title: Adsorption of Ni(II) and Cd(II) from water by novel chelating sponge and the effect of alkali-earth metal ions on the adsorption.
abstract: Novel chelating sponge (PVA-M-H) was prepared with polyvinyl alcohol by graft polymerization and nucleophilic substitution. E.A, SEM, FT-IR, (13)CNMR, and XPS analyses were used to characterize PVA-M-H. The equilibrium adsorption capacities of PVA-M-H for Ni(II) and Cd(II) were 65.39 and 125.11mgg(-1), respectively. Within the range of 278-308K, the adsorption enthalpy changes of Ni(II) and Cd(II) on PVA-M-H were about 36.39-37.72kJmol(-1), and the free energy were about -13.27 to -1.7kJmol(-1). Both pseudo-first- and -second-order equations fit the adsorption kinetic curves well, and the initial adsorption rates of Ni(II) and Cd(II) onto PVA-M-H were 17.83 and 34.81mg (gmin)(-1), respectively. Although the presence of alkali-earth metal ions in solution decreased Ni(II) and Cd(II) removal, PVA-M-H still retained more than 60 and 80% of its adsorption capacity even as the concentration of Ca(2+) and Mg(2+) was up to 10mmolL(-1), respectively. Both 0.1M HCl and 0.1M EDTA solution could desorb Ni(II) and Cd(II) from PVA-M-H effectively, and the adsorption capacity of PVA-M-H for Ni(II) and Cd(II) could still maintain more than 90% level without any obvious decrease at the fifth cycle.
authors: State Key Laboratory of Pollution Control and Resource Reuse & School of the Environment Nanjing University, Nanjing 210023, China.
authors: Cheng
authors: C
authors: Cheng
authors: State Key Laboratory of Pollution Control and Resource Reuse & School of the Environment Nanjing University, Nanjing 210023, China; University of Applied Sciences Northwestern Switzerland, Basel 4132, Switzerland. Electronic address: wjnnju@163.com.
authors: Jinnan
authors: J
authors: Wang
authors: State Key Laboratory of Pollution Control and Resource Reuse & School of the Environment Nanjing University, Nanjing 210023, China.
authors: Xin
authors: X
authors: Yang
authors: State Key Laboratory of Pollution Control and Resource Reuse & School of the Environment Nanjing University, Nanjing 210023, China.
authors: Aimin
authors: A
authors: Li
authors: University of Applied Sciences Northwestern Switzerland, Basel 4132, Switzerland.
authors: Corvini
authors: C
authors: Philippe
mesh_terms: D000179:Acrylates / Q000737:chemistry*; D000327:Adsorption; D002104:Cadmium / Q000302:isolation & purification*; D008673:Metals, Alkaline Earth / Q000737:chemistry; D009532:Nickel / Q000302:isolation & purification*; D011142:Polyvinyl Alcohol / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D000179:Acrylates; D008673:Metals, Alkaline Earth; D014874:Water Pollutants, Chemical; D002104:Cadmium; D009532:Nickel; D011142:Polyvinyl Alcohol; C035956:methyl acrylate
keywords: Adsorption; Alkali-earth metal ions; Chelating sponge; Ni(II) and Cd(II)