title: Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity.
abstract: The synthesis of a new MOF with Cu2 paddle-wheels connected to glutarate and 1,3-bis(4-pyridyl)propane linkers has been explored. Experimental gas adsorption measurements reveal that the MOF is essentially non-porous to methane whereas it presents a type III isotherm upon CO2 adsorption, leading to high capacity and outstanding CO2 selectivity.
authors.affiliation: Departamento de Química Aplicada, Facultad de Ciencias Químicas de San Sebastián, Universidad del País Vasco, Spain.
authors.forename: José M
authors.initials: JM
authors.lastname: Seco
authors.forename: David
authors.initials: D
authors.lastname: Fairen-Jimenez
authors.forename: Antonio J
authors.initials: AJ
authors.lastname: Calahorro
authors.forename: Laura
authors.initials: L
authors.lastname: Méndez-Liñán
authors.forename: Manuel
authors.initials: M
authors.lastname: Pérez-Mendoza
authors.forename: Nicola
authors.initials: N
authors.lastname: Casati
authors.forename: Enrique
authors.initials: E
authors.lastname: Colacio
authors.forename: Antonio
authors.initials: A
authors.lastname: Rodríguez-Diéguez