title: Spectroscopic study of the experimental parameters controlling the structural properties of chitosan-Ag nanoparticles composite.
abstract: Chitosan as reducing, stabilizing and capping agent was used to synthesize chitosan-silver nanoparticles composite under different experimental conditions of temperature or time. The UV-Vis spectra exhibited a single peak at 430nm which provided strong evidence for the formation of surface plasmon resonance (SPR) band of Ag nanoparticles. The rate of the increase of this absorbance with temperature increases with increasing the time of reduction. It was found that the variation of the temperature from 60°C to 100°C and the time of reduction from 6h to 16h resulted in no significant changes in the intensities and positions of the FTIR absorption bands of the composite. The TEM micrographs showed distinct typical spherical silver nanoparticles separated from each other quite well at reduction temperature range (60-80°C) and displayed some of accumulations at high temperature range (90-100°C). The TEM micrographs investigation indicated various shapes with different reduction time. The SEM images of the prepared samples were discussed.
authors.affiliation: Spectroscopy Department, Physics Division, National Research Center, Cairo, Egypt.
authors.forename: M A
authors.initials: MA
authors.lastname: Moharram
authors.affiliation: Basic Sciences Department, Dammam University, Main Campus, Rakah, Saudi Arabia.
authors.forename: S K H
authors.initials: SK
authors.lastname: Khalil
authors.affiliation: Spectroscopy Department, Physics Division, National Research Center, Cairo, Egypt. Electronic address: hhasherif@yahoo.com.
authors.forename: H H A
authors.initials: HH
authors.lastname: Sherif
authors.affiliation: Biophysics Department, Faculty of Science, University of Cairo, Cairo, Egypt.
authors.forename: W A
authors.initials: WA
authors.lastname: Khalil
mesh_terms: D048271:Chitosan / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D010084:Oxidation-Reduction; D012834:Silver / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D020349:Surface Plasmon Resonance
chemical_list: D012834:Silver; D048271:Chitosan
keywords: Chemical reduction method; Chitosan; Silver nanoparticles composite; Spectroscopic techniques