title: (enH2)(4.5)[In(As(V)S4)3][As2(III)(μ-S2)S3]Cl and (enH2)MnAs(III)As(V)S6: two thioarsenates(III, V) with mixed-valent optical properties.
abstract: Two mixed-valent thioarsenates, namely (enH2)(4.5)[In(As(V)S4)3][As2(III)(μ-S2)S3]Cl (1) and (enH2)MnAs(III)As(V)S6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China. xyhuang@fjirsm.ac.cn.
authors.forename: Ke-Zhao
authors.initials: KZ
authors.lastname: Du
authors.forename: Mei-Ling
authors.initials: ML
authors.lastname: Feng
authors.forename: Xing-Hui
authors.initials: XH
authors.lastname: Qi
authors.forename: Zu-Ju
authors.initials: ZJ
authors.lastname: Ma
authors.forename: Long-Hua
authors.initials: LH
authors.lastname: Li
authors.forename: Jian-Rong
authors.initials: JR
authors.lastname: Li
authors.forename: Cheng-Feng
authors.initials: CF
authors.lastname: Du
authors.forename: Guo-Dong
authors.initials: GD
authors.lastname: Zou
authors.forename: Xiao-Ying
authors.initials: XY
authors.lastname: Huang