Studies toward communesin F: a Diels-Alder approach.
A Diels-Alder reaction is used as a key step in a synthetic study toward communesin F, in order to simultaneously introduce both of the all-carbon quaternary stereocenters with complete control of relative stereochemistry. Further manipulations of the cycloadduct, toward the hexacyclic core-structure of communesin F, are also disclosed.
Centre for Analysis and Synthesis, Department of Chemistry, Lund University , Box 124, 221 00 Lund, Sweden.
Jakob
J
Danielsson
Peter
P
Somfai
D061565:Cycloaddition Reaction / Q000379:methods*; D006576:Heterocyclic Compounds, 4 or More Rings / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D006576:Heterocyclic Compounds, 4 or More Rings; D011083:Polycyclic Compounds; C522025:communesin F