title: Perylene-derived triplet acceptors with optimized excited state energy levels for triplet-triplet annihilation assisted upconversion.
abstract: A series of perylene derivatives are prepared as triplet energy acceptors for triplet-triplet annihilation (TTA) assisted upconversion. The aim is to optimize the energy levels of the T1 and S1 states of the triplet acceptors, so that the prerequisite for TTA (2E(T1) > E(S1)) can be better satisfied, and eventually to increase the upconversion efficiency. Tuning of the energy levels of the excited states of the triplet acceptors is realized either by attaching aryl groups to perylene (via single or triple carbon-carbon bonds), or by assembling a perylene-BODIPY dyad, in which the components present complementary S1 and T1 state energy levels. The S1 state energy levels of the perylene derivatives are generally decreased compared to perylene. The anti-Stokes shift, TTA, and upconversion efficiencies of the new triplet acceptors are improved with respect to the perylene hallmark. For the perylene-BODIPY dyads, the fluorescence emission was substantially quenched in polar solvents. Moreover, we found that extension of the π-conjugation of BODIPY energy donor significantly reduces the energy level of the S1 state. Low S1 state energy level and high T1 state energy level are beneficial for triplet photosensitizers.
authors: State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology , E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, P. R. China.
authors: Xiaoneng
authors: X
authors: Cui
authors: Azzam
authors: A
authors: Charaf-Eddin
authors: Junsi
authors: J
authors: Wang
authors: Boris
authors: B
authors: Le Guennic
authors: Jianzhang
authors: J
authors: Zhao
authors: Denis
authors: D
authors: Jacquemin