title: Preparation of hydrophobic metal-organic frameworks via plasma enhanced chemical vapor deposition of perfluoroalkanes for the removal of ammonia.
abstract: Plasma enhanced chemical vapor deposition (PECVD) of perfluoroalkanes has long been studied for tuning the wetting properties of surfaces. For high surface area microporous materials, such as metal-organic frameworks (MOFs), unique challenges present themselves for PECVD treatments. Herein the protocol for development of a MOF that was previously unstable to humid conditions is presented. The protocol describes the synthesis of Cu-BTC (also known as HKUST-1), the treatment of Cu-BTC with PECVD of perfluoroalkanes, the aging of materials under humid conditions, and the subsequent ammonia microbreakthrough experiments on milligram quantities of microporous materials. Cu-BTC has an extremely high surface area (~1,800 m(2)/g) when compared to most materials or surfaces that have been previously treated by PECVD methods. Parameters such as chamber pressure and treatment time are extremely important to ensure the perfluoroalkane plasma penetrates to and reacts with the inner MOF surfaces. Furthermore, the protocol for ammonia microbreakthrough experiments set forth here can be utilized for a variety of test gases and microporous materials.
authors.affiliation: Research and Development, Science Applications International Corporation (SAIC).
authors.forename: Jared B
authors.initials: JB
authors.lastname: DeCoste
authors.forename: Gregory W
authors.initials: GW
authors.lastname: Peterson
mesh_terms: D000641:Ammonia / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D000073396:Metal-Organic Frameworks; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D058626:Plasma Gases / Q000737:chemistry
chemical_list: D000073396:Metal-Organic Frameworks; D009942:Organometallic Compounds; D058626:Plasma Gases; C539834:bis(1,3,5-benzenetricarboxylate)tricopper(II); D000641:Ammonia; D003300:Copper