A bidentate boryl ligand: syntheses of platinum and iridium complexes.
A methylenediphenylphosphine substituted diazaborole was obtained in a two-step procedure in amounts around 4 g. This B-P ligand was coordinated at platinum and iridium and the structures of the boryl complexes are discussed. In the case of the iridium derivative an interesting boron-boron contact was found.
Institute of Inorganic Chemistry, University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany. l.wesemann@uni-tuebingen.de.
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