title: A dynamic study of the structural change in the binary network in response to guest inclusion.
abstract: In the present work flexible binary networks of 1,3,5-benzenetricarboxylic acid (TMA) with 4,4'-bipyridine (Bpy) or 1,3,5-tris(4-pyridyl)-2,4,6-triazine(TPTZ) molecules at the liquid-solid interface were constructed. When coronene (COR) molecules are introduced into these systems, the binary networks collapse and at the same time, new COR/TMA host-guest structures are formed. Both experiments and calculations unambiguously indicate that the COR/TMA host-guest complex structure has stronger adsorption energy, resulting in the deconstruction-reconstruction phenomenon.
authors.affiliation: CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, the Chinese Academy of Sciences, Beijing 100049, P. R. China. zwei@ihep.ac.cn.
authors.forename: Min
authors.initials: M
authors.lastname: Li
authors.forename: Peng
authors.initials: P
authors.lastname: Xie
authors.forename: Ke
authors.initials: K
authors.lastname: Deng
authors.forename: Yan-Lian
authors.initials: YL
authors.lastname: Yang
authors.forename: Sheng-Bin
authors.initials: SB
authors.lastname: Lei
authors.forename: Zhong-Qing
authors.initials: ZQ
authors.lastname: Wei
authors.forename: Qing-Dao
authors.initials: QD
authors.lastname: Zeng
authors.forename: Chen
authors.initials: C
authors.lastname: Wang