title: Four levels of wavelength-selective uncaging for oligonucleotides.
abstract: In this study the new nucleobase-caged nucleotides dT(NpHP) and dT(DEACM) are introduced. Together with two other caging groups (NDBF and NPP) this results in four layers of wavelength-selective uncaging for oligonucleotides, sequentially going from 505 to 440 nm, 365 nm, and finally to 313 nm for the photolysis reaction.
authors.affiliation: Institute for Organic Chemistry and Chemical Biology, Buchmann Institute for Molecular Life Sciences, Goethe-University Frankfurt , Max-von-Laue-Str. 9, 60438 Frankfurt, Germany.
authors.forename: Alexandre
authors.initials: A
authors.lastname: Rodrigues-Correia
authors.forename: Xenia M M
authors.initials: XM
authors.lastname: Weyel
authors.forename: Alexander
authors.initials: A
authors.lastname: Heckel
mesh_terms: D003374:Coumarins / Q000737:chemistry; D004247:DNA / Q000737:chemistry*; D015394:Molecular Structure; D009705:Nucleosides / Q000737:chemistry*; D009841:Oligonucleotides / Q000737:chemistry*; D055668:Photochemical Processes; D010782:Photolysis; D013056:Spectrophotometry, Ultraviolet
chemical_list: D003374:Coumarins; D009705:Nucleosides; D009841:Oligonucleotides; D004247:DNA