title: The organic-inorganic hybrid material 1-cyclohexylpiperazine-1,4-diium tetrachloridozincate.
abstract: In the crystal structure of the title organic-inorganic hybrid material, (C10H22N2)[ZnCl4], the tetrachloridozincate anions and 1-cyclohexylpiperazine-1,4-diium dications are interconnected via N-H...Cl and C-H...Cl hydrogen bonds to form layers parallel to the (001) plane. The cyclohexyl groups from adjacent chains interdigitate, thus building the three-dimensional structure. The piperazinium and cyclohexyl rings exhibit regular spatial chair conformations. The title salt was also characterized by FT-IR and Raman spectroscopic analyses.
authors.affiliation: Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia.
authors.forename: Sarra
authors.initials: S
authors.lastname: Soudani
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Aubert
authors.forename: Christian
authors.initials: C
authors.lastname: Jelsch
authors.forename: Cherif
authors.initials: C
authors.lastname: Ben Nasr
mesh_terms: D000838:Anions / Q000737:chemistry*; D002412:Cations / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D015394:Molecular Structure; D010879:Piperazines / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D000838:Anions; D002412:Cations; D002712:Chlorides; D010879:Piperazines; D017967:Zinc Compounds; C016837:zinc chloride
keywords: 1-cyclohexylpiperazine-1,4-diium cations; crystal structure; organic–inorganic hybrid materials; organic–inorganic salts; tetrachloridozincate anions