Radiation dose dependent change in physiochemical, mechanical and barrier properties of guar gum based films.
Mechanical and water vapor barrier properties of biodegradable films prepared from radiation processed guar gum were investigated. Films prepared from GG irradiated up to 500 Gy demonstrated significantly higher tensile strength as compared to non-irradiated control films. This improvement in tensile strength observed was demonstrated to be due to the ordering of polymer structures as confirmed by small angle X-ray scattering analysis. Exposure to doses higher than 500 Gy, however, resulted in a dose dependent decrease in tensile strength. A dose dependent decrease in puncture strength with no significant differences in the percent elongation was also observed at all the doses studied. Water vapor barrier properties of films improved up to 15% due to radiation processing. Radiation processing at lower doses for improving mechanical and barrier properties of guar based packaging films is demonstrated here for the first time.
Food Technology Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India.
Chaturbhuj K
CK
Saurabh
Sumit
S
Gupta
Jitendra
J
Bahadur
S
S
Mazumder
Prasad S
PS
Variyar
Arun
A
Sharma
D004307:Dose-Response Relationship, Radiation; D018857:Food Packaging; D005685:Galactans / Q000737:chemistry / Q000528:radiation effects*; D008351:Mannans / Q000737:chemistry / Q000528:radiation effects*; D010539:Permeability; D053149:Plant Gums / Q000737:chemistry / Q000528:radiation effects*; D011839:Radiation, Ionizing; D053838:Scattering, Small Angle; D013227:Steam; D013718:Tensile Strength; D014867:Water / Q000737:chemistry*; D014961:X-Ray Diffraction
D005685:Galactans; D008351:Mannans; D053149:Plant Gums; D013227:Steam; D014867:Water; C007894:guar gum
Biodegradable film; Guar gum; Irradiation; Mechanical properties; Small angle X-ray scattering