title: Plasmon-enhanced energy transfer for improved upconversion of infrared radiation in doped-lanthanide nanocrystals.
abstract: Upconversion of infrared radiation into visible light has been investigated for applications in photovoltaics and biological imaging. However, low conversion efficiency due to small absorption cross-section for infrared light (Yb(3+)), and slow rate of energy transfer (to Er(3+) states) has prevented application of upconversion photoluminescence (UPL) for diffuse sunlight or imaging tissue samples. Here, we utilize resonant surface plasmon polaritons (SPP) waves to enhance UPL in doped-lanthanide nanocrystals. Our analysis indicates that SPP waves not only enhance the electromagnetic field, and hence weak Purcell effect, but also increase the rate of resonant energy transfer from Yb(3+) to Er(3+) ions by 6 fold. While we do observe strong metal mediated quenching (14-fold) of green fluorescence on flat metal surfaces, the nanostructured metal is resonant in the infrared and hence enhances the nanocrystal UPL. This strong Coulombic effect on energy transfer can have important implications for other fluorescent and excitonic systems too.
authors.affiliation: Department of Chemical and Biological Engineering, ‡Department of Physics, §Materials Science and Engineering, and ∥Renewable and Sustainable Energy Institute (RASEI), University of Colorado Boulder , Boulder, Colorado 80309, United States.
authors.forename: Qi-C
authors.initials: QC
authors.lastname: Sun
authors.forename: Haridas
authors.initials: H
authors.lastname: Mundoor
authors.forename: Josep C
authors.initials: JC
authors.lastname: Ribot
authors.forename: Vivek
authors.initials: V
authors.lastname: Singh
authors.forename: Ivan I
authors.initials: II
authors.lastname: Smalyukh
authors.forename: Prashant
authors.initials: P
authors.lastname: Nagpal