Anodic oxidation of benzoquinone using diamond anode.
The anodic degradation of 1,4-benzoquinone (BQ), one of the most toxic xenobiotic, was investigated by electrochemical oxidation at boron-doped diamond anode. The electrolyses have been performed in a single-compartment flow cell in galvanostatic conditions. The influence of applied current (0.5-2 A), BQ concentration (1-2 g dm(-3)), temperature (20-45 °C) and flow rate (100-300 dm(3) h(-1)) has been studied. BQ decay kinetic, the evolution of its oxidation intermediates and the mineralization of the aqueous solutions were monitored during the electrolysis by high-performance liquid chromatograph (HPLC) and chemical oxygen demand (COD) measurements. The results obtained show that the use of diamond anode leads to total mineralization of BQ in any experimental conditions due to the production of oxidant hydroxyl radicals electrogenerated from water discharge. The decay kinetics of BQ removal follows a pseudo-first-order reaction, and the rate constant increases with rising current density. The COD removal rate was favoured by increasing of applied current, recirculating flow rate and it is almost unaffected by solution temperature.
Department of Civil, Chemical and Environmental Engineering, University of Genoa, P.le J.F. Kennedy 1, 16129, Genoa, Italy, marco.panizza@unige.it.
Marco
M
Panizza
D016227:Benzoquinones / Q000737:chemistry*; D057919:Biological Oxygen Demand Analysis; D001895:Boron / Q000737:chemistry; D018130:Diamond / Q000737:chemistry*; D004566:Electrodes; D004572:Electrolysis; D017665:Hydroxyl Radical / Q000737:chemistry*; D007700:Kinetics; D016877:Oxidants / Q000737:chemistry*; D010084:Oxidation-Reduction; D013696:Temperature; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods
D016227:Benzoquinones; D016877:Oxidants; D014874:Water Pollutants, Chemical; D017665:Hydroxyl Radical; C004532:quinone; D018130:Diamond; D001895:Boron