title: Surface-junction effects on interfacial electron transfer between bis(terpyridine)iron(II) and hydrogen-terminated silicon(111) electrode.
abstract: Interfacial electron transfer at bis(tpy)–iron(II) complexes (tpy=2,2’:6’,2’’-terpyridine) on Si(111) electrodes was investigated by using four types of surfaceanchor terpyridine ligands. Despite the greater distance, electron transfer between the bis(tpy)–iron(II) unit and the electrode is accelerated in surface-anchor ligands with an additional phenylene group.
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Maeda
authors.forename: Ryota
authors.initials: R
authors.lastname: Sakamoto
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nishihara