Selective turn-on fluorescence sensor for Ag+ using cysteamine capped CdS quantum dots: determination of free Ag+ in silver nanoparticles solution.
Cadmium sulfide quantum dots capped with cysteamine (Cys-CdS QDs) were demonstrated as a selective fluorescence probe for sensing of free trace silver ions. The fluorescence intensity of the Cys-CdS QDs can be enhanced only in the presence of free Ag(+) and the fluorescence spectrum was slightly red shift from the original spectra. In addition, the fluorescence intensities were linearly increased upon increasing Ag(+) concentration. At the optimized condition for Ag(+) detection, when adding other metal ions to the Cys-CdS QDs solution, fluorescence spectra of Cys-CdS QDs did not change significantly revealing good selectivity of the sensors towards Ag(+). The working linear concentration range was found to be 0.1-1.5 µM with LOD of 68 nM. The proposed sensor was then applied to detect free Ag(+) in the silver nanoparticles solution. The results showed that the proposed sensor can be efficiently used with good accuracy and precision providing the simple method for detection of free Ag(+) in silver nanoparticles of quality control products.
Materials Chemistry Research Unit, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand.
Thitima
T
Khantaw
Chanida
C
Boonmee
Thawatchai
T
Tuntulani
Wittaya
W
Ngeontae
D019187:Cadmium Compounds / Q000737:chemistry*; D002414:Cations, Monovalent; D003543:Cysteamine / Q000737:chemistry*; D005456:Fluorescent Dyes; D057230:Limit of Detection; D053758:Nanoparticles / Q000737:chemistry*; D045663:Quantum Dots; D012834:Silver / Q000032:analysis*; D012996:Solutions; D013050:Spectrometry, Fluorescence; D013440:Sulfides / Q000737:chemistry*
D019187:Cadmium Compounds; D002414:Cations, Monovalent; D005456:Fluorescent Dyes; D012996:Solutions; D013440:Sulfides; C034939:cadmium sulfide; D012834:Silver; D003543:Cysteamine
Chemical sensors; Fluorescence sensors; Quantum dots; Silver ions; Silver nanoparticles