title: Synthesis and Study the Effect of Donor-Acceptor Substituent on Fluorescence Behavior of Thieno[3, 2-c]pyridine Derivatives.
abstract: 4-Hetero-1-yl-2-bromothieno[3,2-c]pyridines 3(a-d) were synthesized by the reaction of 2-bromo-4-chlorothieno[3,2-c]pyridine (1) and cyclic amine 2(a-d), which on Suzuki coupling with substituted boronic acids 4(a-f) exclusively converted to corresponding 4-hetero -1-yl-2-arylthieno[3,2-c]pyridine 5(a-x) in good yields. The effect of donor-acceptor substituent on absorption emission properties and fluorescent quantum yield of new thienopyridine derivatives 5(a-x) were studied.
authors.affiliation: Organic Chemistry Research Centre, Department of Chemistry, K. T. H. M. College, Gangapur Road, Nashik, 422 002, M.S., India. raghunath_toche@rediffmail.com.
authors.forename: Raghunath B
authors.initials: RB
authors.lastname: Toche
authors.affiliation: Organic Chemistry Research Centre, Department of Chemistry, K. T. H. M. College, Gangapur Road, Nashik, 422 002, M.S., India.
authors.forename: Sunil N
authors.initials: SN
authors.lastname: Chavan
keywords: 4-Hetero-1-yl-2-bromothieno[3,2-c]pyridines; Fluorescence; HOMO- LUMO; Quantum yield; Thieno[3, 2-c]pyridine