title: Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction.
abstract: The reactivity of a rhenium complex containing an NAD(+) model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C(+).
authors.affiliation: Brookhaven National Laboratory, Chemistry Department, Upton, New York 11973, USA. fujita@bnl.gov.
authors.forename: Yasuo
authors.initials: Y
authors.lastname: Matsubara
authors.forename: Sean E
authors.initials: SE
authors.lastname: Hightower
authors.forename: Jinzhu
authors.initials: J
authors.lastname: Chen
authors.forename: David C
authors.initials: DC
authors.lastname: Grills
authors.forename: Dmitry E
authors.initials: DE
authors.lastname: Polyansky
authors.forename: James T
authors.initials: JT
authors.lastname: Muckerman
authors.forename: Koji
authors.initials: K
authors.lastname: Tanaka
authors.forename: Etsuko
authors.initials: E
authors.lastname: Fujita
mesh_terms: D002245:Carbon Dioxide / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D008024:Ligands; D008954:Models, Biological; D008958:Models, Molecular; D009243:NAD / Q000737:chemistry*; D010084:Oxidation-Reduction; D012211:Rhenium / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D009243:NAD; D002245:Carbon Dioxide; D012211:Rhenium