title: Shape-selective deposition and assembly of anisotropic nanoparticles.
abstract: We report the large-area assembly of anisotropic gold nanoparticles into lithographically defined templates with control over their angular position using a capillary force-based approach. We elucidate the role of the geometry of the templates in the assembly of anisotropic nanoparticles consisting of different shapes and sizes. These insights allow us to design templates that immobilize individual triangular nanoprisms and concave nanocubes in a shape-selective manner and filter undesired impurity particles from a mixture of triangular prisms and other polyhedra. Furthermore, by studying the assembly of two particles in the same template, we elucidate the importance of interparticle forces in this method. These advances allow for the construction of face-to-face and edge-to-edge nanocube dimers as well as triangular nanoprism bowtie antennas. As an example of the fundamental studies enabled by this assembly method, we investigate the surface-enhanced Raman scattering (SERS) of face-to-face concave cube dimers both experimentally and computationally and reveal a strong polarization dependence of the local field enhancement.
authors.affiliation: Department of Materials Science and Engineering, Northwestern University , 2220 Campus Drive, Evanston, Illinois 60208, United States.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhou
authors.forename: Xiaozhu
authors.initials: X
authors.lastname: Zhou
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Park
authors.forename: Korosh
authors.initials: K
authors.lastname: Torabi
authors.forename: Keith A
authors.initials: KA
authors.lastname: Brown
authors.forename: Matthew R
authors.initials: MR
authors.lastname: Jones
authors.forename: Chuan
authors.initials: C
authors.lastname: Zhang
authors.forename: George C
authors.initials: GC
authors.lastname: Schatz
authors.forename: Chad A
authors.initials: CA
authors.lastname: Mirkin