title: Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide.
abstract: The first highly effective iron-catalyzed carbonylative Suzuki reaction has been developed. Substrates with electron-donating or electron-withdrawing functionality, ortho-substitution, as well as active groups proceeded smoothly, affording desired products in high yields. This protocol is economical, environmentally benign and practical for the synthesis of biaryl ketones.
authors.affiliation: Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road No. 1, 210023 Nanjing, China. whhanwei@gmail.com.
authors.forename: Yanzhen
authors.initials: Y
authors.lastname: Zhong
authors.forename: Wei
authors.initials: W
authors.lastname: Han
mesh_terms: D001274:Atmospheric Pressure; D001897:Boronic Acids / Q000737:chemistry; D002248:Carbon Monoxide / Q000737:chemistry*; D002384:Catalysis; D004583:Electrons; D007501:Iron / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D011092:Polyethylene Glycols / Q000737:chemistry
chemical_list: D001897:Boronic Acids; D007659:Ketones; D011092:Polyethylene Glycols; D010165:Palladium; D002248:Carbon Monoxide; D007501:Iron