title: Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst.
abstract: In any artificial photosynthetic system, the oxidation of water to molecular oxygen provides the electrons needed for the reduction of protons or carbon dioxide to a fuel. Understanding how this four-electron reaction works in detail is important for the development of improved robust catalysts made of Earth-abundant materials, like first-row transition-metal oxides. Here, using time-resolved Fourier-transform infrared spectroscopy and under reaction conditions, we identify intermediates of water oxidation catalysed by an abundant metal-oxide catalyst, cobalt oxide (Co3O4). One intermediate is a surface superoxide (three-electron oxidation intermediate absorbing at 1,013 cm(-1)), whereas a second observed intermediate is attributed to an oxo Co(IV) site (one-electron oxidation intermediate absorbing at 840 cm(-1)). The temporal behaviour of the intermediates reveals that they belong to different catalytic sites. Knowledge of the structure and kinetics of surface intermediates will enable the design of improved metal-oxide materials for more efficient water oxidation catalysis.
authors.affiliation: Physical Biosciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720.
authors.forename: Miao
authors.initials: M
authors.lastname: Zhang
authors.affiliation: 1] Physical Biosciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720 [2].
authors.forename: Moreno
authors.initials: M
authors.lastname: de Respinis
authors.affiliation: Physical Biosciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720.
authors.forename: Heinz
authors.initials: H
authors.lastname: Frei