title: Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones.
abstract: A range of highly enantioenriched primary allylic amines underwent palladium-catalyzed oxidative coupling with sulfonyl hydrazides open to air at room temperature to give structurally diverse allylic sulfones in moderate to excellent yields with excellent retention of ee.
authors.affiliation: Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China. tiansk@ustc.edu.cn.
authors.forename: Ting-Ting
authors.initials: TT
authors.lastname: Wang
authors.forename: Fu-Xiang
authors.initials: FX
authors.lastname: Wang
authors.forename: Fu-Lai
authors.initials: FL
authors.lastname: Yang
authors.forename: Shi-Kai
authors.initials: SK
authors.lastname: Tian
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D006834:Hydrazines / Q000737:chemistry*; D058451:Oxidative Coupling; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013450:Sulfones / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D000588:Amines; D006834:Hydrazines; D013450:Sulfones; C029424:hydrazine; D010165:Palladium