title: Cyanoborohydride-based ionic liquids as green aerospace bipropellant fuels.
abstract: In propellant systems, the most common bipropellants are composed of two chemicals, a fuel (or reducer) and an oxidizer. Currently, the choices for propellant fuels rely mainly on hydrazine and its methylated derivatives, even though they are extremely toxic, highly volatile, sensitive to adiabatic compression (risk of detonation), and, therefore, difficult to handle. With this background, the search for alternative green propellant fuels has been an urgent goal of space science. In this study, a new family of cyanoborohydride-based ionic liquids (ILs) with properties and performances comparable to hydrazine derivatives were designed and synthesized. These new ILs as bipropellant fuels, have some unique advantages including negligible vapor pressure, ultra-short ignition delay (ID) time, and reduced synthetic and storage costs, thereby showing great application potential as environmentally friendly fuels in bipropellant formulations.
authors.affiliation: Institute of Chemical Materials, China Academy of Engineering Physics (CAEP), Mianyang, 621900 (P.R. China). wfqinghua@licp.cas.cn.
authors.forename: Qinghua
authors.initials: Q
authors.lastname: Zhang
authors.forename: Ping
authors.initials: P
authors.lastname: Yin
authors.forename: Jiaheng
authors.initials: J
authors.lastname: Zhang
authors.forename: Jean'ne M
authors.initials: JM
authors.lastname: Shreeve
keywords: green chemistry; hypergolic fuels; ignition delay; ionic liquids; propellants