1-Nitro-4-(4-nitro-phen-oxy)benzene: a second monoclinic polymorph.
In the title compound, C12H8N2O5, the aromatic rings are inclined to one another by 56.14 (7)°. The nitro groups are inclined by to the benzene rings to which they are attached by 3.86 (17) and 9.65 (15)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming a three-dimensional structure. The title compound is a new monoclinic polymorph, crystallizing in space group P21/c. The first polymorph crystallized in space group C2/c and the mol-ecule possesses twofold rotation symmetry. Two low-temperature structures of this polymorph (150 K and 100 K, respectively) have been reported [Meciarova et al. (2004). Private Communication (refcode IXOGAD). CCDC, Cambridge, England, and Dey & Desiraju (2005). Chem. Commun. pp. 2486-2488].
Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan.
Mehwish
M
Naz
Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan.
Zareen
Z
Akhter
Chemistry Department, Loughborough University, Loughborough, LE11 3TU, England.
Vickie
V
McKee
Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan.
Arif
A
Nadeem