title: An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion.
abstract: Reaction of a nonheme iron(III)-peroxo complex, [Fe(III)(14-TMC)(O2)](+), with NO(+), a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2˙(-)) + NO], affords an iron(IV)-oxo complex, [Fe(IV)(14-TMC)(O)](2+), and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [Fe(III)(14-TMC)(NO3)(F)](+).
authors.affiliation: Department of Chemistry and Nano Science, Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea. wwnam@ewha.ac.kr.
authors.forename: Atsutoshi
authors.initials: A
authors.lastname: Yokoyama
authors.forename: Jung Eun
authors.initials: JE
authors.lastname: Han
authors.forename: Kenneth D
authors.initials: KD
authors.lastname: Karlin
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
mesh_terms: D032701:Biomimetics; D056831:Coordination Complexes / Q000737:chemistry*; D004583:Electrons; D007501:Iron / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D009585:Nitrogen Dioxide / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D010105:Oxygenases / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; C504137:nitrosonium ion; D009569:Nitric Oxide; D007501:Iron; D010105:Oxygenases; C114415:nitric oxide dioxygenase; D009585:Nitrogen Dioxide; D010100:Oxygen