title: Direct grafting of poly(pentafluorophenyl acrylate) onto oxides: versatile substrates for reactive microcapillary printing and self-sorting modification.
abstract: Poly(pentafluorophenyl acrylate) was covalently attached to silicon oxide through the direct coupling of the reactive ester to surface silanol groups. Subsequently, reactive microcapillary printing (R-μCaP) and a one-pot, self-sorting postpolymerization modification reaction were used to generate patterns of spatially resolved chemical functionality.
authors.affiliation: Department of Chemistry, College of Engineering, and the Center for Nanoscale Science and Engineering, University of Georgia, Athens, GA 30602, USA. jlocklin@uga.edu.
authors.forename: Rachelle M
authors.initials: RM
authors.lastname: Arnold
authors.forename: Christopher D
authors.initials: CD
authors.lastname: McNitt
authors.forename: Vladimir V
authors.initials: VV
authors.lastname: Popik
authors.forename: Jason
authors.initials: J
authors.lastname: Locklin