Dehydration-triggered magnetic phase conversion in the porous Cu(II)Mn(III) metal-organic framework.
Dehydration of the three-dimensional Cu(II)-Mn(III) coordination network undergoes a dramatic magnetic phase transformation from a paramagnetic state to a long-range magnetic ordered phase with glassy behavior. The gas adsorption behavior and re-entrant spin glass character are uniquely apparent in the dehydrated sample.
Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea. cshong@korea.ac.kr.
Dae Won
DW
Ryu
Jin Ho
JH
Shin
Kwang Soo
KS
Lim
Woo Ram
WR
Lee
Won Ju
WJ
Phang
Sung Won
SW
Yoon
Byoung Jin
BJ
Suh
Eui Kwan
EK
Koh
Chang Seop
CS
Hong
D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D003681:Dehydration; D005029:Ethylenediamines / Q000737:chemistry; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D016062:Porosity; D013696:Temperature
D056831:Coordination Complexes; D005029:Ethylenediamines; D009930:Organic Chemicals; D008345:Manganese; D003300:Copper; C011452:disalicylaldehyde ethylenediamine