title: Solvent effects on the molecular recognition of anions.
abstract: Anion recognition of two flexible diols in different solvents and binary mixtures were examined. Binding constants (K) in CD3CN and CDCl3 are surprisingly similar, and CD3CN-solvent mixtures led to reduced values of K that are smaller than in either pure solvent. A surprising U-shaped dependence is observed.
authors.affiliation: Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA. kass@umn.edu.
authors.forename: Alireza
authors.initials: A
authors.lastname: Shokri
authors.forename: Steven R
authors.initials: SR
authors.lastname: Kass
mesh_terms: D000838:Anions / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry; D003486:Cyanides / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012492:Salts / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D000838:Anions; D002712:Chlorides; D003486:Cyanides; D000644:Quaternary Ammonium Compounds; D012492:Salts; D012997:Solvents; C009405:tetrabutylammonium