title: Doped nanocrystals as plasmonic probes of redox chemistry.
abstract: A (nano)crystal-clear view: With doped semiconductor nanocrystals, local chemical events can be probed through their perturbation of the carrier density of the nanocrystal. Examples demonstrate that redox processes and ligand chemistry can induce changes in the vacancy density within copper(I) sulfide nanorods, allowing such events to be detected by strong shifts in localized surface plasmon resonance.
authors.affiliation: Department of Chemistry, University of Illinois at Urbana, Champaign, 600 S. Mathews Ave, Urbana, IL 61801 (USA) http://www.nanogold.org; Department of Physics and Materials Research Lab, University of Illinois at Urbana Champaign, Urbana, IL 61801 (USA). jain@illinois.edu.
authors.forename: Prashant K
authors.initials: PK
authors.lastname: Jain
authors.forename: Karthish
authors.initials: K
authors.lastname: Manthiram
authors.forename: Jesse H
authors.initials: JH
authors.lastname: Engel
authors.forename: Sarah L
authors.initials: SL
authors.lastname: White
authors.forename: Jacob A
authors.initials: JA
authors.lastname: Faucheaux
authors.forename: A Paul
authors.initials: AP
authors.lastname: Alivisatos
keywords: copper sulfide; doping; ion exchange; nanocrystals; semiconductor plasmons