title: Ultrasonic assisted-Fenton-like degradation of nitrobenzene at neutral pH using nanosized oxides of Fe and Cu.
abstract: Ultrasonic-assisted heterogeneous Fenton reaction was used for degradation of nitrobenzene (NB) at neutral pH conditions. Nano-sized oxides of α-Fe2O3 and CuO were prepared, characterized and tested in degradation of NB (10 mg L(-1)) under sonication of 20 kHz at 25 °C. Complete degradation of NB was effected at pH 7 in presence of 10 mM H2O2 after 10 min of sonication in presence of α-Fe2O3 (1.0 g L(-1)), (k=0.58 min(-1)) and after 25 min in case of CuO (k=0.126 min(-1)). α-Fe2O3 showed also effective degradation under the conditions of 0.1 g L(-1) oxide and 5.0 mM of H2O2, even though with a lower rate constant (0.346 min(-1)). Sonication plays a major role in enhancing the production of hydroxyl radicals in presence of solid oxides. Hydroxyl radicals-degradation pathway is suggested and adopted to explain the differences noted in rate constants recorded on using different oxides.
authors.affiliation: Taibah University, Faculty of Science, Chemistry Department, AlMadina Almounawara, Saudi Arabia. Electronic address: elshafei_gamal57@yahoo.com.
authors.forename: Gamal M S
authors.initials: GM
authors.lastname: ElShafei
authors.affiliation: Department of Petrochemicals, Egyptian Petroleum Research Institute, Nasr City, Cairo, Egypt.
authors.forename: F Z
authors.initials: FZ
authors.lastname: Yehia
authors.affiliation: Department of Petrochemicals, Egyptian Petroleum Research Institute, Nasr City, Cairo, Egypt.
authors.forename: O I H
authors.initials: OI
authors.lastname: Dimitry
authors.affiliation: Department of Petrochemicals, Egyptian Petroleum Research Institute, Nasr City, Cairo, Egypt.
authors.forename: A M
authors.initials: AM
authors.lastname: Badawi
authors.affiliation: Department of Petrochemicals, Egyptian Petroleum Research Institute, Nasr City, Cairo, Egypt.
authors.forename: Gh
authors.initials: G
authors.lastname: Eshaq
keywords: Heterogeneous Fenton; Nano oxides; Nitrobenzene; Ultrasonic; α-Fe(2)O(3)