title: Nanocrystalline ZnCO3-A novel sorbent for low-temperature removal of H2S.
abstract: The reactivity of a nanocrystalline ZnCO3 toward H2S (0.2vol% in N2/H2 mixture) at 140-180°C was characterized by thermal gravimetric analysis and by breakthrough curves measurements. We have found that under used conditions transformation of ZnCO3 into ZnS is complete and the rate determining step of the sulfidation is the surface reaction. Such behavior is in strike contrast with that of ZnO whose sulfidation is severely limited by diffusion. The higher reactivity of ZnCO3 in comparison with ZnO is attributed to the different microstructure of ZnS layer formed in these materials after a partial sulfidation. As in ZnO-ZnS transformation the molar volume increases (from 14.5 to 23.8cm(3)/mol), a continuous protective ZnS layer is formed hampering the access of H2S to the non reacted ZnO core. By contrast, in ZnCO3-ZnS transformation the molar volume decreases (from 27.9 to 23.8cm(3)/mol), which produces a discontinuous non-protective ZnS layer enabling a complete transformation of ZnCO3 even at 140°C. The higher reactivity of ZnCO3 results in a considerable increase of the breakthrough sulfur capacity of the carbonate in comparison with oxide. The material has therefore a good potential for being used as a disposable sorbent for H2S capture at low temperature.
authors.affiliation: Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS - Université de Bourgogne, 9 av. A. Savary, BP47870, 21078 Dijon Cedex, France.
authors.forename: Kevin
authors.initials: K
authors.lastname: Balichard
authors.affiliation: Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS - Université de Bourgogne, 9 av. A. Savary, BP47870, 21078 Dijon Cedex, France.
authors.forename: Camille
authors.initials: C
authors.lastname: Nyikeine
authors.affiliation: Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR6303 CNRS - Université de Bourgogne, 9 av. A. Savary, BP47870, 21078 Dijon Cedex, France. Electronic address: igor.bezverkhyy@u-bourgogne.fr.
authors.forename: Igor
authors.initials: I
authors.lastname: Bezverkhyy
mesh_terms: D002254:Carbonates / Q000737:chemistry*; D006862:Hydrogen Sulfide / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D013696:Temperature; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D002254:Carbonates; D017967:Zinc Compounds; C036650:zinc carbonate; D006862:Hydrogen Sulfide
keywords: H(2)S capture; H(2)S removal; Zinc carbonate sulfidation