title: Hydrodefluorination of carbon-fluorine bonds by the synergistic action of a ruthenium-palladium catalyst.
abstract: Catalytic hydrodefluorination of organic molecules is a major organometallic challenge, owing to the strength of C-F sigma bonds, and it is a process with multiple industrial applications. Here we report a new heterodimetallic ruthenium-palladium complex based on a triazolyl-di-ylidene ligand. The complex is remarkably active in the hydrodefluorination of aromatic and aliphatic carbon-fluorine bonds under mild reaction conditions. We observe that both metals are required to promote the reaction process. The overall process implies that the palladium fragment facilitates the C-F activation, whereas the ruthenium centre allows the reduction of the substrate via transfer hydrogenation from isopropanol/sodium t-butoxide. The activity of this heterodimetallic complex is higher than that shown by a mixture of the related homodimetallic complexes of ruthenium and palladium, demonstrating the catalytic benefits of the heterodimetallic complex linked by a single-frame ligand.
authors.affiliation: Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, Avda. Sos Baynat s/n, 12071 Castellón, Spain.
authors.forename: Sara
authors.initials: S
authors.lastname: Sabater
authors.forename: Jose A
authors.initials: JA
authors.lastname: Mata
authors.forename: Eduardo
authors.initials: E
authors.lastname: Peris