Cleavage of C-C and C-Si σ-bonds and their intramolecular exchange.
C-C and C-Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University , Katsura, Kyoto 615-8510, Japan.
Naoki
N
Ishida
Wataru
W
Ikemoto
Masahiro
M
Murakami