title: Catalytic cascade hydroalkoxylation/isomerization/ [4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles.
abstract: Enyne alcohols can react as precursors of either dienes or dienophiles with different substrates after hydroxylation and isomerization by gold catalysis. As such, oxa-bridged tricyclo[5.2.2.02,6]-undec-8-ene-3,5-dione derivatives have been obtained by the Diels–Alder reaction and tetrahydro-1H-furo[3,4-c]pyran derivatives could be accessed by the hetero-Diels–Alder cycloaddition.
authors.forename: Rui
authors.initials: R
authors.lastname: Guo
authors.forename: Kang-Nan
authors.initials: KN
authors.lastname: Li
authors.forename: Liu-Zhu
authors.initials: LZ
authors.lastname: Gong
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D061565:Cycloaddition Reaction; D006046:Gold / Q000737:chemistry; D007536:Isomerism; D015394:Molecular Structure; D011714:Pyrans / Q000737:chemistry
chemical_list: D000438:Alcohols; D000475:Alkenes; D000480:Alkynes; D011714:Pyrans; D006046:Gold