title: Development of a novel multifunctional n,p ligand for highly enantioselective palladium-catalyzed asymmetric allylic etherification of alcohols and silanols.
abstract: CycloN2P2-Phos! The use of the multidentate phosphine, CycloN2P2-Phos, which contains four heteroatoms (two nitrogen and two phosphorus atoms), in the palladium-catalyzed asymmetric allylic etherification (AAE) of alcohols and silanols leads to excellent levels of enantioselectivity (up to 99 % ee).
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012 (P. R. China), Fax: (+86) 571-28865135.
authors.forename: Fei
authors.initials: F
authors.lastname: Ye
authors.forename: Zhan-Jiang
authors.initials: ZJ
authors.lastname: Zheng
authors.forename: Li
authors.initials: L
authors.lastname: Li
authors.forename: Ke-Fang
authors.initials: KF
authors.lastname: Yang
authors.forename: Chun-Gu
authors.initials: CG
authors.lastname: Xia
authors.forename: Li-Wen
authors.initials: LW
authors.lastname: Xu
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D004987:Ethers / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D000498:Allyl Compounds; D004987:Ethers; D008024:Ligands; D010720:Phosphines; D012821:Silanes; C082343:silanol; D010165:Palladium
keywords: allylic etherification; asymmetric catalysis; chiral ligands; palladium; silanols