title: Synthesis, crystal structure, fluorescence and electrochemical studies of a new tridentate Schiff base ligand and its nickel(II) and palladium(II) complexes.
abstract: A new unsymmetrical tridentate Schiff base ligand was derived from the 1:1M condensation of ortho-vanillin with 2-mercaptoethylamine. Nickel and palladium complexes were obtained by the reaction of the tridentate Schiff base ligand with nickel(II) acetate tetrahydrate and palladium(II) acetate in 2:1M ratio. In nickel and palladium complexes the ligand was coordinated to metals via the imine N and enolic O atoms. The S groups of Schiff bases were not coordinated to the metals and S-S coupling was occured. The complexes have been found to possess 1:2 Metal:Ligand stoichiometry and the molar conductance data revealed that the metal complexes were non-electrolytes. The complexes exhibited octahedral coordination geometry. The emission spectra of the ligand and its complexes were studied in methanol. Electrochemical properties of the ligand and its metal complexes were investigated in the CH3CN solvent at the 100 mV s(-1) scan rate. The ligand and metal complexes showed both reversible and quasi-reversible processes at this scan rate. The Schiff base and its complexes have been characterized by IR, (1)H NMR, UV/Vis, elemental analyses and conductometry. The crystal structure of nickel complex has been determined by single crystal X-ray diffraction.
authors.affiliation: School of Chemistry, Damghan University, Damghan 3671641167, Iran. Electronic address: shafaatian@du.ac.ir.
authors.forename: Bita
authors.initials: B
authors.lastname: Shafaatian
authors.affiliation: School of Chemistry, Damghan University, Damghan 3671641167, Iran.
authors.forename: Ahmad
authors.initials: A
authors.lastname: Soleymanpour
authors.affiliation: School of Chemistry, Damghan University, Damghan 3671641167, Iran.
authors.forename: Nasim
authors.initials: N
authors.lastname: Kholghi Oskouei
authors.affiliation: Chemistry Department, Shahid Beheshti University, G.C., Evin, Tehran 1983963113, Iran.
authors.forename: Behrouz
authors.initials: B
authors.lastname: Notash
authors.affiliation: School of Chemistry, Damghan University, Damghan 3671641167, Iran.
authors.forename: Seyyed Ahmad
authors.initials: SA
authors.lastname: Rezvani
mesh_terms: D018360:Crystallography, X-Ray; D003543:Cysteamine / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D012545:Schiff Bases / Q000138:chemical synthesis* / Q000737:chemistry; D013053:Spectrophotometry
chemical_list: D012545:Schiff Bases; D010165:Palladium; D003543:Cysteamine; D009532:Nickel
keywords: Electrochemistry; Nickel(II) complex; Palladium(II) complex; Schiff base; Tridentate; Unsymmetrical