title: Engineering switchable rotors in molecular crystals with open porosity.
abstract: The first example of a porous molecular crystal containing rotors is presented. The permanently porous crystal architecture is sustained by rotor-bearing molecular rods which are connected through charge-assisted hydrogen bonds. The rotors, as fast as 10(8) Hz at 240 K, are exposed to the crystalline channels, which absorb CO2 and I2 vapors at low pressure. The rotor dynamics could be switched off and on by I2 absorption/desorption, showing remarkable change of material dynamics by the interaction with gaseous species and suggesting the use of molecular crystals in sensing and pollutant management.
authors.affiliation: Department of Materials Science, University of Milano Bicocca , Via R. Cozzi 55, 20125 Milano, Italy.
authors.forename: Angiolina
authors.initials: A
authors.lastname: Comotti
authors.forename: Silvia
authors.initials: S
authors.lastname: Bracco
authors.forename: Atsushi
authors.initials: A
authors.lastname: Yamamoto
authors.forename: Mario
authors.initials: M
authors.lastname: Beretta
authors.forename: Tomofumi
authors.initials: T
authors.lastname: Hirukawa
authors.forename: Norimitsu
authors.initials: N
authors.lastname: Tohnai
authors.forename: Mikiji
authors.initials: M
authors.lastname: Miyata
authors.forename: Piero
authors.initials: P
authors.lastname: Sozzani