title: Hybrid gold/chiral Brønsted acid relay catalysis allows an enantioselective synthesis of (-)-5-epi-eupomatilone-6.
abstract: An enantioselective synthesis of (-)-5-epi-eupomatilone-6 has been accomplished by using relay catalytic cascade intramolecular hydrosiloxylation and Mukaiyama aldol reaction of 2,3,4-trimethoxy-6-(phenylethynyl)phenyl dimethylsilanol with fluorenylglyoxylate.
authors: Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China , Hefei 230026, China.
authors: Xiang
authors: X
authors: Wu
authors: Ming-Li
authors: ML
authors: Li
authors: Pu-sheng
authors: PS
authors: Wang
mesh_terms: D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006038:Glyoxylates / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D015394:Molecular Structure; D012821:Silanes / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: C000590898:2,3,4-trimethoxy-6-(phenylethynyl)phenyl dimethylsilanol; D001572:Benzofurans; D006038:Glyoxylates; D012821:Silanes; C485126:eupomatilone-6; D006046:Gold