Steric hindrance-enforced distortion as a general strategy for the design of fluorescence "turn-on" cyanide probes.
For the rational design of fluorescence "turn-on" cyanide probes, a general strategy is developed by introducing a dicyanovinyl group at the sterically demanding position of a large π framework.
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, P. R. China. yshxie@ecust.edu.cn.
Bin
B
Chen
Yubin
Y
Ding
Xin
X
Li
Weihong
W
Zhu
Jonathan P
JP
Hill
Katsuhiko
K
Ariga
Yongshu
Y
Xie
D000838:Anions; D018360:Crystallography, X-Ray; D003486:Cyanides / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry; D011789:Quantum Theory; D011807:Quinolizines / Q000737:chemistry; D013997:Time Factors
D000838:Anions; D003486:Cyanides; D005456:Fluorescent Dyes; D009570:Nitriles; D011807:Quinolizines; C061441:9-(dicyanovinyl)julolidine