title: Nickel-catalyzed C-P cross-coupling of arylboronic acids with P(O)H compounds.
abstract: A novel and efficient Ni-catalyzed coupling of a wide range of arylboronic acids with H-phosphites, H-phosphinate esters, and H-phosphine oxides has been developed, providing a general and powerful tool for the synthesis of various aryl-phosphorus compounds, especially for valuable triarylphosphine oxides, in good to excellent yield. This protocol is the first Ni-catalyzed C-P bond-forming reaction between arylboronic acids and P(O)H compounds.
authors.affiliation: Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, Fujian, China.
authors.forename: Gaobo
authors.initials: G
authors.lastname: Hu
authors.forename: Weizhu
authors.initials: W
authors.lastname: Chen
authors.forename: Tingting
authors.initials: T
authors.lastname: Fu
authors.forename: Zhimin
authors.initials: Z
authors.lastname: Peng
authors.forename: Hongwei
authors.initials: H
authors.lastname: Qiao
authors.forename: Yuxing
authors.initials: Y
authors.lastname: Gao
authors.forename: Yufen
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010721:Phosphinic Acids / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D010721:Phosphinic Acids; D017905:Phosphites; D009532:Nickel