Ethyl-enedi-ammonium sodium tetra-kis-[bis-(ethyl-enedi-amine-κ(2) N,N')(oxalato-κ(2) O (1),O (2))cobalt(III)] [penta-hydrogen di(phosphato-octa-deca-tungstate)] tetra-deca-hydrate.
The title compound, Na(C2H10N2)[Co(C2O4)(C2H8N2)2]4[H5(P2W18O62)2]·14H2O, prepared under hydro-thermal conditions, consists of two Dawson-type [P2W18O62](6-) anions, four isolated [Co(en)2(ox)](+) cations (en = ethyl-enedi-amine and ox = oxalate), one Na(+) cation, one [H2en](2+) cation, and a number of ordered (14) and disordered solvent water mol-ecules. The [P2W18O62](6-) polyoxidometalate anion has site symmetry 1 and contains two structurally distinct types of W atoms: viz. six W atoms on vertical pseudo-mirror planes grouped in two sets of three, and 12 equatorial W atoms that do not lie in the pseudo-mirror planes grouped in two sets of six. In each [Co(en)2(ox)](+) cation, the Co(III) ion is coordinated by four N atoms from two en ligands and two O atoms from the ox ligands, completing a distorted octa-hedral structure. The sodium cation lies on an inversion centre and additionally links the complex cations and anions. In the crystal, the various units are linked by N-H⋯O and O-H⋯O hydrogen bonds, which together with C-H⋯O hydrogen bonds form a three-dimensional structure. The contribution of a region of disordered electron density, possibly highly disordered solvent water mol-ecules, to the scattering was removed with the SQUEEZE option of PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. To equilibrate the charges five H(+) ions have been added to the polyoxidometalate. These H(+) ions and the disordered solvent contribution were not included in the reported mol-ecular weight and density.
Department of Material Engineering Invention Examination, Patent Examination Cooperation Center of the Patent Office, SIPO, Beijing, People's Republic of China.
Shuzhuo
S
Zhang
Department of Material Engineering Invention Examination, Patent Examination Cooperation Center of the Patent Office, SIPO, Beijing, People's Republic of China.
Jing
J
Wang
Department of Material Engineering Invention Examination, Patent Examination Cooperation Center of the Patent Office, SIPO, Beijing, People's Republic of China.
Yun
Y
Xu