title: Radionuclide transport behavior in a generic geological radioactive waste repository.
abstract: We performed numerical simulations of groundwater flow and radionuclide transport to study the influence of several factors, including the ambient hydraulic gradient, groundwater pressure anomalies, and the properties of the excavation damaged zone (EDZ), on the prevailing transport mechanism (i.e., advection or molecular diffusion) in a generic nuclear waste repository within a clay-rich geological formation. By comparing simulation results, we show that the EDZ plays a major role as a preferential flowpath for radionuclide transport. When the EDZ is not taken into account, transport is dominated by molecular diffusion in almost the totality of the simulated domain, and transport velocity is about 40% slower. Modeling results also show that a reduction in hydraulic gradient leads to a greater predominance of diffusive transport, slowing down radionuclide transport by about 30% with respect to a scenario assuming a unit gradient. In addition, inward flow caused by negative pressure anomalies in the clay-rich formation further reduces transport velocity, enhancing the ability of the geological barrier to contain the radioactive waste. On the other hand, local high gradients associated with positive pressure anomalies can speed up radionuclide transport with respect to steady-state flow systems having the same regional hydraulic gradients. Transport behavior was also found to be sensitive to both geometrical and hydrogeological parameters of the EDZ. Results from this work can provide useful knowledge toward correctly assessing the post-closure safety of a geological disposal system.
authors.affiliation: Earth Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA.
authors.forename: Marco
authors.initials: M
authors.lastname: Bianchi
authors.forename: Hui-Hai
authors.initials: HH
authors.lastname: Liu
authors.forename: Jens T
authors.initials: JT
authors.lastname: Birkholzer
mesh_terms: D000538:Aluminum Silicates; D000077215:Clay; D004058:Diffusion; D055593:Geological Phenomena; D060587:Groundwater; D062070:Hydrology; D008962:Models, Theoretical; D011850:Radioactive Waste; D011868:Radioisotopes; D012037:Refuse Disposal / Q000379:methods; D014872:Water Movements
chemical_list: D000538:Aluminum Silicates; D011850:Radioactive Waste; D011868:Radioisotopes; D000077215:Clay