title: Remarkable scan rate dependence for a highly constrained dinuclear iron(II) spin crossover complex with a wide thermal hysteresis loop.
abstract: The abrupt [HS-HS] ↔ localized [HS-LS] spin crossovers of a new triazole-based diiron(II) complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (ΔT = 22 K by SQUID magnetometer in "settle" mode) and show a remarkable scan rate dependence of only the cooling branch, as revealed by detailed magnetic, DSC, and Mössbauer studies.
authors.affiliation: Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago , P.O. Box 56, Dunedin 9054, New Zealand.
authors.forename: Rafal
authors.initials: R
authors.lastname: Kulmaczewski
authors.forename: Juan
authors.initials: J
authors.lastname: Olguín
authors.forename: Jonathan A
authors.initials: JA
authors.lastname: Kitchen
authors.forename: Humphrey L C
authors.initials: HL
authors.lastname: Feltham
authors.forename: Guy N L
authors.initials: GN
authors.lastname: Jameson
authors.forename: Jeffery L
authors.initials: JL
authors.lastname: Tallon
authors.forename: Sally
authors.initials: S
authors.lastname: Brooker