title: 1,4-Metal migration in a Cp*Rh(III) complex.
abstract: The reaction of [Cp*RhCl(Ph)(PR3)] (R = Ph or Me) with internal alkynes in the presence of NaBAr(F)4 affords the o-vinylaryl complex with a Rh-(vinyl CH) agostic interaction by way of the alkyne insertion followed by 1,4-rhodium migration, providing the first example of the 1,4-migration of a Rh(III) center.
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo, Japan. yo-ishii@kc.chuo-u.ac.jp.
authors.forename: Yousuke
authors.initials: Y
authors.lastname: Ikeda
authors.forename: Koichi
authors.initials: K
authors.lastname: Takano
authors.forename: Shintaro
authors.initials: S
authors.lastname: Kodama
authors.forename: Youichi
authors.initials: Y
authors.lastname: Ishii