Delayed electron-hole pair recombination in iron(III)-oxo metal-organic frameworks.
The photodynamic properties of a series of Fe(III)-MOFs have been examined via redox reactions with N,N,N',N'-tetramethyl-p-phenylenediamine as an electron donor and methyl viologen as an electron acceptor. Furthermore, photogeneration of long-lived species in MIL-88B(Fe) has been proven via transient absorption spectroscopy.
Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001, Heverlee, Belgium.
Katrien G M
KG
Laurier
Eduard
E
Fron
Pedro
P
Atienzar
Koen
K
Kennes
Hermenegildo
H
Garcia
Mark
M
Van der Auweraer
Dirk E
DE
De Vos
Johan
J
Hofkens
Maarten B J
MB
Roeffaers
D004583:Electrons; D005290:Ferric Compounds / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D010269:Paraquat / Q000737:chemistry
D005290:Ferric Compounds; D009930:Organic Chemicals; D010269:Paraquat