title: Synthesis of dihydrobenzo[b]furans by diastereoselective acyloxyarylation.
abstract: A highly diastereoselective synthesis of 2-aryl-3-acyloxy-2,3-dihydrobenzofurans by palladium-catalyzed acyloxyarylation involving dearomatization of benzofurans with arylboronic acids and carboxylic acids occurring under mild conditions has been developed.
authors.affiliation: Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. itami.kenichiro@a.mbox.nagoya-u.ac.jp.
authors.forename: Kazuhiro
authors.initials: K
authors.lastname: Hata
authors.forename: Zhiheng
authors.initials: Z
authors.lastname: He
authors.forename: Constantin Gabriel
authors.initials: CG
authors.lastname: Daniliuc
authors.forename: Kenichiro
authors.initials: K
authors.lastname: Itami
authors.forename: Armido
authors.initials: A
authors.lastname: Studer
mesh_terms: D001572:Benzofurans / Q000138:chemical synthesis / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D001572:Benzofurans; D001897:Boronic Acids; D002264:Carboxylic Acids; D010165:Palladium