title: Effects of ultrasound and temperature on copper electro reduction in Deep Eutectic Solvents (DES).
abstract: This paper concerns a preliminary study for a new copper recovery process from ionic solvent. The aim of this work is to study the reduction of copper in Deep Eutectic Solvent (choline chloride-ethylene glycol) and to compare the influence of temperature and the ultrasound effects on kinetic parameters. Solutions were prepared by dissolution of chloride copper salt CuCl2 (to obtain Copper in oxidation degree II) or CuCl (to obtain Copper in oxidation degree I) and by leaching metallic copper directly in DES. The spectrophotometry UV-visible analysis of the leached solution showed that the copper soluble form obtained is at oxidation degree I (Copper I). Both cyclic voltammetry and linear voltammetry were performed in the three solutions at three temperatures (25, 50 and 80°C) and under ultrasonic conditions (F=20kHz, PT=5.8W) to calculate the mass transfer diffusion coefficient kD and the standard rate coefficient k°. These parameters are used to determine that copper reduction is carried out via a mixed kinetic-diffusion control process. Temperature and ultrasound have the same effect on mass transfer for reduction of Cu(II)/Cu(I). On the other hand, temperature is more beneficial than ultrasound for mass transfer of Cu(I)/Cu. Standard rate constant improvement due to temperature increase is of the same order as that obtained with ultrasound. But, by combining higher temperature and ultrasound (F=20kHz, PT=5.6W at 50°C), reduction limiting current is increased by a factor of 10 compared to initial conditions (T=25°C, silent), because ultrasonic stirring is more efficient in lower viscosity fluid. These values can be considered as key-parameters in the design of copper recovery in global processes using ultrasound.
authors.affiliation: Équipe Sonochimie et Réactivité des Surfaces, Institut UTINAM, UMR CNRS 6213, Université de Bourgogne Franche Comté (UFC), 25009 Besançon, France.
authors.forename: Audrey
authors.initials: A
authors.lastname: Mandroyan
authors.affiliation: Équipe Sonochimie et Réactivité des Surfaces, Institut UTINAM, UMR CNRS 6213, Université de Bourgogne Franche Comté (UFC), 25009 Besançon, France.
authors.forename: Mahmoud
authors.initials: M
authors.lastname: Mourad-Mahmoud
authors.affiliation: Équipe Sonochimie et Réactivité des Surfaces, Institut UTINAM, UMR CNRS 6213, Université de Bourgogne Franche Comté (UFC), 25009 Besançon, France.
authors.forename: Marie-Laure
authors.initials: ML
authors.lastname: Doche
authors.affiliation: Équipe Sonochimie et Réactivité des Surfaces, Institut UTINAM, UMR CNRS 6213, Université de Bourgogne Franche Comté (UFC), 25009 Besançon, France. Electronic address: jean-yves.hihn@univ-fcomte.fr.
authors.forename: Jean-Yves
authors.initials: JY
authors.lastname: Hihn
keywords: Copper electrodeposition; Deep Eutectic Solvent; Electrochemistry; Power ultrasound