title: Vapochemically and mechanochemically reversible polymerization/depolymerization of S-Fe-Cu carbonyl clusters.
abstract: A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [{(μ3-S)Fe3(CO)9}Cu2(dppe)] (2) and its 1D polymer [{(μ4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n (3) was demonstrated, in which polymer 3 exhibited semi-conducting properties with an energy gap of 1.69 eV.
authors: Department of Chemistry, National Taiwan Normal University, 88, Sec. 4, Tingchow Road, Taipei 11677, Taiwan, Republic of China. mshieh@ntnu.edu.tw.
authors: Chien-Nan
authors: CN
authors: Lin
authors: Wei-Ting
authors: WT
authors: Jhu
authors: Minghuey
authors: M
authors: Shieh