title: A novel chemiluminescence system with diperiodatonickelate (IV) for the determination of adrenaline.
abstract: A novel chemiluminescence (CL) system with diperiodatonickelate (IV) (DPN) was developed for the determination of adrenaline for the first time. The possible CL emission mechanism was briefly discussed by comparing the fluorescence emission spectra with CL spectra. Under the optimum conditions, the relative CL intensity was linear over the concentration of AD ranging from 1.0×10(-7) to 1.0×10(-5) g mL(-1) with a detection limit of 4.0×10(-8) g mL(-1) (3σ). And the relative standard deviation was 3.7% for 2.0×10(-6) g mL(-1) AD (n=11). The developed method has been successfully applied to the determination of AD in pharmaceutical preparations.
authors.affiliation: Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China. Electronic address: yangchunyancfb@126.com.
authors.forename: Chunyan
authors.initials: C
authors.lastname: Yang
authors.affiliation: Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China.
authors.forename: Fubin
authors.initials: F
authors.lastname: Chen
authors.affiliation: Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China.
authors.forename: Ziqiang
authors.initials: Z
authors.lastname: Chang
authors.affiliation: Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions, College of Material and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China.
authors.forename: Yonghua
authors.initials: Y
authors.lastname: Sun
authors.affiliation: College of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, Shaanxi 710062, China.
authors.forename: Zhujun
authors.initials: Z
authors.lastname: Zhang
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D004837:Epinephrine / Q000032:analysis*; D017022:Flow Injection Analysis; D007700:Kinetics; D008163:Luminescent Measurements / Q000379:methods*; D009532:Nickel / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
chemical_list: D056831:Coordination Complexes; D009532:Nickel; D004837:Epinephrine
keywords: Adrenaline; Chemiluminescence; Diperiodatonickelate