title: Synthesis of mesoporous silica materials from municipal solid waste incinerator bottom ash.
abstract: Incinerator bottom ash contains a large amount of silica and can hence be used as a silica source for the synthesis of mesoporous silica materials. In this study, the conditions for alkaline fusion to extract silica from incinerator bottom ash were investigated, and the resulting supernatant solution was used as the silica source for synthesizing mesoporous silica materials. The physical and chemical characteristics of the mesoporous silica materials were analyzed using BET, XRD, FTIR, SEM, and solid-state NMR. The results indicated that the BET surface area and pore size distribution of the synthesized silica materials were 992 m2/g and 2-3.8 nm, respectively. The XRD patterns showed that the synthesized materials exhibited a hexagonal pore structure with a smaller order. The NMR spectra of the synthesized materials exhibited three peaks, corresponding to Q(2) [Si(OSi)2(OH)2], Q(3) [Si(OSi)3(OH)], and Q(4) [Si(OSi)4]. The FTIR spectra confirmed the existence of a surface hydroxyl group and the occurrence of symmetric Si-O stretching. Thus, mesoporous silica was successfully synthesized from incinerator bottom ash. Finally, the effectiveness of the synthesized silica in removing heavy metals (Pb2+, Cu2+, Cd2+, and Cr2+) from aqueous solutions was also determined. The results showed that the silica materials synthesized from incinerator bottom ash have potential for use as an adsorbent for the removal of heavy metals from aqueous solutions.
authors.affiliation: Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, Taishan District, New Taipei City 24301, Taiwan, ROC. Electronic address: zsliu@mail.mcut.edu.tw.
authors.forename: Zhen-Shu
authors.initials: ZS
authors.lastname: Liu
authors.affiliation: Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, Taishan District, New Taipei City 24301, Taiwan, ROC.
authors.forename: Wen-Kai
authors.initials: WK
authors.lastname: Li
authors.affiliation: Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, Taishan District, New Taipei City 24301, Taiwan, ROC.
authors.forename: Chun-Yi
authors.initials: CY
authors.lastname: Huang
mesh_terms: D060729:Coal Ash / Q000032:analysis*; D017745:Incineration; D019216:Metals, Heavy / Q000032:analysis*; D012037:Refuse Disposal; D012822:Silicon Dioxide / Q000737:chemistry*; D062611:Solid Waste / Q000032:analysis*
chemical_list: D060729:Coal Ash; D019216:Metals, Heavy; D062611:Solid Waste; D012822:Silicon Dioxide
keywords: Adsorption; Bottom ash; Heavy metal; Mesoporous silica; Recycling