title: Synthesis of spiroaminals and spiroketals with bimetallic relay catalysis.
abstract: A novel tandem metal relay catalytic system was developed by combining gold-catalyzed cycloisomerization with an early transition-metal-catalyzed inverse-electron-demand hetero-Diels-Alder (IED-HDA) reaction. Various biologically important spiroaminals and spiroketals were obtained with very high efficiency under mild conditions.
authors: Key Lab for Colloid and Interface Chemistry of Education Ministry School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, China.
authors: Xianghua
authors: X
authors: Wang
authors: Shuli
authors: S
authors: Dong
authors: Zhili
authors: Z
authors: Yao
authors: Lei
authors: L
authors: Feng
authors: Philias
authors: P
authors: Daka
authors: Hong
authors: H
authors: Wang
authors: Zhenghu
authors: Z
authors: Xu
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013141:Spiro Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D000588:Amines; D009942:Organometallic Compounds; D013141:Spiro Compounds; D028561:Transition Elements