title: Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.
abstract: Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine.
authors: Department of Chemistry, Chemistry Research Laboratory, University of Oxford , Mansfield Road, Oxford OX1 3TA, U.K.
authors: Andrew R
authors: AR
authors: Jupp
authors: Jose M
authors: JM
authors: Goicoechea