(μ3-Hydrido)[μ3-2-(tri-methyl-sil-yl)ethyl-idyne-κ(3) C (1):C (1):C (1)]tetra-kis-[(η(5)-cyclo-penta-dien-yl)cobalt(II)].
In the title compound, [Co4(C5H5)4(μ3-CCH2SiMe3)(μ3-H)], the Co atoms form a distorted tetra-hedron with the ethyl-idyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co-Co bond lengths in the Co4 tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η(5)-bonded to a cyclopentadienyl (Cp) anion.
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
Martin
M
Haehnel
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
Anke
A
Spannenberg
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
Uwe
U
Rosenthal