title: Evaluating the thermal damage resistance of graphene/carbon nanotube hybrid composite coatings.
abstract: We study laser irradiation behavior of multiwalled carbon nanotubes (MWCNT) and chemically modified graphene (rGO)-composite spray coatings for use as a thermal absorber material for high-power laser calorimeters. Spray coatings on aluminum test coupon were exposed to increasing laser irradiance for extended exposure times to quantify their damage threshold and optical absorbance. The coatings, prepared at varying mass % of MWCNTs in rGO, demonstrated significantly higher damage threshold values at 2.5 kW laser power at 10.6 μm wavelength than carbon paint or MWCNTs alone. Electron microscopy and Raman spectroscopy of irradiated specimens show that the coating prepared at 50% CNT loading endure at least 2 kW x cm(-2) for 10 seconds without significant damage. The improved damage resistance is attributed to the unique structure of the composite in which the MWCNTs act as an efficient absorber of laser light while the much larger rGO sheets surrounding them, dissipate the heat over a wider area.
authors.affiliation: 1] Mechanical and Nuclear Engineering, Kansas State University Manhattan, Kansas 66506, USA [2].
authors.forename: L
authors.initials: L
authors.lastname: David
authors.affiliation: 1] National Institute of Standards and Technology (NIST) Boulder, Colorado 80305, USA [2].
authors.forename: A
authors.initials: A
authors.lastname: Feldman
authors.affiliation: National Institute of Standards and Technology (NIST) Boulder, Colorado 80305, USA.
authors.forename: E
authors.initials: E
authors.lastname: Mansfield
authors.affiliation: National Institute of Standards and Technology (NIST) Boulder, Colorado 80305, USA.
authors.forename: J
authors.initials: J
authors.lastname: Lehman
authors.affiliation: Mechanical and Nuclear Engineering, Kansas State University Manhattan, Kansas 66506, USA.
authors.forename: G
authors.initials: G
authors.lastname: Singh