title: Pressure-induced frustration-frustration process in 1-butyl-3-methylimidazolium hexafluorophosphate, a room-temperature ionic liquid.
abstract: We have found that the room-temperature ionic liquid (RTIL) reveals outstanding pressure-induced phase changes from a liquid state to a crystal polymorph and finally to a glass form upon compression by up to 8 GPa. The RTIL is 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6], which offers the opportunity to investigate a variety of fluctuations in one system and can be completely recovered without dissociation or polymerization, even after decompression. Similar to charge frustration, spin ice-like frustration, and geometric frustration in high potential spintronics/multiferroic materials, the RTIL frustrations are classified into charge (scalar), orientation (vector), and coordination number (topology). Degrees of freedom at each state of [C4mim][PF6] are described by charge balancing, molecular orientational order/disorder, molecular conformations of the C4mim(+) cation, and the coordination number. Here, we show a novel "conformation glass" induced by high pressure.
authors.affiliation: Department of Materials Science and Engineering and ‡Department of Applied Chemistry, National Defense Academy , Yokosuka 239-8686, Japan.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Abe
authors.forename: Takahiro
authors.initials: T
authors.lastname: Takekiyo
authors.forename: Naohiro
authors.initials: N
authors.lastname: Hatano
authors.forename: Machiko
authors.initials: M
authors.lastname: Shigemi
authors.forename: Nozomu
authors.initials: N
authors.lastname: Hamaya
authors.forename: Yukihiro
authors.initials: Y
authors.lastname: Yoshimura