Silver-catalyzed vinylogous fluorination of vinyl diazoacetates.
A silver-catalyzed vinylogous fluorination of vinyl diazoacetates to generate γ-fluoro-α,β-unsaturated carbonyls is presented. Application of this method to the fluorination of farnesol and steroid derivatives was achieved.
Department of Chemistry, Emory University , 1515 Dickey Drive, Atlanta, Georgia 30322, United States.
Changming
C
Qin
Huw M L
HM
Davies
D002384:Catalysis; D003979:Diazonium Compounds / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D003979:Diazonium Compounds; D007659:Ketones; D009942:Organometallic Compounds; D012834:Silver; C032111:diazoacetic ester