A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals.
A novel N,N'-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PC(NHC)P ligand for M2 or linear M3 (M = Cu, Ag, Au) arrays with metallophilic interactions.
Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67081 Strasbourg Cedex, France. danopoulos@unistra.fr braunstein@unistra.fr.
Pengfei
P
Ai
Andreas A
AA
Danopoulos
Pierre
P
Braunstein
Kirill Yu
KY
Monakhov