title: Latent and delayed action polymerization systems.
abstract: Various approaches to latent polymerization processes are described. In order to highlight recent advances in this field, the discussion is subdivided into chapters dedicated to diverse classes of polymers, namely polyurethanes, polyamides, polyesters, polyacrylates, epoxy resins, and metathesis-derived polymers. The described latent initiating systems encompass metal-containing as well as purely organic compounds that are activated by external triggers such as light, heat, or mechanical force. Special emphasis is put on the different chemical venues that can be taken to achieve true latency, which include masked N-heterocyclic carbenes, latent metathesis catalysts, and photolatent radical initiators, among others. Scientific challenges and the advantageous application of latent polymerization processes are discussed.
authors: Institute of Polymer Chemistry, University of Stuttgart, Pfaffenwaldring 55, D-70569, Stuttgart, Germany.
authors: Stefan
authors: S
authors: Naumann
authors: Michael R
authors: MR
authors: Buchmeiser
mesh_terms: D002384:Catalysis / Q000187:drug effects; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry / Q000494:pharmacology; D055668:Photochemical Processes / Q000187:drug effects / Q000528:radiation effects; D058105:Polymerization / Q000187:drug effects / Q000528:radiation effects; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D009942:Organometallic Compounds; D011108:Polymers
keywords: anionic polymerization; curing of polymers; metathesis; photopolymerization; reactive processing