title: Atmospheric deposition of current use pesticides in the Arctic: snow core records from the Devon Island Ice Cap, Nunavut, Canada.
abstract: Current use pesticides (CUPs) have been detected in the Arctic, even though there are no direct sources and their long range atmospheric transport potential is generally lower than that of legacy pesticides. Data on the deposition of CUPs in the Arctic are required to assess the impact of their global usage and emission. In this study, selected CUPs were measured in the layers of a snow pit sampled on the Devon Ice Cap, Nunavut, Canada. The oldest sampled layers correspond to deposition from the early 1990s. Dacthal and endosulfan sulfate were most frequently detected, with peak deposition fluxes of 1.0 and 0.4 pg cm(-2) per year. While endosulfan sulfate was more abundant than its parent compounds in most years, endosulfan (sum of α and β isomers) was predominant in 2003 and 2006, which together with air mass backward trajectories suggests a possible origin from ongoing use in Eurasia. The interannual variation in CUP deposition fluxes could not be explained with annual variations in the extent of air mass origin over agricultural lands, suggesting that other factors, such as the interannual variation in pesticide use, play a role in affecting the long range transport of CUPs to the Arctic. The very high variability in the concentrations of CUPs in the horizontal layers of Arctic ice caps is most plausibly explained by the highly episodic nature of long range atmospheric transport and deposition. While this strong influence of rare events limits the suitability of ice caps as reliable records of historical trends in Arctic contaminant deposition with annual resolution, the presence of concentration peaks in the ice record is proof of the possibility of such transport and deposition.
authors.affiliation: Department of Physical and Environmental Sciences, University of Toronto Scarborough, 1265 Military Trail, Toronto, Ontario M1C 1A4, Canada.
authors.forename: Xianming
authors.initials: X
authors.lastname: Zhang
authors.forename: Torsten
authors.initials: T
authors.lastname: Meyer
authors.forename: Derek C G
authors.initials: DC
authors.lastname: Muir
authors.forename: Camilla
authors.initials: C
authors.lastname: Teixeira
authors.forename: Xiaowa
authors.initials: X
authors.lastname: Wang
authors.forename: Frank
authors.initials: F
authors.lastname: Wania
mesh_terms: D001110:Arctic Regions; D001272:Atmosphere; D002170:Canada; D004726:Endosulfan / Q000032:analysis; D008401:Gas Chromatography-Mass Spectrometry; D046448:Ice Cover; D010575:Pesticides / Q000032:analysis*; D010795:Phthalic Acids / Q000032:analysis; D012914:Snow / Q000737:chemistry*
chemical_list: D010575:Pesticides; D010795:Phthalic Acids; C007220:dimethyl 2,3,5,6-tetrachloroterephthalate; D004726:Endosulfan