title: The superior catalytic CO oxidation capacity of a Cr-phthalocyanine porous sheet.
abstract: Two-dimensional organometallic sheets containing regularly and separately distributed transition atoms (TMs) have received tremendous attentions due to their flexibility in synthesis, well-defined geometry and the promising applications in hydrogen storage, electronic circuits, quantum Hall effect, and spintronics. Here for the first time we present a study on the superior catalytic CO oxidation capacity of a Cr-phthalocyanine porous sheet proceeding first via Langmuir-Hinshelwood (LH) mechanism and then via Eley-Rideal (ER) mechanism. Compared to the noble metal based catalysts or graphene supported catalysts, our studied system has following unique features: without poisoning effect and clustering problem, having comparable reaction energy barrier for low-temperature oxidation, and low cost for large-scale catalytic CO oxidation in industry.
authors: Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China.
authors: Yawei
authors: Y
authors: Li
authors: 1] Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China [2] Center for Applied Physics and Technology, Peking University, Beijing 100871, China.
authors: Qiang
authors: Q
authors: Sun