Copper-catalyzed coupling reaction of arylhydrazines and trialkylphosphites.
A novel CuO-catalyzed coupling reaction of arylhydrazines with trialkyl phosphites to afford arylphosphonates is described. The reaction proceeded at 80 °C in air without external reductants, oxidants, and ligands.
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Material Science, Soochow University , Suzhou 215123, People's Republic of China.
Sheng-Yan
SY
Chen
Run-Sheng
RS
Zeng
Jian-Ping
JP
Zou
Olayinka Taiwo
OT
Asekun
D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006834:Hydrazines / Q000737:chemistry*; D008024:Ligands; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*
D006834:Hydrazines; D008024:Ligands; D009943:Organophosphorus Compounds; D016877:Oxidants; D017905:Phosphites; D003300:Copper