title: Electrochemical modulation of SERS at the liquid/liquid interface.
abstract: A surface enhanced Raman scattering system to detect silver nanoparticle adsorption at the water|1,2-dichlorobenzene interface is reported. The Raman response as a function of distance on either side of the interface reveals a reproducible spatial variation, which is potential dependent for a number of adsorption and desorption cycles.
authors.affiliation: Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK. robert.dryfe@manchester.ac.uk.
authors.forename: Samuel G
authors.initials: SG
authors.lastname: Booth
authors.forename: David P
authors.initials: DP
authors.lastname: Cowcher
authors.forename: Royston
authors.initials: R
authors.lastname: Goodacre
authors.forename: Robert A W
authors.initials: RA
authors.lastname: Dryfe
mesh_terms: D002722:Chlorobenzenes / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000295:instrumentation; D053768:Metal Nanoparticles / Q000737:chemistry; D012834:Silver / Q000737:chemistry; D013059:Spectrum Analysis, Raman; D014867:Water / Q000737:chemistry*
chemical_list: D002722:Chlorobenzenes; D014867:Water; D012834:Silver; C004726:2-dichlorobenzene