title: Synthesis and characterization of cyclooctatetrathiophenes with different connection sequences.
abstract: Based on the selectivity of deprotonation of 5,5'-bistrimethylsilyl-2,3'-bithiophene (4) in the presence of n-BuLi, three new cyclooctatetrathiophenes (COThs), COTh-1, COTh-2, and COTh-3 have been efficiently developed via intermolecular or intramolecular cyclizations. Their crystal structures clearly show that the different connectivity sequence of the thiophene rings in the molecules. The CV data and UV-vis absorbance spectra of COThs are also described. In addition, the time-dependent density functional theory (TDDFT) calculations accurately reproduce experimental observations and afford band assignment.
authors: Key Lab for Special Functional Materials of Ministry of Education and ‡College of Chemistry and Chemical Engineering, Henan University , Kaifeng 475004, China.
authors: Yong
authors: Y
authors: Wang
authors: Jinsheng
authors: J
authors: Song
authors: Li
authors: L
authors: Xu
authors: Yuhe
authors: Y
authors: Kan
authors: Jianwu
authors: J
authors: Shi
authors: Hua
authors: H
authors: Wang