title: Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands.
abstract: Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.
authors: Dipartimento di Chimica e Biologia, Università di Salerno , via Giovanni Paolo II, 132, 84084 Fisciano, Italy.
authors: Alessia
authors: A
authors: Pilone
authors: Konstantin
authors: K
authors: Press
authors: Israel
authors: I
authors: Goldberg
authors: Moshe
authors: M
authors: Kol
authors: Mina
authors: M
authors: Mazzeo
authors: Marina
authors: M
authors: Lamberti