Effects of igneous intrusion on microporosity and gas adsorption capacity of coals in the Haizi Mine, China.
This paper describes the effects of igneous intrusions on pore structure and adsorption capacity of the Permian coals in the Huaibei Coalfield, China. Twelve coal samples were obtained at different distances from a ~120 m extremely thick sill. Comparisons were made between unaltered and heat-affected coals using geochemical data, pore-fracture characteristics, and adsorption properties. Thermal alteration occurs down to ~1.3 × sill thickness. Approaching the sill, the vitrinite reflectance (R(o)) increased from 2.30% to 2.78%, forming devolatilization vacuoles and a fine mosaic texture. Volatile matter (VM) decreased from 17.6% to 10.0% and the moisture decreased from 3.0% to 1.6%. With decreasing distance to the sill, the micropore volumes initially increased from 0.0054 cm(3)/g to a maximum of 0.0146 cm(3)/g and then decreased to 0.0079 cm(3)/g. The results show that the thermal evolution of the sill obviously changed the coal geochemistry and increased the micropore volume and adsorption capacity of heat-affected coal (60-160 m from the sill) compared with the unaltered coals. The trap effect of the sill prevented the high-pressure gas from being released, forming gas pocket. Mining activities near the sill created a low pressure zone leading to the rapid accumulation of methane and gas outbursts in the Haizi Mine.
Faculty of Safety Engineering, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China ; National Engineering Research Center for Coal & Gas Control, China University of Mining & Technology, Xuzhou 221008, China ; Post-Doctoral Research Station, Yima Mining Corporation Limited, Sanmenxia, Henan 472300, China.
Jingyu
0000-0003-4197-0858
J
Jiang
Faculty of Safety Engineering, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China ; National Engineering Research Center for Coal & Gas Control, China University of Mining & Technology, Xuzhou 221008, China.
Yuanping
0000-0002-3743-3569
Y
Cheng
D000327:Adsorption; D002681:China; D003031:Coal; D005740:Gases / Q000737:chemistry*; D016062:Porosity
D003031:Coal; D005740:Gases