Metastable interwoven mesoporous metal-organic frameworks.
Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.
College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua 321004, China.
Yabing
Y
He
Zhiyong
Z
Guo
Shengchang
S
Xiang
Zhangjing
Z
Zhang
Wei
W
Zhou
Frank R
FR
Fronczek
Sean
S
Parkin
Stephen T
ST
Hyde
Michael
M
O'Keeffe
Banglin
B
Chen