title: Highly diastereo- and enantioselective [3+2] annulation of isatin-derived Morita-Baylis-Hillman carbonates with trifluoropyruvate catalyzed by tertiary amines.
abstract: An enantioselective [3+2] annulation of Morita-Baylis-Hillman carbonates with trifluoropyruvate catalyzed by modified cinchona alkaloids was developed in good to excellent yields with excellent diastereo- and enantioselectivities.
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. lliu@iccas.ac.cn.
authors.forename: Neng-Jun
authors.initials: NJ
authors.lastname: Zhong
authors.forename: Feng
authors.initials: F
authors.lastname: Wei
authors.forename: Qing-Qing
authors.initials: QQ
authors.lastname: Xuan
authors.forename: Li
authors.initials: L
authors.lastname: Liu
authors.forename: Dong
authors.initials: D
authors.lastname: Wang
authors.forename: Yong-Jun
authors.initials: YJ
authors.lastname: Chen
mesh_terms: D000588:Amines / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D007510:Isatin / Q000737:chemistry*; D019289:Pyruvic Acid / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
chemical_list: D000588:Amines; D002254:Carbonates; D007510:Isatin; D019289:Pyruvic Acid