title: Phosphate functionalized graphene with tunable mechanical properties.
abstract: The synthesis of a covalently modified graphene oxide derivative with exceptional and tunable compressive strength is reported. Treatment of graphene oxide with triethyl phosphite in the presence of LiBr produces monolithic structures comprised of lithium phosphate oligomers tethered to graphene through covalent phosphonate linkages. Variation of the both phosphate content and associated cation produces materials of various compressive strengths and elasticity.
authors.affiliation: Department of Chemistry and The Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.
authors.forename: John B
authors.initials: JB
authors.lastname: Goods
authors.forename: Stefanie A
authors.initials: SA
authors.lastname: Sydlik
authors.forename: Joseph J
authors.initials: JJ
authors.lastname: Walish
authors.forename: Timothy M
authors.initials: TM
authors.lastname: Swager
mesh_terms: D001965:Bromides / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D018020:Lithium Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry*
chemical_list: D001965:Bromides; D018020:Lithium Compounds; D010087:Oxides; D010710:Phosphates; D006108:Graphite; C040949:lithium bromide
keywords: Arbuzov reaction; graphene oxide; lithium phosphate