Room-temperature synthesis of flower-like BiOX (X═Cl, Br, I) hierarchical structures and their visible-light photocatalytic activity.
A simple method for facile synthesis of three-dimensional (3D) bismuth oxyhalide (BiOX, X═Cl, Br, I) hierarchical structures at room temperature has been developed. Under the influence of L-lysine surfactant, the bismuth and halogen (Cl, Br, I) sources hydrolyze and self-assemble into flower-like hierarchical architectures within 10 min. The resulted materials were characterized by XRD, FESEM, TEM, UV-vis DRS, and N2 adsorption-desorption techniques. We found that l-lysine is indispensable for their formation and the amount of HX has great effect on the final morphology. The BiOX (X═Cl, Br, I) hierarchical architectures are composed of single-crystalline nanoplates. We propose an amino-and-carboxyl structure-directing mechanism for the formation of the hierarchical structures. To evaluate the photocatalytic activity of the as-prepared materials, rhodamine-B was employed as a probe dye for degradation under visible light. All of the BiOX (X═Cl, Br, I) with 3D architectures show higher photocatalytic activities than their sheet-like counterparts. The superior activity is ascribed to the better light-harvesting capacity of the 3D hierarchical structures. The adopted method can be applied for large-scale generation of novel structures of similar kinds in a facile manner.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha, Hunan 410082, People's Republic of China.
Lang
L
Chen
Rui
R
Huang
Miao
M
Xiong
Qing
Q
Yuan
Jie
J
He
Jing
J
Jia
Meng-Yuan
MY
Yao
Sheng-Lian
SL
Luo
Chak-Tong
CT
Au
Shuang-Feng
SF
Yin