Palladium-catalyzed oxidative olefination of phenols bearing removable directing groups under molecular oxygen.
An efficient Pd(II)-catalyzed oxidative olefination of phenols bearing removable directing groups with molecular oxygen as the sole oxidant has been developed. This reaction protocol provides an efficient and robust synthetic tool for the synthesis of o-alkenyl phenols under mild conditions.
Department of Chemistry, Zhejiang University , Hangzhou 310027, China.
Bin
B
Liu
Huai-Zhi
HZ
Jiang
Bing-Feng
BF
Shi
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*
D000475:Alkenes; D010636:Phenols; D010165:Palladium; D010100:Oxygen