title: Yttrium hydride nanoantennas for active plasmonics.
abstract: A key challenge for the development of active plasmonic nanodevices is the lack of materials with fully controllable plasmonic properties. In this work, we demonstrate that a plasmonic resonance in top-down nanofabricated yttrium antennas can be completely and reversibly turned on and off using hydrogen exposure. We fabricate arrays of yttrium nanorods and optically observe, in extinction spectra, the hydrogen-induced phase transition between the metallic yttrium dihydride and the insulating trihydride. Whereas the yttrium dihydride nanostructures exhibit a pronounced particle plasmon resonance, the transition to yttrium trihydride leads to a complete vanishing of the resonant behavior. The plasmonic resonance in the dihydride state can be tuned over a wide wavelength range by simply varying the size of the nanostructures. Furthermore, we develop an analytical diffusion model to explain the temporal behavior of the hydrogen loading and unloading trajectories observed in our experiments and gain information about the thermodynamics of our device. Thus, our nanorod system serves as a versatile basic building block for active plasmonic devices ranging from switchable perfect absorbers to active local heating control elements.
authors.affiliation: 4th Physics Institute and Research Center SCoPE, University of Stuttgart , Pfaffenwaldring 57, 70569 Stuttgart, Germany.
authors.forename: Nikolai
authors.initials: N
authors.lastname: Strohfeldt
authors.forename: Andreas
authors.initials: A
authors.lastname: Tittl
authors.forename: Martin
authors.initials: M
authors.lastname: Schäferling
authors.forename: Frank
authors.initials: F
authors.lastname: Neubrech
authors.forename: Uwe
authors.initials: U
authors.lastname: Kreibig
authors.forename: Ronald
authors.initials: R
authors.lastname: Griessen
authors.forename: Harald
authors.initials: H
authors.lastname: Giessen