title: Application of cooperative iron/copper catalysis to a palladium-free borylation of aryl bromides with pinacolborane.
abstract: A new cooperative copper/iron catalysis for the borylation of various aryl bromides with pinacolborane, at -10 °C, is reported. Use of the toxic, precious metal Pd is avoided. The mechanism of the protodebromination side reaction is discussed.
authors.affiliation: Département de Chimie Moléculaire , UMR 5250-ICMG FR2607, CNRS-Université Joseph Fourier , BP 53, 38041 Grenoble Cedex 9, France.
authors.forename: Flavien
authors.initials: F
authors.lastname: Labre
authors.forename: Yves
authors.initials: Y
authors.lastname: Gimbert
authors.forename: Pierre
authors.initials: P
authors.lastname: Bannwarth
authors.forename: Sandra
authors.initials: S
authors.lastname: Olivero
authors.forename: Elisabet
authors.initials: E
authors.lastname: Duñach
authors.forename: Pierre Y
authors.initials: PY
authors.lastname: Chavant