title: Solvatochromic behavior of some α-styrylpyridinium dyes.
abstract: The influences of solvent polarity and substituent on the electronic transition of six different N-butyl-α-styrylpyridinium dyes have been investigated in 21 solvents. Reichardt's E(T)(30) scale has been used to propose a quantitative approach towards the relative stability of the electronic ground and excited state species. The solvents have been classified into three types and the dyes have been classified into four groups based on the contribution of field and inductive effects of the substituents towards the change in their absorption maxima values. Instead of a steady solvatochromism, all the dyes except p-nitro substituted one, suffer reversals in solvatochromism at E(T)(30) values of ~37 and ~48. The extents of contribution of non-polar and polar protic solvents towards the solvation of the excited states of the dye molecules have been determined to be 30-40% more than that towards the stability of their ground states by the dipolar aprotic solvents. The ortho effect shown by this class of dyes in contrast to their corresponding γ-isomers might have been responsible for their better solvent polarity sensing capability.
authors.affiliation: Department of Chemistry, Veer Surendra Sai University of Technology, Burla 768 018, India.
authors.forename: Sarita
authors.initials: S
authors.lastname: Tripathy
authors.affiliation: Department of Chemistry, Veer Surendra Sai University of Technology, Burla 768 018, India.
authors.forename: Partha Sarathi
authors.initials: PS
authors.lastname: Guru
authors.affiliation: Department of Chemistry, Veer Surendra Sai University of Technology, Burla 768 018, India. Electronic address: sukalyan_dash@yahoo.com.
authors.forename: Sukalyan
authors.initials: S
authors.lastname: Dash
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D011726:Pyridinium Compounds / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
chemical_list: D004396:Coloring Agents; D011726:Pyridinium Compounds; D012997:Solvents
keywords: Ortho effect; Solvatochromic switch; Solvatochromism; Styrylpyridinium dye; Substituent effect