title: A two-dimensional Cu(I) framework incorporating the 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol ligand.
abstract: The new two-dimensional coordination polymer, poly[(μ4-1-phenyl-1H-1,2,3,4-tetrazole-5-thiolato)copper(I)], [Cu(C7H5N4S)]n, has been prepared under solvothermal conditions by reacting CuBr with 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol (Hptt) in an acetonitrile and acetone solution. In the crystal structure, each Cu(I) ion is coordinated by two N atoms and two S atoms from four ptt(-) ligands, and each ptt(-) ligand links four Cu(I) ions to form two-dimensional layers which lie parallel to the (100) plane. These layers stack along the [100] direction via van der Waals interactions.
authors: Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155, People's Republic of China.
authors: Fang-Xia
authors: FX
authors: Zhou
authors: Cheng-Yang
authors: CY
authors: Yue
authors: Hui-Ping
authors: HP
authors: Zhang
authors: Xiao-Wu
authors: XW
authors: Lei
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D015394:Molecular Structure; D013777:Tetrazoles / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D013777:Tetrazoles; C587643:poly((mu4-1-phenyl-1H-1,2,3,4-tetrazole-5-thiolato)copper(I)); D003300:Copper
keywords: 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol; Hptt; copper(I) coordination polymer; crystal structure; two-dimensional coordination polymer