title: A new one-dimensional nickel metal-organic framework: catena-poly[[[diaquabis(4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κO)nickel(II)]-μ-4,4'-bipyridine-κ(2)N:N'] monohydrate].
abstract: The title complex, {[Ni(C15H11N4O2S)2(C10H8N2)(H2O)2]·H2O}n, was synthesized by the reaction of nickel chloride, 4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoic acid (HL) and 4,4'-bipyridine (bpy) under hydrothermal conditions. The asymmetric unit contains two half Ni(II) ions, each located on an inversion centre, two L(-) ligands, one bpy ligand, two coordinated water molecules and one unligated water molecule. Each Ni(II) centre is six-coordinated by two monodentate carboxylate O atoms from two different L(-) ligands, two pyridine N atoms from two different bpy ligands and two terminal water molecules, displaying a nearly ideal octahedral geometry. The Ni(II) ions are bridged by 4,4'-bipyridine ligands to afford a linear array, with an Ni...Ni separation of 11.361 (1) Å, which is further decorated by two monodentate L(-) ligands trans to each other, resulting in a one-dimensional fishbone-like chain structure. These one-dimensional fishbone-like chains are further linked by O-H...O, O-H...N and C-H...O hydrogen bonds and π-π stacking interactions to form a three-dimensional supramolecular architecture. The thermal stability of the title complex was investigated via thermogravimetric analysis.
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
authors.forename: Aijing
authors.initials: A
authors.lastname: Geng
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
authors.forename: Qingfu
authors.initials: Q
authors.lastname: Zhang
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
authors.forename: Jiajia
authors.initials: J
authors.lastname: Wang
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
authors.forename: Haina
authors.initials: H
authors.lastname: Zhang
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.
authors.forename: Dezhi
authors.initials: D
authors.lastname: Sun
mesh_terms: D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007477:Ions / Q000737:chemistry*; D008024:Ligands; D009532:Nickel / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
chemical_list: D007477:Ions; D008024:Ligands; D011108:Polymers; D011725:Pyridines; C022838:nickel chloride; D009532:Nickel; C034306:4,4'-bipyridyl
keywords: 4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoic acid; MOFs; crystal engineering; crystal structure; hydrogen bonding; metal–organic framework; one-dimensional nickel coordination polymer; π–π stacking