title: Aminolysis of aryl ester using tertiary amine as amino donor via C-O and C-N bond activations.
abstract: An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.
authors.affiliation: College of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University , Hohhot 010022, China .
authors.forename: Yong-Sheng
authors.initials: YS
authors.lastname: Bao
authors.forename: Bao
authors.initials: B
authors.lastname: Zhaorigetu
authors.forename: Bao
authors.initials: B
authors.lastname: Agula
authors.forename: Menghe
authors.initials: M
authors.lastname: Baiyin
authors.forename: Meilin
authors.initials: M
authors.lastname: Jia