Quantitative photoswitching in bis(dithiazole)ethene enables modulation of light for encoding optical signals.
Using one ray of light to encode another ray of light is highly desirable because information in optical format can be directly transferred from one beam to another without converting back to the electronic format. One key medium to accomplish such an amazing task is photoswitchable molecules. Using bis(dithiazole)ethene that can be photoswitched between its ring-open and ring-closed states quantitatively with excellent fatigue resistance and high thermal stability, it is shown that quantitative photoreversibility allowed the photoswitching light to control other light travelling through the photoswitchable medium, a phenomenon of transferring information encoded in one light ray to others, thus imparting photo-optical modulation on the orthogonal light beam.
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Meilong Road 130, Shanghai, 200237 (China); Department of Chemistry, Washington State University, Pullman, WA (USA) http://chem.wsu.edu/lia/
Yue
Y
Wu
Yongshu
Y
Xie
Qiong
Q
Zhang
He
H
Tian
Weihong
W
Zhu
Alexander D Q
AD
Li
D018360:Crystallography, X-Ray; D003500:Cyclization; D005030:Ethylenes / Q000737:chemistry*; D008027:Light; D008968:Molecular Conformation; D013696:Temperature; D013844:Thiazoles / Q000737:chemistry*
D005030:Ethylenes; D013844:Thiazoles; C036216:ethylene
bis(dithiazole)ethene; communication; light modulation; photochemistry; photochromism