title: Stereoselective synthesis of vinyl triflones and heteroaryl triflones through anionic O→C(vinyl) and N→C(vinyl) trifluoromethanesulfonyl migration reactions.
authors.affiliation: Department of Frontier Materials&Department of Nanopharmaceutical Science, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan).
authors.forename: Xiu-Hua
authors.initials: XH
authors.lastname: Xu
authors.forename: Misaki
authors.initials: M
authors.lastname: Taniguchi
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.forename: Etsuko
authors.initials: E
authors.lastname: Tokunaga
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Ozawa
authors.forename: Hideki
authors.initials: H
authors.lastname: Masuda
authors.forename: Norio
authors.initials: N
authors.lastname: Shibata
mesh_terms: D005617:Chlorofluorocarbons, Methane / Q000737:chemistry*; D054879:Halogenation; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D005617:Chlorofluorocarbons, Methane; D014753:Vinyl Compounds; C009554:fluoroform
keywords: alkenes; lithiation; rearrangement; stereoselectivity; synthetic methods