title: Photocatalytic hydrogen evolution with a hydrogenase in a mediator-free system under high levels of oxygen.
abstract: Take a breath: An oxygen-tolerant hydrogenase can be employed with a dye in a photocatalytic scheme for the generation of H2 . The homogeneous system does not require a redox mediator and visible-light irradiation yields high amounts of H2 even in the presence of air.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-reisner.ch.cam.ac.uk/
authors.forename: Tsubasa
authors.initials: T
authors.lastname: Sakai
authors.forename: Dirk
authors.initials: D
authors.lastname: Mersch
authors.forename: Erwin
authors.initials: E
authors.lastname: Reisner
keywords: hydrogen; hydrogenases; oxygen; photocatalysis; water splitting