Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.
Complexes [M(n)MST(NH3)](n-3) (M(n) = Fe(II), Fe(III), Ga(III)) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe(III)-NH3 complex afforded a putative [Fe(III)MST(NH2)](-) species whose reactivity has been explored.
Department of Chemistry, University of California-Irvine, 1102 Natural Sciences II, Irvine, CA 92697, USA. aborovik@uci.edu.
Nathaniel S
NS
Sickerman
Sonja M
SM
Peterson
Joseph W
JW
Ziller
A S
AS
Borovik
D000641:Ammonia / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D005708:Gallium / Q000737:chemistry; D006860:Hydrogen Bonding; D008024:Ligands
D005290:Ferric Compounds; D005296:Ferrous Compounds; D008024:Ligands; D000641:Ammonia; D005708:Gallium