title: Investigating the need for complex vs. simple scenarios to improve predictions of aquatic ecosystem exposure with the SoilPlus model.
abstract: A spatially-explicit version of the recent multimedia fate model SoilPlus was developed and applied to predict the runoff of three pesticides in a small agricultural watershed in north-eastern Italy. In order to evaluate model response to increasing spatial resolution, a tiered simulation approach was adopted, also using a dynamic model for surface water (DynA model), to predict the fate of pesticides in runoff water and sediment, and concentrations in river water. Simulation outputs were compared to water concentrations measured in the basin. Results showed that a high spatial resolution and scenario complexity improved model predictions of metolachlor and terbuthylazine in runoff to an acceptable performance (R(2) = 0.64-0.70). The importance was also shown of a field-based database of properties (i.e. soil texture and organic carbon, rainfall and water flow, pesticides half-life in soil) in reducing the distance between predicted and measured surface water concentrations and its relevance for risk assessment.
authors.affiliation: Environmental Modelling Group, Department of Science and High Technology, University of Insubria, Via Valleggio 11, 22100 Como, CO, Italy.
authors.forename: Davide
authors.initials: D
authors.lastname: Ghirardello
authors.forename: Melissa
authors.initials: M
authors.lastname: Morselli
authors.forename: Stefan
authors.initials: S
authors.lastname: Otto
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Zanin
authors.forename: Antonio
authors.initials: A
authors.lastname: Di Guardo
mesh_terms: D000383:Agriculture; D017753:Ecosystem; D004784:Environmental Monitoring / Q000379:methods*; D005618:Fresh Water / Q000737:chemistry; D006207:Half-Life; D007558:Italy; D008956:Models, Chemical; D010575:Pesticides / Q000032:analysis*; D012987:Soil / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014877:Water Pollution, Chemical / Q000706:statistics & numerical data*
chemical_list: D010575:Pesticides; D012987:Soil; D014874:Water Pollutants, Chemical
keywords: Aquatic ecosystem exposure; DynA; Fugacity model; GIS; Sensitivity; SoilPlus; Spatial resolution