title: Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series.
abstract: The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.
authors: CSIRO Division of Materials Science and Engineering, Clayton South MDC, VIC3169, Australia. matthew.hill@csiro.au ravichandar.babarao@csiro.au.
authors: Ravichandar
authors: R
authors: Babarao
authors: Campbell J
authors: CJ
authors: Coghlan
authors: Damien
authors: D
authors: Rankine
authors: Witold M
authors: WM
authors: Bloch
authors: Gemma K
authors: GK
authors: Gransbury
authors: Hiroshi
authors: H
authors: Sato
authors: Susumu
authors: S
authors: Kitagawa
authors: Christopher J
authors: CJ
authors: Sumby
authors: Matthew R
authors: MR
authors: Hill
authors: Christian J
authors: CJ
authors: Doonan