title: Characterization and performance of carbonaceous materials obtained from exhausted sludges for the anaerobic biodecolorization of the azo dye Acid Orange II.
abstract: This work presents the preliminary study of new carbonaceous materials (CMs) obtained from exhausted sludge, their use in the heterogeneous anaerobic process of biodecolorization of azo dyes and the comparison of their performance with one commercial active carbon. The preparation of carbonaceous materials was conducted through chemical activation and carbonization. Chemical activation was carried out through impregnation of sludge-exhausted materials with ZnCl2 and the activation by means of carbonization at different temperatures (400, 600 and 800°C). Their physicochemical and surface characteristics were also investigated. Sludge based carbonaceous (SBC) materials SBC400, SBC600 and SBC800 present values of 13.0, 111.3 and 202.0m(2)/g of surface area. Biodecolorization levels of 76% were achieved for SBC600 and 86% for SBC800 at space time (τ) of 1.0min, similar to that obtained with commercial activated carbons in the continuous anaerobic up-flow packed bed reactor (UPBR). The experimental data fit well to the first order kinetic model and equilibrium data are well represented by the Langmuir isotherm model. Carbonaceous materials show high level of biodecolorization even at very short space times. Results indicate that carbonaceous materials prepared from sludge-exhausted materials have outstanding textural properties and significant degradation capacity for treating textile effluents.
authors.affiliation: Departament d'Enginyeria Quimica, ETSEQ, Universitat Rovira i Virgili, Av. Paisos Catalans 26, 43007 Tarragona, Catalunya, Spain.
authors.forename: S
authors.initials: S
authors.lastname: Athalathil
authors.affiliation: Departament d'Enginyeria Quimica, ETSEQ, Universitat Rovira i Virgili, Av. Paisos Catalans 26, 43007 Tarragona, Catalunya, Spain.
authors.forename: F
authors.initials: F
authors.lastname: Stüber
authors.affiliation: Departament d'Enginyeria Quimica, ETSEQ, Universitat Rovira i Virgili, Av. Paisos Catalans 26, 43007 Tarragona, Catalunya, Spain.
authors.forename: C
authors.initials: C
authors.lastname: Bengoa
authors.affiliation: Departament d'Enginyeria Quimica, ETSEQ, Universitat Rovira i Virgili, Av. Paisos Catalans 26, 43007 Tarragona, Catalunya, Spain.
authors.forename: J
authors.initials: J
authors.lastname: Font
authors.affiliation: Departament d'Enginyeria Quimica, EPSEVG, Universitat Politecnica de Catalunya, Av. Victor Balaguer s/n, 08800 Vilanova i la Geltru, Catalunya, Spain.
authors.forename: A
authors.initials: A
authors.lastname: Fortuny
authors.affiliation: Departament d'Enginyeria Quimica, ETSEQ, Universitat Rovira i Virgili, Av. Paisos Catalans 26, 43007 Tarragona, Catalunya, Spain. Electronic address: azael.fabregat@urv.cat.
authors.forename: A
authors.initials: A
authors.lastname: Fabregat
mesh_terms: D000327:Adsorption; D000465:Algorithms; D000693:Anaerobiosis; D001391:Azo Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D003116:Color; D007700:Kinetics; D009281:Naphthalenes / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D012722:Sewage / Q000032:analysis*; D017550:Spectroscopy, Fourier Transform Infrared; D013816:Thermodynamics; D013818:Thermogravimetry; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: C456587:Acid Orange II; D001391:Azo Compounds; D009281:Naphthalenes; D012722:Sewage; D014874:Water Pollutants, Chemical; D002244:Carbon; D009584:Nitrogen
keywords: Azo dye; Biodecolorization; Biological carbonaceous material; Sewage exhausted materials