Probing adsorption interactions in metal-organic frameworks using X-ray spectroscopy.
We explore the local electronic signatures of molecular adsorption at coordinatively unsaturated binding sites in the metal-organic framework Mg-MOF-74 using X-ray spectroscopy and first-principles calculations. In situ measurements at the Mg K-edge reveal distinct pre-edge absorption features associated with the unique, open coordination of the Mg sites which are suppressed upon adsorption of CO2 and N,N'-dimethylformamide. Density functional theory shows that these spectral changes arise from modifications of local symmetry around the Mg sites upon gas uptake and are strongly dependent on the metal-adsorbate binding strength. The expanded MOF Mg2(dobpdc) displays the same behavior upon adsorption of CO2 and N,N'-dimethylethylenediamine. Similar sensitivity to local symmetry is expected for any open metal site, making X-ray spectroscopy an ideal tool for examining adsorption in such MOFs. Qualitative agreement between ambient-temperature experimental and 0 K theoretical spectra is good, with minor discrepancies thought to result from framework vibrational motion.
Materials Sciences Division, Lawrence Berkeley National Laboratory , Berkeley, California 94720, United States.
Walter S
WS
Drisdell
Roberta
R
Poloni
Thomas M
TM
McDonald
Jeffrey R
JR
Long
Berend
B
Smit
Jeffrey B
JB
Neaton
David
D
Prendergast
Jeffrey B
JB
Kortright