Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule.
The self-assembly of [Mo(V)(CN)8](3-) and [Fe(II)(bik)2(S)2](2+) affords a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.
Sorbonne Universités, UPMC Univ. Paris 06, UMR 8232, IPCM, F-75005, Paris, France. rodrigue.lescouezec@upmc.fr.
Abhishake
A
Mondal
Yanling
Y
Li
Lise-Marie
LM
Chamoreau
Mannan
M
Seuleiman
Lionel
L
Rechignat
Azzedine
A
Bousseksou
Marie-Laure
ML
Boillot
Rodrigue
R
Lescouëzec