Angle-resolved neutralization-reionization mass spectrometry.
Neutralization -reionization mass spectra of 2-propenal, isomeric butenes, and isomeric n-hexenes have been found to depend significantly on the z-axis scattering angle of the neutralization event. As shown by Cooks for ion dissociations, increasing scattering angles generally favor products of higher activation-energy reactions. For isomeric butenes and n-hexenes, these reactions provide more definitive information for isomeric characterization.
Department of Chemistry, Cornell University, Ithaca, New York, USA.
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Turecek
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McLafferty