title: Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior.
abstract: Four iso-structural layered coordination polymers (CPs) of Cd(II) and Zn(II) were shown to exhibit breathing transitions with N2/H2 gases. Furthermore, the solid solutions containing Zn(II)/Cd(II) have shown better uptake capacities of gas than parent CPs. These results give some insights into the role of metal ions and anions for fine-tuning the porosity of CPs.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India. kbiradha@chem.iitkgp.ernet.in.
authors.forename: Gargi
authors.initials: G
authors.lastname: Mukherjee
authors.forename: Kumar
authors.initials: K
authors.lastname: Biradha