[2,6-Di-fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC (4)](penta-ne-2,4-dionato-κ(2) O,O')iridium(III).
The title compound, [Ir(C10H5F2N2)2(C5H7O2)], has a distorted octa-hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C/trans-N,N chelate disposition in two 2,6-di-fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)°]. The mol-ecular structure is stabilized by weak C-H⋯O and C-H⋯F hydrogen-bond inter-actions. The crystal structure is stabilized by π-π stacking inter-actions (centroid-centroid distance = 3.951 Å).
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, People's Republic of China.
Kaijun
K
Luo
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, People's Republic of China.
Chenyang
C
Zhang
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, People's Republic of China.
Juan
J
Jia
Analytical and Testing Center, Sichuan University, Chengdu, Sichuan 610065, People's Republic of China.
Daibing
D
Luo