Investigation of the scaling law on gelation of oppositely charged nanocrystalline cellulose and polyelectrolyte.
The sol-gel transition in the mixture system of oppositely charged polyelectrolyte (quaternized hydroxyethylcellulose ethoxylate, QHEC) and nanocrystalline cellulose (NCC) induced by electrostatic adsorption interaction was investigated by rheological means. Winter and Chambon theory was validated to be applicable for the critical gel point determination, and critical gel point have been successfully determined. With QHEC concentration increasing, more NCC were needed to form a critical gel, and smaller loss tangent and relaxation exponent (n) values at the gel point were observed, indicating the elastic nature of mixture was enhanced with QHEC increase. Gel strength behaved as a function of both QHEC and NCC concentrations, suggesting the gel network at the critical point was composed of entanglements and association of QHEC macromolecular chains, as well as the electrostatic adsorption interaction between QHEC chains and NCC rods. The calculated number of NCC rods per junction decreased from 0.30 to 0.01 when the QHEC concentration increased from 1.0wt% to 3.0wt%, indicating the electrostatic adsorption interaction between the NCC rods and QHEC chains was less significant to gel formation at higher QHEC concentrations. Therefore, the exponents of scaling law η0∝ϵ(-γ) and Ge∝ϵ (z) for the QHEC/NCC mixtures revealed that the scaling law n=z/(z+γ) between n, γ, and z was only feasible at highest QHEC concentration, since the intermolecular interaction (electrostatic adsorption interaction in this article) was so weak that can be neglected and the critical gel network was dominated by QHEC chain entanglements and association.
Department of Civil and Environmental Engineering, University of Alberta, Edmonton, Alberta T6G 2G2, Canada; Department of Chemistry, Wuhan University, Wuhan, 430072, China.
Ang
A
Lu
Department of Agricultural, Food and Nutritional Science, University of Alberta, Edmonton, Alberta T6G 2P5, Canada.
Yixiang
Y
Wang
Department of Civil and Environmental Engineering, University of Alberta, Edmonton, Alberta T6G 2G2, Canada; National Institute for Nanotechnology, National Research Council of Canada, Edmonton, Alberta T6G 2M9, Canada. Electronic address: yaman.boluk@ualberta.ca.
Yaman
Y
Boluk
D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry; D005782:Gels / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D044367:Phase Transition; D012212:Rheology; D055672:Static Electricity
D005782:Gels; C531250:hydroxyethyl cellulose ethoxylate; D002482:Cellulose
Gelation; Nanocrystalline cellulose; Opposite charge