title: Ru(II)-catalyzed ortho-C-H amination of arenes and heteroarenes at room temperature.
abstract: The Ru(II)-catalyzed ortho-C-H amination directed by a weakly coordinating amide auxiliary with O-benzoyl hydroxylamines at room temperature has been achieved. This reaction is compatible with heterocycles including pyrazole, thiophene, benzothiophene, furan, benzofuran, and indole.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China, and Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.
authors.forename: Ming
authors.initials: M
authors.lastname: Shang
authors.forename: Shao-Hang
authors.initials: SH
authors.lastname: Zeng
authors.forename: Shang-Zheng
authors.initials: SZ
authors.lastname: Sun
authors.forename: Hui-Xiong
authors.initials: HX
authors.lastname: Dai
authors.forename: Jin-Quan
authors.initials: JQ
authors.lastname: Yu
mesh_terms: D000577:Amides / Q000737:chemistry; D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013696:Temperature
chemical_list: D000577:Amides; D000588:Amines; D006841:Hydrocarbons, Aromatic; D009942:Organometallic Compounds; D012428:Ruthenium