title: Epitaxial graphene growth and shape dynamics on copper: phase-field modeling and experiments.
abstract: The epitaxial growth of graphene on copper foils is a complex process, influenced by thermodynamic, kinetic, and growth parameters, often leading to diverse island shapes including dendrites, squares, stars, hexagons, butterflies, and lobes. Here, we introduce a phase-field model that provides a unified description of these diverse growth morphologies and compare the model results with new experiments. Our model explicitly accounts for the anisotropies in the energies of growing graphene edges, kinetics of attachment of carbon at the edges, and the crystallinity of the underlying copper substrate (through anisotropy in surface diffusion). We show that anisotropic diffusion has a very important, counterintuitive role in the determination of the shape of islands, and we present a "phase diagram" of growth shapes as a function of growth rate for different copper facets. Our results are shown to be in excellent agreement with growth shapes observed for high symmetry facets such as (111) and (001) as well as for high-index surfaces such as (221) and (310).
authors.affiliation: Department of Mathematics, University of California , Irvine, California 92697-3875, United States.
authors.forename: Esteban
authors.initials: E
authors.lastname: Meca
authors.forename: John
authors.initials: J
authors.lastname: Lowengrub
authors.forename: Hokwon
authors.initials: H
authors.lastname: Kim
authors.forename: Cecilia
authors.initials: C
authors.lastname: Mattevi
authors.forename: Vivek B
authors.initials: VB
authors.lastname: Shenoy
mesh_terms: D016880:Anisotropy; D002244:Carbon / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D007700:Kinetics; D036103:Nanotechnology; D013499:Surface Properties; D013816:Thermodynamics
chemical_list: D002244:Carbon; D006108:Graphite; D003300:Copper