title: A copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide.
abstract: A novel copper-catalyzed formal O-H insertion of α-diazo-1,3-dicarbonyl compounds to carboxylic acids has been developed, providing a straightforward synthetic method for α-acyloxy-1,3-dicarbonyl compounds, in which the activation of carboxylic acids by isocyanide plays a crucial role.
authors.affiliation: Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China. yjliang@ciac.ac.cn dwdong@ciac.ac.cn.
authors.forename: Zikun
authors.initials: Z
authors.lastname: Wang
authors.forename: Xihe
authors.initials: X
authors.lastname: Bi
authors.forename: Yongjiu
authors.initials: Y
authors.lastname: Liang
authors.forename: Peiqiu
authors.initials: P
authors.lastname: Liao
authors.forename: Dewen
authors.initials: D
authors.lastname: Dong