A supramolecular Co(II)14-metal-organic cube in a hydrogen-bonded network and a Co(II)-organic framework with a flexible methoxy substituent.
The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, and a hydrogen-bonded network consisting of tetradecanuclear Co(ii)14-metal organic cube () are achieved. shows the bcu net with 14 cobalt atoms.
Institut für Chemie, Anorganische Chemie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, 14476 Potsdam, Germany. holdt@uni-potsdam.de.
Suvendu Sekhar
SS
Mondal
Asamanjoy
A
Bhunia
Alexandra
A
Kelling
Uwe
U
Schilde
Christoph
C
Janiak
Hans-Jürgen
HJ
Holdt