The CVD graphene transfer procedure introduces metallic impurities which alter the graphene electrochemical properties.
High quality graphene films can be fabricated by chemical vapor deposition (CVD) using Ni and Cu as catalytic substrates. Such a synthesis procedure always requires a subsequent transfer process to be performed in order to eliminate the metallic substrate and transfer the graphene onto the desired surface. We show here that such a transfer process causes significant contamination of the graphene film with residual Fe and Ni metal impurities. Fe contamination derives from the use of Fe-based etching solutions to dissolve Ni (or Cu) substrates, while residual Ni (or Cu) is due to an incomplete metal substrate etching. The presence of these metallic impurities within the transferred graphene film affects tremendously its electrochemical behavior when adopted as an electrode material.
Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore. pumera@ntu.edu.sg Pumera@outlook.com.
Adriano
A
Ambrosi
Martin
M
Pumera
D002384:Catalysis; D003300:Copper / Q000737:chemistry; D055664:Electrochemical Techniques; D004566:Electrodes; D006108:Graphite / Q000737:chemistry*; D007501:Iron / Q000737:chemistry; D009532:Nickel / Q000737:chemistry; D013499:Surface Properties
D006108:Graphite; D003300:Copper; D009532:Nickel; D007501:Iron