title: The rearrangement of tert-butylperoxides for the construction of polysubstituted furans.
abstract: The Brønsted acid catalyzed rearrangement of tert-butyl peroxides provides a new strategy to construct 2,3-disubstituted furans via 1,2-aryl migration. In addition, tert-butyl peroxides could also be transformed into 2,3,5-trisubstituted or 2,5-disubstituted furans through a sequence of base-catalyzed Kornblum-DelaMare rearrangements and acid-promoted Paal-Knorr reactions.
authors.affiliation: Department of Chemistry, Renmin University of China , Beijing 100872, China.
authors.forename: Xiaojian
authors.initials: X
authors.lastname: Zheng
authors.forename: Shenglin
authors.initials: S
authors.lastname: Lu
authors.forename: Zhiping
authors.initials: Z
authors.lastname: Li