title: Non-Poissonian formation of multiple excitons in photoexcited CdTe colloidal quantum qots by femtosecond nonresonant two-photon absorption.
abstract: Using direct multiexcitonic spectroscopy, we experimentally observe for the first time the non-Poissonian formation of multiple excitons by femtosecond nonresonant two-photon absorption process in semiconductor colloidal quantum dots (QDs). Each of the multiple excitons is individually generated via the absorption of a pair of photons during the femtosecond pulse irradiation. The non-Poissonian distribution of the generated excitons is reflected as a non-quadratic dependence on the pulse intensity of the average number of excitons per QD. This is the main observation of the present work. It is explained by a multiexcitonic formation model that is based on the phenomenon of intrapulse state filling of the few quantum electronic states accessed by the two-photon transitions. The experiments are conducted with 3.9-nm CdTe QDs in room-temperature hexane solution using the femtosecond pump-probe transient absorption technique, where an intense pump pulse generates the excitons and a weak probe pulse measures their number via intraband one-photon absorption.
authors.forename: Andrey
authors.initials: A
authors.lastname: Gandman
authors.forename: Michal
authors.initials: M
authors.lastname: Bronstein-Tojen
authors.forename: Viki
authors.initials: V
authors.lastname: Kloper
authors.forename: Merav
authors.initials: M
authors.lastname: Muallem
authors.forename: Diana
authors.initials: D
authors.lastname: Yanover
authors.forename: Efrat
authors.initials: E
authors.lastname: Lifshitz
authors.forename: Zohar
authors.initials: Z
authors.lastname: Amitay