title: Competition between sp³-C-N vs sp³-C-F reductive elimination from Pd(IV) complexes.
abstract: This communication describes the design of a model system that allows direct investigation of competing sp(3)-C-N and sp(3)-C-F bond-forming reductive elimination from a Pd(IV) fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.
authors.affiliation: Department of Chemistry, University of Michigan , 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
authors.forename: Mónica H
authors.initials: MH
authors.lastname: Pérez-Temprano
authors.forename: Joy M
authors.initials: JM
authors.lastname: Racowski
authors.forename: Jeff W
authors.initials: JW
authors.lastname: Kampf
authors.forename: Melanie S
authors.initials: MS
authors.lastname: Sanford