title: The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties.
abstract: Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)-Fe(III) centers and the interesting metamagnetic behavior at about 5.0 K resulted from the intermolecular π-π interaction.
authors.affiliation: College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China. dpzhang@sdut.edu.cn.
authors.forename: Daopeng
authors.initials: D
authors.lastname: Zhang
authors.forename: Yongzhong
authors.initials: Y
authors.lastname: Bian
authors.forename: Jie
authors.initials: J
authors.lastname: Qin
authors.forename: Ping
authors.initials: P
authors.lastname: Wang
authors.forename: Xia
authors.initials: X
authors.lastname: Chen