title: Structure-activity relationship of unsaturated fatty acids as mosquito ovipositional repellents.
abstract: Various straight-chain unsaturated fatty acids from C14 to C24 were evaluated for their ovipositional repellency against gravid females of the southern house mosquitoCulex quinquefasciatus Say, and the relationship between the structures of the fatty acids and their ovipositional repellency was determined. A double bond withZ configuration was prerequisite for an unsaturated fatty acid to be highly repellent;E isomers were less active or even inactive. No relationship was found between the repellency and the number of double bonds in the unsaturated fatty acids. In C18 monounsaturated fatty acids, (Z)-9 acid was more active than (Z)-11 and (Z)-6 acids, indicating that a double bond at the 9 position rendered an acid highly repellent. Among (Z)-9-alkenoic acids of different chain lengths, the most repellent was C18 acid which was also more active than (Z)-11-C20, (Z)-13-C22, and (Z)-15-C24 acids. Oleic[(Z)-9-octadecenoic]acid, which met all these criteria, was the most ovipositionally repellent among the unsaturated fatty acids tested.
authors: Department of Entomology, University of California, 92521, Riverside, California.
authors: Y S
authors: YS
authors: Hwang
authors: G W
authors: GW
authors: Schultz
authors: M S
authors: MS
authors: Mulla