title: Synthesis and characterization of Sr3Al2O6 nanocomposite as catalyst for biodiesel production.
abstract: Sr-Al mixed oxides nanocomposite as Sr3Al2O6 was prepared by sol-gel method and used as a basic heterogeneous catalyst for transesterification of soybean oil to methyl esters (biodiesel) by methanol. The prepared catalyst was characterized using X-ray diffraction (XRD), Transmission electron microscope (TEM), thermogravimetric analysis (TGA/DTA), temperature-programmed desorption (TPD) and nitrogen adsorption-desorption techniques. The response surface methodology (RSM) based on the Box-Behnken design was employed to investigate the effects of methanol to oil molar ratio, reaction time, catalyst amount and specifically the effect of interaction between process variables on the conversion of oil to biodiesel. Results from this study revealed that individual as well as bilateral variables interactions significantly affect the yield of biodiesel. With this information, it was found that utilization of methanol to oil molar ratio of 25 and 1.3 wt.% of catalyst within reaction time of 61 min and gave the biodiesel yield of 95.7 ± 0.5%.
authors.affiliation: Department of Chemistry, Alzahra University, P.O. Box 1993891176, Vanak, Tehran, Iran.
authors.forename: Elnaz
authors.initials: E
authors.lastname: Rashtizadeh
authors.affiliation: Department of Chemistry, Alzahra University, P.O. Box 1993891176, Vanak, Tehran, Iran. Electronic address: faezeh_farzaneh@yahoo.com.
authors.forename: Faezeh
authors.initials: F
authors.lastname: Farzaneh
authors.affiliation: Department of Chemistry, Alzahra University, P.O. Box 1993891176, Vanak, Tehran, Iran.
authors.forename: Zahra
authors.initials: Z
authors.lastname: Talebpour
mesh_terms: D000327:Adsorption; D017607:Aluminum Compounds / Q000737:chemistry*; D000704:Analysis of Variance; D056804:Biofuels; D001709:Biotechnology / Q000379:methods*; D002245:Carbon Dioxide / Q000737:chemistry; D002384:Catalysis; D004951:Esterification; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D010087:Oxides / Q000737:chemistry*; D059027:Recycling; D013324:Strontium / Q000737:chemistry*; D013696:Temperature; D013818:Thermogravimetry; D014961:X-Ray Diffraction
chemical_list: D017607:Aluminum Compounds; D056804:Biofuels; D010087:Oxides; D002245:Carbon Dioxide; D013324:Strontium
keywords: Biodiesel; Nanocomposite; Response surface methodology; Solid catalyst; Transesterification