title: Continuous coflow synthesis of hybrid palladium nanocrystals as catalysts for borylation reaction.
abstract: The combination of highly active Pd nanocrystal (NC) types with tailored surface properties (various ligands) - e.g. organic-inorganic hybrid NCs - as catalysts opens avenues towards new synthetic pathways, implying a faster practical alternative for adjusting and screening the reaction conditions. Pd@dppf and Pd@PCy3 NCs have been successfully prepared via a continuous supercritical fluid assisted coflow route with promising results as catalysts in borylation reaction. It has been found that the ligands not only influence the catalytic properties of the systems, but also contribute to Pd metal core characteristics (size, shape and time stability).
authors.affiliation: CNRS, Univ. Bordeaux, ICMCB, UPR 9048, 87 avenue du Dr Albert Schweitzer, F-33600 Pessac Cedex, France. aymonier@icmcb-bordeaux.cnrs.fr.
authors.forename: Oana
authors.initials: O
authors.lastname: Pascu
authors.forename: Ludovic
authors.initials: L
authors.lastname: Marciasini
authors.forename: Samuel
authors.initials: S
authors.lastname: Marre
authors.forename: Michel
authors.initials: M
authors.lastname: Vaultier
authors.forename: Mathieu
authors.initials: M
authors.lastname: Pucheault
authors.forename: Cyril
authors.initials: C
authors.lastname: Aymonier