title: Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes.
abstract: Reaction of a variety of dienynes with bis(pinacolato)diboron catalysed by Pd bis(trifluoroacetate) affords allylic boronates containing five or six membered carbo- or heterocycles, by concomitant formation of one C-C and one C-B bonds. Resulting allylboronates can be employed for a variety of subsequent transformations.
authors.affiliation: Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain. diego.cardenas@uam.es.
authors.forename: Ruth
authors.initials: R
authors.lastname: López-Durán
authors.forename: Alicia
authors.initials: A
authors.lastname: Martos-Redruejo
authors.forename: Elena
authors.initials: E
authors.lastname: Buñuel
authors.forename: Virtudes
authors.initials: V
authors.lastname: Pardo-Rodríguez
authors.forename: Diego J
authors.initials: DJ
authors.lastname: Cárdenas