title: Copper-catalyzed allylation of α,α-difluoro-substituted organozinc reagents.
abstract: A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon-zinc bond followed by copper-catalyzed allylic substitution.
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry , Leninsky prosp. 47, 119991 Moscow, Russian Federation.
authors.forename: Artem A
authors.initials: AA
authors.lastname: Zemtsov
authors.forename: Nikolay S
authors.initials: NS
authors.lastname: Kondratyev
authors.forename: Vitalij V
authors.initials: VV
authors.lastname: Levin
authors.forename: Marina I
authors.initials: MI
authors.lastname: Struchkova
authors.forename: Alexander D
authors.initials: AD
authors.lastname: Dilman
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D003300:Copper; D015032:Zinc