title: Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis.
abstract: Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.
authors.affiliation: School of Chemistry & Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland. martin.albrecht@ucd.ie.
authors.forename: Juan
authors.initials: J
authors.lastname: Olguín
authors.forename: Helge
authors.initials: H
authors.lastname: Müller-Bunz
authors.forename: Martin
authors.initials: M
authors.lastname: Albrecht