title: One-dimensional silicone nanofilaments.
abstract: A decade ago one-dimensional silicone nanofilaments (1D-SNF) such as fibres and wires were described for the first time. Since then, the exploration of 1D-SNF has led to remarkable advancements with respect to material science and surface science: one-, two- and three-dimensional nanostructures of silicone were unknown before. The discovery of silicone nanostructures marks a turning point in the research on the silicone material at the nanoscale. Coatings made of 1D-SNF are among the most superhydrophobic surfaces known today. They are free of fluorine, can be applied to a large range of technologically important materials and their properties can be modified chemically. This opens the way to many interesting applications such as water harvesting, superoleophobicity, separation of oil and water, patterned wettability and storage and manipulation of data on a surface. Because of their high surface area, coatings consisting of 1D-SNF are used for protein adsorption experiments and as carrier systems for catalytically active nanoparticles. This paper reviews the current knowledge relating to the broad development of 1D-SNF technologies. Common preparation and coating techniques are presented along with a comparison and discussion of the published coating parameters to provide an insight on how these affect the topography of the 1D-SNF or coating. The proposed mechanisms of growth are presented, and their potentials and shortcomings are discussed. We introduce all explored applications and finally identify future prospects and potentials of 1D-SNF with respect to applications in material science and surface science.
authors.affiliation: Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland.
authors.forename: Georg R J
authors.initials: GR
authors.lastname: Artus
authors.affiliation: Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland. Electronic address: sseeger@chem.uzh.ch.
authors.forename: Stefan
authors.initials: S
authors.lastname: Seeger
keywords: Coating; Nanostructure; One-dimensional; Polysiloxane; Silicone; Superhydrophobic