title: Cross-coupling reactions involving metal carbene: from C═C/C-C bond formation to C-H bond functionalization.
abstract: Cross-coupling reactions involving metal-carbene are emerging as a new type of carbon-carbon bond-forming reaction. The aim of this JOCSynopsis is to provide an overview of the most recent development of these reactions, focusing on the use of diazo compounds (or in situ formed diazo compounds from N-tosylhydrazones) as carbene precursors. In addition, the integration of this type of reaction with C-H bond functionalization is also surveyed.
authors.affiliation: Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University , Beijing 100871, China.
authors.forename: Zhenxing
authors.initials: Z
authors.lastname: Liu
authors.forename: Jianbo
authors.initials: J
authors.lastname: Wang