title: Giant magnetic anisotropy and tunnelling of the magnetization in Li₂(Li(1-x)Fe(x))N.
abstract: Large magnetic anisotropy and coercivity are key properties of functional magnetic materials and are generally associated with rare earth elements. Here we show an extreme, uniaxial magnetic anisotropy and the emergence of magnetic hysteresis in Li₂(Li(1-x)Fe(x))N. An extrapolated, magnetic anisotropy field of 220 T and a coercivity field of over 11 T at 2 K outperform all known hard ferromagnets and single-molecular magnets. Steps in the hysteresis loops and relaxation phenomena in striking similarity to single-molecular magnets are particularly pronounced for x≪1 and indicate the presence of nanoscale magnetic centres. Quantum tunnelling, in the form of temperature-independent relaxation and coercivity, deviation from Arrhenius behaviour and blocking of the relaxation, dominates the magnetic properties up to 10 K. The simple crystal structure, the availability of large single crystals and the ability to vary the Fe concentration make Li₂(Li(1-x)Fe(x))N an ideal model system to study macroscopic quantum effects at elevated temperatures and also a basis for novel functional magnetic materials.
authors.affiliation: The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: A
authors.initials: A
authors.lastname: Jesche
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: R W
authors.initials: RW
authors.lastname: McCallum
authors.affiliation: The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: S
authors.initials: S
authors.lastname: Thimmaiah
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: J L
authors.initials: JL
authors.lastname: Jacobs
authors.affiliation: Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: V
authors.initials: V
authors.lastname: Taufour
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: A
authors.initials: A
authors.lastname: Kreyssig
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: R S
authors.initials: RS
authors.lastname: Houk
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: S L
authors.initials: SL
authors.lastname: Bud'ko
authors.affiliation: 1] The Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA [2] Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: P C
authors.initials: PC
authors.lastname: Canfield