title: Studies on relationship between activity and electron density on carbonyl oxygen in sex pheromone mimics of the American cockroach, part XI.
abstract: From the relationship between structures of the 2α-substituents of verbanyl analogs and their sex pheromone activities to the American cockroach, electron density of the carbonyl oxygen atom in the substituent, as estimated by the [(17)O]NMR chemical shift, was estimated to be an important factor which influenced the activity, in addition to length of the substituent and the position of the carbonyl group. (+)-Verbanyl methylcarbonate (XX), possessing the highest electron density on the carbonyl oxygen atom, showed the strongest activity among the analogs.
authors: Mitsubishi-Kasei Institute of Life Sciences, 11 Minamiooya Machida-shi, 194, Tokyo, Japan.
authors: S
authors: S
authors: Manabe
authors: C
authors: C
authors: Nishino
authors: K
authors: K
authors: Matsushita