title: Probing the effects of ligand isomerism in chiral luminescent lanthanide supramolecular self-assemblies: a europium "Trinity Sliotar" study.
abstract: "Trinity Sliotar" family: Chiral ligands containing pyridyl and naphthalene moieties were synthesized and characterized. These ligands were successfully used for the synthesis of Eu(III) bundles where chirality of the ligand is successfully transferred onto the lanthanide centre resulting in circularly polarized red luminescence.
authors.affiliation: School of Chemistry, Trinity Biomedical Sciences Institute, University of Dublin, Trinity College Dublin, Dublin 2 (Ireland). kotovao@tcd.ie.
authors.forename: Oxana
authors.initials: O
authors.lastname: Kotova
authors.forename: Jonathan A
authors.initials: JA
authors.lastname: Kitchen
authors.forename: Christophe
authors.initials: C
authors.lastname: Lincheneau
authors.forename: Robert D
authors.initials: RD
authors.lastname: Peacock
authors.forename: Thorfinnur
authors.initials: T
authors.lastname: Gunnlaugsson
mesh_terms: D005063:Europium / Q000737:chemistry*; D007536:Isomerism; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D028581:Lanthanoid Series Elements; D008024:Ligands; D009281:Naphthalenes; D011725:Pyridines; D005063:Europium
keywords: chirality; lanthanides; luminescence; molecular probes; supramolecular chemistry