title: An iron/amine-catalyzed cascade process for the enantioselective functionalization of allylic alcohols.
abstract: Three is a lucky number: An enantioselective transformation of allylic alcohols into β-chiral saturated alcohols has been developed by combining two distinct metal- and organocatalyzed catalytic cycles. This waste-free triple cascade process merges an iron-catalyzed borrowing-hydrogen step with an aminocatalyzed nucleophilic addition reaction.
authors.affiliation: Aix-Marseille Université, Centrale Marseille, CNRS iSm2 UMR 7313, 13397, Marseille (France) http://ism2.univ-amu.fr/pages-bleues/index2.htm. adrien.quintard-inv@univ-amu.fr.
authors.forename: Adrien
authors.initials: A
authors.lastname: Quintard
authors.forename: Thierry
authors.initials: T
authors.lastname: Constantieux
authors.forename: Jean
authors.initials: J
authors.lastname: Rodriguez
keywords: asymmetric catalysis; dual catalysis; hydrogen transfer; iron; organocatalysis