title: Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols.
abstract: Highly nucleophilic (Z)- or (E)-α-fluoroalkenylchromium species could be generated in a stereoselective manner via C-F bond activation of CBrF2-containing molecules, and they reacted smoothly with various aldehydes to give (E)- or (Z)-β-fluoroallylic alcohol derivatives in high yields, respectively.
authors.affiliation: Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan. konno@kit.ac.jp.
authors.forename: Takashi
authors.initials: T
authors.lastname: Nihei
authors.forename: Saya
authors.initials: S
authors.lastname: Yokotani
authors.forename: Takashi
authors.initials: T
authors.lastname: Ishihara
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Konno