title: Magnetic properties and hyperfine interactions in Cr₈, Cr₇Cd, and Cr₇Ni molecular rings from ¹⁹F-NMR.
abstract: A detailed experimental investigation of the (19)F nuclear magnetic resonance is made on single crystals of the homometallic Cr8 antiferromagnetic molecular ring and heterometallic Cr7Cd and Cr7Ni rings in the low temperature ground state. Since the F(-) ion is located midway between neighboring magnetic metal ions in the ring, the (19)F-NMR spectra yield information about the local electronic spin density and (19)F hyperfine interactions. In Cr8, where the ground state is a singlet with total spin S(T) = 0, the (19)F-NMR spectra at 1.7 K and low external magnetic field display a single narrow line, while when the magnetic field is increased towards the first level crossing field, satellite lines appear in the (19)F-NMR spectrum, indicating a progressive increase in the Boltzmann population of the first excited state S(T) = 1. In the heterometallic rings, Cr7Cd and Cr7Ni, whose ground state is magnetic with S(T) = 3/2 and S(T) = 1/2, respectively, the (19)F-NMR spectrum has a complicated structure which depends on the strength and orientation of the magnetic field, due to both isotropic and anisotropic transferred hyperfine interactions and classical dipolar interactions. From the (19)F-NMR spectra in single crystals we estimated the transferred hyperfine constants for both the F(-)-Ni(2+) and the F(-)-Cd(2+) bonds. The values of the hyperfine constants compare well to the ones known for F(-)-Ni(2+) in KNiF3 and NiF2 and for F(-)-Cr(3+) in K2NaCrF6. The results are discussed in terms of hybridization of the 2s, 2p orbitals of the F(-) ion and the d orbitals of the magnetic ion. Finally, we discuss the implications of our results for the electron-spin decoherence.
authors.affiliation: Department of Physics, Università di Pavia, I-27100 Pavia, Italy.
authors.forename: L
authors.initials: L
authors.lastname: Bordonali
authors.affiliation: Department of Physics, Università degli Studi di Milano, Via Celoria 16, 20133 Milano, Italy.
authors.forename: E
authors.initials: E
authors.lastname: Garlatti
authors.affiliation: Department of Physics, Università di Pavia, I-27100 Pavia, Italy.
authors.forename: C M
authors.initials: CM
authors.lastname: Casadei
authors.affiliation: Department of Physics and Astronomy, Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: Y
authors.initials: Y
authors.lastname: Furukawa
authors.affiliation: Department of Physics, Università di Pavia, I-27100 Pavia, Italy.
authors.forename: A
authors.initials: A
authors.lastname: Lascialfari
authors.affiliation: Dipartimento di Fisica e Scienze della Terra, Università di Parma, Viale G. P. Usberti 7/A, 43124 Parma, Italy.
authors.forename: S
authors.initials: S
authors.lastname: Carretta
authors.affiliation: S3 Istituto Nanoscienze, Consiglio Nazionale delle Ricerche, I-4100 Modena, Italy.
authors.forename: F
authors.initials: F
authors.lastname: Troiani
authors.affiliation: The Lewis Magnetism Laboratory, The University of Manchester, M13 9PL Manchester, United Kingdom.
authors.forename: G
authors.initials: G
authors.lastname: Timco
authors.affiliation: The Lewis Magnetism Laboratory, The University of Manchester, M13 9PL Manchester, United Kingdom.
authors.forename: R E P
authors.initials: RE
authors.lastname: Winpenny
authors.affiliation: Department of Physics, Università di Pavia, I-27100 Pavia, Italy.
authors.forename: F
authors.initials: F
authors.lastname: Borsa