Engineering self-assembled N-doped graphene-carbon nanotube composites towards efficient oxygen reduction electrocatalysts.
The importance of the oxygen reduction reaction (ORR) in fuel cells and high energy density metal-air batteries has attracted intense research interests in looking for low-cost ORR catalysts as substitutes for expensive and scarce Pt-based catalysts. N-doped graphene and carbon nanotubes prepared in a low-cost and scalable way have demonstrated their potential although the performance still needs to be improved. In view of the requirements for a high-performance ORR electrocatalyst, this work focused on developing the nanocomposites of N-doped reduced graphene oxide (N-rGO) and N-doped carbon nanotubes (N-CNT) as low-cost efficient ORR catalysts by integrating the advantages of abundant highly-active sites from N-rGO and a three-dimensional conductive network for efficient mass and electron transport from N-CNT. By optimizing the preparation method and dedicatedly tuning the composition, the much enhanced ORR activity and superior durability and tolerance to methanol were achieved for the self-assembled N-doped composite (N-rGO-CNT) at a mass ratio of 1 : 5 rGO/CNT. Further improvement of the ORR electrocatalytic activity of the composite was also demonstrated by introducing iron into the composite.
State Key Laboratory of Power Transmission Equipment & System Security and New Technology, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China. zdwei@cqu.edu.cn.
Yun
Y
Zhang
Wen-Jie
WJ
Jiang
Xing
X
Zhang
Lin
L
Guo
Jin-Song
JS
Hu
Zidong
Z
Wei
Li-Jun
LJ
Wan