title: The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu.
abstract: Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.
authors.affiliation: Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133 Rome, Italy. galloni@scienze.uniroma2.it roberto.paolesse@uniroma2.it.
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Pomarico
authors.forename: Andrea
authors.initials: A
authors.lastname: Vecchi
authors.forename: Federica
authors.initials: F
authors.lastname: Mandoj
authors.forename: Olga
authors.initials: O
authors.lastname: Bortolini
authors.forename: Daniel O
authors.initials: DO
authors.lastname: Cicero
authors.forename: Pierluca
authors.initials: P
authors.lastname: Galloni
authors.forename: Roberto
authors.initials: R
authors.lastname: Paolesse
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D005296:Ferrous Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000075163:Metallocenes; D011166:Porphyrins / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D005296:Ferrous Compounds; D000075163:Metallocenes; D011166:Porphyrins; C431863:corrole; D003300:Copper; C004998:ferrocene