Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes.
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated.
Chemistry Department, University of Pretoria, Private Bag X20, Hatfield 0028, Pretoria, South Africa. daniela.bezuidenhout@up.ac.za.
Daniela I
DI
Bezuidenhout
George
G
Kleinhans
Gregorio
G
Guisado-Barrios
David C
DC
Liles
Gaël
G
Ung
Guy
G
Bertrand