title: Observing the formation and the reactivity of an octahedral iron(V) nitrido complex in real time.
abstract: Give me five: Time-resolved Fourier-transform IR spectroscopy is used to time-resolve the formation and the reaction dynamics of a fourfold symmetrical nitrido iron(V) complex (light blue C, red Fe, blue N) in liquid solution under physiological and technologically relevant conditions.
authors.affiliation: Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer.
authors.forename: Joel
authors.initials: J
authors.lastname: Torres-Alacan
authors.forename: Ujjal
authors.initials: U
authors.lastname: Das
authors.forename: Alexander C
authors.initials: AC
authors.lastname: Filippou
authors.forename: Peter
authors.initials: P
authors.lastname: Vöhringer
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D055668:Photochemical Processes; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D005290:Ferric Compounds; C540999:iron nitrido complex
keywords: IR spectroscopy; high-valent iron; nitride; photochemistry; time-resolved spectroscopy