title: The Role of the Relative Dye/Photocatalyst Concentration in TiO2 Assisted Photodegradation Process.
abstract: Despite photocatalytic degradation is studied generally focusing the catalyst, its interaction with the contaminant molecule plays a fundamental role in the efficiency of that process. Then, we proposed a comparative study about the photodegradation of two well-known dyes, with different acidity/basicity - Methylene Blue (MB) and Rhodamine B (RhB), catalyzed by TiO2 nanoparticles, varying both dye and photocatalyst concentrations. The results showed that the amphoteric character of MB molecules, even in a range of concentration of 5.0-10.0 mg L(-1) , did not imply in pH variation in solution. Therefore, it did not affect the colloidal behavior of TiO2 nanoparticles, independent of the relative dye/catalyst concentration. The acid-base character of RhB influenced the resultant pH of the solution, implicating in different colloidal behavior of the nanoparticles and consequently, in different degradation conditions according to dye concentration. As the isoelectric point of TiO2 is between the pH range of the RhB solutions used in this study, from 1.0 to 7.5 mg L(-1) , the resultant pH was the key factor for degradation conditions, from a well dispersed to an agglomerated suspension.
authors.affiliation: Department of Chemistry, Federal University of São Carlos, São Carlos, Sao Paulo, Brazil.
authors.forename: Vagner R
authors.initials: VR
authors.lastname: de Mendonça
authors.affiliation: Department of Natural Sciences, Mathematics and Education, Federal University of São Carlos, Araras, Sao Paulo, Brazil.
authors.forename: Henrique A J L
authors.initials: HA
authors.lastname: Mourão
authors.affiliation: Department of Pharmacy, Federal University of Vales do Jequitinhonha e Mucuri, Diamantina, Minas Gerais, Brazil.
authors.forename: Andréa R
authors.initials: AR
authors.lastname: Malagutti
authors.affiliation: Embrapa Instrumentation, São Carlos, Sao Paulo, Brazil.
authors.forename: C
authors.initials: C
authors.lastname: Ribeiro