title: Synthesis of vicinal aminoalcohols by stereoselective aza-Wacker cyclizations: access to (-)-acosamine by redox relay.
authors.affiliation: Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI 53706 (USA) stahl.chem.wisc.edu.
authors.forename: Adam B
authors.initials: AB
authors.lastname: Weinstein
authors.forename: David P
authors.initials: DP
authors.lastname: Schuman
authors.forename: Zhi Xu
authors.initials: ZX
authors.lastname: Tan
authors.forename: Shannon S
authors.initials: SS
authors.lastname: Stahl
mesh_terms: D000586:Amination; D000605:Amino Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D003500:Cyclization; D006595:Hexosamines / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000605:Amino Alcohols; D006595:Hexosamines; C010669:acosamine; D010165:Palladium
keywords: amination; oxidation; palladium; stereoselectivity; synthetic methods