title: Asymmetric oxidation catalysis by a porphyrin-inspired manganese complex: highly enantioselective sulfoxidation with a wide substrate scope.
abstract: The first genuinely promising porphyrin-inspired manganese-catalyzed asymmetric sulfoxidation method using hydrogen peroxide has been successfully developed, allowing for rapidly oxidizing (0.5-1.0 h) a wide variety of sulfides in high yields with excellent enantioselectivities (up to >99% ee).
authors.affiliation: Dalian Institute of Chemical Physics, the Chinese Academy of Sciences , Dalian, 116023, People's Republic of China, Dalian National Laboratory for Clean Energy , People's Republic of China, and University of Chinese Academy of Sciences , Beijing 100049, People's Republic of China.
authors.forename: Wen
authors.initials: W
authors.lastname: Dai
authors.forename: Jun
authors.initials: J
authors.lastname: Li
authors.forename: Bo
authors.initials: B
authors.lastname: Chen
authors.forename: Guosong
authors.initials: G
authors.lastname: Li
authors.forename: Ying
authors.initials: Y
authors.lastname: Lv
authors.forename: Lianyue
authors.initials: L
authors.lastname: Wang
authors.forename: Shuang
authors.initials: S
authors.lastname: Gao