title: A highly stable MOF with a rod SBU and a tetracarboxylate linker: unusual topology and CO2 adsorption behaviour under ambient conditions.
abstract: A Mn-based rod metal-organic framework (MOF), ROD-6, with a new lrk net is synthesized. It represents an unusual type of MOF topology containing both a 1-periodic secondary building unit (rod SBU) and a polytopic linker (here 1,3,6,8-tetrakis(p-benzoic acid)pyrene), and also exhibits high stability (up to 485 °C) and unusual CO2 uptake behaviour and selectivity despite the lack of strong interacting sites, demonstrated by the low and increasing heat of adsorption.
authors.affiliation: Department of Chemistry and Research Institute for Biomedical and Advanced Materials, Shantou University, Guangdong 515063, P.R. China. zhouxp@stu.edu.cn dli@stu.edu.cn.
authors.forename: Ru-Jin
authors.initials: RJ
authors.lastname: Li
authors.forename: Mian
authors.initials: M
authors.lastname: Li
authors.forename: Xiao-Ping
authors.initials: XP
authors.lastname: Zhou
authors.forename: Dan
authors.initials: D
authors.lastname: Li
authors.forename: Michael
authors.initials: M
authors.lastname: O'Keeffe
mesh_terms: D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D057965:Carbon Sequestration; D006358:Hot Temperature; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D000393:Air Pollutants; D009942:Organometallic Compounds; D002245:Carbon Dioxide; D008345:Manganese