title: Palladium-catalyzed hydroarylation, hydroalkenylation, and hydrobenzylation of ynol ethers with organohalides: A regio- and stereoselective entry to α,β- and β,β-disubstituted alkenyl ethers.
abstract: A Pd-catalyzed reductive addition of organohalides, including aryl, alkenyl, and benzyl halides, to ynol ethers has been realized in the presence of 2-propanol, giving α,β- and β,β-disubstituted olefinic ethers in satisfactory yields with excellent regio- and stereoselectivity. It represents the first highly regio- and stereoselective hydroarylation, hydroalkenylation, and hydrobenzylation of ynol ethers.
authors.affiliation: Department of Chemistry, Zhejiang Normal University , 688 Yingbin Road, Jinhua 321004, China.
authors.forename: Weijian
authors.initials: W
authors.lastname: Cui
authors.forename: Jing
authors.initials: J
authors.lastname: Yin
authors.forename: Renwei
authors.initials: R
authors.lastname: Zheng
authors.forename: Cungui
authors.initials: C
authors.lastname: Cheng
authors.forename: Yihui
authors.initials: Y
authors.lastname: Bai
authors.forename: Gangguo
authors.initials: G
authors.lastname: Zhu