title: Chelation-assisted photoelimination of B,N-heterocycles.
abstract: Metal-chelation and internal H bonds have been found to greatly enhance the photoelimination quantum efficiency of B,N-heterocycles by 2 orders of magnitude. Green phosphorescent Pt(II)-functionalized 1,2-azaborines have been achieved via photoelimination. A mechanistic pathway for the PE reaction has been established.
authors.affiliation: Department of Chemistry, Queen's University , Kingston, Ontario K7L 3N6, Canada.
authors.forename: Soo-Byung
authors.initials: SB
authors.lastname: Ko
authors.forename: Jia-Sheng
authors.initials: JS
authors.lastname: Lu
authors.forename: Suning
authors.initials: S
authors.lastname: Wang