Removal efficiency of fluoride by novel Mg-Cr-Cl layered double hydroxide by batch process from water.
The fluoride ion removal from aqueous solution using synthesized Mg-Cr-Cl layered double hydroxide has been reported. Mg-Cr-Cl was characterized by X-ray powder diffraction, Fourier-transform infrared, thermo-gravimetric analysis, differential thermal analysis, and scanning electron microscope. Adsorption experiments were carried out in batch mode as a function of adsorption dosages, contact time, pH, and initial fluoride concentration to get optimum adsorption capacity. The adsorption kinetic study showed that the adsorption process followed first order kinetics. The fluoride removal was 88.5% and 77.4% at pH 7 with an adsorbent dose of 0.6 g/100 mL solution and initial fluoride concentration of 10 mg/L and 100 mg/L, respectively. The equilibrium was established at 40 min. Adsorption experiment data were fitted well with Langmuir isotherm with R2 = 0.9924. Thermodynamic constants were also measured and concluded that the adsorption process was spontaneous and endothermic in nature. The removal percentage decreased slowly with increasing pH. This process is suitable for industrial effluents. The regeneration of the material is not possible.
Department of Chemistry, National Institute of Technology, Rourkela 769 008, India.
Sandip
S
Mandal
Swagatika
S
Tripathy
Tapswani
T
Padhi
Manoj Kumar
MK
Sahu
Raj Kishore
RK
Patel
D000327:Adsorption; D002712:Chlorides / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods; D005459:Fluorides / Q000737:chemistry*; D006878:Hydroxides / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry*; D059027:Recycling; D014865:Waste Disposal, Fluid / Q000379:methods; D014874:Water Pollutants, Chemical / Q000737:chemistry*
D002712:Chlorides; D006878:Hydroxides; D014874:Water Pollutants, Chemical; D002857:Chromium; D008274:Magnesium; D005459:Fluorides