title: Cellulose-clay layered nanocomposite films fabricated from aqueous cellulose/LiOH/urea solution.
abstract: Transparent and flexible cellulose-clay (montmorillonite, MTM) nanocomposite films are prepared from cellulose/LiOH/urea solutions. The results show that the composites possess intercalated nanolayered structures. Almost no Na ions are present in MTM, probably because they are substituted by Li ions. The nanocomposite films possess high mechanical strength and gas barrier properties, and lower coefficients of thermal expansion than those of the original cellulose film. In particular, the composite film of 85% cellulose and 15% MTM has the highest tensile strength and Young's modulus 161 and 180% greater than those of the 100% cellulose film, and coefficient of thermal expansion and oxygen permeability at 50-75% RH decrease to 60 and 42-33%, respectively. Moreover, the initial hydrophilic nature of cellulose film changes to somewhat hydrophobic through incorporation of hydrophilic MTM platelets. This is probably because the orientation of cellulose chains on the film surface changes by the formation of numerous hydrogen bonds between cellulose molecules and MTM platelets.
authors.affiliation: Graduate School of Agricultural and Life Sciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan.
authors.forename: Quanling
authors.initials: Q
authors.lastname: Yang
authors.forename: Chun-Nan
authors.initials: CN
authors.lastname: Wu
authors.forename: Tsuguyuki
authors.initials: T
authors.lastname: Saito
authors.forename: Akira
authors.initials: A
authors.lastname: Isogai
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry*; D002482:Cellulose / Q000737:chemistry*; D000077215:Clay; D057927:Hydrophobic and Hydrophilic Interactions; D018020:Lithium Compounds / Q000737:chemistry*; D055595:Mechanical Phenomena; D053761:Nanocomposites / Q000737:chemistry*; D055620:Optical Phenomena; D012996:Solutions; D013696:Temperature; D014508:Urea / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D000538:Aluminum Silicates; D018020:Lithium Compounds; D012996:Solutions; D014867:Water; D014508:Urea; D002482:Cellulose; C028467:lithium hydroxide; D000077215:Clay
keywords: Cellulose; Clay; Gas barrier; Montmorillonite; Nanocomposite