title: Bingel-Hirsch monoadducts of TiSc2N@Ih-C80versus Sc3N@Ih-C80: reactivity improvement via internal metal atom substitution.
abstract: The first Bingel-Hirsch reaction of TiSc2N@Ih-C80 afforded two unconventional singly bonded monoadducts, revealing the dramatically improved reactivity compared to Sc3N@Ih-C80 and obvious change in the addition pattern.
authors.affiliation: Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion & Department of Materials Science and Engineering, University of Science and Technology of China (USTC), Hefei 230026, China. sfyang@ustc.edu.cn.
authors.forename: Shangfeng
authors.initials: S
authors.lastname: Yang
authors.forename: Chuanbao
authors.initials: C
authors.lastname: Chen
authors.forename: Xiaofang
authors.initials: X
authors.lastname: Li
authors.forename: Tao
authors.initials: T
authors.lastname: Wei
authors.forename: Fupin
authors.initials: F
authors.lastname: Liu
authors.forename: Song
authors.initials: S
authors.lastname: Wang
mesh_terms: D037741:Fullerenes / Q000737:chemistry*; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D012538:Scandium / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D037741:Fullerenes; D014025:Titanium; D009584:Nitrogen; D012538:Scandium