title: Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions.
abstract: Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes.
authors.affiliation: Department of Organic Chemistry, University of Granada, Fuentenueva Campus, Granada 18071, Spain. jmcuerva@ugr.es.
authors.forename: Sara P
authors.initials: SP
authors.lastname: Morcillo
authors.forename: Ángela
authors.initials: Á
authors.lastname: Martínez-Peragón
authors.forename: Verena
authors.initials: V
authors.lastname: Jakoby
authors.forename: Antonio J
authors.initials: AJ
authors.lastname: Mota
authors.forename: Christian
authors.initials: C
authors.lastname: Kube
authors.forename: José
authors.initials: J
authors.lastname: Justicia
authors.forename: Juan M
authors.initials: JM
authors.lastname: Cuerva
authors.forename: Andreas
authors.initials: A
authors.lastname: Gansäuer