title: A reversible multi-stimuli-responsive fluorescence probe and the design for combinational logic gate operations.
abstract: Here, a novel multi-stimuli-responsive fluorescence probe is developed by incorporating spiropyran group into the coumarin-substituted polydiacetylene (PDA) vesicles. The fluorescence of PDA can be turned on upon heating, and can be quenched upon exposure to UV light irradiation or pH stimuli owing to the fluorescene resonance energy transfer (FRET) between the red-phase PDA and the open merocyanine (MC) form of spiropyran. Moreover, we have designed and experimentally realized a set of logic gate operations for the first time based on the fluorescence modulation of the designed system upon thermal, photo, and pH stimuli. This novel type of resettable logic gates augur well for practical applications in information storage, optical recording, and sensing in complicated microenvironments.
authors: CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, Key Laboratory of Optoelectronic Science and Technology in Anhui Province, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China.
authors: Hongyan
authors: H
authors: Xia
authors: Yangyang
authors: Y
authors: Xu
authors: Guang
authors: G
authors: Yang
authors: Hao
authors: H
authors: Jiang
authors: Gang
authors: G
authors: Zou
authors: Qijin
authors: Q
authors: Zhang
mesh_terms: D001578:Benzopyrans / Q000737:chemistry*; D005453:Fluorescence; D031541:Fluorescence Resonance Energy Transfer; D005456:Fluorescent Dyes / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D015335:Molecular Probes / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*
chemical_list: D001578:Benzopyrans; D005456:Fluorescent Dyes; D007211:Indoles; D015335:Molecular Probes; D009574:Nitro Compounds; C088184:spiropyran
keywords: PDA vesicles; fluorescence probe; logic gate; stimuli- responsive