title: Tube-in-tube reactor as a useful tool for homo- and heterogeneous olefin metathesis under continuous flow mode.
abstract: A tube-in-tube reactor was successfully applied in homo- and heterogeneous olefin metathesis reactions under continuous flow mode. It was shown that the efficient removal of ethylene facilitated by connection of the reactor with a vacuum pump significantly improves the outcome of metathesis reactions. The beneficial aspects of this approach are most apparent in reactions performed at low concentration, such as macrocyclization reactions. The established system allows achievement of both improved yield and selectivity, and is ideal for industrial applications.
authors.affiliation: Apeiron Catalysts, Duńska 9, 54-427 Wrocław (Poland). krzysztof.skowerski@apeiron-catalysts.com.
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Skowerski
authors.forename: Stefan J
authors.initials: SJ
authors.lastname: Czarnocki
authors.forename: Paweł
authors.initials: P
authors.lastname: Knapkiewicz
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002621:Chemistry / Q000295:instrumentation*; D004129:Dimethylpolysiloxanes / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D014618:Vacuum
chemical_list: D000475:Alkenes; D004129:Dimethylpolysiloxanes; D012997:Solvents; C013830:baysilon
keywords: continuous flow; ethylene removal; heterogeneous catalysis; homogeneous catalysis; metathesis