title: Supramolecular chains of high nuclearity {Mn(III)25} barrel-like single molecule magnets.
abstract: The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {Mn(III)25} barrel-like cluster linked via Na(+) cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.
authors.affiliation: Department of Chemistry, Brock University, St. Catharines, Ontario L2S 3A1, Canada. tstamatatos@brocku.ca.
authors.forename: Dimosthenis P
authors.initials: DP
authors.lastname: Giannopoulos
authors.forename: Annaliese
authors.initials: A
authors.lastname: Thuijs
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.forename: Melanie
authors.initials: M
authors.lastname: Pilkington
authors.forename: George
authors.initials: G
authors.lastname: Christou
authors.forename: Theocharis C
authors.initials: TC
authors.lastname: Stamatatos