title: Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands--P(π)-donor bonds to Ag+ and HgCl2.
abstract: Unprecedented coordination types of non-zerovalent d(10) transition metals (AgX, HgCl2) by π-excess aromatic P=C ligands involving P(π)-donor bond contributions were detected by structural and quantum chemical studies.
authors.affiliation: Institut für Biochemie (Anorganische Chemie), E.-M.-A.-Universität Greifswald, 17487 Greifswald, Germany. heinicke@uni-greifswald.de.
authors.forename: Mohammed
authors.initials: M
authors.lastname: Ghalib
authors.forename: László
authors.initials: L
authors.lastname: Könczöl
authors.forename: László
authors.initials: L
authors.lastname: Nyulászi
authors.forename: Peter G
authors.initials: PG
authors.lastname: Jones
authors.forename: Gottfried J
authors.initials: GJ
authors.lastname: Palm
authors.forename: Joachim W
authors.initials: JW
authors.lastname: Heinicke
mesh_terms: D002414:Cations, Monovalent / Q000737:chemistry; D008024:Ligands; D008627:Mercuric Chloride / Q000737:chemistry*; D008958:Models, Molecular; D009943:Organophosphorus Compounds / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D002414:Cations, Monovalent; D008024:Ligands; D009943:Organophosphorus Compounds; D028561:Transition Elements; D012834:Silver; D008627:Mercuric Chloride