title: Assessment of Ethidium bromide and Ethidium monoazide bromide removal from aqueous matrices by adsorption on cupric oxide nanoparticles.
abstract: The present study was undertaken to develop an effective adsorbent and to study the adsorption of Ethidium bromide and Ethidium monoazide bromide from aqueous solution using the CuO nanoparticles. The characteristics of CuO nanoparticles were determined and found to have a surface area 89.59m(2)/g. Operational parameters such as pH, contact time and adsorbent concentration, initial concentration and temperature were also studied. The amount of removal increases with the increase in pH from one to seven and reaches the maximum when the pH is nine. Adsorption data fitted well with the Langmuir, Freundlich and Florry-Huggins models. The results show that the best fit was achieved with the Langmuir isotherm equation with maximum adsorption capacities of 0.868 and 0.662mg/g for Ethidium bromide and Ethidium monoazide bromide, respectively. The adsorption process was found to follow pseudo-second-order kinetics. The calculated thermodynamic parameters, namely ΔG, ΔH and ΔS showed that adsorption of Ethidium bromide and Ethidium monoazide bromide was spontaneous and endothermic under examined conditions.
authors.affiliation: Department of Chemistry, Shahre-Qods Branch, Islamic Azad University, Tehran, Iran. Electronic address: Ali.fakhri88@yahoo.com.
authors.forename: Ali
authors.initials: A
authors.lastname: Fakhri
mesh_terms: D000327:Adsorption; D001386:Azides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004996:Ethidium / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
chemical_list: D001386:Azides; D014874:Water Pollutants, Chemical; C014535:8-azidoethidium; D003300:Copper; D004996:Ethidium; C030973:cupric oxide
keywords: Adsorption; Aqueous solution; CuO nanoparticles; Equilibrium; Ethidium bromide