Three-dimensional graphene foam supported Fe₃O₄ lithium battery anodes with long cycle life and high rate capability.
Fe3O4 has long been regarded as a promising anode material for lithium ion battery due to its high theoretical capacity, earth abundance, low cost, and nontoxic properties. However, up to now no effective and scalable method has been realized to overcome the bottleneck of poor cyclability and low rate capability. In this article, we report a bottom-up strategy assisted by atomic layer deposition to graft bicontinuous mesoporous nanostructure Fe3O4 onto three-dimensional graphene foams and directly use the composite as the lithium ion battery anode. This electrode exhibits high reversible capacity and fast charging and discharging capability. A high capacity of 785 mAh/g is achieved at 1C rate and is maintained without decay up to 500 cycles. Moreover, the rate of up to 60C is also demonstrated, rendering a fast discharge potential. To our knowledge, this is the best reported rate performance for Fe3O4 in lithium ion battery to date.
Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University , 637371, Singapore.
Jingshan
J
Luo
Jilei
J
Liu
Zhiyuan
Z
Zeng
Chi Fan
CF
Ng
Lingjie
L
Ma
Hua
H
Zhang
Jianyi
J
Lin
Zexiang
Z
Shen
Hong Jin
HJ
Fan
D011211:Electric Power Supplies; D004566:Electrodes; D005290:Ferric Compounds / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry; D013499:Surface Properties
D005290:Ferric Compounds; C000499:ferric oxide; D006108:Graphite; D008094:Lithium