title: The bark of holm oak (Quercus ilex, L.) for airborne Cr(VI) monitoring.
abstract: In this work, the bark of holm oak was used as a bioindicator to study the atmospheric distribution of Cr(VI). The chosen method (alkaline extraction and atomic absorption determination) was found in the literature, adapted for use with the matrix involved, and validated. The method had some limits, but provided an excellent estimation of Cr(VI) concentrations with good sensitivity and a reasonable time of analysis and cost. Thirty-four samples of holm oak collected in three areas characterised by different possible sources of pollution (the area near a former chromate production plant, an urban area, and a rural "reference" area) were analysed, obtaining concentrations ranging from 1.54 to 502 μg g(-1) near the industrial plant, ranging from 0.22 to 1.35 μg g(-1) in the urban area, and mostly below the detection limit (0.04 μg g(-1)) in the rural area. The bark of holm oak proved to be a good bioindicator to detect Cr(VI) in the environment. The extraction procedure followed by atomic absorption analysis is simple, provides good sensitivity, and it is suitable for environmental studies.
authors.affiliation: Dipartimento di Farmacia (DIFAR), Università degli Studi di Genova, Viale Cembrano 4, 16148 Genova, Italy. Electronic address: minganti@difar.unige.it.
authors.forename: Vincenzo
authors.initials: V
authors.lastname: Minganti
authors.affiliation: Dipartimento di Farmacia (DIFAR), Università degli Studi di Genova, Viale Cembrano 4, 16148 Genova, Italy.
authors.forename: Giuliana
authors.initials: G
authors.lastname: Drava
authors.affiliation: Dipartimento di Farmacia (DIFAR), Università degli Studi di Genova, Viale Cembrano 4, 16148 Genova, Italy.
authors.forename: Rodolfo
authors.initials: R
authors.lastname: De Pellegrini
authors.affiliation: Dipartimento di Farmacia (DIFAR), Università degli Studi di Genova, Viale Cembrano 4, 16148 Genova, Italy.
authors.forename: Marco
authors.initials: M
authors.lastname: Anselmo
authors.affiliation: Dipartimento di Scienze della Terra, dell'Ambiente e della Vita (DISTAV), Polo Botanico "Hanbury", Università degli Studi di Genova, Corso Dogali 1 M, 16126 Genova, Italy.
authors.forename: Paolo
authors.initials: P
authors.lastname: Modenesi
authors.affiliation: Dipartimento di Scienze della Terra, dell'Ambiente e della Vita (DISTAV), Polo Botanico "Hanbury", Università degli Studi di Genova, Corso Dogali 1 M, 16126 Genova, Italy.
authors.forename: Paola
authors.initials: P
authors.lastname: Malaspina
authors.affiliation: Dipartimento di Scienze della Terra, dell'Ambiente e della Vita (DISTAV), Polo Botanico "Hanbury", Università degli Studi di Genova, Corso Dogali 1 M, 16126 Genova, Italy.
authors.forename: Paolo
authors.initials: P
authors.lastname: Giordani
mesh_terms: D000397:Air Pollution / Q000032:analysis*; D002857:Chromium / Q000032:analysis*; D003362:Cost-Benefit Analysis; D004784:Environmental Monitoring / Q000379:methods*; D024301:Plant Bark / Q000737:chemistry*; D029963:Quercus / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013054:Spectrophotometry, Atomic / Q000379:methods
chemical_list: D002857:Chromium; C074702:chromium hexavalent ion
keywords: Bioindicator; ET-AAS; Hexavalent chromium; Tree bark