Observation of allylic rearrangement in water-rich reaction.
Allylic rearrangement or the migration of a double bond from its original position in the carbon skeleton to an adjacent site was observed when 3,4,5,6-tetrahydrophthalate was hydrolyzed in a basic solution and in the presence of Co(ii) and Mn(ii) under hydrothermal conditions.
Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China. zheng.yanzhen@mail.xjtu.edu.cn chaowu@mail.xjtu.edu.cn.
Yuan-Chao
YC
Pang
Xiufang
X
Hou
Lei
L
Qin
Chao
C
Wu
Wei
W
Xue
Yan-Zhen
YZ
Zheng
Zhiping
Z
Zheng
Xiao-Ming
XM
Chen