title: Iron(II) complexes of ditopic carbanionic carbenes.
abstract: Reaction of dimesityliron(II) (Fe2(mes)4) with the N-heterocyclic carbenes 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) and 1,3-bis(2,6-dimethylphenyl)hexahydropyrimidin-2-ylidene (6-Xyl) afforded the novel trigonal planar complexes [Fe(IPr)(mes)2] (1) and [Fe(6-Xyl)(mes)2] (2), respectively. Both species were structurally characterized by single crystal X-ray diffraction and display structures and magnetic responses consistent with a quintet ground state (S = 2). Reaction of 1 with KC8 in THF afforded K(+) salts of the anionic complex [{:C[N(2,6-(i)Pr2C6H3)]2(CH)C}2Fe(mes)](-) (3) and the homoleptic organometallic anion [Fe(mes)3](-) (4). By contrast, reduction of 2 resulted in extensive decomposition and intractable product mixtures. Complex 3 is coordinated by two ditopic carbanionic carbenes via the C4/C5 position while the C2 position retains unquenched carbenic character and remains vacant for further coordination. This was corroborated by reacting solutions of 3 with one and two equivalents of triethylaluminium (AlEt3) which resulted in the formation of [{Et3Al:C[N(2,6-(i)Pr2C6H3)]2(CH)C}{:C[N(2,6-(i)Pr2C6H3)]2(CH)C}Fe(mes)](-) (5) and [{Et3Al:C[N(2,6-(i)Pr2C6H3)]2(CH)C}2Fe(mes)](-) (6), respectively. Both of these species were structurally characterized as [K(2,2,2-crypt)](+) salts.
authors.affiliation: Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK. jose.goicoechea@chem.ox.ac.uk.
authors.forename: Rebecca A
authors.initials: RA
authors.lastname: Musgrave
authors.forename: Robert S P
authors.initials: RS
authors.lastname: Turbervill
authors.forename: Mark
authors.initials: M
authors.lastname: Irwin
authors.forename: Radovan
authors.initials: R
authors.lastname: Herchel
authors.forename: Jose M
authors.initials: JM
authors.lastname: Goicoechea