Transition metal catalyzed borylation of functional π-systems.
Borylated functional π-systems are useful building blocks to enable efficient synthesis of novel molecular architectures with beautiful structures, intriguing properties and unique functions. Introduction of boronic ester substituents to a variety of extended π-systems can be achieved through either iridium-catalyzed direct C-H borylation or the two-step procedure via electrophilic halogenation followed by palladium-catalyzed borylation. This review article focuses on our recent progress on borylation of large π-conjugated systems such as porphyrins, perylene bisimides, hexabenzocoronenes and dipyrrins.
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University.
Hiroshi
H
Shinokubo
D001895:Boron / Q000737:chemistry*; D002384:Catalysis; D004583:Electrons; D008670:Metals / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry; D028561:Transition Elements / Q000737:chemistry*
D008670:Metals; D009930:Organic Chemicals; D028561:Transition Elements; D001895:Boron