title: Room temperature synthesis of a copper ink for the intense pulsed light sintering of conductive copper films.
abstract: Conducting films are becoming increasingly important for the printed electronics industry with applications in various technologies including antennas, RFID tags, photovoltaics, flexible electronics, and displays. To date, expensive noble metals have been utilized in these conductive films, which ultimately increases the cost. In the present work, more economically viable copper based conducting films have been developed for both glass and flexible PET substrates, using copper and copper oxide nanoparticles. The copper nanoparticles (with copper(I) oxide impurity) are synthesized by using a simple copper reduction method in the presence of Tergitol as a capping agent. Various factors such as solvent, pH, and reductant concentration have been explored in detail and optimized in order to produce a nanoparticle ink at room temperature. Second, the ink obtained at room temperature was used to fabricate conducting films by intense pulse light sintering of the deposited films. These conducting films had sheet resistances as low as 0.12 Ω/□ over areas up to 10 cm(2) with a thickness of 8 μm.
authors.affiliation: Conn Center for Renewable Energy Research and ‡Department of Chemical Engineering, J.B. Speed School of Engineering, University of Louisville , Louisville, Kentucky 40202, United States.
authors.forename: Ruvini
authors.initials: R
authors.lastname: Dharmadasa
authors.forename: Menaka
authors.initials: M
authors.lastname: Jha
authors.forename: Delaina A
authors.initials: DA
authors.lastname: Amos
authors.forename: Thad
authors.initials: T
authors.lastname: Druffel