title: N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene.
abstract: The new phosphaalkenyl(chloro)tin(II) compound NHC-Sn(Cl)[C(SiMe3)=PMes*] was isolated and fully characterized including molecular structure determination by a single crystal X-ray diffraction analysis. Its reaction with Me2SAuCl led to the formation of an unprecedented P=C-bridged trinuclear gold complex [AuC(SiMe3)=PMes*]3 through the transfer of the phosphaalkenyl substituent to the gold atom.
authors.affiliation: Université de Toulouse, UPS, CNRS, LHFA, UMR 5069, 118 Route de Narbonne, F-31062 Toulouse cedex 09, France.
authors.forename: T-G
authors.initials: TG
authors.lastname: Kocsor
authors.forename: G
authors.initials: G
authors.lastname: Nemes
authors.forename: N
authors.initials: N
authors.lastname: Saffon
authors.forename: S
authors.initials: S
authors.lastname: Mallet-Ladeira
authors.forename: D
authors.initials: D
authors.lastname: Madec
authors.forename: A
authors.initials: A
authors.lastname: Castel
authors.forename: J
authors.initials: J
authors.lastname: Escudié