title: Communication: nuclear quadrupole moment-induced Cotton-Mouton effect in noble gas atoms.
abstract: New, high-sensitivity and high-resolution spectroscopic and imaging methods may be developed by exploiting nuclear magneto-optic effects. A first-principles electronic structure formulation of nuclear electric quadrupole moment-induced Cotton-Mouton effect (NQCME) is presented for closed-shell atoms. In NQCME, aligned quadrupole moments alter the index of refraction of the medium along with and perpendicular to the direction of nuclear alignment. The roles of basis-set convergence, electron correlation, and relativistic effects are investigated for three quadrupolar noble gas isotopes: (21)Ne, (83)Kr, and (131)Xe. The magnitude of the resulting ellipticities is predicted to be 10(-4)-10(-6) rad/(M cm) for fully spin-polarized nuclei. These should be detectable in the Voigt setup. Particularly interesting is the case of (131)Xe, in which a high degree of spin polarization can be achieved via spin-exchange optical hyperpolarization.
authors: NMR Research Group, Department of Physics, University of Oulu, P.O. Box 3000, FIN-90014 Oulu, Finland.
authors: Li-juan
authors: LJ
authors: Fu
authors: Antonio
authors: A
authors: Rizzo
authors: Juha
authors: J
authors: Vaara