title: Preconcentration of heavy metals on activated carbon and their determination in fruits by inductively coupled plasma optical emission spectrometry.
abstract: A method of separation and preconcentration of cadmium, cobalt, copper, nickel, lead, and zinc at trace level using activated carbon is proposed. Activated carbon with the adsorbed trace metals was mineralised using a high-pressure microwave mineraliser. The heavy metals were determined after preconcentration by inductively coupled plasma optical emission spectrometry (ICP-OES). The influence of several parameters, such as pH, sorbent mass, shaking time was examined. Moreover, effects of inorganic matrix on recovery of the determined elements were studied. The experiment shows that foreign ions did not influence recovery of the determined elements. The detection limits (DL) of Cd, Co, Cu, Ni, Pb, and Zn were 0.17, 0.19, 1.60, 2.60, 0.92 and 1.50 μg L(-)(1), respectively. The recovery of the method for the determined elements was better than 95% with relative standard deviation from 1.3% to 3.7%. The preconcentration factor was 80. The proposed method was applied for determination of Cd, Co, Cu, Ni, Pb, and Zn in fruits materials. Accuracy of the proposed method was verified using certified reference material (NCS ZC85006 Tomato).
authors.affiliation: Department of Analytical Chemistry, Institute of Chemistry, University of Silesia, 40-006 Katowice, Szkolna 9, Poland. Electronic address: barbara.feist@us.edu.pl.
authors.forename: Barbara
authors.initials: B
authors.lastname: Feist
authors.forename: Barbara
authors.initials: B
authors.lastname: Mikula
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry; D005506:Food Contamination / Q000032:analysis; D005638:Fruit / Q000737:chemistry*; D057230:Limit of Detection; D018551:Solanum lycopersicum / Q000737:chemistry*; D013058:Mass Spectrometry / Q000379:methods*; D019216:Metals, Heavy / Q000737:chemistry* / Q000302:isolation & purification; D052616:Solid Phase Extraction / Q000295:instrumentation / Q000379:methods*
chemical_list: D019216:Metals, Heavy; D002606:Charcoal
keywords: Activated carbon; Fruits; Inductively coupled plasma optical emission spectrometry; Multi element preconcentration; Simultaneous determination