title: Enhancement of spin-crossover cooperativity mediated by lone pair-π interactions and halogen bonding.
abstract: Rational ligand design has allowed the generation of a highly cooperative spin-transition iron(II) complex, an unprecedented result in the family of (2,2'-dipyridylamino/s-triazine)-based SCO materials.
authors.affiliation: Departament de Química Inorgànica, QBI, Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona, Spain. patrick.gamez@qi.ub.es.
authors.forename: Nassim
authors.initials: N
authors.lastname: Nassirinia
authors.forename: Saeid
authors.initials: S
authors.lastname: Amani
authors.forename: Simon J
authors.initials: SJ
authors.lastname: Teat
authors.forename: Olivier
authors.initials: O
authors.lastname: Roubeau
authors.forename: Patrick
authors.initials: P
authors.lastname: Gamez
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry; D018360:Crystallography, X-Ray; D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry; D006219:Halogens / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D011789:Quantum Theory; D013696:Temperature; D013816:Thermodynamics; D014227:Triazines / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D005296:Ferrous Compounds; D006219:Halogens; D014227:Triazines; D015082:2,2'-Dipyridyl