title: Engineering new layered solids from exfoliated inorganics: a periodically alternating hydrotalcite-montmorillonite layered hybrid.
abstract: Two-dimensional (2D) nanosheets obtained by exfoliating inorganic layered crystals have emerged as a new class of materials with unique attributes. One of the critical challenges is to develop robust and versatile methods for creating new nanostructures from these 2D-nanosheets. Here we report the delamination of layered materials that belonging to two different classes--the cationic clay, montmorillonite, and the anionic clay, hydrotalcite--by intercalation of appropriate ionic surfactants followed by dispersion in a non-polar solvent. The solids are delaminated to single layers of atomic thickness with the ionic surfactants remaining tethered to the inorganic and consequently the nanosheets are electrically neutral. We then show that when dispersions of the two solids are mixed the exfoliated sheets self-assemble as a new layered solid with periodically alternating hydrotalcite and montmorillonite layers. The procedure outlined here is easily extended to other layered solids for creating new superstructures from 2D-nanosheets by self-assembly.
authors: Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012. India.
authors: Rajesh
authors: R
authors: Chalasani
authors: Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012. India.
authors: Amit
authors: A
authors: Gupta
authors: Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012. India.
authors: Sukumaran
authors: S
authors: Vasudevan