title: DABCO catalyzed cross-Rauhut-Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight.
abstract: DABCO catalyzed the cross-Rauhut-Currier/transesterification reaction of α-cyano-α,β-unsaturated ketones and aryl acrylates was discovered. The reaction rate law was determined by an integral method under pseudo-first-order reaction conditions, which assisted in proposing the mechanism of cross-Rauhut-Currier reaction promoted by Brønsted acid and establishing the rate-determining step.
authors: Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. zhaog@mail.sioc.ac.cn.
authors: Wen
authors: W
authors: Liu
authors: Gang
authors: G
authors: Zhao
mesh_terms: D000179:Acrylates / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D007700:Kinetics; D010879:Piperazines / Q000737:chemistry*
chemical_list: D000179:Acrylates; D000475:Alkenes; D010879:Piperazines; C007306:triethylenediamine