title: Stern layer formation induced by hydrophobic interactions: a molecular level study.
abstract: The molecular ionic surface structure and charge of the electric double layer around a nanodroplet and its structural change induced by hydrophobic effects are measured using vibrational coherent surface scattering spectroscopy, second harmonic scattering, and electrokinetic mobility measurements. Tetraalkylammonium chloride salts were added to negatively charged nanoscopic oil droplets in water. When we vary the alkyl chain length of the cation from CH3 to C4H10, both the size of the cation and its hydrophobic interaction are increased. We find that tetramethylammonium ions change the electrokinetic potential and the water structure but do not detectably adsorb to the interface. Tetrapropylammonium and tetrabutylammonium ions clearly adsorb to the interface. The corresponding (Stern) layer appears to be a mixed monolayer of anions and cations. An estimate of the amount of cations in the Stern layer is also made.
authors: Laboratory for fundamental BioPhotonics (LBP), Institute of Bioengineering (IBI), School of Engineering, École Polytechnique Fédérale de Lausanne (EPFL) , 1015 Lausanne, Switzerland.
authors: Rüdiger
authors: R
authors: Scheu
authors: Yixing
authors: Y
authors: Chen
authors: Mireia
authors: M
authors: Subinya
authors: Sylvie
authors: S
authors: Roke
mesh_terms: D057927:Hydrophobic and Hydrophilic Interactions; D007477:Ions; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry*; D009821:Oils; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D007477:Ions; D009821:Oils; D000644:Quaternary Ammonium Compounds; D014867:Water