Characterizing nano-scale electrocatalysis during partial oxidation of methane.
Electrochemical analysis allows in situ characterization of solid oxide electrochemical cells (SOCs) under operating conditions. However, the SOCs that have been analyzed in this way have ill-defined or uncommon microstructures in terms of porosity and tortuosity. Therefore, the nano-scale characterization of SOCs with respect to three-phase boundaries has been hindered. We introduce novel in situ electrochemical analysis for SOCs that uses combined solid electrolyte potentiometry (SEP) and impedance measurements. This method is employed to investigate the oscillatory behavior of a porous Ni-yttria-stabilized zirconia (YSZ) anode during the partial oxidation of methane under ambient pressure at 800°C. The cyclic oxidation and reduction of nickel induces the oscillatory behavior in the impedance and electrode potential. The in situ characterization of the nickel surface suggests that the oxidation of the nickel occurs predominantly at the two-phase boundaries, whereas the nickel at the three-phase boundaries remains in the metallic state during the cyclic redox reaction.
Department of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea.
Daehee
D
Lee
Department of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea.
Dongha
D
Kim
High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea.
Joosun
J
Kim
Department of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea.
Jooho
J
Moon