title: Catalytic stereodivergent functionalization of H2@C60.
abstract: A complete stereocontrol of 1,3-dipolar cycloaddition of N-metalated azomethine ylides onto endohedral fullerene H2@C60 is reported for the first time. The stereodivergent synthesis of either the cis or the trans endohedral cycloadduct is achieved with excellent diastereo- and enantioselectivities.
authors.affiliation: Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Ciudad Universitaria, s/n 28040 Madrid, Spain. nazmar@quim.ucm.es.
authors.forename: Enrique E
authors.initials: EE
authors.lastname: Maroto
authors.forename: Marta
authors.initials: M
authors.lastname: Izquierdo
authors.forename: Michihisa
authors.initials: M
authors.lastname: Murata
authors.forename: Salvatore
authors.initials: S
authors.lastname: Filippone
authors.forename: Koichi
authors.initials: K
authors.lastname: Komatsu
authors.forename: Yasujiro
authors.initials: Y
authors.lastname: Murata
authors.forename: Nazario
authors.initials: N
authors.lastname: Martín