title: Substituent effects in cation-π interactions revisited: a general approach based on intrinsic properties of the arenes.
abstract: The controversial proposal that substituent effects in cation-π interactions can be attributed mainly to electrostatic effects between the ion and local dipoles has been theoretically studied by analyzing 171 aromatics interacting with Na(+). Our results stress the importance of both electrostatic and π-polarization effects to properly describe cation-π interactions.
authors: Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca, Spain. david.quinonero@uib.es.
authors: A
authors: A
authors: Bauzá
authors: P M
authors: PM
authors: Deyà
authors: A
authors: A
authors: Frontera
authors: D
authors: D
authors: Quiñonero