title: Catalytic enantioselective Michael addition of α-aryl-α-isocyanoacetates to vinyl selenone: synthesis of α,α-disubstituted α-amino acids and (+)- and (-)-trigonoliimine A.
authors.affiliation: Laboratory of Synthesis and Natural Products, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, CH-1015 Lausanne (Switzerland).
authors.forename: Thomas
authors.initials: T
authors.lastname: Buyck
authors.forename: Qian
authors.initials: Q
authors.lastname: Wang
authors.forename: Jieping
authors.initials: J
authors.lastname: Zhu
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000596:Amino Acids / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D026121:Indole Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D016566:Organoselenium Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000085:Acetates; D000596:Amino Acids; D026121:Indole Alkaloids; D016566:Organoselenium Compounds; C551376:trigonoliimine A
keywords: asymmetric synthesis; heterocycles; natural products; organocatalysis; selenium