title: Investigation of the sample preparation and curing treatment effects on mechanical properties and bioactivity of silica rich metakaolin geopolymer.
abstract: In many biomedical applications both the biological and mechanical behaviours of implants are of relevant interest; in the orthopaedic field, for example, favourable bioactivity and biocompatibility capabilities are necessary, but at the same time the mechanical characteristics of the implants must be such as to allow one to support the body weight. In the present work, the authors have examined the application of geopolymers with composition H24AlK7Si31O79 and ratio Si/Al=31 to be used in biomedical field, considering two different preparation methods: one of the activators (KOH) has been added as pellets in the potassium silicate solution, in the other as a water solution with 8M concentration. Moreover, a different water content was used and only some of the synthesized samples were heat treated. The chemical and microstructural characterizations of those materials have been carried out by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). Subsequently, the effects of the adopted preparation on the mechanical and biological properties have been studied: compressive strength tests have demonstrated that more fragile specimens were obtained when KOH was added as a solution. The bioactivity was successfully evaluated with the soaking of the samples in a simulated body fluid (SBF) for 3 weeks. The formation of a layer of hydroxyapatite on the surface of the materials has been shown both by SEM micrographs and EDS analyses.
authors.affiliation: Department of Industrial and Information Engineering, Second University of Naples, Via Roma 29, 81031 Aversa, Italy. Electronic address: michelina.catauro@unina2.it.
authors.forename: M
authors.initials: M
authors.lastname: Catauro
authors.affiliation: Department of Industrial and Information Engineering, Second University of Naples, Via Roma 29, 81031 Aversa, Italy.
authors.forename: F
authors.initials: F
authors.lastname: Bollino
authors.affiliation: Department of Industrial and Information Engineering, Second University of Naples, Via Roma 29, 81031 Aversa, Italy.
authors.forename: F
authors.initials: F
authors.lastname: Papale
authors.affiliation: Department of Industrial and Information Engineering, Second University of Naples, Via Roma 29, 81031 Aversa, Italy.
authors.forename: G
authors.initials: G
authors.lastname: Lamanna
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry*; D019245:Compressive Strength; D007616:Kaolin / Q000737:chemistry*; D008422:Materials Testing / Q000379:methods*; D055595:Mechanical Phenomena; D008855:Microscopy, Electron, Scanning; D011108:Polymers / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D001672:Biocompatible Materials; D011108:Polymers; D007616:Kaolin; D012822:Silicon Dioxide
keywords: Bioactivity; Compressive strength; Geopolymers; Molar ratio Si/Al=31