title: Direct synthesis of a trifluoromethyl copper reagent from trifluoromethyl ketones: application to trifluoromethylation.
authors.affiliation: Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-2776.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Serizawa
authors.forename: Kohsuke
authors.initials: K
authors.lastname: Aikawa
authors.forename: Koichi
authors.initials: K
authors.lastname: Mikami
mesh_terms: D003300:Copper / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D006845:Hydrocarbons, Fluorinated; D007659:Ketones; D003300:Copper
keywords: Ruppert-Prakash reagents; copper; fluorine; ketones; trifluoromethylation