title: Artificial weathering as a function of CO2 injection in Pahang Sandstone Malaysia: investigation of dissolution rate in surficial condition.
abstract: Formation of carbonate minerals by CO2 sequestration is a potential means to reduce atmospheric CO2 emissions. Vast amount of alkaline and alkali earth metals exist in silicate minerals that may be carbonated. Laboratory experiments carried out to study the dissolution rate in Pahang Sandstone, Malaysia, by CO2 injection at different flow rate in surficial condition. X-ray Powder Diffraction (XRD), Scanning Electron Microscope (SEM) with Energy Dispersive X-ray Spectroscopy (EDX), Atomic Absorption Spectroscopy (AAS) and weight losses measurement were performed to analyze the solid and liquid phase before and after the reaction process. The weight changes and mineral dissolution caused by CO2 injection for two hours CO2 bubbling and one week' aging were 0.28% and 18.74%, respectively. The average variation of concentrations of alkaline earth metals in solution varied from 22.62% for Ca(2+) to 17.42% for Mg(2+), with in between 16.18% observed for the alkali earth metal, potassium. Analysis of variance (ANOVA) test is performed to determine significant differences of the element concentration, including Ca, Mg, and K, before and after the reaction experiment. Such changes show that the deposition of alkali and alkaline earth metals and the dissolution of required elements in sandstone samples are enhanced by CO2 injection.
authors.affiliation: National Iranian Oil Company, EOR-IOR Institute, 81310 Johor Bahru, Johor.
authors.forename: Madjid
authors.initials: M
authors.lastname: Jalilavi
authors.affiliation: Universiti Teknologi Malaysia, Faculty of Petroleum & Renewable Energy Engineering, 81310 Johor Bahru, Johor.
authors.forename: Mansoor
authors.initials: M
authors.lastname: Zoveidavianpoor
authors.affiliation: Universiti Teknologi Malaysia, Faculty of Petroleum & Renewable Energy Engineering, 81310 Johor Bahru, Johor.
authors.forename: Farshid
authors.initials: F
authors.lastname: Attarhamed
authors.affiliation: Universiti Teknologi Malaysia, Faculty of Petroleum & Renewable Energy Engineering, 81310 Johor Bahru, Johor.
authors.forename: Radzuan
authors.initials: R
authors.lastname: Junin
authors.affiliation: Universiti Teknologi Malaysia, Faculty of Petroleum & Renewable Energy Engineering, 81310 Johor Bahru, Johor.
authors.forename: Rahmat
authors.initials: R
authors.lastname: Mohsin