title: A highly porous NbO type metal-organic framework constructed from an expanded tetracarboxylate.
abstract: A novel NbO type microporous metal–organic framework Cu2L (ZJU-32; H4L = 5'-((3,5-dicarboxyphenyl)ethynyl)-[1,1':3',1"-terphenyl]-4,4"-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a exhibits high permanent porosity with the Brunauer–Emmett–Teller (BET) surface area of 3831 m(2) g(-1) and the pore volume of 1.482 cm(3) g(-1), enabling it to be a promising material for both methane storage and carbon dioxide capture at room temperature.
authors.affiliation: State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China. gdqian@zju.edu.cn.
authors.forename: Jianfeng
authors.initials: J
authors.lastname: Cai
authors.forename: Xingtang
authors.initials: X
authors.lastname: Rao
authors.forename: Yabing
authors.initials: Y
authors.lastname: He
authors.forename: Jancan
authors.initials: J
authors.lastname: Yu
authors.forename: Chuande
authors.initials: C
authors.lastname: Wu
authors.forename: Wei
authors.initials: W
authors.lastname: Zhou
authors.forename: Taner
authors.initials: T
authors.lastname: Yildirim
authors.forename: Banglin
authors.initials: B
authors.lastname: Chen
authors.forename: Guodong
authors.initials: G
authors.lastname: Qian
mesh_terms: D002245:Carbon Dioxide / Q000302:isolation & purification; D002264:Carboxylic Acids / Q000737:chemistry*; D008958:Models, Molecular; D009556:Niobium / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D016062:Porosity
chemical_list: D002264:Carboxylic Acids; D009942:Organometallic Compounds; D010087:Oxides; D009556:Niobium; D002245:Carbon Dioxide