title: Rh(III)-catalyzed synthesis of 1-substituted isoquinolinium salts via a C-H bond activation reaction of ketimines with alkynes.
abstract: An efficient synthesis of highly substituted isoquinolinium salts from ketimines and alkynes via a Rh(III)-catalyzed C-H bond activation and annulation reaction is described.
authors: Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan. chcheng@mx.nthu.edu.tw.
authors: Natarajan
authors: N
authors: Senthilkumar
authors: Parthasarathy
authors: P
authors: Gandeepan
authors: Jayachandran
authors: J
authors: Jayakumar
authors: Chien-Hong
authors: CH
authors: Cheng
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D007546:Isoquinolines / Q000138:chemical synthesis* / Q000737:chemistry; D009570:Nitriles / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D012492:Salts / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000480:Alkynes; D007097:Imines; D007546:Isoquinolines; D009570:Nitriles; D012492:Salts; C542835:ketimine; D012238:Rhodium