title: (OC-6-13)-difluoridooxidobis(propan-2-ol)(propan-2-olato)vanadium(V).
abstract: The distorted octahedral title complex, [V(V)(C3H7O)(C3H8O)2F2O], was synthesized via ligand exchange at [V(V)O(OiPr)3] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D)chloroform at 238 K after a few weeks. Crystal structure determination shows two C1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along [100] via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif.
authors: Institut für Chemie, Technische Universität Berlin, Straße des 17 Juni 135, 10623 Berlin, Germany.
authors: Julia
authors: J
authors: Kohl
authors: Dennis
authors: D
authors: Wiedemann
keywords: alcoholates; crystal structure; hydrogen bonds; hydrogen fluoride; vanadium complexes