Mid- and near-infrared spectroscopic investigation of homogeneous cation distribution in Mg(x)Zn(y)Al(x+y)/2-layered double hydroxide (LDH).
In this report, a detailed FTIR fitting analysis was used to recognize Mg, Zn and Al homogeneous distribution in Mg(x)Zn(y)Al(x+y)/2-Layered double hydroxide (LDH) hydroxyl layer. In detail, OH-Mg2Al:OH-Mg3 ratios decreased from 95.2:4.8 (MIR) and 94.2:5.8 (NIR) to 58.9:41.1 (MIR) and 61.8:38.2 (NIR), when Mg:Al increased from 2.2:1.0 to 4.1:1.0 in MgAl-LDHs. These fitting results were similar with theoretical calculations of 94.3:5.7 and 59.0:41.0. In a further analysis of Mg(x)Zn(y)Al(x+y)/2-LDHs, OH bonded Zn2Mg, Zn2Al, MgZnAl, Mg2Al and Mg2Zn peaks were identified at 3420, 3430, 3445-3450, 3454 and 3545 cm(-1), respectively. With the decrease of Mg:Zn from 3:1 to 1:3, metal-hydroxyl bands changed from OH-Mg2Al and MgZnAl (with a ratio of 49.4:50.6) to OH-MgZnAl and Zn2Al (with a ratio of 55.0:45.0). They were also similar with theoretical calculations of 47.6:52.4 and 54.6:45.4. As a result, these results show that there is an ordered cation distribution in Mg(x)Zn(y)Al(x+y)/2-LDH, and FTIR is feasible in recognizing this structure.
School of Environmental and Chemical Engineering, Shanghai University, No. 333 Nanchen Rd., Shanghai 200444, PR China.
Jia
J
Zhang
Huimin
H
Su
Jizhi
J
Zhou
Guangren
G
Qian
Zhiping
Z
Xu
Yunfei
Y
Xi
Yunfeng
Y
Xu
Frederick L
FL
Theiss
Ray
R
Frost
Cation distribution; Homogeneous; Layered double hydroxide; MIR; NIR