title: trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies.
abstract: The auto-oxidation of trans-1,2-disiloxybenzocyclobutene was found to be very efficient, giving endo-peroxide in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2((3)Σg) was studied by both EPR/spin trapping and theoretical studies.
authors.affiliation: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France. yannick.carissan@univ-amu.fr laurent.commeiras@univ-amu.fr jl.parain@univ-amu.fr.
authors.forename: Jean
authors.initials: J
authors.lastname: Drujon
authors.forename: Raphaël
authors.initials: R
authors.lastname: Rahmani
authors.forename: Virginie
authors.initials: V
authors.lastname: Héran
authors.forename: Romain
authors.initials: R
authors.lastname: Blanc
authors.forename: Yannick
authors.initials: Y
authors.lastname: Carissan
authors.forename: Béatrice
authors.initials: B
authors.lastname: Tuccio
authors.forename: Laurent
authors.initials: L
authors.lastname: Commeiras
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Parrain