title: The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones.
abstract: The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.
authors.affiliation: WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan. tjin@m.tohoku.ac.jp.
authors.forename: Qiang
authors.initials: Q
authors.lastname: Chen
authors.forename: Shinya
authors.initials: S
authors.lastname: Tanaka
authors.forename: Takeshi
authors.initials: T
authors.lastname: Fujita
authors.forename: Luyang
authors.initials: L
authors.lastname: Chen
authors.forename: Taketoshi
authors.initials: T
authors.lastname: Minato
authors.forename: Yoshifumi
authors.initials: Y
authors.lastname: Ishikawa
authors.forename: Mingwei
authors.initials: M
authors.lastname: Chen
authors.forename: Naoki
authors.initials: N
authors.lastname: Asao
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Yamamoto
authors.forename: Tienan
authors.initials: T
authors.lastname: Jin