title: Cantilever energy effects on bimodal AFM: phase and amplitude contrast of multicomponent samples.
abstract: Bimodal atomic force microscopy (AFM) is a recently developed technique of dynamic AFM where a higher eigenmode of the cantilever is simultaneously excited along with the fundamental eigenmode. The effects of different operating parameters while imaging an impact copolymer blend of polypropylene (PP) and ethylene-propylene (E-P) rubber in bimodal mode are explored through experiments and numerical simulations. The higher mode amplitude and phase contrasts between the two components of the sample reverse at different points as the free amplitude of the higher eigenmode is increased. Three different regimes are identified experimentally depending on the relative contrast between the PP and the E-P rubber. It is observed that the kinetic energy and free air drive input energy of the two cantilever eigenmodes play a role in determining the regimes of operation. Numerical simulations conducted with appropriate tip-sample interaction forces support the experimental results. An understanding of these regimes and the associated cantilever dynamics will guide a rational approach towards selecting appropriate operating parameters.
authors.affiliation: Corporate Strategic Research, ExxonMobil Research and Engineering, Annandale, NJ 08801, USA.
authors.forename: Ishita
authors.initials: I
authors.lastname: Chakraborty
authors.forename: Dalia G
authors.initials: DG
authors.lastname: Yablon