title: Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands.
abstract: The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.
authors.affiliation: Department of Chemistry, University of Pannonia, H-8200 Veszprém, Hungary. kaizer@almos.vein.hu speier@almos.uni-pannon.hu.
authors.forename: József S
authors.initials: JS
authors.lastname: Pap
authors.forename: Apparao
authors.initials: A
authors.lastname: Draksharapu
authors.forename: Michel
authors.initials: M
authors.lastname: Giorgi
authors.forename: Wesley R
authors.initials: WR
authors.lastname: Browne
authors.forename: József
authors.initials: J
authors.lastname: Kaizer
authors.forename: Gábor
authors.initials: G
authors.lastname: Speier
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008024:Ligands; D009584:Nitrogen / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D005296:Ferrous Compounds; D008024:Ligands; D006861:Hydrogen Peroxide; D009584:Nitrogen