title: 3,6,9,12-Tetrasubstituted chrysenes: synthesis, photophysical properties, and application as blue fluorescent OLED.
abstract: A short synthesis of unsubstituted chrysene is described to provide a cheap source of this compound. This chrysene was used to prepare 3,6,9,12-tetrabromochrysene, which was subsequently transformed into various 3,6,9,12-tetrasubstituted chrysenes bearing four aryl, alkynyl, or amino groups by means of the Suzuki, Sonogashira, or Buchwald-Hartwig coupling reaction, respectively. These substituents result in large bathochromic shifts in the chrysene absorption and emission spectra. These new chrysene derivatives show blue fluorescent emission (401-471 nm) with high quantum yields (0.44-0.87). DFT calculations on these chrysenes rationalize well the substituent effects on their HOMO and LUMO energy levels. One representative chrysene (6g) was used as a blue fluorescent emitter in an OLED device that showed an outstanding external quantum efficiency (η = 6.31%) with blue emission [CIE (x, y) = (0.13, 0.20)] and a low turn-on voltage (3.0 V).
authors.affiliation: Department of Chemistry, National Tsing Hua University , Hsinchu, Taiwan, ROC.
authors.forename: Tien-Lin
authors.initials: TL
authors.lastname: Wu
authors.forename: Ho-Hsiu
authors.initials: HH
authors.lastname: Chou
authors.forename: Pei-Yun
authors.initials: PY
authors.lastname: Huang
authors.forename: Chien-Hong
authors.initials: CH
authors.lastname: Cheng
authors.forename: Rai-Shung
authors.initials: RS
authors.lastname: Liu