title: Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst.
abstract: Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.
authors.affiliation: Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK. g.hogarth@ucl.ac.uk.
authors.forename: Shishir
authors.initials: S
authors.lastname: Ghosh
authors.forename: Graeme
authors.initials: G
authors.lastname: Hogarth
authors.forename: Nathan
authors.initials: N
authors.lastname: Hollingsworth
authors.forename: Katherine B
authors.initials: KB
authors.lastname: Holt
authors.forename: Shariff E
authors.initials: SE
authors.lastname: Kabir
authors.forename: Ben E
authors.initials: BE
authors.lastname: Sanchez
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry / Q000378:metabolism*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry* / Q000378:metabolism; D018360:Crystallography, X-Ray; D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry* / Q000378:metabolism; D006864:Hydrogenase / Q000737:chemistry / Q000378:metabolism*; D000075163:Metallocenes; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D010720:Phosphines / Q000737:chemistry; D011522:Protons
chemical_list: D001672:Biocompatible Materials; D056831:Coordination Complexes; D005296:Ferrous Compounds; D000075163:Metallocenes; D010720:Phosphines; D011522:Protons; D006859:Hydrogen; D006864:Hydrogenase; C519379:1,1'-bis(diphenylphosphino)ferrocene