title: Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network.
abstract: An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn3(PhCO2)6(THF)4]2 and a unique [Mn(PhCO2)2]n chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.
authors.affiliation: Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland. lewin@ch.pw.edu.pl.
authors.forename: Arkadiusz
authors.initials: A
authors.lastname: Kornowicz
authors.forename: Szymon
authors.initials: S
authors.lastname: Komorski
authors.forename: Zbigniew
authors.initials: Z
authors.lastname: Wróbel
authors.forename: Iwona
authors.initials: I
authors.lastname: Justyniak
authors.forename: Natalia
authors.initials: N
authors.lastname: Nedelko
authors.forename: Anna
authors.initials: A
authors.lastname: Ślawska-Waniewska
authors.forename: Robert
authors.initials: R
authors.lastname: Balawender
authors.forename: Janusz
authors.initials: J
authors.lastname: Lewiński
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D002264:Carboxylic Acids; D056831:Coordination Complexes; D008345:Manganese; D006859:Hydrogen