title: A mixed flow reactor method to synthesize amorphous calcium carbonate under controlled chemical conditions.
abstract: This study describes a new procedure to synthesize amorphous calcium carbonate (ACC) from well-characterized solutions that maintain a constant supersaturation. The method uses a mixed flow reactor to prepare ACC in significant quantities with consistent compositions. The experimental design utilizes a high-precision solution pump that enables the reactant solution to continuously flow through the reactor under constant mixing and allows the precipitation of ACC to reach steady state. As a proof of concept, we produced ACC with controlled Mg contents by regulating the Mg/Ca ratio of the input solution and the carbonate concentration and pH. Our findings show that the Mg/Ca ratio of the reactant solution is the primary control for the Mg content in ACC, as shown in previous studies, but ACC composition is further regulated by the carbonate concentration and pH of the reactant solution. The method offers promise for quantitative studies of ACC composition and properties and for investigating the role of this phase as a reactive precursor to biogenic minerals.
authors.affiliation: Department of Geosciences, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA.
authors.forename: Christina R
authors.initials: CR
authors.lastname: Blue
authors.forename: J Donald
authors.initials: JD
authors.lastname: Rimstidt
authors.forename: Patricia M
authors.initials: PM
authors.lastname: Dove
mesh_terms: D002119:Calcium Carbonate / Q000138:chemical synthesis* / Q000737:chemistry; D011232:Chemical Precipitation; D006863:Hydrogen-Ion Concentration; D008274:Magnesium / Q000737:chemistry; D010316:Particle Size; D012996:Solutions; D013054:Spectrophotometry, Atomic; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D013818:Thermogravimetry
chemical_list: D012996:Solutions; D002119:Calcium Carbonate; D008274:Magnesium
keywords: Amorphous calcium carbonate; Magnesium; Mixed flow reactor; Partitioning; Synthesis