title: Influence of drinking water treatments on chlorine dioxide consumption and chlorite/chlorate formation.
abstract: Disinfection is the last treatment stage of a Drinking Water Treatment Plant (DWTP) and is carried out to maintain a residual concentration of disinfectant in the water distribution system. Chlorine dioxide (ClO2) is a widely used chemical employed for this purpose. The aim of this work was to evaluate the influence of several treatments on chlorine dioxide consumption and on chlorite and chlorate formation in the final oxidation/disinfection stage. A number of tests was performed at laboratory scale employing water samples collected from the DWTP of Cremona (Italy). The following processes were studied: oxidation with potassium permanganate, chlorine dioxide and sodium hypochlorite, coagulation/flocculation with ferric chloride and aluminum sulfate, filtration and adsorption onto activated carbon. The results showed that the chlorine dioxide demand is high if sodium hypochlorite or potassium permanganate are employed in pre-oxidation. On the other hand, chlorine dioxide leads to the highest production of chlorite and chlorate. The coagulation/flocculation process after pre-oxidation shows that chlorine dioxide demand decreases if potassium permanganate is employed as an oxidant, both with ferric chloride and aluminum sulfate. Therefore, the combination of these processes leads to a lower production of chlorite and chlorate. Aluminum sulfate is preferable in terms of the chlorine dioxide demand reduction and minimization of the chlorite and chlorate formation. Activated carbon is the most effective solution as it reduced the chlorine dioxide consumption by about 50% and the DBP formation by about 20-40%.
authors.affiliation: University of Brescia, Department of Civil Engineering, Architecture, Land, Environment and Mathematics, via Branze 43, 25123 Brescia, Italy. Electronic address: sabrina.sorlini@unibs.it.
authors.forename: Sabrina
authors.initials: S
authors.lastname: Sorlini
authors.affiliation: University of Brescia, Department of Civil Engineering, Architecture, Land, Environment and Mathematics, via Branze 43, 25123 Brescia, Italy.
authors.forename: Francesca
authors.initials: F
authors.lastname: Gialdini
authors.affiliation: University of Brescia, Department of Civil Engineering, Architecture, Land, Environment and Mathematics, via Branze 43, 25123 Brescia, Italy.
authors.forename: Michela
authors.initials: M
authors.lastname: Biasibetti
authors.affiliation: University of Brescia, Department of Civil Engineering, Architecture, Land, Environment and Mathematics, via Branze 43, 25123 Brescia, Italy.
authors.forename: Carlo
authors.initials: C
authors.lastname: Collivignarelli
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry; D002704:Chlorates / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D017606:Chlorine Compounds / Q000737:chemistry*; D060766:Drinking Water / Q000737:chemistry*; D005374:Filtration; D005427:Flocculation; D007558:Italy; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*; D013997:Time Factors; D022882:Trihalomethanes / Q000032:analysis; D018508:Water Purification / Q000379:methods*; D060753:Water Quality
chemical_list: D002704:Chlorates; D002712:Chlorides; D017606:Chlorine Compounds; D060766:Drinking Water; D010087:Oxides; D022882:Trihalomethanes; D002606:Charcoal; C025109:chlorine dioxide; C001599:chlorite
keywords: Chlorate; Chlorine dioxide demand; Chlorite; Drinking water treatment plant