title: SANS, ATR-IR, and 1D- and 2D-NMR studies of mixing states of imidazolium-based ionic liquid and aryl solvents.
abstract: The mixing states of imidazolium-based ionic liquid, 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide (C12mim(+)TFSA(-)), and two aryl solvents toluene and α,α,α-trifluorotoluene (TFT) have been clarified on both meso- and microscopic scales using small-angle neutron scattering (SANS) and ATR-IR techniques. To elucidate the interactions between C12mim(+)TFSA(-) and aryl solvent molecules from the change in the electron densities of C12mim(+) and TFSA(-), 1D-NMR measurements for (1)H and (13)C atoms have been conducted on C12mim(+)TFSA(-)-aryl solvent solutions as a function of the aryl solvent mole fraction. In addition, the interactions between the dodecyl chain of C12mim(+) and aryl solvent molecules have been observed using 2D-NMR techniques of (1)H{(1)H} ROESY and (19)F{(1)H} HOESY. These results have been compared with those of benzene solutions previously investigated. The SANS measurements have shown that toluene is heterogeneously mixed with C12mim(+)TFSA(-) as well as benzene. However, the heterogeneity of the toluene solutions is slightly lower than that of the benzene solutions. In contrast, TFT is homogeneously mixed with the ionic liquid at least on the present SANS scale. The substituent effects of the three aryl solvent molecules of benzene, toluene, and TFT on the mixing states of the solutions have been discussed in terms of the cation-π interaction between the imidazolium and phenyl rings and the interaction between the dodecyl group and aryl solvent molecules.
authors.affiliation: Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan. takamut@cc.saga-u.ac.jp.
authors.forename: Takuya
authors.initials: T
authors.lastname: Shimomura
authors.forename: Saori
authors.initials: S
authors.lastname: Inoue
authors.forename: Shoya
authors.initials: S
authors.lastname: Kadohata
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Umecky
authors.forename: Toshiyuki
authors.initials: T
authors.lastname: Takamuku