title: Electrophilic C-H Borylation and Related Reactions of B-H Boron Cations.
abstract: Catalytic procedures are described for aminedirected borylation of aliphatic and aromatic tertiary amine boranes. Sequential double borylation is observed in cases where two or more C-H bonds are available that allow 5-center or 6-center intramolecular borylation. The HNTf2catalyzed borylation of benzylamine boranes provides a practical means for the synthesis of ortho-substituted arylboronic acid derivatives, suitable for Suzuki-Miyaura cross-coupling applications.
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Aleksandrs
authors.initials: A
authors.lastname: Prokofjevs
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Janis
authors.initials: J
authors.lastname: Jermaks
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Alina
authors.initials: A
authors.lastname: Borovika
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Jeff W
authors.initials: JW
authors.lastname: Kampf
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Edwin
authors.initials: E
authors.lastname: Vedejs