Bis(2-meth-oxy-anilinium) hexa-bromido-stannate(IV) dihydrate.
The asymmetric unit of the title compound, (C7H10NO)2[SnBr6]·2H2O, contains one cation, one half-dianion and one lattice water mol-ecule. The [SnBr6](2-) dianion, located on an inversion center, exhibits a highly distorted octa-hedral coordination environment, with Sn-Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O-H⋯Br, N-H⋯Br, N-H⋯O and C-H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol-ecules) and cationic layers parallel to ab plane.
Laboratoire de Genie des Materiaux et Environnement, Ecole Nationale d'Ingenieurs de Sfax, BP 1173, Sfax, Tunisia.
Hassen
H
Chouaib
Laboratoire de Genie des Materiaux et Environnement, Ecole Nationale d'Ingenieurs de Sfax, BP 1173, Sfax, Tunisia.
Sahel
S
Karoui
Laboratoire de Genie des Materiaux et Environnement, Ecole Nationale d'Ingenieurs de Sfax, BP 1173, Sfax, Tunisia.
Slaheddine
S
Kamoun
Service commun d'analyse par diffraction des rayons X, Universite de Brest, 6, avenue Victor Le Gorgeu, CS 93837, F-29238 Brest cedex 3, France.
Francois
F
Michaud