title: Fluorescence probing of the ferric Fenton reaction via novel chelation.
abstract: A new probe-chelator PET dyad was synthesised, which can be used to detect Fe(3+)via fluorescence enhancement to discriminate between Fe(2+) and Fe(3+)via Fenton chemistry involving hydrogen peroxide. This is the first BODIPY which works as a 2 : 1 multiplexer for Fe(3+), Fe(2+) and H2O2.
authors.affiliation: Molecular Logic Gate Laboratory, Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong-dong, Yuseong-gu, Daejeon, 305-701, Republic of Korea. dchurchill@kaist.ac.kr.
authors.forename: Dhiraj P
authors.initials: DP
authors.lastname: Murale
authors.forename: Sudesh T
authors.initials: ST
authors.lastname: Manjare
authors.forename: Yoon-Sup
authors.initials: YS
authors.lastname: Lee
authors.forename: David G
authors.initials: DG
authors.lastname: Churchill
mesh_terms: D001896:Boron Compounds / Q000737:chemistry; D002614:Chelating Agents / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: C095489:4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; D001896:Boron Compounds; D002614:Chelating Agents; C045076:Fenton's reagent; D005290:Ferric Compounds; D005296:Ferrous Compounds; D005456:Fluorescent Dyes; D007477:Ions; D006861:Hydrogen Peroxide; D007501:Iron