title: Halogenated volatiles from the fungus Geniculosporium and the actinomycete Streptomyces chartreusis.
abstract: Two unidentified chlorinated volatiles X and Y were detected in headspace extracts of the fungus Geniculosporium. Their mass spectra pointed to the structures of a chlorodimethoxybenzene for X and a dichlorodimethoxybenzene for Y. The mass spectra of some constitutional isomers for X and Y were included in our databases and proved to be very similar, thus preventing a full structural assignment. For unambiguous structure elucidation all possible constitutional isomers for X and Y were obtained by synthesis or from commercial suppliers. Comparison of mass spectra and GC retention times rigorously established the structures of the two chlorinated volatiles. Chlorinated volatiles are not very widespread, but brominated or even iodinated volatiles are even more rare. Surprisingly, headspace extracts from Streptomyces chartreusis contained methyl 2-iodobenzoate, a new natural product that adds to the small family of iodinated natural products.
authors.affiliation: Institut für Organische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
authors.forename: Tao
authors.initials: T
authors.lastname: Wang
authors.affiliation: Institut für Organische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
authors.forename: Patrick
authors.initials: P
authors.lastname: Rabe
authors.affiliation: Institut für Organische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
authors.forename: Christian A
authors.initials: CA
authors.lastname: Citron
authors.affiliation: Institut für Organische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
authors.forename: Jeroen S
authors.initials: JS
authors.lastname: Dickschat
keywords: GC-MS; constitutional isomerism; natural products; organohalogen compounds; volatiles