title: Effects of environmental factors on sulfamethoxazole photodegradation under simulated sunlight irradiation: kinetics and mechanism.
abstract: To advance the knowledge of the environmental fate of sulfamethoxazole (SMX), we systematically investigated the effects of natural water constituents and synthetic substances (i.e., TiO2 nanoparticles (nTiO2) and Ti-doped beta-Bi2O3 (NTB)) on the photodegradation kinetics of SMX under xenon lamp irradiation. The photolysis of SMX in aqueous solution followed first-order kinetics. Our results showed that higher concentrations of SMX, fulvic acid, suspended sediments, NTB and higher pH value decreased the photodegradation rates of SMX, whereas H2O2 improved the SMX photodegradation. TiO2 nanoparticles had a dual effect on photodegradation due to their photocatalytic activity and photoabsorption of photons. No intermediates more toxic toward Vibrio fischeri than SMX were produced after direct photolysis and photocatalytic degradation for 3 hr. The photolysis of SMX involved three pathways: hydroxylation, cleavage of the sulfonamide bond, and fragmentation of the isoxazole ring. This study lays the groundwork for a better understanding of the environmental fate of SMX.
authors.affiliation: State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, PR China. junfengn@bnu.edu.cn
authors.forename: Junfeng
authors.initials: J
authors.lastname: Niu
authors.forename: Lilan
authors.initials: L
authors.lastname: Zhang
authors.forename: Yang
authors.initials: Y
authors.lastname: Li
authors.forename: Jinbo
authors.initials: J
authors.lastname: Zhao
authors.forename: Sidan
authors.initials: S
authors.lastname: Lv
authors.forename: Keqing
authors.initials: K
authors.lastname: Xiao
mesh_terms: D006861:Hydrogen Peroxide / Q000737:chemistry; D007700:Kinetics; D010782:Photolysis; D013420:Sulfamethoxazole / Q000737:chemistry*; D013472:Sunlight
chemical_list: D006861:Hydrogen Peroxide; D013420:Sulfamethoxazole