title: Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: charge-transfer interaction and remarkable high ambipolar transport characteristics.
abstract: A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm(2) V(-1) s(-1) , respectively.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China; University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
authors.forename: Yunke
authors.initials: Y
authors.lastname: Qin
authors.forename: Jing
authors.initials: J
authors.lastname: Zhang
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: Zheng
authors.forename: Hua
authors.initials: H
authors.lastname: Geng
authors.forename: Guangyao
authors.initials: G
authors.lastname: Zhao
authors.forename: Wei
authors.initials: W
authors.lastname: Xu
authors.forename: Wenping
authors.initials: W
authors.lastname: Hu
authors.forename: Zhigang
authors.initials: Z
authors.lastname: Shuai
authors.forename: Daoben
authors.initials: D
authors.lastname: Zhu
keywords: ambipolar transport; charge-transfer complexes; co-crystals; field-effect transistor