Amine formylation via carbon dioxide recycling catalyzed by a simple and efficient heterogeneous palladium catalyst.
A simple and efficient Pd/Al2O3-NR-RD catalyst was prepared by depositing palladium on a shape controllable Al2O3-NR support through a two-step process that involves hydrothermal synthesis of Al2O3-NRs followed by reductive-deposition of palladium. This catalyst showed high activity in the catalytic formylation of amines by CO2-H2 under mild conditions with up to 96% yield.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Centre for Green Chemistry and Catalysis Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences No.18, Tianshui Middle Road, Lanzhou, 730000, China. fshi@licp.cas.cn.
Xinjiang
X
Cui
Yan
Y
Zhang
Youquan
Y
Deng
Feng
F
Shi