title: On rates and mechanisms of OH and O3 reactions with isoprene-derived hydroxy nitrates.
abstract: Eight distinct hydroxy nitrates are stable products of the first step in the atmospheric oxidation of isoprene by OH. The subsequent chemical fate of these molecules affects global and regional production of ozone and aerosol as well as the location of nitrogen deposition. We synthesized and purified 3 of the 8 isoprene hydroxy nitrate isomers: (E/Z)-2-methyl-4-nitrooxybut-2-ene-1-ol and 3-methyl-2-nitrooxybut-3-ene-1-ol. Oxidation of these molecules by OH and ozone was studied using both chemical ionization mass spectrometry and thermo-dissociation laser induced fluorescence. The OH reaction rate constants at 300 K measured relative to propene at 745 Torr are (1.1 ± 0.2) × 10(-10) cm(3) molecule(-1) s(-1) for both the E and Z isomers and (4.2 ± 0.7) × 10(-11) cm(3) molecule(-1) s(-1) for the third isomer. The ozone reaction rate constants for (E/Z)-2-methyl-4-nitrooxybut-2-ene-1-ol are (2.7 ± 0.5) × 10(-17) and (2.9 ± 0.5) × 10(-17) cm(3) molecule(-1) s(-1), respectively. 3-Methyl-2-nitrooxybut-3-ene-1-ol reacts with ozone very slowly, within the range of (2.5-5) × 10(-19) cm(3) molecule(-1) s(-1). Reaction pathways, product yields, and implications for atmospheric chemistry are discussed. A condensed mechanism suitable for use in atmospheric chemistry models is presented.
authors.affiliation: Department of Chemistry, University of California , Berkeley, California 94709, United States.
authors.forename: Lance
authors.initials: L
authors.lastname: Lee
authors.forename: Alex P
authors.initials: AP
authors.lastname: Teng
authors.forename: Paul O
authors.initials: PO
authors.lastname: Wennberg
authors.forename: John D
authors.initials: JD
authors.lastname: Crounse
authors.forename: Ronald C
authors.initials: RC
authors.lastname: Cohen
mesh_terms: D002070:Butadienes / Q000737:chemistry*; D045782:Hemiterpenes / Q000737:chemistry*; D006878:Hydroxides / Q000737:chemistry*; D015394:Molecular Structure; D009566:Nitrates / Q000737:chemistry*; D010126:Ozone / Q000737:chemistry*; D010420:Pentanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D002070:Butadienes; D045782:Hemiterpenes; D006878:Hydroxides; D009566:Nitrates; D010420:Pentanes; C005059:isoprene; D010126:Ozone; C031356:hydroxide ion