title: Nitronyl nitroxide-metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p-3d-4f) chains.
abstract: A novel approach for the preparation of hetero-tri-spin magnetic compounds is described. It consists in using preformed metal-nitronyl nitroxide complexes as metallo-ligands in an assembling process involving an additional metal centre. This is illustrated by two unprecedented radical-Cu-Ln chain compounds (Ln = Gd(3+), Tb(3+)).
authors.affiliation: Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry and Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China. llicun@nankai.edu.cn.
authors.forename: Mei
authors.initials: M
authors.lastname: Zhu
authors.forename: Xuelan
authors.initials: X
authors.lastname: Mei
authors.forename: Yue
authors.initials: Y
authors.lastname: Ma
authors.forename: Licun
authors.initials: L
authors.lastname: Li
authors.forename: Daizheng
authors.initials: D
authors.lastname: Liao
authors.forename: Jean-Pascal
authors.initials: JP
authors.lastname: Sutter