title: Experimental and theoretical study on palladium-catalyzed C-P bond formation via direct coupling of triarylbismuths with P(O)-H compounds.
abstract: A novel and highly efficient Pd-catalyzed cross-coupling of triarylbismuths with a variety of P(O)-H compounds has been developed that proceeds smoothly without exclusion of moisture or air and provides a general and powerful tool for the preparation of various valuable arylphosphonates, arylphosphinates, and arylphosphine oxides, with high atom-economy, operational simplicity of the procedure, and good to high yield. The coupling reaction is the first example of transition-metal-catalyzed C-P bond construction using triarylbismuth compounds as substrates. DFT calculations reveal that C-P bond formation is the rate-determing step.
authors: Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University , Xiamen 361005, Fujian, China.
authors: Tao
authors: T
authors: Wang
authors: Shuai
authors: S
authors: Sang
authors: Liu Leo
authors: LL
authors: Liu
authors: Hongwei
authors: H
authors: Qiao
authors: Yuxing
authors: Y
authors: Gao
authors: Yufen
authors: Y
authors: Zhao
mesh_terms: D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D010165:Palladium; D001729:Bismuth