title: Double C(sp3)-H bond functionalization mediated by sequential hydride shift/cyclization process: diastereoselective construction of polyheterocycles.
abstract: Described herein are two novel types of double C(sp(3))-H bond functionalizations triggered by a sequential hydride shift/cyclization process: (1) construction of a bicyclo[3.2.2]nonane skeleton by a [1,6]- and [1,5]-hydride shift sequence and (2) sequential [1,4]- and [1,5]-hydride shift mediated construction of a linear tricyclic skeleton.
authors.affiliation: Department of Chemistry, Faculty of Science, Gakushuin University , Mejiro, Toshima-ku, Tokyo 171-8588, Japan.
authors.forename: Keiji
authors.initials: K
authors.lastname: Mori
authors.forename: Kazuki
authors.initials: K
authors.lastname: Kurihara
authors.forename: Shinnosuke
authors.initials: S
authors.lastname: Yabe
authors.forename: Masahiro
authors.initials: M
authors.lastname: Yamanaka
authors.forename: Takahiko
authors.initials: T
authors.lastname: Akiyama