title: A three-dimensional chiral crystal structure constructed from a chiral triazolate ligand showing an SrSi2 topology: poly[bis(μ3-3,5-diethyl-1,2,4-triazolato-κ(3)N(1):N(2):N(4))trisilver nitrate].
abstract: In the title metal-organic framework (MOF), {[Ag3(C6H10N3)2]NO3}n, the Ag(I) cation is coordinated by two N atoms from two different 3,5-diethyl-1,2,4-triazolate (detz) ligands in a linear configuration. Each Ag(I) cation is then connected to two adjacent Ag(I) cations via a μ3-N(1):N(2):N(4)-detrz ligand, resulting in a three-dimensional chiral silver-triazolate structure showing an SrSi2 (srs) net with 10(3) topology.
authors: School of Pharmacy, China Pharmaceutical University, Nanjing 211198, People's Republic of China.
authors: Feng
authors: F
authors: Jiang
authors: Lin
authors: L
authors: Dai
authors: Yiqiang
authors: Y
authors: Shi
authors: Zhixiang
authors: Z
authors: Wang
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D015394:Molecular Structure; D012834:Silver / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; C587644:poly(bis(mu3-3,5-diethyl-1,2,4-triazolato-kappa(3)N(1)-N(2)-N(4))trisilver nitrate); D012834:Silver
keywords: SrSi2 topology; crystal structure; metal–organic frameworks; silver–triazolates; srs net