Superporous thermo-responsive hydrogels by combination of cellulose fibers and aligned micropores.
In the area of artificial hydrogels, simultaneous engineering of the volume transition characteristics and mechanical properties of stimuli-responsive hydrogels is an important subject. By unrestricted architecting of hierarchical structures, natural hydrogels are able to provide a wide range of swelling and mechanical properties, beyond the limits of artificial hydrogels. Herein, a combination of nanostructures and microstructures was developed to construct superporous hydrogels. Fibers of microfibrillated cellulose (MFC), an eco-friendly reinforcing material, were used as nanostructures, aligned micropores were used as microstructures, and in situ photopolymerization was used to immobilize the two structures together within the gel networks of poly(N-isopropyl acrylamide) (PNIPAm). The introduction of MFC distinctly enhanced volume transition, mainly by decreasing the swelling ratios above the transition. The introduction of directional micropores increased the swelling ratio below the transition and decreased the swelling ratio above the transition, thereby also enhancing the volume transition. Additionally, the formation of aligned micropores achieved fast water infiltration, which is beneficial for superabsorbent applications. The introduction of aligned micropores reduced the elastic modulus, but this could partially be compensated for by reinforcement with MFC. This combination of crystalline nanofibers and aligned micropores has great potential for the development of stimuli-responsive superporous hydrogels outperforming current artificial hydrogels.
Department of Chemical Engineering and Material Science, Chung-Ang University, Seoul 156-756, South Korea.
Kantappa S
KS
Halake
Department of Chemical Engineering and Material Science, Chung-Ang University, Seoul 156-756, South Korea. Electronic address: jong@cau.ac.kr.
Jonghwi
J
Lee
D000180:Acrylic Resins / Q000737:chemistry*; D002482:Cellulose / Q000737:chemistry* / Q000648:ultrastructure; D005615:Freezing; D020100:Hydrogels / Q000737:chemistry*; D057139:Nanofibers / Q000737:chemistry* / Q000648:ultrastructure; D016062:Porosity; D013696:Temperature; D014867:Water / Q000737:chemistry*
D000180:Acrylic Resins; D020100:Hydrogels; D014867:Water; C052970:poly-N-isopropylacrylamide; D002482:Cellulose
Composite; Directional freezing; Microfibrillated cellulose; Micropore; Responsive hydrogel; Superabsorbent; Superporous hydrogel