title: Structural and electronic properties of TM(n)[(BN)(3)H(6)](m) complexes with TM = Co (n, m = 1-3) and with TM = Fe, Ni, Ru, Rh, Pd (n = m = 1-3).
abstract: Using the density functional method with the generalized gradient approximation for the exchange and correlation, we investigated the geometrical and electronic properties of free-standing complexes of Con clusters combined with hydrogen-saturated boron-nitrogen (BN) rings [(BN)3H6]m. The Co atoms tend to form a subcluster capped by BN rings that preserve the Co subcluster against the environment and with which they weakly interact. Thus, the Co subcluster is capable of sustaining a noticeable magnetic moment. These facts are relevant for designing grains with localized magnetic moments. We also optimized those TMn[(BN)3H6]n complexes with n = 1-3 and TM = Fe, Ni, Ru, Rh, and Pd, starting with the ground-state geometry obtained previously for TM = Co, in order to analyze the dependence of the electronic properties with the number of d electrons in the transition-metal atoms.
authors.affiliation: Instituto de Fı́sica, Universidad Autónoma de San Luis Potosı́ , San Luis Potosı́, México.
authors.forename: F
authors.initials: F
authors.lastname: Aguilera-Granja
authors.forename: R H
authors.initials: RH
authors.lastname: Aguilera-del-Toro
authors.forename: A
authors.initials: A
authors.lastname: Vega
authors.forename: L C
authors.initials: LC
authors.lastname: Balbás