title: Synthesis, characterization and reactivity of potassium and barium complexes containing phosphane-borane stabilized methanides.
abstract: The polymeric potassium complex [K{CH(PPh2BH3)2}]∞ (1) was prepared and used as a starting material for the syntheses of related N,N,N',N'-tetramethylethylenediamine (tmeda) and N,N,N',N',N''-pentamethyldiethylenetriamine (pmdta) ligated potassium derivatives [K{CH(PPh2BH3)2}(tmeda)2]∞ (2) and [K{CH(PPh2BH3)2}(pmdta)]2 (3). Salt metathesis reactions with [BaI2(thf)5] allowed the synthesis of the barium derivatives [BaI{CH(PPh2BH3)2}(thf)5] (5) and [Ba{CH(PPh2BH3)2}2(solv)2}] (solv = Et2O, thf) (6), which are more prone to subsequent reactions than the potassium derivatives. One of the resulting products, [Ba4O{CH(PPh2BH3)2}3{Ph2PCH(BH3)PPh2BH3}3] (7), which contains two different isomeric forms of the bis(borane) adduct of Ph2PCHPPh2, was isolated. The complexes were characterized by NMR techniques and single crystal X-ray diffraction measurements.
authors.affiliation: Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-University Jena, Humboldtstraße 8, D-07743 Jena, Germany. j.langer@uni-jena.de.
authors.forename: Jens
authors.initials: J
authors.lastname: Langer
authors.forename: Helmar
authors.initials: H
authors.lastname: Görls