of the proposed method ranged from 0.002mg/kg to 0.01mg/kg, and average recoveries were 78.7-104.2%. The trial results showed that clethodim dissipated so rapidly that few clethodim residues were detectable. Clethodim sulfoxide dissipated quickly in rape plant and soil with half-lives of 4.3 and 4.0days, respectively. Clethodim sulphone showed a tendency of rapid increase initially followed by a decrease in rape plant but could not be detected in soil. The terminal residues of clethodim in rape seedsat harvest time were below the maximum residue limit (MRL, 0.5mg/kg).
College of Science, China Agricultural University, Beijing 100193, PR China.
Xiangwei
X
You
Lin
L
Liang
Fengmao
F
Liu
D029741:Brassica rapa / Q000737:chemistry* / Q000254:growth & development; D005591:Chemical Fractionation / Q000379:methods*; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D003512:Cyclohexanones / Q000737:chemistry* / Q000302:isolation & purification; D017753:Ecosystem; D010084:Oxidation-Reduction; D010573:Pesticide Residues / Q000737:chemistry* / Q000302:isolation & purification; D012989:Soil Pollutants / Q000737:chemistry* / Q000302:isolation & purification; D053719:Tandem Mass Spectrometry / Q000379:methods*
D003512:Cyclohexanones; D010573:Pesticide Residues; D012989:Soil Pollutants; C441919:clethodim
Clethodim; HPLC–MS/MS; Oxidation metabolites; QuEChERS; Rape; Soil