title: Improvement in day zero recoveries in field soil dissipation studies using larger diameter soil samples.
abstract: Obtaining acceptable recovery of the applied test substance at zero time in field soil dissipation studies has been a subject of considerable interest among scientists conducting regulatory field studies. In particular, achieving recoveries of ≥90% in soil samples collected immediately after applications in most studies has been elusive. This study investigated a modified soil sampling method, which could be used not only on day zero but for the entire study duration, to see if the recoveries in soil samples, especially in the early stages, can be improved. The modified sampling system has demonstrated that recoveries averaging 90% are possible and can be routinely obtained on day zero. Description of this modified sampling procedure and statistical analysis of the data collected for day zero samples are discussed.
authors.affiliation: Stine Haskell Research Center, E. I. DuPont de Nemours and Co., Newark, Delaware 19711, United States.
authors.forename: Ashok K
authors.initials: AK
authors.lastname: Sharma
authors.forename: Harry J
authors.initials: HJ
authors.lastname: Strek
authors.forename: Aldos C
authors.initials: AC
authors.lastname: Barefoot
mesh_terms: D053000:Analytic Sample Preparation Methods / Q000295:instrumentation* / Q000379:methods; D004784:Environmental Monitoring / Q000295:instrumentation* / Q000379:methods; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D012987:Soil; D012989:Soil Pollutants
keywords: day zero recoveries; field dissipation studies; large diameter soil cores