A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials.
The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex.
Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham, B4 7ET, UK. a.j.sutherland@aston.ac.uk.
O A
OA
Efremova
M A
MA
Shestopalov
N A
NA
Chirtsova
A I
AI
Smolentsev
Y V
YV
Mironov
N
N
Kitamura
K A
KA
Brylev
A J
AJ
Sutherland