title: Enantioselective Black rearrangement catalyzed by chiral bicyclic imidazole.
abstract: A newly developed chiral imidazole nucleophilic catalyst, , was readily prepared and successfully applied to the enantioselective Black rearrangement with up to 88% ee for a wide range of substrates possessing different substituted groups. A plausible mechanism for the high enantioselectivity was proposed.
authors: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China. wanbin@sjtu.edu.cn.
authors: Mingli
authors: M
authors: Wang
authors: Zhenfeng
authors: Z
authors: Zhang
authors: Shan
authors: S
authors: Liu
authors: Fang
authors: F
authors: Xie
authors: Wanbin
authors: W
authors: Zhang
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D002384:Catalysis; D007093:Imidazoles / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D007093:Imidazoles