title: From a mononuclear Ni(II) precursor to antiferromagnetically coupled trinuclear double-stranded helicates.
abstract: Reaction of the mononuclear Ni(II) complex [Ni{2-Py(6-NH2)NHC(S)NP(S)(OiPr)2}2] with different salicylaldehydes leads to new antiferromagnetically coupled trinuclear double-stranded helicates , where Ni(II) metal ions are coordinated by two bis-anionic thiourea ligands and two deprotonated molecules of the corresponding aldehyde.
authors.affiliation: Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST), Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium. yann.garcia@uclouvain.be.
authors.forename: Damir A
authors.initials: DA
authors.lastname: Safin
authors.forename: Maria G
authors.initials: MG
authors.lastname: Babashkina
authors.forename: Koen
authors.initials: K
authors.lastname: Robeyns
authors.forename: Mathieu
authors.initials: M
authors.lastname: Rouzières
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac
authors.forename: Yann
authors.initials: Y
authors.lastname: Garcia
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry*; D060328:Magnetic Phenomena; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D000447:Aldehydes; D056831:Coordination Complexes; C013243:salicylaldehyde; D009532:Nickel