Catalytic enantioselective synthesis of α-substituted secondary allylic alcohols from terminal alkynes and aldehydes via vinylaluminum reagents.
Venture Laboratory, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan).
Ravindra
R
Kumar
Hiroki
H
Kawasaki
Toshiro
T
Harada
allylic alcohols; asymmetric catalysis; asymmetric synthesis; hydrometalation; titanium