title: Organocatalytic reactions of α-trifluoromethylated esters with terminal alkenes at room temperature.
abstract: CF3-containing esters smoothly reacted with electron-deficient alkenes in the presence of a phosphine (2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl) organocatalyst at room temperature in an aerobic atmosphere. These Michael reactions efficiently provided products with a CF3 quaternary carbon center.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, P. R. China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Wang
authors.forename: Feng
authors.initials: F
authors.lastname: Huan
authors.forename: Haiming
authors.initials: H
authors.lastname: Shen
authors.forename: Ji-Chang
authors.initials: JC
authors.lastname: Xiao
authors.forename: Min
authors.initials: M
authors.lastname: Gao
authors.forename: Xianjin
authors.initials: X
authors.lastname: Yang
authors.forename: Shun-Ichi
authors.initials: S
authors.lastname: Murahashi
authors.forename: Qing-Yun
authors.initials: QY
authors.lastname: Chen
authors.forename: Yong
authors.initials: Y
authors.lastname: Guo
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001713:Biphenyl Compounds / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D015394:Molecular Structure; D010720:Phosphines / Q000737:chemistry*; D013696:Temperature
chemical_list: D000475:Alkenes; D001713:Biphenyl Compounds; D004952:Esters; D010720:Phosphines; C000589270:phosphine(2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl)