Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource.
Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using CO2 as a C1 resource was realized for the first time in the presence of hydrosilanes and base DBU under mild conditions, giving a series of aldehydes in good yields.
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. liuzm@iccas.ac.cn.
Bo
B
Yu
Yanfei
Y
Zhao
Hongye
H
Zhang
Jilei
J
Xu
Leiduan
L
Hao
Xiang
X
Gao
Zhimin
Z
Liu