Sorption and desorption of sulfadimethoxine, sulfaquinoxaline and sulfamethazine antimicrobials in Brazilian soils.
Adsorption and desorption are important processes that influence the transport, transformation and bioavailability of antimicrobials in soils. The adsorption-desorption characteristics of sulfadimethoxine, sulfaquinoxaline and sulfamethazine in Brazilian soils (sandy, sandy-clay and clay) were evaluated using the batch equilibrium method. The sulfonamides were quantified in the soil solutions by a previously in house validated HPLC-PAD method. The adsorption/desorption data for the sulfonamides in soils fit the Freundlich isotherms well in the logarithmic form. The Freundlich adsorption coefficients ranged from 1.4 to 19.0 μg(1-1/n)(cm(3))(1/n)g(-1), suggesting that all of the sulfonamides weakly adsorbed on the evaluated soils. The Freundlich desorption coefficients ranged from 0.85 to 24.8 μg(1-1/n)(cm(3))(1/n)g(-1), indicating that the sulfonamides tend to be leached from soils with high sand and low organic carbon contents, suggesting that there is high potential for surface and groundwater contamination.
Institute of Chemistry, Department of Analytical Chemistry, University of Campinas, Campinas, SP, Brazil.
Keity Margareth
KM
Doretto
Institute of Chemistry, Department of Analytical Chemistry, University of Campinas, Campinas, SP, Brazil.
Livia Maniero
LM
Peruchi
Institute of Chemistry, Department of Analytical Chemistry, University of Campinas, Campinas, SP, Brazil. Electronic address: raths@iqm.unicamp.br.
Susanne
S
Rath
D000327:Adsorption; D000890:Anti-Infective Agents / Q000737:chemistry*; D001938:Brazil; D008956:Models, Chemical; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D013412:Sulfadimethoxine / Q000737:chemistry; D013418:Sulfamethazine / Q000737:chemistry; D013424:Sulfanilamides / Q000737:chemistry*; D013428:Sulfaquinoxaline / Q000737:chemistry
D000890:Anti-Infective Agents; D012987:Soil; D012989:Soil Pollutants; D013424:Sulfanilamides; D013412:Sulfadimethoxine; D013418:Sulfamethazine; D013428:Sulfaquinoxaline
Batch equilibrium method; Freundlich sorption isotherms; Mobility; Soils; Sulfonamides; Veterinary drugs