title: Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes.
abstract: Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.
authors.affiliation: UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California , San Diego, La Jolla, California 92093-0343, United States.
authors.forename: Janell K
authors.initials: JK
authors.lastname: Mahoney
authors.forename: David
authors.initials: D
authors.lastname: Martin
authors.forename: Curtis E
authors.initials: CE
authors.lastname: Moore
authors.forename: Arnold L
authors.initials: AL
authors.lastname: Rheingold
authors.forename: Guy
authors.initials: G
authors.lastname: Bertrand
mesh_terms: D003500:Cyclization; D005609:Free Radicals; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular
chemical_list: D005609:Free Radicals; C030011:carbene; D008697:Methane