Synthesis, structure and reactivity of group 4 corrole complexes.
A series of early transition metal corrole complexes has been prepared via salt metathesis with the corresponding lithium corrole. Their characterization by single crystal X-ray diffraction, NMR, and absorption spectroscopy is described. Organometallic derivatives of the titanium complex were obtained via treatment of 2 with NaCp* or ClMgCH2SiMe3.
Department of Chemistry, University of California, Berkeley, California 94720, USA. arnold@berkeley.edu.
Rosa
R
Padilla
Heather L
HL
Buckley
Ashleigh L
AL
Ward
John
J
Arnold