Diethyl [4-(2,2':6',2''-terpyridine-4'-yl)phen-yl]phospho-nate.
The title compound, C25H24N3O3P, was obtained by catalytic phospho-nation of 4'-(4-bromphen-yl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti-periplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6)°.
Department of Chemistry, Faculty of Science, Masaryk University, Kotlarska 2, CZ-61137 Brno, Czech Republic ; Central European Institute of Technology (CEITEC), Masaryk University, 625 00 Brno, Czech Republic.
Jan
J
Chyba
Department of Chemistry, Faculty of Science, Masaryk University, Kotlarska 2, CZ-61137 Brno, Czech Republic ; Central European Institute of Technology (CEITEC), Masaryk University, 625 00 Brno, Czech Republic.
Marek
M
Necas
Department of Chemistry, Faculty of Science, Masaryk University, Kotlarska 2, CZ-61137 Brno, Czech Republic ; Central European Institute of Technology (CEITEC), Masaryk University, 625 00 Brno, Czech Republic.
Jiri
J
Pinkas