title: Structural and magnetic studies of a new Co(II) thiocyanato coordination polymer showing slow magnetic relaxations and a metamagnetic transition.
abstract: Reaction of Co(NCS)2 with 4-ethylpyridine leads to the formation of three new compounds of composition Co(NCS)2(4-ethylpyridine)4 (1), [(Co(NCS)2]2(4-ethylpyridine)6 (2), and [Co(NCS)2(4-ethylpyridine)2]n (3). In all compounds the coordination of the Co(II) ions is distorted octahedral. 1 consists of discrete monomeric complexes and in 2 two Co(II) cations are linked by pairs of μ-1,3-bridging thiocyanato ligands into dimers. In the crystal structure of 3 the Co(II) cations are connected into chains by the same bridge as in 2. Magnetic studies show that 1 and 2 are paramagnets down to a temperature of 2 K, while compound 3, which is the main object of this study, is an antiferromagnet with the Néel temperature T(N) = 3.4 K. Its magnetic structure is built from ferromagnetic chains, which are weakly antiferromagnetically coupled. With increasing magnetic field a metamagnetic transition starts at ~175 Oe, as observed for a polycrystalline sample. Magnetic relaxations, which were observed in the antiferromagnetic state, are retained at the metamagnetic transition. With decreasing field 3 remains in a state, in which except of the faster magnetic relaxation process in single chains also a slower process coexists resulting in the appearance of a magnetic hysteresis loop.
authors.affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel , Max-Eyth-Straße 2, 24118 Kiel, Germany.
authors.forename: Susanne
authors.initials: S
authors.lastname: Wöhlert
authors.forename: Tomasz
authors.initials: T
authors.lastname: Fic
authors.forename: Zbigniew
authors.initials: Z
authors.lastname: Tomkowicz
authors.forename: Stefan G
authors.initials: SG
authors.lastname: Ebbinghaus
authors.forename: Michał
authors.initials: M
authors.lastname: Rams
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Haase
authors.forename: Christian
authors.initials: C
authors.lastname: Näther