A singlet ground state for a cobalt(II)-anilinosalen radical complex.
The cobalt(II) anilinosalen complex [Co(II)(L)] was prepared and subsequently oxidized by one electron. The resulting cation comprises a square planar low spin Co(II) ion anti-ferromagnetically exchange coupled to an anilinyl radical.
Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (CIRE) - UMR CNRS 5250, Université J. Fourier, B. P. 53, 38041 Grenoble cedex 9, France. Fabrice.Thomas@ujf-grenoble.fr.
Amélie
A
Kochem
Gisèle
G
Gellon
Olivier
O
Jarjayes
Christian
C
Philouze
Nicolas
N
Leconte
Maurice
M
van Gastel
Eckhard
E
Bill
Fabrice
F
Thomas
D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry*; D008968:Molecular Conformation; D011789:Quantum Theory
D056831:Coordination Complexes; D005029:Ethylenediamines; D005609:Free Radicals; D003035:Cobalt; C011452:disalicylaldehyde ethylenediamine