title: tert-Butyl N-(thio-phen-2-yl)carbamate.
abstract: In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra-molecular C-H⋯O inter-actions in tandem with the tert-butyl groups render the packing of adjacent mol-ecules in the [001] direction nearly perpendicular [the angle between adjacent thio-phene rings is 74.83 (7)°]. An inter-molecular N-H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.
authors.affiliation: Department of Chemistry & Biochemistry, Texas Tech University, Memorial Circle & Boston, Lubbock, TX 79409, USA.
authors.forename: Gene C
authors.initials: GC
authors.lastname: Hsu
authors.affiliation: Department of Chemistry & Biochemistry, Texas Tech University, Memorial Circle & Boston, Lubbock, TX 79409, USA.
authors.forename: Laci M
authors.initials: LM
authors.lastname: Singer
authors.affiliation: Department of Chemistry & Biochemistry, Texas Tech University, Memorial Circle & Boston, Lubbock, TX 79409, USA.
authors.forename: David B
authors.initials: DB
authors.lastname: Cordes
authors.affiliation: Department of Chemistry & Biochemistry, Texas Tech University, Memorial Circle & Boston, Lubbock, TX 79409, USA.
authors.forename: Michael
authors.initials: M
authors.lastname: Findlater