Synthesis of sequence controlled acrylate oligomers via consecutive RAFT monomer additions.
An effective procedure to synthesize sequence controlled oligoacrylates with up to four monomer insertions via the RAFT technique is presented. Two different sets of oligomers with a preferred monomer order were synthesized. Recycling SEC allowed for facile and automated purification of the monodisperse sequence-controlled materials.
Polymer Reaction Design Group Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium. tanja.junkers@uhasselt.be.
Joke
J
Vandenbergh
Nuclear Magnetic Resonance Spectroscopy Group, Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium.
Gunter
G
Reekmans
Nuclear Magnetic Resonance Spectroscopy Group, Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium.
Peter
P
Adriaensens
Polymer Reaction Design Group Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium. tanja.junkers@uhasselt.be.
Tanja
T
Junkers