title: Highly diastereoselective addition of alkoxyethynyl aluminium reagents to N-tert-butylsulfinyl aldimines.
abstract: The addition of dimethylaluminium alkoxyacetylides to Ellman's sulfinylimines is described. The reaction proceeds with excellent diastereoselectivity and high yield to produce oxygenated propargylamines in one step starting from simple dichloroenol ethers.
authors.affiliation: Université Joseph Fourier, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, ICMG FR-2607, BP 53, 38041, Grenoble Cedex 9, France. jean-francois.poisson@ujf-grenoble.fr.
authors.forename: Charlie
authors.initials: C
authors.lastname: Verrier
authors.forename: Sébastien
authors.initials: S
authors.lastname: Carret
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Poisson
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000588:Amines; D007097:Imines; D009942:Organometallic Compounds; D000535:Aluminum