title: Computationally Efficient Steady-State Solution of the Bloch Equations for Rapid Sinusoidal Scans Based on Fourier Expansion in Harmonics of the Scan Frequency.
abstract: Rapid-scan EPR has been shown to improve the signal-to-noise ratio relative to conventional continuous wave spectroscopy. Equations are derived for the steady-state solution to the Bloch equations as a Fourier expansion in the harmonics of the scan frequency. This simulation method is about two orders of magnitude faster than time-domain numerical integration.
authors.affiliation: Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208.
authors.forename: Mark
authors.initials: M
authors.lastname: Tseitlin
authors.affiliation: Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208.
authors.forename: Gareth R
authors.initials: GR
authors.lastname: Eaton
authors.affiliation: Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208.
authors.forename: Sandra S
authors.initials: SS
authors.lastname: Eaton