title: One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation.
abstract: A concise and highly efficient strategy for the synthesis of N-glycosyl imidazole analogues is reported. This reaction is based on a palladium catalysed decarboxylative allylation and three steps, namely, carbamation, decarboxylation and allylation are involved. All the substrates can afford the desired products with excellent yields and selectivities.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore. xuewei@ntu.edu.sg.
authors.forename: Shaohua
authors.initials: S
authors.lastname: Xiang
authors.forename: Jingxi
authors.initials: J
authors.lastname: He
authors.forename: Jimei
authors.initials: J
authors.lastname: Ma
authors.forename: Xue-Wei
authors.initials: XW
authors.lastname: Liu
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D003653:Decarboxylation; D006031:Glycosylation; D007093:Imidazoles / Q000138:chemical synthesis*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D007093:Imidazoles; D010165:Palladium