title: Enhanced removal of aqueous BPA model compounds using Metalloligs.
abstract: A model compound, 4-(t-butyl)phenol, was used as a substitute for BPA (bisphenol acetone or Bisphenol A) a material used for the production of a large volume of common plastics. Unfortunately, BPA is suspected to have estrogenic properties, and there is a suspicion that even small amounts can have a deleterious effect against humans, especially female infants. The model compound has some similarities to BPA, but lacks some of the serious properties of BPA dust. Since other workers have demonstrated the capability of removing BPA from plastics by extraction with saline or alcohol, we studied whether Octolig, a polyethylenediimine supported on silica gel, or transition metal derivatives of Octolig could be used to remove concentrations for model compounds from aqueous solution. Octolig gave modest results 20%, the manganese (II) and iron (III) derivatives gave poor results, Cuprilig was an improvement over those two Metalloligs, but the cobalt(II) derivative was able to remove up to 56% of the model compound. Two methods were studied, batch and column chromatography. Under the conditions used in this study, the batch method was superior.
authors.affiliation: a Institute for Environmental Studies, Department of Chemistry , University of South Florida , Tampa , Florida , USA.
authors.forename: Douglas M
authors.initials: DM
authors.lastname: Franz
authors.forename: Dean F
authors.initials: DF
authors.lastname: Martin
mesh_terms: D001559:Benzhydryl Compounds / Q000737:chemistry / Q000302:isolation & purification*; D010636:Phenols / Q000737:chemistry / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D010636:Phenols; D014874:Water Pollutants, Chemical; C056559:2,4-di-tert-butylphenol; C006780:bisphenol A; D000098826:Bisphenol A Compounds; C006862:butylphen