title: Rh(III)-catalyzed olefination of N-sulfonyl imines: synthesis of ortho-olefinated benzaldehydes.
abstract: Rh(III)-catalyzed olefination of N-sulfonyl imines using acrylates and styrenes has been achieved for the synthesis of ortho-olefinated benaldehydes. This reaction proceeds via a chelation assisted C-H olefination/in situ hydrolysis process.
authors.affiliation: College of Chemistry and Materials Science, South-Central University for Nationalities , Wuhan 430074, China, and Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Zhang
authors.forename: Lamei
authors.initials: L
authors.lastname: Wu
authors.forename: Xingwei
authors.initials: X
authors.lastname: Li
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001547:Benzaldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001547:Benzaldehydes; D007097:Imines; D009942:Organometallic Compounds; D012238:Rhodium