Polydopamine as an efficient and robust platform to functionalize carbon fiber for high-performance polymer composites.
Carbon fibers (CFs), which exhibit excellent physical performances and low density, suffer from their low surface activity in some application. Herein, based on dopamine chemistry, we proposed an efficient method to functionalize them: through a simple dip-coating procedure, the CFs were inverted from amphiphobic to hydrophilic with deposition of polydopamine film. Furthermore, using polydopamine as a bridge, the hydrophilic functionalized CFs were transformed to be oleophilic after following octadecylamine grafting. To illustrate applications of this functionalization strategy, we added 15 wt % functionalized CFs into polar epoxy and nonpolar poly(ethylene-co-octene), and as a consequence, their tensile strength respectively increase by 70 and 60%, which show greater reinforcing effect than the unmodified ones (35 and 35%). The results of dynamic mechanical analysis and scanning electron microscope observations indicate that this polydopamine-based functionalization route brought about satisfactory improvements in interfacial adhesion between fillers and matrix. Considering that this simple approach is facile and robust enough to allow further specific functionalization to adjust surface properties, these findings may lead to the development of new efficient strategies for surface functionalization of CFs that are of great interest to the industrial field.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University , Shanghai 200433, China.
Shusheng
S
Chen
Yewen
Y
Cao
Jiachun
J
Feng
D002244:Carbon / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D011108:Polymers / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties
D007211:Indoles; D011108:Polymers; C568283:polydopamine; D002244:Carbon