Bis[μ-3,5-bis-(pyridin-2-yl)-1H-pyrazole]-bis-[di-bromido-iron(III)].
The title dinuclear complex, [Fe2Br4(C13H9N4)2], which lies on an inversion center, features two approximately planar bis-(pyridin-2-yl)pyrazole (bpypz(-)) ligands [maximum deviation = 0.082 (3) Å] and four bromide ions. Each Fe(III) ion is octa-hedrally coordinated by four N atoms of two bpypz(-) ligands and two Br ions. π-π stacking inter-actions [centroid-centroid distances = 3.7004 (17)-4.0123 (18) Å] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex mol-ecules.
Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan.
Nagisa
N
Katsuta
Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan.
Akio
A
Mishima
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Akira
A
Fuyuhiro
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kurokami, Kumamoto 860-8555, Japan.
Shinya
S
Hayami
Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan.
Satoshi
S
Kawata