title: Co-catalyzed synthesis of 1,4-dicarbonyl compounds using TBHP oxidant.
abstract: A Co-catalyzed reaction for the construction of 1,4-dicarbonyls has been reported in which cascade organocobalt addition/trapping/Kornblum-DeLaMare rearrangement were involved. In view of the easy availability of starting materials, wide substrate scope, high functionality tolerance, and operational simplicity, this protocol constituted a simple, practical, and powerful alternative compared with previous approaches.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University , Suzhou 215123, China.
authors.forename: Feng
authors.initials: F
authors.lastname: Zhang
authors.forename: Peng
authors.initials: P
authors.lastname: Du
authors.forename: Jijun
authors.initials: J
authors.lastname: Chen
authors.forename: Hongxiang
authors.initials: H
authors.lastname: Wang
authors.forename: Qiang
authors.initials: Q
authors.lastname: Luo
authors.forename: Xiaobing
authors.initials: X
authors.lastname: Wan