Modulating guest binding in sulfonylcalixarene-based metal-organic supercontainers.
Metal-organic supercontainers (MOSCs) represent a new family of synthetic receptors derived from container precursors and featuring both endo and exo cavities. A neutral MOSC has been functionalized into an anionic container by incorporating sulfo groups. The anionic MOSC exhibits cavity-specific binding properties in both solid state and solution.
Department of Chemistry, University of South Dakota, Churchill-Haines Laboratories, Room 115, 414 East Clark Street, Vermillion, South Dakota 57069-2390, USA. Zhenqiang.Wang@usd.edu.
Feng-Rong
FR
Dai
Dustin C
DC
Becht
Zhenqiang
Z
Wang
D047250:Calixarenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D013237:Stereoisomerism; D013441:Sulfinic Acids / Q000737:chemistry*; D013499:Surface Properties; D013816:Thermodynamics
D008670:Metals; D009942:Organometallic Compounds; D010636:Phenols; D013441:Sulfinic Acids; D047250:Calixarenes; C044255:sulfonyl chloride