title: 4-Methyl-N-(4-methyl-phenyl-sulfon-yl)-N-[4-(4-methyl-phen-yl)-1,3-thia-zol-2-yl]benzene-sulfonamide.
abstract: There are two independent mol-ecules in the asymmetric unit of the title compound, C24H22N2O4S3. In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia-zole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methyl-phenyl-sulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S-N-S planes in the two mol-ecules. The thia-zole groups are rotated around the C-N bonds and are almost perpendicular to the S-N-S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C-H⋯O inter-actions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent mol-ecules into inversion dimers.
authors: Facultad de Química, Universidad, Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP 97150, Mérida, Yucatán, Mexico.
authors: Rubén M
authors: RM
authors: Carballo
authors: Instituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF 04510, Mexico.
authors: Simón
authors: S
authors: Hernández-Ortega
authors: Facultad de Química, Universidad, Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP 97150, Mérida, Yucatán, Mexico.
authors: Nayely
authors: N
authors: Padilla-Montaño
authors: Facultad de Química, Universidad, Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP 97150, Mérida, Yucatán, Mexico.
authors: Reyna
authors: R
authors: Reyes-Martínez
authors: Facultad de Química, Universidad, Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP 97150, Mérida, Yucatán, Mexico.
authors: Gumersindo
authors: G
authors: Mirón-López