title: Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor.
abstract: Supramolecular CHπ interactions cause a ruffling of the otherwise coplanar ribbon-like arrays of radicals in the structure of the oxobenzene-bridged bisdithiazolyl . The material displays a conductivity σ(300 K) = 6 × 10(-3) S cm(-1) (Eact = 0.16 eV) and orders antiferromagnetically below 4 K. At applied fields above 1 kOe the material displays metamagnetic behavior.
authors.affiliation: Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. oakley@uwaterloo.ca.
authors.forename: Joanne W L
authors.initials: JW
authors.lastname: Wong
authors.forename: Aaron
authors.initials: A
authors.lastname: Mailman
authors.forename: Stephen M
authors.initials: SM
authors.lastname: Winter
authors.forename: Craig M
authors.initials: CM
authors.lastname: Robertson
authors.forename: Rebecca J
authors.initials: RJ
authors.lastname: Holmberg
authors.forename: Muralee
authors.initials: M
authors.lastname: Murugesu
authors.forename: Paul A
authors.initials: PA
authors.lastname: Dube
authors.forename: Richard T
authors.initials: RT
authors.lastname: Oakley