Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion.
Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent- and halogen-free conditions without any additives or co-catalysts.
Key Laboratory of Cluster Science, Ministry of Education School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China. bowang@bit.edu.cn cwhu@bit.edu.cn dongxinmei@gmail.com.
Xianqiang
X
Huang
Yifa
Y
Chen
Zhengguo
Z
Lin
Xiaoqian
X
Ren
Yuna
Y
Song
Zhenzhu
Z
Xu
Xinmei
X
Dong
Xingguo
X
Li
Changwen
C
Hu
Bo
B
Wang