Magnitude, decadal changes, and impact of regional background ozone transported into the greater Houston, Texas, area.
Two independent analyses of the daily maximum 8 h average ozone concentrations measured during the high ozone season (May through October) at Continuous Ambient Monitoring Stations are used to quantify the regional background ozone transported into the Houston-Galveston-Brazoria (HGB) area. The dependence on wind direction is examined, and long-term trends are determined using measurements made between 1998 and 2012. Both analyses show that the regional background ozone has declined during periods of continental outflow: i.e., the conditions associated with most high ozone episodes in HGB. The changes in regional background ozone found for northeasterly and southeasterly flow are -0.50 ± 0.54 and -0.79 ± 0.65 (95% confidence limit) ppbv yr(-1), respectively, which correspond to decreases of ∼7-11 ppbv between 1998 and 2012. This finding is consistent with the summertime downward trend of -0.45 ppbv yr(-1) (range of sites: -0.87 to +0.07 ppbv yr(-1)) for ozone in the eastern U.S. between 1990 and 2010 reported by Cooper et al. and shows that changing background concentrations are at least partially responsible for the decreased surface ozone in the HGB area over the past decade. Baseline ozone concentrations in air flowing into Texas from the Gulf of Mexico have not changed significantly over this period.
Chemical Sciences Division, NOAA ESRL , 325 Broadway R/CSD7, Boulder, Colorado 80305, United States.
Shaena R
SR
Berlin
Andrew O
AO
Langford
Mark
M
Estes
Melody
M
Dong
David D
DD
Parrish
D000393:Air Pollutants / Q000032:analysis*; D000397:Air Pollution / Q000032:analysis*; D060851:Gulf of America; D010126:Ozone / Q000032:analysis*; D025341:Principal Component Analysis; D013781:Texas; D013997:Time Factors; D014919:Wind
D000393:Air Pollutants; D010126:Ozone