title: Tri-carbonyl-chlorido-(6',7'-di-hydro-5'H-spiro-[cyclo-hexane-1,6'-dipyrido[3,2-d:2',3'-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I).
abstract: In the title compound, [ReCl(C16H18N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H⋯Cl hydrogen bonds link complex mol-ecules, forming a two-dimensional network parallel to (100).
authors.affiliation: Department of Chemical & Biological Sciences, University of Huddersfield, Queensgate, Huddersfield HD1 3DH, England.
authors.forename: Oliver R
authors.initials: OR
authors.lastname: Clegg
authors.forename: Lindsay P
authors.initials: LP
authors.lastname: Harding
authors.forename: John W
authors.initials: JW
authors.lastname: Miller
authors.forename: Craig R
authors.initials: CR
authors.lastname: Rice