title: Giant magnetic susceptibility of gold nanorods detected by magnetic alignment.
abstract: We have determined the magnetic properties of single-crystalline Au nanorods in solution using an optically detected magnetic alignment technique. The rods exhibit a large anisotropy in the magnetic volume susceptibility (Δχ(V)). Δχ(V) increases with decreasing rod size and increasing aspect ratio and corresponds to an average volume susceptibility (χ(V)), which is drastically enhanced relative to bulk Au. This high value of χ(V) is confirmed by SQUID magnetometry and is temperature independent (between 5 and 300 K). Given this peculiar size, shape, and temperature dependence, we speculate that the enhanced χ(V) is the result of orbital magnetism due to mesoscopic electron trajectories within the nanorods.
authors.affiliation: High Field Magnet Laboratory, Institute of Molecules and Materials, Radboud University Nijmegen, Toernooiveld 7, 6525 ED Nijmegen, Netherlands.
authors.forename: P G
authors.initials: PG
authors.lastname: van Rhee
authors.forename: P
authors.initials: P
authors.lastname: Zijlstra
authors.forename: T G A
authors.initials: TG
authors.lastname: Verhagen
authors.forename: J
authors.initials: J
authors.lastname: Aarts
authors.forename: M I
authors.initials: MI
authors.lastname: Katsnelson
authors.forename: J C
authors.initials: JC
authors.lastname: Maan
authors.forename: M
authors.initials: M
authors.lastname: Orrit
authors.forename: P C M
authors.initials: PC
authors.lastname: Christianen