title: Photoredox-induced three-component oxy-, amino-, and carbotrifluoromethylation of enecarbamates.
abstract: A photoredox-catalzyed trifluoromethylation of enecarbamates process is reported. This pathway uses Togni's reagent as the CF3 source and follows a radical/cationic pathway. Under the optimized conditions using [Ru(bpy)3(PF6)2] as the photocatalyst, a wide range of substituted enecarbamates can readily be difunctionalized by means of various O, N, and C nucleophiles.
authors: Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS , 91198 Gif-sur-Yvette Cedex, France.
authors: Aude
authors: A
authors: Carboni
authors: Guillaume
authors: G
authors: Dagousset
authors: Emmanuel
authors: E
authors: Magnier
authors: Géraldine
authors: G
authors: Masson
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D055668:Photochemical Processes
chemical_list: D000588:Amines; D002219:Carbamates; D006845:Hydrocarbons, Fluorinated