Controlling exfoliation in order to minimize damage during dispersion of long SWCNTs for advanced composites.
We propose an approach to disperse long single-wall carbon nanotubes (SWCNTs) in a manner that is most suitable for the fabrication of high-performance composites. We compare three general classes of dispersion mechanisms, which encompass 11 different dispersion methods, and we have dispersed long SWCNTs, short multi-wall carbon nanotubes, and short SWCNTs in order to understand the most appropriate dispersion methods for the different types of CNTs. From this study, we have found that the turbulent flow methods, as represented by the Nanomizer and high-pressure jet mill methods, produced unique and superior dispersibility of long SWCNTs, which was advantageous for the fabrication of highly conductive composites. The results were interpreted to imply that the biaxial shearing force caused an exfoliation effect to disperse the long SWCNTs homogeneously while suppressing damage. A conceptual model was developed to explain this dispersion mechanism, which is important for future work on advanced CNT composites.
Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Howon
H
Yoon
Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Motoi
M
Yamashita
1] Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan [2] Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Seisuke
S
Ata
1] Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan [2] Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Don N
DN
Futaba
1] Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan [2] Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Takeo
T
Yamada
1] Technology Research Association for Single Wall Carbon Nanotubes (TASC), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan [2] Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Kenji
K
Hata