title: Cerium(IV) ammonium nitrate mediated three-component α-allylation of imine surrogates.
abstract: A general and practical CAN-mediated oxidative radical α-coupling reaction of various imine surrogates with allylsilanes has been described. This multicomponent process affords β-allylated α-carbamido ethers as stable imine precursors in respectable yields under mild conditions.
authors.affiliation: Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS , 91198 Gif-sur-Yvette Cedex, France.
authors.forename: Mathieu
authors.initials: M
authors.lastname: Bekkaye
authors.forename: Géraldine
authors.initials: G
authors.lastname: Masson
mesh_terms: D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D002563:Cerium / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D009566:Nitrates / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D002219:Carbamates; D007097:Imines; D009566:Nitrates; D012821:Silanes; C532772:cerium(IV) ammonium nitrate; D002563:Cerium