title: Palladium(II)-catalyzed ortho-olefination of arenes applying sulfoxides as remote directing groups.
abstract: A novel palladium-catalyzed ortho-C(sp(2))-H olefination protocol has been developed by the use of sulfoxide as the directing group. Importantly, relatively remote coordination can be accessed to achieve the ortho olefination of benzyl, 2-arylethyl, and 3-arylpropenyl sulfoxide substrates, and the olefinated sulfoxide can be easily transformed to other functionalities.
authors: ZJU-NHU United R&D Center, Department of Chemistry, Zhejiang University , Hangzhou 310027, China.
authors: Binjie
authors: B
authors: Wang
authors: Chuang
authors: C
authors: Shen
authors: Jinzhong
authors: J
authors: Yao
authors: Hong
authors: H
authors: Yin
authors: Yuhong
authors: Y
authors: Zhang