title: Generalized net analyte signal standard addition as a novel method for simultaneous determination: application in spectrophotometric determination of some pesticides.
abstract: Simultaneous spectrophotometric determination of three neonicotinoid insecticides (acetamiprid, imidacloprid, and thiamethoxam) by a novel method named generalized net analyte signal standard addition method (GNASSAM) in some binary and ternary synthetic mixtures was investigated. For this purpose, standard addition was performed using a single standard solution consisting of a mixture of standards of all analytes. Savings in time and amount of used materials are some of the advantages of this method. All determinations showed appropriate applicability of this method with less than 5% error. This method may be applied for linearly dependent data in the presence of known interferents. The GNASSAM combines the advantages of both the generalized standard addition method and net analyte signal; therefore, it may be a proper alternative for some other multivariate methods.
authors.forename: Karim
authors.initials: K
authors.lastname: Asadpour-Zeynali
authors.forename: Elhameh
authors.initials: E
authors.lastname: Saeb
authors.forename: Javad
authors.initials: J
authors.lastname: Vallipour
authors.forename: Mehdi
authors.initials: M
authors.lastname: Bamorowat
mesh_terms: D004785:Environmental Pollutants / Q000737:chemistry; D005163:Factor Analysis, Statistical; D007093:Imidazoles / Q000737:chemistry*; D007306:Insecticides / Q000737:chemistry*; D000073943:Neonicotinoids; D009574:Nitro Compounds / Q000737:chemistry*; D010078:Oxazines / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*; D000077922:Thiamethoxam; D013844:Thiazoles / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D007093:Imidazoles; D007306:Insecticides; D000073943:Neonicotinoids; D009574:Nitro Compounds; D010078:Oxazines; D011725:Pyridines; D013844:Thiazoles; C082359:imidacloprid; C464485:acetamiprid; D000077922:Thiamethoxam