title: A C(3v)-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties.
abstract: A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected.
authors.affiliation: Dpt. de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Vicente Sos Baynat s/n, 12071-Castellón, Spain. eperis@uji.es.
authors.forename: Candela
authors.initials: C
authors.lastname: Segarra
authors.forename: Jens
authors.initials: J
authors.lastname: Linke
authors.forename: Elena
authors.initials: E
authors.lastname: Mas-Marzá
authors.forename: Dietmar
authors.initials: D
authors.lastname: Kuck
authors.forename: Eduardo
authors.initials: E
authors.lastname: Peris