title: Towards waste free organic synthesis using nanostructured hybrid silicas.
abstract: As catalysis and organic synthesis come together again, the need for stable, selective and truly heterogeneous solid catalysts for clean and efficient synthetic organic chemistry has increased. Hybrid silica glasses obtained by the sol-gel nanochemistry approach can be successfully used for the waste-free synthesis of valued chemicals in various applications. This success derives from the deliberate chemical design of hybrid nanostructures capable of immobilizing and stabilizing organocatalytic species and unstable metal nanoparticles. The highly selective activity along with a broad scope and ease of application of these mesoporous materials to high-throughput reactions opens the route to faster, cleaner and more convenient processes for both small and large scale manufacturing of useful molecules.
authors.affiliation: Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146 Palermo, Italy. mario.pagliaro@cnr.it.
authors.forename: Rosaria
authors.initials: R
authors.lastname: Ciriminna
authors.forename: Laura M
authors.initials: LM
authors.lastname: Ilharco
authors.forename: Valerica
authors.initials: V
authors.lastname: Pandarus
authors.forename: Alexandra
authors.initials: A
authors.lastname: Fidalgo
authors.forename: François
authors.initials: F
authors.lastname: Béland
authors.forename: Mario
authors.initials: M
authors.lastname: Pagliaro