title: Graphene size control via a mechanochemical method and electroresponsive properties.
abstract: Highly dispersible graphene oxide (GO) sheets of uniform submicrometer size were successfully fabricated from pristine graphite using a simple mechanochemical process. The GO flake morphology was transformed into a spherical form, and the density was decreased slightly via the ball-milling process. Ball-milled GO can be used as an electrorheological (ER) material because of its small particle size, low conductivity, and outstanding dispersibility in silicone oil. We found that the 2-h ball-milled GO-based ER fluid had the best ER performance (shear stress of 78.5 Pa and 630% ER efficiency), which was double that of the nonmilled GO-based ER fluid. The response time to form a fibrillar structure along the applied electric field direction and the recovery time to the starting level decreased with increasing ball-milling time. Additionally, the retarded settling velocity of isolated GO sheets and the electrostatic repulsion between oxygen functional groups on the GO sheets combined to improve the antisedimentation property. The ability to control the size of graphene sheets is a great opportunity to advance graphene commercialization in a high-quality, scalable production setting.
authors.affiliation: World Class University (WCU) Program of Chemical Convergence for Energy & Environment (C2E2), School of Chemical and Biological Engineering, Seoul National University , 599 Gwanangno, Gwanakgu, Seoul 151-742, Korea.
authors.forename: Keun-Young
authors.initials: KY
authors.lastname: Shin
authors.forename: Seungae
authors.initials: S
authors.lastname: Lee
authors.forename: Seunghee
authors.initials: S
authors.lastname: Hong
authors.forename: Jyongsik
authors.initials: J
authors.lastname: Jang