title: Two highly stable and selective solid phase microextraction fibers coated with crown ether functionalized ionic liquids by different sol-gel reaction approaches.
abstract: In this work, two novel crown ether functionalized ionic liquid (FIL)-based solid phase microextraction (SPME) fibers were prepared by sol-gel technology using the synthesized 1-(trimethoxysily)propyl 3-(6'-oxo-benzo-15-crown-5 hexyl) imidazolium bis(trifluoromethanesulphonyl)imide ([TMSP(Benzo15C5)HIM][N(SO2CF3)2]) and 1-allyl-3-(6'-oxo-benzo-15-crown-5 hexyl) imidazolium bis(trifluoromethanesulphonyl)imide ([A(Benzo15C5)HIM][N(SO2CF3)2]) as selective stationary phases. Owing to the introduction of trimethoxysilypropyl to the imidazole cation, the [TMSP(Benzo15C5)HIM][N(SO2CF3)2] could be chemically bonded to the formed sol-gel silica substrate through the hydrolysis and polycondensation reaction. Similarly, the [A(Benzo15C5)HIM][N(SO2CF3)2] was able to participate in the formation of the organic-inorganic copolymer coatings through the free radical crosslinking reaction. These two fibers were determined to have "bubble-like" surface characteristics analogous to a previously prepared [A(Benzo15C5)HIM][PF6]-based fiber. Their thermal stabilities were much higher than that of the [A(Benzo15C5)HIM][PF6]-based coating. They were capable of withstanding temperatures as high as 400°C without evident loss of the crown ether FILs. They also had strong solvent, acid and alkali resistance, good coating preparation reproducibility and high selectivity for medium polar to polar compounds. The high selectivity of these two fibers could be attributed to the strong ion-dipole, hydrogen bonding and π-π interactions provided by the synergetic effect of ILs and benzo-15-crown-5 functionalities. Moreover, the selectivity of these two fibers was rather different although the structures of these two crown ether FILs were very similar. This is maybe because the relative contents of the crown ether FILs chemically bonded to the organic-inorganic copolymer coatings were quite different when prepared by different sol-gel reaction approaches.
authors: College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China.
authors: Jianjun
authors: J
authors: Shu
authors: College of Science, Huazhong Agricultural University, Wuhan 430070, China.
authors: Pengfei
authors: P
authors: Xie
authors: College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China.
authors: Danni
authors: D
authors: Lin
authors: College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China.
authors: Rongfeng
authors: R
authors: Chen
authors: College of Science, Huazhong Agricultural University, Wuhan 430070, China.
authors: Jiang
authors: J
authors: Wang
authors: College of Science, Huazhong Agricultural University, Wuhan 430070, China.
authors: Beibei
authors: B
authors: Zhang
authors: College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China. Electronic address: liumm@mail.hzau.edu.cn.
authors: Mingming
authors: M
authors: Liu
authors: College of Science, Huazhong Agricultural University, Wuhan 430070, China. Electronic address: hanlan001@126.com.
authors: Hanlan
authors: H
authors: Liu
authors: College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China.
authors: Fan
authors: F
authors: Liu
keywords: Crown ether functionalized ionic liquids; Ionic liquids; Solid-phase microextraction; Sol–gel technology; Sorbent coating