Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones.
The first copper-catalyzed oxysulfonylation reaction of alkenes with dioxygen and sulfonylhydrazides for the construction of β-ketosulfones has been developed under mild conditions without any ligand or additive.
The Key Laboratory of Life-Organic Analysis, Qufu Normal University, Qufu 273165, China. huawang_qfnu@126.com.
Wei
W
Wei
Chunli
C
Liu
Daoshan
D
Yang
Jiangwei
J
Wen
Jinmao
J
You
Yourui
Y
Suo
Hua
H
Wang
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006834:Hydrazines / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013450:Sulfones / Q000138:chemical synthesis* / Q000737:chemistry*
D000475:Alkenes; D006834:Hydrazines; D007659:Ketones; D009942:Organometallic Compounds; D013450:Sulfones; D003300:Copper; D010100:Oxygen