title: Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex.
abstract: A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.
authors.affiliation: Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan. ynishiba@sogo.t.u-tokyo.ac.jp.
authors.forename: Kazuya
authors.initials: K
authors.lastname: Arashiba
authors.forename: Shogo
authors.initials: S
authors.lastname: Kuriyama
authors.forename: Kazunari
authors.initials: K
authors.lastname: Nakajima
authors.forename: Yoshiaki
authors.initials: Y
authors.lastname: Nishibayashi