title: A flexible porous Cu(II) bis-imidazolate framework with ultrahigh concentration of active sites for efficient and recyclable CO2 capture.
abstract: By virtue of planar Cu2(μ-OH)2(2+) cluster units, a flexible porous metal azolate framework not only adsorbs large amounts of CO2 (19.6 wt% or 266 g L(-1) at 298 K and 1 atm) with a high zero-coverage adsorption enthalpy (-47 kJ mol(-1)), but also desorbs quickly at very low temperatures.
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China. zhangjp7@mail.sysu.edu.cn.
authors.forename: Dong-Dong
authors.initials: DD
authors.lastname: Zhou
authors.forename: Chun-Ting
authors.initials: CT
authors.lastname: He
authors.forename: Pei-Qin
authors.initials: PQ
authors.lastname: Liao
authors.forename: Wei
authors.initials: W
authors.lastname: Xue
authors.forename: Wei-Xiong
authors.initials: WX
authors.lastname: Zhang
authors.forename: Hao-Long
authors.initials: HL
authors.lastname: Zhou
authors.forename: Jie-Peng
authors.initials: JP
authors.lastname: Zhang
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Chen