Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.
The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with nitrogen-centered radical ligands are described. Complexes with aminyl ([M(˙NR2)]), nitrene/imidyl ([M(˙NR)]), and nitridyl radical ligands ([M(˙N)]) are detectable and sometimes even isolable species, and despite their radical nature frequently reveal selective reactivity patterns towards a variety of organic substrates. A classification system for complexes with nitrogen-centered radical ligands based on their electronic structure leads to their description as one-electron-reduced Fischer-type systems, one-electron-oxidized Schrock-type systems, or systems with a (nearly) covalent M-N π bond. Experimental data relevant for the assignment of the radical locus (i.e. metal or ligand) are discussed, and the application of complexes with nitrogen-centered radical ligands in the (catalytic) syntheses of nitrogen-containing organic molecules such as aziridines and amines is demonstrated with recent examples. This Review should contribute to a better understanding of the (catalytic) reactivity of nitrogen-centered radical ligands and the role they play in tuning the reactivity of coordination compounds.
Homogeneous and Supramolecular Catalysis van't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam, Science Park 904, 1098 XH Amsterdam (The Netherlands).
Alma I
AI
Olivos Suarez
Volodymyr
V
Lyaskovskyy
Joost N H
JN
Reek
Jarl Ivar
JI
van der Vlugt
Bas
B
de Bruin
aminyls; imidyls; nitrenes; nitridyls; redox-active ligands