Stable carbon isotopes in dissolved inorganic carbon: extraction and implications for quantifying the contributions from silicate and carbonate weathering in the Krishna River system during peak discharge.
We present a comparative study of two offline methods, a newly developed method and an existing one, for the measurement of the stable carbon isotopic composition (δ(13)C) of dissolved inorganic carbon (DIC; δ(13)CDIC) in natural waters. The measured δ(13)CDIC values of different water samples, prepared from laboratory Na2CO3, ground and oceanic waters, and a laboratory carbonate isotope standard, are found to be accurate and reproducible to within 0.5 ‰\ (1σ). The extraction of CO2 from water samples by these methods does not require pre-treatment or sample poisoning and can be applied to a variety of natural waters to address carbon cycling in the hydrosphere. In addition, we present a simple method (based on a two-end-member mixing model) to estimate the silicate-weathering contribution to DIC in a river system by using the concentration of DIC and its δ(13)C. This approach is tested with data from the Krishna River system as a case study, thereby quantifying the contribution of silicate and carbonate weathering to DIC, particularly during peak discharge.
a Geosciences Division, Physical Research Laboratory , Navrangpura, Ahmedabad , Gujarat , India.
Amzad H
AH
Laskar
Naveen
N
Gandhi
Kaustubh
K
Thirumalai
Madhusudan G
MG
Yadava
Rengaswamy
R
Ramesh
Ramakant R
RR
Mahajan
Dharmendra
D
Kumar
D002244:Carbon / Q000032:analysis*; D002247:Carbon Isotopes / Q000032:analysis; D002254:Carbonates / Q000737:chemistry; D008962:Models, Theoretical; D045483:Rivers / Q000737:chemistry*; D017640:Silicates / Q000737:chemistry
D002247:Carbon Isotopes; D002254:Carbonates; D017640:Silicates; D002244:Carbon