title: Merging oxidative dearomatization and aminocatalysis: one-pot enantioselective synthesis of tricyclic architectures.
abstract: The combination of oxidative dearomatization and trienamine/enamine activation in a single vessel is described. Under these conditions, a three-bond forming process generates functionalized tricyclic architectures with up to six contiguous stereocenters with excellent stereoselectivities from readily available planar substrates.
authors.affiliation: Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles-St-Quentin-en-Yvelines , 45 Avenue des États-Unis, 78035 Versailles cedex, France.
authors.forename: François
authors.initials: F
authors.lastname: Portalier
authors.forename: Flavien
authors.initials: F
authors.lastname: Bourdreux
authors.forename: Jérôme
authors.initials: J
authors.lastname: Marrot
authors.forename: Xavier
authors.initials: X
authors.lastname: Moreau
authors.forename: Vincent
authors.initials: V
authors.lastname: Coeffard
authors.forename: Christine
authors.initials: C
authors.lastname: Greck
mesh_terms: D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011083:Polycyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000588:Amines; D011083:Polycyclic Compounds