title: Giant Zn14 molecular building block in hydrogen-bonded network with permanent porosity for gas uptake.
abstract: In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn14(L2)12(O)(OH)2(H2O)4] molecular building block (MBB) with a Zn6 octahedron inscribed in a Zn8 cube. The MBBs connect by amide-amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N2, CO2, CH4, and H2 gas sorption.
authors: Institut für Chemie, Anorganische Chemie, Universität Potsdam , Karl-Liebknecht-Straße 24-25, 14476 Potsdam, Germany.
authors: Suvendu Sekhar
authors: SS
authors: Mondal
authors: Asamanjoy
authors: A
authors: Bhunia
authors: Alexandra
authors: A
authors: Kelling
authors: Uwe
authors: U
authors: Schilde
authors: Christoph
authors: C
authors: Janiak
authors: Hans-Jürgen
authors: HJ
authors: Holdt