title: Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions.
abstract: Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H(+), D(+), and H3(+) are calculated.
authors.affiliation: Department of Physics, University of Latvia, Riga LV-1586, Latvia.
authors.forename: M
authors.initials: M
authors.lastname: Auzinsh
authors.forename: E I
authors.initials: EI
authors.lastname: Dashevskaya
authors.forename: I
authors.initials: I
authors.lastname: Litvin
authors.forename: E E
authors.initials: EE
authors.lastname: Nikitin
authors.forename: J
authors.initials: J
authors.lastname: Troe
mesh_terms: D003903:Deuterium / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D008697:Methane / Q000737:chemistry*; D010316:Particle Size; D011789:Quantum Theory; D055672:Static Electricity; D013499:Surface Properties; D014316:Tritium / Q000737:chemistry*
chemical_list: D014316:Tritium; D006859:Hydrogen; D003903:Deuterium; D008697:Methane