title: Response surface analysis of photocatalytic degradation of methyl tert-butyl ether by core/shell Fe3O4/ZnO nanoparticles.
abstract: The degradation of methyl tert-butyl ether (MTBE) was investigated in the aqueous solution of coated ZnO onto magnetite nanoparticale based on an advanced photocatalytic oxidation process. The photocatalysts were synthesized by coating of ZnO onto magnetite using precipitation method. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and vibration sample magnetometer (VSM). Besides, specific surface area was also determined by BET method. The four effective factors including pH of the reaction mixture, Fe3O4/ZnO magnetic nanoparticles concentration, initial MTBE concentration and molar ratio of [H2O2]/ [MTBE] were optimized using response surface modeling (RSM). Using the four-factor-three-level Box-Behnken design, 29 runs were designed considering the effective ranges of the influential factors. The optimized values for the operational parameters under the respective constraints were obtained at PH of 7.2, Fe3O4/ZnO concentration of 1.78 g/L, initial MTBE concentration of 89.14 mg/L and [H2O2]/ [MTBE] molar ratio of 2.33. Moreover, kinetics of MTBE degradation was determined under optimum condition. The study about core/shell magnetic nanoparticles (MNPs) recycling were also carried out and after about four times, the percentage of the photocatalytic degradation was about 70%.
authors.forename: Mojtaba
authors.initials: M
authors.lastname: Safari
authors.affiliation: Department Of Chemical Engineering, Amirkabir University Of Technology, Tehran, Iran. mhossein.rostami@gmail.com.
authors.forename: Mohammad Hossein
authors.initials: MH
authors.lastname: Rostami
authors.forename: Mehriana
authors.initials: M
authors.lastname: Alizadeh
authors.forename: Atefeh
authors.initials: A
authors.lastname: Alizadehbirjandi
authors.forename: Seyyed Ali Akbar
authors.initials: SA
authors.lastname: Nakhli
authors.forename: Reza
authors.initials: R
authors.lastname: Aminzadeh