title: Preparation via an electrochemical  method of graphene films coated on both  sides with NiO nanoparticles for use as  high-performance lithium ion anodes.
abstract: We report on a simple strategy for the direct synthesis of a thin film comprising interconnected NiO nanoparticles deposited on both sides of a graphene sheet via cathodic deposition. For the co-electrodeposition, graphene oxide (GO) is treated with water-soluble cationic poly(ethyleneimine) (PEI) which acts as a stabilizer and trapping agent to form complexes of GO and Ni2+. The positively charged complexes migrate toward the stainless steel substrate, resulting in the electrochemical deposition of PEI-modified GO/Ni(OH)2 at the electrode surface under an applied electric field. The as-synthesized film is then converted to graphene/NiO after annealing at 350 ° C. The interconnected NiO nanoparticles are uniformly deposited on both sides of the graphene surface, as evidenced by field emission scanning electron microscopy, transmission electron microscopy and energy dispersive spectrometry. This graphene/NiO structure shows enhanced electrochemical performance with a large reversible capacity, good cyclic performance and improved electronic conductivity as an anode material for lithium ion batteries. A reversible capacity is retained above 586 mA h g−1 after 50 cycles. The findings reported herein suggest that this strategy can be effectively used to overcome a bottleneck problem associated with the electrochemical production of graphene/metal oxide films for lithium ion battery anodes.
authors.forename: Gil-Pyo
authors.initials: GP
authors.lastname: Kim
authors.forename: Inho
authors.initials: I
authors.lastname: Nam
authors.forename: Soomin
authors.initials: S
authors.lastname: Park
authors.forename: Junsu
authors.initials: J
authors.lastname: Park
authors.forename: Jongheop
authors.initials: J
authors.lastname: Yi