A twin-free single-crystal Ag nanoplate plasmonic platform: hybridization of the optical nano-antenna and surface plasmon active surface.
Surface plasmons based on metallic nanostructures enable light manipulation beyond the optical diffraction limit. We have epitaxially synthesized twin-free single-crystal Ag nanoplates on SrTiO3 substrates. Unlike the nanoplates synthesized in a solution phase, these nanoplates have perfectly clean surfaces as well as a quite large size of tens of micrometers. As-synthesized defect-free single-crystal Ag nanoplates have an atomically flat surface and sides with well-defined angles, allowing long distance propagation of surface plasmons and highly reliable plasmonic integration. By spatially separating receiving and transmitting antennas and plasmonically interfacing them, the signal quality of transmission/reception can be largely improved. Furthermore, by combining sub-dimensional nanostructures onto the two-dimensional space effective hierarchical plasmonic nano-complexes can be built up. Theoretical simulations well reproduced unique experimental results of coupling between SPPs and free-space radiation by the nanoplate antenna sides, low-loss long-range SPP propagation, and tunneling or scattering of SPPs at a nano-gap as well as a nano-structure introduced on the nanoplate. The single-crystal Ag nanoplate will find superb applications in plasmonic nano-circuitry and lab-on-a-chip for biochemical sensing.
Department of Chemistry, KAIST, Daejeon 305-701, Korea. bongsoo@kaist.ac.kr.
Hyoban
H
Lee
Kwang-Yong
KY
Jeong
Taejoon
T
Kang
Min-Kyo
MK
Seo
Bongsoo
B
Kim