Solid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+2] cycloaddition reaction.
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal-organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, S. Korea. sslee@gnu.ac.kr.
In-Hyeok
IH
Park
Anjana
A
Chanthapally
Hyeong-Hwan
HH
Lee
Hong Sheng
HS
Quah
Shim Sung
SS
Lee
Jagadese J
JJ
Vittal