title: The aminocyclodextrin/Pd(OAc)2 complex as an efficient catalyst for the Mizoroki-Heck cross-coupling reaction.
abstract: An aminocyclodextrin/Pd(OAc)2 complex is used as an efficient, reusable catalyst in the Mizoroki-Heck reaction of aryl halides/triflates with olefins to give carbon-carbon-coupled products in good to excellent yields. This simple, efficient catalytic system is applicable to a wide range of aryl and heteroaryl halides/triflates and olefins. This environmentally benign procedure is less hazardous, milder, uses a catalytic amount of ligand and Pd(OAc)2 , avoids an inert atmosphere, and catalyst recovery and reusability are achieved.
authors.affiliation: School of Chemistry, Madurai Kamaraj University, Madurai 625021 (India), Fax: (+91) 4522459181.
authors.forename: Kuppusamy
authors.initials: K
authors.lastname: Kanagaraj
authors.forename: Kasi
authors.initials: K
authors.lastname: Pitchumani
keywords: Mizoroki-Heck reaction; aminocyclodextrins; aqueous media; aryl halides/triflates; reusable catalysts; water chemistry