title: Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons.
abstract: Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, (119)Sn Mössbauer spectroscopy and quantum chemical analyses.
authors.affiliation: Institut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany. joerg.wagler@chemie.tu-freiberg.de.
authors.forename: Erik
authors.initials: E
authors.lastname: Wächtler
authors.forename: Robert
authors.initials: R
authors.lastname: Gericke
authors.forename: Lyuben
authors.initials: L
authors.lastname: Zhechkov
authors.forename: Thomas
authors.initials: T
authors.lastname: Heine
authors.forename: Thorsten
authors.initials: T
authors.lastname: Langer
authors.forename: Birgit
authors.initials: B
authors.lastname: Gerke
authors.forename: Rainer
authors.initials: R
authors.lastname: Pöttgen
authors.forename: Jörg
authors.initials: J
authors.lastname: Wagler