title: Oxidative methane reforming with an intelligent catalyst: sintering-tolerant supported nickel nanoparticles.
abstract: Smart Catalyst: The cyclical diffusion of nanometer-sized nickel clusters into and out of the perovskite structure under elevated temperature and reducing and oxidizing atmosphere could in situ redeliver and redisperse Ni, thereby reinforcing the anti-coking and -sintering of Ni during oxidative reforming of CH4 .
authors.affiliation: Department of Chemical Engineering, Sichuan University, Address Chengdu 610065 (PR China); Department of Chemical Engineering, University of Queensland, Brisbane 4067 (Australia).
authors.forename: Jie
authors.initials: J
authors.lastname: Deng
authors.forename: Mengdie
authors.initials: M
authors.lastname: Cai
authors.forename: Wenjing
authors.initials: W
authors.lastname: Sun
authors.forename: Xuemei
authors.initials: X
authors.lastname: Liao
authors.forename: Wei
authors.initials: W
authors.lastname: Chu
authors.forename: Xiu Song
authors.initials: XS
authors.lastname: Zhao
mesh_terms: D017610:Calcium Compounds / Q000737:chemistry; D002384:Catalysis; D053768:Metal Nanoparticles / Q000737:chemistry*; D008697:Methane / Q000737:chemistry*; D036103:Nanotechnology; D009532:Nickel / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry; D014025:Titanium / Q000737:chemistry
chemical_list: D017610:Calcium Compounds; D010087:Oxides; C059910:perovskite; D009532:Nickel; D014025:Titanium; D008697:Methane
keywords: diffusion; heterogeneous catalysis; methane reforming; nanoparticles; nickel