title: A robust, catalytic metal-organic framework with open 2,2'-bipyridine sites.
abstract: We report two synthetic approaches to prepare a highly crystalline Zr(IV)-based metal-organic framework (MOF) containing open 2,2'-bipyridine (bpy) chelating sites. The resulting UiO-67-bpydc readily forms complexes with PdCl2 to produce a MOF that exhibits efficient and recyclable catalytic activity for the Suzuki-Miyaura cross-coupling reaction.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
authors.forename: Honghan
authors.initials: H
authors.lastname: Fei
authors.forename: Seth M
authors.initials: SM
authors.lastname: Cohen
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry* / Q000378:metabolism; D002384:Catalysis; D008958:Models, Molecular; D010165:Palladium / Q000737:chemistry* / Q000378:metabolism; D015040:Zirconium / Q000737:chemistry* / Q000378:metabolism
chemical_list: D015082:2,2'-Dipyridyl; D010165:Palladium; D015040:Zirconium; C008756:palladium chloride