title: Transition metal complexes and radical anion salts of 1,10-phenanthroline derivatives annulated with a 1,2,5-tiadiazole and 1,2,5-tiadiazole 1,1-dioxide moiety: multidimensional crystal structures and various magnetic properties.
abstract: Advances in the molecular variety and the elucidation of the physical properties of 1,10-phenanthroline annulated with 1,2,5-thiadiazole and 1,2,5-thiadiazole 1,1-dioxide moieties have been achieved, and are described herein. A 1,2,5-thiadiazole compound, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline (tdap), was used as a ligand to create multidimensional network structures based on S•••S and S•••N intermolecular interactions. A 1,2,5-thiadiazole 1,1-dioxide compound, [1,2,5] thiadiazolo[3,4-f][1,10]phenanthroline, 1,1-dioxide (tdapO2), was designed to create a stable radical anion, as well as good network structures. Single crystal X-ray structure analyses revealed that transition metal complexes of tdap, and radical anion salts of tdapO2 formed multidimensional network structures, as expected. Two kinds of tdap iron complexes, namely [Fe(tdap)2(NCS)2] and [Fe(tdap)2(NCS)2]•MeCN exhibited spin crossover transitions, and their transition temperatures showed a difference of 150 K, despite their similar molecular structures. Magnetic measurements for the tdapO2 radical anion salts revealed that the magnetic coupling constants between neighboring radical species vary from strongly antiferromagnetic (J=-320 K) to ferromagnetic (J=24 K), reflecting the differences in their π overlap motifs.
authors.affiliation: Department of Chemistry & Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan. shiyuku.yoshiaki@d.mbox.nagoya-u.ac.jp.
authors.forename: Yoshiaki
authors.initials: Y
authors.lastname: Shuku
authors.affiliation: Department of Chemistry & Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan. awaga@mbox.chem.nagoya-u.ac.jp.
authors.forename: Kunio
authors.initials: K
authors.lastname: Awaga
mesh_terms: D001393:Azoles / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry; D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals / Q000737:chemistry; D060328:Magnetic Phenomena; D008958:Models, Molecular; D008968:Molecular Conformation; D010618:Phenanthrolines / Q000737:chemistry*; D012996:Solutions; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D001393:Azoles; D056831:Coordination Complexes; D005609:Free Radicals; D010618:Phenanthrolines; D012996:Solutions; D028561:Transition Elements; C025205:1,10-phenanthroline