title: Support curvature and conformational freedom control chemical reactivity of immobilized species.
abstract: We show that bimolecular reactions between species confined to the surfaces of nanoparticles can be manipulated by the nature of the linker, as well as by the curvature of the underlying particles.
authors: Department of Organic Chemistry, Weizmann Institute of Science , Rehovot 76100, Israel.
authors: Tino
authors: T
authors: Zdobinsky
authors: Pradipta Sankar
authors: PS
authors: Maiti
authors: Rafal
authors: R
authors: Klajn
mesh_terms: D000873:Anthracenes / Q000737:chemistry; D004800:Enzymes, Immobilized / Q000737:chemistry* / Q000378:metabolism; D006046:Gold / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry; D008958:Models, Molecular; D011487:Protein Conformation; D013499:Surface Properties
chemical_list: D000873:Anthracenes; D004800:Enzymes, Immobilized; D006046:Gold; C034020:anthracene