title: Reversible light-driven polymerization of polyoxometalate tethered with coumarin molecules.
abstract: A new photosensitive polyoxometalate (POM) organic-inorganic hybrid compound has been prepared by covalently tethering coumarin moieties onto a Mn-Anderson cluster. This compound has been fully characterized by (1)H NMR, (13)C NMR, FTIR, and UV/Vis spectroscopy, and ESI-MS. This organic-inorganic hybrid compound can undergo reversible light-driven polymerization and this process has been characterized in detail.
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Institution Beijing University of Chemical Technology, 100029 Beijing (P.R. China).
authors.forename: UnSong
authors.initials: U
authors.lastname: Tong
authors.forename: Wei
authors.initials: W
authors.lastname: Chen
authors.forename: Chris
authors.initials: C
authors.lastname: Ritchie
authors.forename: Xiaoting
authors.initials: X
authors.lastname: Wang
authors.forename: Yu-Fei
authors.initials: YF
authors.lastname: Song
keywords: coumarins; covalent functionalization; photopolymerization; polyoxometalates