title: [Determination of hydrazine ion in explosion dust of liquid explosive by ion chromatography].
abstract: A method for the determination of hydrazine ion in explosion dust of liquid explosive has been established by ion chromatography. The hydrazine ion in an explosion dust sample was extracted with deionized water by sonification and centrifugation. The large molecules and solid particles in supernatant were removed by an OnGuard II RP column and a 0.22 microm filtration membrane, respectively. The filtrate was separated on an IonPac CS-12A column with isocratic elution of 5 mmol/L methanesulfonic acid (MSA). Then 0.1 mol/L NaOH solution was post-column added and the resultant solution was detected by an ampere detector with golden electrode. The results showed that, the calibration curve was linear in the range of 0.02 - 2.0 mg/L with a correlation coefficient (r2 ) of 0.999 7. The limits of detection (LOD, S/N = 3) and quantification (LOQ, S/N = 10) of hydrazine were 5.0 microg/L and 16.6 microg/L, respectively. The recoveries ranged between 95.4% and 99.1% with the relative standard deviations (RSDs, n = 5) of 2.1% - 3.3%. The hydrazine content in a real explosion dust sample of liquid explosive was 10.3 mg/kg by this method. The method is simple, accurate, and suitable for the quantitative detection of hydrazine ions in explosion dust of liquid explosive, and the method can meet the needs of the criminal evidence identification work.
authors.affiliation: Nanjing Public Security Bureau, Nanjing 210001, China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Wang
authors.affiliation: Nanjing Public Security Bureau, Nanjing 210001, China.
authors.forename: Qing
authors.initials: Q
authors.lastname: Geng
authors.affiliation: Nanjing Public Security Bureau, Nanjing 210001, China.
authors.forename: Yuexian
authors.initials: Y
authors.lastname: Zuo
authors.affiliation: Nanjing Public Security Bureau, Nanjing 210001, China.
authors.forename: Xinwen
authors.initials: X
authors.lastname: Zhou
authors.affiliation: State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry & Chemical Engineering and Modern Analysis Center, Nanjing University, Nanjing 210093, China.
authors.forename: Hongzhen
authors.initials: H
authors.lastname: Lian
authors.affiliation: ThermoFisher Scientific (China) Limited, Shanghai 201203, China.
authors.forename: Guangwen
authors.initials: G
authors.lastname: Pan