title: Nickel-tungsten carbide catalysts for the production of 2,5-dimethylfuran from biomass-derived molecules.
abstract: The development of new catalytic systems for the conversion of biomass-derived molecules into liquid fuels has attracted much attention. We propose a non-noble bimetallic catalyst based on nickel-tungsten carbide for the conversion of the platform molecules 5-(hydroxymethyl)furfural into the liquid-fuel molecule 2,5-dimethylfuran (DMF). Different catalysts, metal ratios and reaction conditions have been tested and give rise to a 96% yield of DMF. The catalysts have been characterized and are discussed. The reaction mechanism is also explored through capture of reaction intermediates. The analysis of the reaction mixture over different catalysts is presented and helps to understand the role of nickel and tungsten carbide during the reaction.
authors.affiliation: Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026 (PR China).
authors.forename: Yao-Bing
authors.initials: YB
authors.lastname: Huang
authors.forename: Meng-Yuan
authors.initials: MY
authors.lastname: Chen
authors.forename: Long
authors.initials: L
authors.lastname: Yan
authors.forename: Qing-Xiang
authors.initials: QX
authors.lastname: Guo
authors.forename: Yao
authors.initials: Y
authors.lastname: Fu
mesh_terms: D018533:Biomass; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D005663:Furans / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*
chemical_list: D005663:Furans; D017973:Tungsten Compounds; C510647:nickel carbide; C002802:tungsten carbide; D002244:Carbon; D009532:Nickel; C037555:2,5-dimethylfuran
keywords: biomass; heterogeneous catalysis; hydrogenolysis; nickel; platform molecules