Understanding the synthetic pathway of a single-phase quarternary semiconductor using surface-enhanced Raman scattering: a case of wurtzite Cu₂ZnSnS₄ nanoparticles.
Single-phase Cu2ZnSnS4 (CZTS) is an essential prerequisite toward a high-efficiency thin-film solar cell device. Herein, the selective phase formation of single-phase CZTS nanoparticles by ligand control is reported. Surface-enhanced Raman scattering (SERS) spectroscopy is demonstrated for the first time as a characterization tool for nanoparticles to differentiate the mixed compositional phase (e.g., CZTS, CTS, and ZnS), which cannot be distinguished by X-ray diffraction. Due to the superior selectivity and sensitivity of SERS, the growth mechanism of CZTS nanoparticle formation by hot injection is revealed to involve three growth steps. First, it starts with nucleation of Cu(2-x)S nanoparticles, followed by diffusion of Sn(4+) into Cu(2-x)S nanoparticles to form the Cu3SnS4 (CTS) phase and diffusion of Zn(2+) into CTS nanoparticles to form the CZTS phase. In addition, it is revealed that single-phase CZTS nanoparticles can be obtained via balancing the rate of CTS phase formation and diffusion of Zn(2+) into the CTS phase. We demonstrate that this balance can be achieved by 1 mL of thiol with Cu(OAc)2, Sn(OAc)4, and Zn(acac)2 metal salts to synthesize the CZTS phase without the presence of a detectable binary/ternary phase with SERS.
Interdisciplinary Graduate School, ‡Energy Research Institute, §Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ∥School of Material Science and Engineering, Nanyang Technological University , Singapore 639798.
Joel Ming Rui
JM
Tan
Yih Hong
YH
Lee
Srikanth
S
Pedireddy
Tom
T
Baikie
Xing Yi
XY
Ling
Lydia Helena
LH
Wong