title: Highly sensitive and selective detection of nitrophenolic explosives by using nanospheres of a tetraphenylethylene macrocycle displaying aggregation-induced emission.
abstract: A tetraphenylethylene (TPE) Schiff-base macrocycle showing an aggregation-induced emission (AIE) effect has been synthesized, which could aggregate into nanospheres and emit yellow fluorescence in aqueous media. By virtue of its AIE effect, the macrocycle showed a sensitive and selective response to 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) among a number of nitroaromatic compounds, which could be used to detect TNP and DNP at nanomolar levels. Moreover, it exhibited a superamplified quenching effect with DNP but not with TNP, providing a possible means of discriminating these two compounds. In comparison with open-chain TPE Schiff-bases, the cavity of the macrocycle is essential for the selectivity for DNP over TNP. In addition, quantitative analyses of both DNP and TNP in real water samples and qualitative detection of these two analytes in the solid state by the macrocycle have been tested. The reliability of the quantitative analysis has been confirmed by HPLC. Our findings demonstrate that the TPE Schiff-base macrocycle has great potential as an excellent sensor for DNP and TNP.
authors.affiliation: School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China), Fax: (+86) 27-87543632.
authors.forename: Hai-Tao
authors.initials: HT
authors.lastname: Feng
authors.forename: Yan-Song
authors.initials: YS
authors.lastname: Zheng
keywords: Schiff-base macrocycles; aggregation-induced emission; explosives; fluorescent probes; nitrophenols; sensors