Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry.
A versatile strategy to prepare fac-[M(I)(CO)3](+) and cis-[M(I)(CO)2](+) (M = Re, (99m)Tc) complexes was developed using Huisgen click chemistry and monodentate phosphine ligands to readily incorporate biomolecules and tailor the chemical properties.
Washington State University, 100 Dairy Rd, Pullman, WA, USA. bennyp@wsu.edu.
Thomas R
TR
Hayes
Benjamin B
BB
Kasten
Charles L
CL
Barnes
Paul D
PD
Benny
D057930:Click Chemistry; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008968:Molecular Conformation; D010720:Phosphines / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*; D013667:Technetium / Q000737:chemistry*
D056831:Coordination Complexes; D008024:Ligands; D010720:Phosphines; D012211:Rhenium; D013667:Technetium; C044646:phosphine