title: Construction of mesoporous frameworks with vanadoborate clusters.
abstract: A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.
authors.affiliation: Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, 10691 Stockholm (Sweden); Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (P.R. China).
authors.forename: Hong
authors.initials: H
authors.lastname: Chen
authors.forename: Zheng-Bao
authors.initials: ZB
authors.lastname: Yu
authors.forename: Zoltán
authors.initials: Z
authors.lastname: Bacsik
authors.forename: Huishuang
authors.initials: H
authors.lastname: Zhao
authors.forename: Qingxia
authors.initials: Q
authors.lastname: Yao
authors.forename: Junliang
authors.initials: J
authors.lastname: Sun
keywords: 3D frameworks; CO2 adsorption; cluster compounds; mesoporous materials; vanadoborates