title: Fractionation of (137)Cs and Pu in natural peatland.
abstract: High Cs-137 concentrations in plants growing on peatland inspired us to investigate the quantity of its bioavailable fraction in natural peat. Our investigation aims to: a) estimate the quantity of bioavailable Cs-137 and Pu present in peat, b) verify the similarity of Cs-137 and K-40 behaviours, and c) perform a quantification of Cs-137 and Pu transfer from peat to plants. We analysed the vertical distribution of Cs-137 and Pu isotopes in the peat and their concentrations in plants growing on these places. Bioavailability of radionuclides was investigated by sequential extraction. Sequential analyses revealed that it was the upper layer which contained the majority of Cs-137 in an available form while deeper layers retained Cs-137 in immobile fractions. We can conclude that 18% of all Cs-137 in the peat is still bioavailable. Despite of the low quantity of bioavailable fraction of Cs-137 its transfer factor reached extremely high values. In the case of Pu, 64% of its total amount was associated with fulvic/humic acids which resulted in the high transfer factor from peat to plants. 27 years after the Chernobyl nuclear accident, the significant part of radionuclides deposited in peatland is still bioavailable.
authors.affiliation: National Radiation Protection Institute, Bartoškova 28, 14000 Prague 4, Czech Republic. Electronic address: mihalik.radeco@gmail.com.
authors.forename: Ján
authors.initials: J
authors.lastname: Mihalík
authors.affiliation: National Radiation Protection Institute, Syllabova 21, Ostrava, Czech Republic.
authors.forename: Miluše
authors.initials: M
authors.lastname: Bartusková
authors.affiliation: National Radiation Protection Institute, Bartoškova 28, 14000 Prague 4, Czech Republic.
authors.forename: Zoltán
authors.initials: Z
authors.lastname: Hölgye
authors.affiliation: National Radiation Protection Institute, Bartoškova 28, 14000 Prague 4, Czech Republic.
authors.forename: Tereza
authors.initials: T
authors.lastname: Ježková
authors.affiliation: National Radiation Protection Institute, Bartoškova 28, 14000 Prague 4, Czech Republic.
authors.forename: Ondřej
authors.initials: O
authors.lastname: Henych
mesh_terms: D002588:Cesium Radioisotopes / Q000737:chemistry*; D005591:Chemical Fractionation / Q000379:methods*; D011005:Plutonium / Q000737:chemistry*; D011834:Radiation Monitoring; D012987:Soil / Q000737:chemistry*; D012990:Soil Pollutants, Radioactive / Q000737:chemistry*
chemical_list: D002588:Cesium Radioisotopes; D012987:Soil; D012990:Soil Pollutants, Radioactive; D011005:Plutonium
keywords: Cesium; Peat; Plutonium; Sequential extraction; Sphagnum; Vertical distribution