title: Chiral single-chain magnet: helically stacked [Mn(III)2Cu(II)] triangles.
abstract: The one-dimensional complex [Mn(III)2Cu(II)(μ3-O)(Cl-sao)3(EtOH)2]·EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[Mn(III)3(μ3-O)Cl2(Cl-sao)3(MeOH)2(H2O)2] with [Cu(acac)2]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba , Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Shiga
authors.forename: Kazuya
authors.initials: K
authors.lastname: Maruyama
authors.forename: Graham N
authors.initials: GN
authors.lastname: Newton
authors.forename: Ross
authors.initials: R
authors.lastname: Inglis
authors.forename: Euan K
authors.initials: EK
authors.lastname: Brechin
authors.forename: Hiroki
authors.initials: H
authors.lastname: Oshio