title: Theoretical study of gas hydrate decomposition kinetics: model predictions.
abstract: In order to provide an estimate of intrinsic gas hydrate dissolution and dissociation kinetics, the Consecutive Desorption and Melting Model (CDM) was developed in a previous publication (Windmeier, C.; Oellrich, L. R. J. Phys. Chem. A 2013, 117, 10151-10161). In this work, an extensive summary of required model data is given. Obtained model predictions are discussed with respect to their temperature dependence as well as their significance for technically relevant areas of gas hydrate decomposition. As a result, an expression for determination of the intrinsic gas hydrate decomposition kinetics for various hydrate formers is given together with an estimate for the maximum possible rates of gas hydrate decomposition.
authors.affiliation: Institut für Technische Thermodynamik und Kältetechnik, Karlsruher Institut für Technologie , 76128 Karlsruhe, Germany.
authors.forename: Christoph
authors.initials: C
authors.lastname: Windmeier
authors.forename: Lothar R
authors.initials: LR
authors.lastname: Oellrich