title: Electrochemical sensor based on magnetic molecularly imprinted nanoparticles at surfactant modified magnetic electrode for determination of bisphenol A.
abstract: A selective electrochemical sensor based on magnetic molecularly imprinted nanoparticles was developed for determination of bisphenol A (BPA). The particles with regular morphology, high saturation magnetization and good monodispersion were prepared. The hydrophilicity, sensitivity and anti-fouling of the sensor were enhanced by modifying carbon paste electrode with surfactant CTAB in advanced. The results demonstrated that the response of BPA on imprinted electrode was 2.6 times as much as that on non-imprinted sensor. Moreover, the separation factors of BPA to β-estradiol, estriol and diethylstilbestrol were 16.5, 17.3 and 6.6, respectively. Under optimized conditions, the currents were found to be proportional to the BPA concentrations in the range of 6.0×10(-7)-1.0×10(-4) mol/L with a detection limit of 1.0×10(-7) mol/L (S/N=3). A rapid response of the imprinted sensor was obtained within 3 min. The developed sensor was successfully used for determination of BPA in actual samples such as drink bottles and lake water.
authors.affiliation: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122, China.
authors.forename: Lili
authors.initials: L
authors.lastname: Zhu
authors.affiliation: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122, China. Electronic address: yuhuacao64@gmail.com.
authors.forename: Yuhua
authors.initials: Y
authors.lastname: Cao
authors.affiliation: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi 214122, China.
authors.forename: Guangqun
authors.initials: G
authors.lastname: Cao
mesh_terms: D001559:Benzhydryl Compounds / Q000032:analysis*; D001628:Beverages / Q000032:analysis; D055664:Electrochemical Techniques / Q000295:instrumentation*; D004566:Electrodes; D052244:Endocrine Disruptors / Q000032:analysis*; D060106:Lakes / Q000032:analysis; D057230:Limit of Detection; D059346:Magnets / Q000737:chemistry; D054802:Molecular Imprinting; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D010636:Phenols / Q000032:analysis*; D013501:Surface-Active Agents / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D052244:Endocrine Disruptors; D010636:Phenols; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; C006780:bisphenol A; D000098826:Bisphenol A Compounds
keywords: Bisphenol A; Electrochemical sensor; Magnetic nanoparticles; Miniemulsion polymerization; Molecularly imprinted polymers