Fluorescence Properties and Electrochemical Behavior of Some Schiff Bases Derived from N-Aminopyrimidine.
A series of Schiff bases (L 1 , L 2 and L 3) were prepared by refluxing aromatic aldehydes with N-Aminopyrimidine derivatives in methanol and ethanol. The structures of synthesized compounds were characterized by FTIR, (1)H NMR, (13)C NMR and microanalysis. The electrochemical behaviors of the Schiff base ligands were also discussed. Moreover, the evaluation of absorption and emission properties of the structures were carried out in five different solvents. The products show visible absorption maxima in the range of 304-576 nm, and emission maxima from 636 to 736 nm in all solvents tested.
Department of Chemistry, Faculty of Science, University of Yuzuncu Yil, 65080, Van, Turkey. mehmetgulcan65@gmail.com.
Mehmet
M
Gulcan
Department of Chemistry, Faculty of Science, University of Dokuz Eylül, 35160, Tınaztepe, Izmir, Turkey.
Ümit
Ü
Doğru
Department of Chemistry, Faculty of Science, University of Dokuz Eylül, 35160, Tınaztepe, Izmir, Turkey. gulsiyeozturk@yahoo.com.
Gülsiye
G
Öztürk
Health Services Vocational College, Batman University, 72100, Batman, Turkey.
Abdulkadir
A
Levent
Department of Chemistry, Faculty of Science, University of Yuzuncu Yil, 65080, Van, Turkey.
Esvet
E
Akbaş
D066241:Carbon-13 Magnetic Resonance Spectroscopy; D066244:Proton Magnetic Resonance Spectroscopy; D011743:Pyrimidines / Q000737:chemistry*; D012545:Schiff Bases / Q000737:chemistry*; D013050:Spectrometry, Fluorescence / Q000379:methods*
D011743:Pyrimidines; D012545:Schiff Bases; C012180:2-aminopyrimidine
N-Aminopyrimidine; Schiff base; electrochemistry; fluorescence