title: Unprecedented induced axial chirality in a molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region.
abstract: Enantiomeric bis(BODIPYs) 1a and 1b exhibit strong bisignated ECD due to the formation of a stable helical conformation with induced axial chirality, which allows efficient exciton coupling of the BODIPY chromophores in the Vis region.
authors.affiliation: Depto. de Química Orgánica I, Facultad de CC. Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040, Madrid, Spain. santmoya@ucm.es.
authors.forename: Esther M
authors.initials: EM
authors.lastname: Sánchez-Carnerero
authors.forename: Florencio
authors.initials: F
authors.lastname: Moreno
authors.forename: Beatriz L
authors.initials: BL
authors.lastname: Maroto
authors.forename: Antonia R
authors.initials: AR
authors.lastname: Agarrabeitia
authors.forename: Jorge
authors.initials: J
authors.lastname: Bañuelos
authors.forename: Teresa
authors.initials: T
authors.lastname: Arbeloa
authors.forename: Iñigo
authors.initials: I
authors.lastname: López-Arbeloa
authors.forename: María J
authors.initials: MJ
authors.lastname: Ortiz
authors.forename: Santiago
authors.initials: S
authors.lastname: de la Moya
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D002942:Circular Dichroism; D004583:Electrons; D005456:Fluorescent Dyes / Q000737:chemistry*; D008958:Models, Molecular; D013237:Stereoisomerism
chemical_list: C095489:4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; D001896:Boron Compounds; D005456:Fluorescent Dyes