Partial sublimation of enantioenriched amino acids at low temperature. Is it coming from the formation of a euatmotic composition of the gaseous phase?
The partial sublimation of enantioenriched amino acids was performed slowly at low temperature with the aim to determine the rules of sublimation of these compounds. Although the formation of a euatmotic composition of the gaseous phase starting from DL + L mixtures of Leu, Pro, and Phe can be deduced from the enantiomeric excess of sublimates, the behavior of the kinetic conglomerate explains the results for D + L mixtures of Ala, Leu, Val, and Pro. Consequently, the enantiomeric excess of the partial sublimate is dependent not only on the studied compound but also on the composition of the starting mixture.
École Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226 , 11 Allée de Beaulieu, CS 50837, 35708 Rennes cedex 7, France.
Arkadii V
AV
Tarasevych
Alexander E
AE
Sorochinsky
Valery P
VP
Kukhar
Aurélien
A
Chollet
Richard
R
Daniellou
Jean-Claude
JC
Guillemin
D000595:Amino Acid Sequence; D000596:Amino Acids / Q000737:chemistry*; D007700:Kinetics; D010446:Peptide Fragments / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
D000596:Amino Acids; D010446:Peptide Fragments