title: Copper-mediated trifluoromethylthiolation of α-diazoesters.
abstract: A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Ling-Ling Road, Shanghai 200032, China.
authors.forename: Mingyou
authors.initials: M
authors.lastname: Hu
authors.forename: Jian
authors.initials: J
authors.lastname: Rong
authors.forename: Wenjun
authors.initials: W
authors.lastname: Miao
authors.forename: Chuanfa
authors.initials: C
authors.lastname: Ni
authors.forename: Yongxin
authors.initials: Y
authors.lastname: Han
authors.forename: Jinbo
authors.initials: J
authors.lastname: Hu
mesh_terms: D000081:Acetamides / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D001593:Benzyl Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D004952:Esters; D008745:Methylation; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*
chemical_list: D000081:Acetamides; D001391:Azo Compounds; D001593:Benzyl Compounds; D004952:Esters; D011725:Pyridines; D003300:Copper; C013959:dimethylacetamide