title: Electron-beam-assisted oxygen purification at low temperatures for electron-beam-induced pt deposits: towards pure and high-fidelity nanostructures.
abstract: Nanoscale metal deposits written directly by electron-beam-induced deposition, or EBID, are typically contaminated because of the incomplete removal of the original organometallic precursor. This has greatly limited the applicability of EBID materials synthesis, constraining the otherwise powerful direct-write synthesis paradigm. We demonstrate a low-temperature purification method in which platinum-carbon nanostructures deposited from MeCpPtIVMe3 are purified by the presence of oxygen gas during a post-electron exposure treatment. Deposit thickness, oxygen pressure, and oxygen temperature studies suggest that the dominant mechanism is the electron-stimulated reaction of oxygen molecules adsorbed at the defective deposit surface. Notably, pure platinum deposits with low resistivity and retain the original deposit fidelity were accomplished at an oxygen temperature of only 50 °C.
authors.affiliation: Institute for Electron Microscopy and Nanoanalsis, Graz University of Technology , Steyrergasse 17, 8010 Graz, Austria.
authors.forename: Harald
authors.initials: H
authors.lastname: Plank
authors.forename: Joo Hyon
authors.initials: JH
authors.lastname: Noh
authors.forename: Jason D
authors.initials: JD
authors.lastname: Fowlkes
authors.forename: Kevin
authors.initials: K
authors.lastname: Lester
authors.forename: Brett B
authors.initials: BB
authors.lastname: Lewis
authors.forename: Philip D
authors.initials: PD
authors.lastname: Rack
mesh_terms: D002244:Carbon / Q000737:chemistry; D004583:Electrons; D008670:Metals / Q000737:chemistry; D049329:Nanostructures / Q000737:chemistry*; D036103:Nanotechnology; D010100:Oxygen / Q000737:chemistry* / Q000302:isolation & purification; D010984:Platinum / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature
chemical_list: D008670:Metals; D010984:Platinum; D002244:Carbon; D010100:Oxygen