title: Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties.
abstract: Lanthanide complexes LnL3 (Ln = Sm, Eu, Tb, Dy, Tm, Yb, Lu) with aromatic o-phosphorylated ligands (HL(1) and HL(2)) have been synthesized and identified. Their molecular structure was proposed on the basis of a new complex approach, including DFT calculations, Sparkle/PM3 modelling, EXAFS spectroscopy and luminescent probing. The photophysical properties of all of the complexes were investigated in detail to obtain a deeper insight into the energy transfer processes.
authors.affiliation: Department of Materials Science, Lomonosov Moscow State University, 119991, Leninskie gory, 1/3, Moscow, Russia. sergeyshuvaev@gmail.com.
authors.forename: Sergey
authors.initials: S
authors.lastname: Shuvaev
authors.forename: Valentina
authors.initials: V
authors.lastname: Utochnikova
authors.forename: Łukasz
authors.initials: Ł
authors.lastname: Marciniak
authors.forename: Alexandra
authors.initials: A
authors.lastname: Freidzon
authors.forename: Ilya
authors.initials: I
authors.lastname: Sinev
authors.forename: Rik
authors.initials: R
authors.lastname: Van Deun
authors.forename: Ricardo O
authors.initials: RO
authors.lastname: Freire
authors.forename: Yan
authors.initials: Y
authors.lastname: Zubavichus
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Grünert
authors.forename: Natalia
authors.initials: N
authors.lastname: Kuzmina