Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates.
A series of tripodal alcohols substituted Anderson-type polyoxometalates (POMs) including mono-substituted (compounds and ), asymmetrical bi-substituted (compound ), and symmetrical bi-substituted ones (compounds and ) have been synthesized under hydrothermal conditions using a pre-designed step-by-step strategy, and compounds , and have been fully characterized by single-crystal X-ray diffraction, ESI-MS, and elemental analysis.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China. songyufei@hotmail.com songyf@mail.buct.edu.cn.
Chang-Gen
CG
Lin
Wei
W
Chen
De-Liang
DL
Long
Leroy
L
Cronin
Yu-Fei
YF
Song
D002857:Chromium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D002857:Chromium; D009942:Organometallic Compounds; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates