title: Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes.
abstract: Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction. These new, inexpensive reaction conditions allow the gram-scale synthesis of α-heteroaryl carboxylic acids.
authors.affiliation: Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. junichiro@chem.nagoya-u.ac.jp.
authors.forename: Keika
authors.initials: K
authors.lastname: Hattori
authors.forename: Asraa
authors.initials: A
authors.lastname: Ziadi
authors.forename: Kenichiro
authors.initials: K
authors.lastname: Itami
authors.forename: Junichiro
authors.initials: J
authors.lastname: Yamaguchi
mesh_terms: D002384:Catalysis; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*
chemical_list: D006571:Heterocyclic Compounds; D008345:Manganese