An unprecedented cyclometallated platinum(II) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour.
The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.
UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire (UMR 8232), 4 place Jussieu, 75252 Paris Cedex 05, France. jamal.moussa@upmc.fr hani.amouri@upmc.fr.
Jamal
J
Moussa
Thomas
T
Cheminel
Gemma R
GR
Freeman
Lise-Marie
LM
Chamoreau
J A Gareth
JA
Williams
Hani
H
Amouri