N2-, O2- and He-collision-induced broadening of sulfur dioxide ro-vibrational lines in the 9.2 μm atmospheric window.
Sulfur dioxide (SO2) is a molecule of considerable interest for both atmospheric chemistry and astrophysics. In the Earth's atmosphere, it enters in the sulfur cycle and it is ubiquitous present in polluted atmospheres, where it is responsible for acid rains. It is also of astrophysical and planetological importance, being present on Venus and in interstellar clouds. In this work the collisional broadening of a number of ν1 ro-vibrational lines of SO2 perturbed by N2, O2 and He are investigated at room temperature in the 9 μm atmospheric region by means of high resolution tunable diode laser (TDL) infrared spectroscopy. From N2- and O2-broadening coefficients, the broadening parameters of sulfur dioxide in air, useful for atmospheric applications, are derived as well. From the present measurements some conclusions on the quantum number dependence of the N2-, O2- and He-broadening coefficients are drawn. While the J dependence is weak for all the perturbers investigated, different trends with Ka are reported. N2-broadening coefficients show a slight decrease with increasing values of Ka, whereas O2 and He broadening cross sections first increase up to Ka(″)≈6 and then they keep a nearly constant value. A comparison and a brief discussion on the efficiency of self-, N2-, O2- and He-collisional dynamics are given. The data obtained represent a significant analysis on foreign broadening of SO2 useful for atmospheric remote sensing and astrophysical applications.
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Calle Larga S. Marta 2137, I-30123 Venezia, Italy. Electronic address: tasinato@unive.it.
Nicola
N
Tasinato
Andrea
A
Pietropolli Charmet
Paolo
P
Stoppa
Santi
S
Giorgianni
Giovanni
G
Buffa
D001272:Atmosphere / Q000737:chemistry*; D006371:Helium / Q000737:chemistry*; D008958:Models, Molecular; D009584:Nitrogen / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013458:Sulfur Dioxide / Q000737:chemistry*
D013458:Sulfur Dioxide; D006371:Helium; D009584:Nitrogen; D010100:Oxygen
Collisional cross sections; Foreign broadening coefficients; N(2), O(2), He broadening; Sulfur dioxide; TDL spectroscopy