title: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution.
abstract: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th(IV)vs. Ln(III); Se(IV)O3(2-)vs. I(V)O3(-)) are possible in this structure type.
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, 310 DLC, Tallahassee, Florida 32306, USA. albrecht-schmitt@chem.fsu.edu.
authors.forename: Teresa
authors.initials: T
authors.lastname: Eaton
authors.forename: Jian
authors.initials: J
authors.lastname: Lin
authors.forename: Justin N
authors.initials: JN
authors.lastname: Cross
authors.forename: Jared T
authors.initials: JT
authors.lastname: Stritzinger
authors.forename: Thomas E
authors.initials: TE
authors.lastname: Albrecht-Schmitt