α-Vinylation of amides with arylacetylenes: synthesis of allylamines under metal-free conditions.
A novel methodology for the α-vinylation of amides with arylacetylenes under metal-free conditions has been introduced. This methodology provides a new protocol to synthesize allylamines. In each product, the amount of the cis-isomer was more than that of the trans-isomer.
Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou 310028, People's Republic of China. wlbao@css.zju.edu.cn.
Manman
M
Sun
Huandong
H
Wu
Weiliang
W
Bao