title: Separation of carbon dioxide from nitrogen or methane by supported ionic liquid membranes (SILMs): influence of the cation charge of the ionic liquid.
abstract: Supported ionic liquid membranes (SILMs) are promising tools for the separation of carbon dioxide from other gases. In this paper, new imidazolium, pyrrolidinium, piperidinium, and morpholinium ionic liquids with a triethylene glycol side chain and tosylate anions, as well as their symmetrical dicationic analogues, have been synthesized and incorporated into SILMs. The selectivities for CO2/N2 and CO2/CH4 separations have been measured. The selectivities exhibited by the dicationic ionic liquids are up to two times higher than the values of the corresponding monocationic ionic liquids. Quantum chemical calculations have been used to investigate the difference in the interaction of carbon dioxide with monocationic and dicationic ionic liquids. The reason for the increased gas separation selectivity of the dicationic ionic liquids is two-fold: (1) a decrease in permeance of nitrogen and methane through the ionic liquid layer, presumably due to their less favorable interactions with the gases, while the permeance of carbon dioxide is reduced much less; (2) an increase in the number of interaction sites for the interactions with the quadrupolar carbon dioxide molecules in the dicationic ionic liquids, compared to the monocationic analogues.
authors.affiliation: Department of Chemistry, KU Leuven , Celestijnenlaan 200F - Box 2404, B-3001 Leuven, Belgium.
authors.forename: Sandra D
authors.initials: SD
authors.lastname: Hojniak
authors.forename: Asim Laeeq
authors.initials: AL
authors.lastname: Khan
authors.forename: Oldamur
authors.initials: O
authors.lastname: Hollóczki
authors.forename: Barbara
authors.initials: B
authors.lastname: Kirchner
authors.forename: Ivo F J
authors.initials: IF
authors.lastname: Vankelecom
authors.forename: Wim
authors.initials: W
authors.lastname: Dehaen
authors.forename: Koen
authors.initials: K
authors.lastname: Binnemans