A direct, versatile route to functionalized trialkoxysilanes.
The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.
Laboratoire de Synthèse Organique, CNRS UMR 7652, Ecole Polytechnique, F-91128 Palaiseau, France. zard@poly.polytechnique.fr.
Béatrice
B
Quiclet-Sire
Yuuki
Y
Yanagisawa
Samir Z
SZ
Zard