title: Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction.
abstract: New peroxynitrite-copper chemistry ensues via addition of nitric oxide (˙NO(g)) to a Cu(II)-hydroperoxo species. In characterizing the system, the ligand-Cu(i) complex was shown to effect a seldom observed ˙NO(g) reductive coupling reaction. Biological implications are discussed.
authors: Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA. karlin@jhu.edu.
authors: Sunghee
authors: S
authors: Kim
authors: Maxime A
authors: MA
authors: Siegler
authors: Kenneth D
authors: KD
authors: Karlin
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D030421:Peroxynitrous Acid / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D030421:Peroxynitrous Acid; D009569:Nitric Oxide; D003300:Copper