Synthesis, photophysical properties, and excited state dynamics of a platinum complex of tetracene imide disulfide.
A platinum complex containing a tetracene dicarboxylic imide disulfide (TIDS) was synthesized and structurally characterized by X-ray analysis. Steady-state absorption and emission spectroscopy for Pt-TIDS revealed its extended π-conjugated structure. Excited state studies characterized its triplet state with a lifetime of 0.18-0.28 μs.
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. matsuo@chem.s.u-tokyo.ac.jp.
Takafumi
T
Nakagawa
Tsuyoshi
T
Suzuki
Matthias
M
König
Dirk M
DM
Guldi
Yutaka
Y
Matsuo
D000042:Absorption; D060326:Chemistry Techniques, Synthetic; D007094:Imides / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009944:Organoplatinum Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D007094:Imides; D009944:Organoplatinum Compounds