title: Catalytic Radical Domino Reactions in Organic Synthesis.
abstract: Catalytic radical-based domino reactions represent important advances in synthetic organic chemistry. Their development benefits synthesis by providing atom- and step-economical methods to complex molecules. Intricate combinations of radical, cationic, anionic, oxidative/reductive, and transition metal mechanistic steps result in cyclizations, additions, fragmentations, ring-expansions, and rearrangements. This Perspective summarizes recent developments in the field of catalytic domino processes.
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, MI.
authors.forename: Leanne J
authors.initials: LJ
authors.lastname: Sebren
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, MI.
authors.forename: James J
authors.initials: JJ
authors.lastname: Devery
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, MI.
authors.forename: Corey R J
authors.initials: CR
authors.lastname: Stephenson
keywords: cascade; domino; photoredox; radical; tandem; transition metal