Rubidium penta-aqua-(l-serine)cobalt(II) hexa-hydrogenhexa-molybdocobaltate(III) l-serine monosolvate deca-hydrate.
The Co(2+) ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol-ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the [H6Co(III)Mo6O24](3-) polyanions are stacked along the b-axis direction, mediated by bridging Rb-O bonds. N-H⋯O and O-H⋯O hydrogen bonds are observed involving the l-serine mol-ecules.
Department of Chemical Engineering, School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan.
Jun
J
Iijima
Chemical Resouces Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, Yokohama-city, Kanagawa, Japan.
Haruo
H
Naruke
Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan.
Hiroshi
H
Takiyama