title: Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes.
abstract: A copper-mediated trifluoromethylation of propargyl acetates with S-(trifluoromethyl)diphenylsulfonium triflate leading to trifluoromethylated allenes in moderate to excellent yields is described.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. jlin@sioc.ac.cn jchxiao@sioc.ac.cn.
authors.forename: Yun-Long
authors.initials: YL
authors.lastname: Ji
authors.forename: Jun-Jie
authors.initials: JJ
authors.lastname: Kong
authors.forename: Jin-Hong
authors.initials: JH
authors.lastname: Lin
authors.forename: Ji-Chang
authors.initials: JC
authors.lastname: Xiao
authors.forename: Yu-Cheng
authors.initials: YC
authors.lastname: Gu
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000466:Alkadienes / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D017611:Fluorine Compounds / Q000737:chemistry*; D008745:Methylation; D010293:Pargyline / Q000737:chemistry*
chemical_list: D000085:Acetates; D000466:Alkadienes; D002712:Chlorides; D004952:Esters; D017611:Fluorine Compounds; C025947:propadiene; D003300:Copper; D010293:Pargyline