Determination of sulfonylureas in cereal samples with electrophoretic method using ionic liquid with dispersed carbon nanotubes as electrophoretic buffer.
A capillary electrophoresis method to determine four sulfonylureas in grain samples was developed using 10mM of 1-butyl-3-methyl imidazolium tetrafluoroborate (bminBF4) as electrophoretic buffer solution. 2mgL(-1) of Surfactant Coated-Single Wall-Carbon Nanotubes (SC-SWCNTs) was added to the buffer solution to improve the resolution. In this way, the separation of nicosulfuron, ethoxysulfuron, sulfometuron methyl and chlorsulfuron was carried out in 16min without using organic solvents. A clean up-preconcentration procedure was done prior to inject the sample into the CE instrument, in order to achieve the established maximum residue limits (MRLs). So, the detection limits (LODs) for each analytes were between 16.8 and 26.6μgkg(-1). The relative standard deviations (RSDs) were in the range 1.9-6.7%. A recovery study using the so-called matrix matched calibration demonstrates that no matrix interferences were found throughout the determination. The recovery percentages were ranged between 80% and 113%.
FIA Laboratory, Analytical Chemistry Section, INQUISUR (UNS-CONICET), Av. Alem 1253, B8000CPB Bahía Blanca, Buenos Aires, Argentina.
Valeria H
VH
Springer
Francisco
F
Aprile
Adriana G
AG
Lista
D002523:Edible Grain / Q000737:chemistry*; D019075:Electrophoresis, Capillary / Q000295:instrumentation / Q000379:methods*; D005506:Food Contamination / Q000032:analysis*; D006540:Herbicides / Q000032:analysis*; D052578:Ionic Liquids / Q000737:chemistry / Q000145:classification; D057230:Limit of Detection; D037742:Nanotubes, Carbon / Q000737:chemistry; D013453:Sulfonylurea Compounds / Q000032:analysis*
D006540:Herbicides; D052578:Ionic Liquids; D037742:Nanotubes, Carbon; D013453:Sulfonylurea Compounds
Capillary electrophoresis; Cereal samples; Ionic liquid; Single walled carbon nanotubes