title: Bis(μ2-iso-propyl-imido-κ(2) N:N)bis-[(η(5)-cyclo-penta-dien-yl)(ethenolato-κO)titanium(IV)].
abstract: The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(μ2-N-iPr)]2 (Cp = cyclo-penta-dien-yl; iPr = isopropyl), was ob-tained from the reaction of Cp2TiCl2, n-butyl-lithium and iso-propyl-amine in tetra-hydro-furan. Each Ti(IV) atom is coordinated by one Cp ligand, one vin-yloxy unit and two bridging imido groups in a strongly distorted tetra-hedral geometry. There are two half mol-ecules in the asymmetric unit, such that whole mol-ecules being generated by inversion symmetry.
authors: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors: Martin
authors: M
authors: Haehnel
authors: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors: Anke
authors: A
authors: Spannenberg
authors: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors: Uwe
authors: U
authors: Rosenthal