title: Effects of benzo-annelation of asymmetric phthalocyanine on the photovoltaic performance of dye-sensitized solar cells.
abstract: Novel highly asymmetric zinc tetraazaporphyrin (TAP) derivatives (Zn-tri-TAPNc and Zn-tri-PcNc) with one carboxyl and three tert-butyl peripheral substituent groups were synthesized. A highly asymmetric zinc phthalocyanine (ZnPc) derivative (Zn-tri-PcNc) has a benzo-annelated ring which contains tribenzonaphtho-condensed tetraazaporphyrin with the same peripheral substituents as Zn-tri-TAPNc. As a sensitizer for the TiO2-based dye-sensitized solar cell, Zn-tri-PcNc derived from the benzo-annelation of the TAP macrocycle showed improved light harvesting and electron injection efficiency, which can retard the charge recombination, resulting in a great improvement in the incident photon-to-current conversion efficiency (IPCE). The Zn-tri-PcNc-sensitized solar cell exhibited a higher conversion efficiency (2.89%) than the Zn-tri-TAPNc-sensitized one (1.20%) under AM 1.5G solar irradiation. The present results on the TAP macrocycle's benzo-annelation demonstrate that optimization of molecular structure via changing the peripheral substituent group's "push-pull" effect and enlarging the conjugated π-system is an effective approach to improve the performance of the tetraazaporphyrin-based dye-sensitized solar cell.
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, P. R. China. typeng@whu.edu.cn lirj@whu.edu.cn.
authors.forename: Lijuan
authors.initials: L
authors.lastname: Yu
authors.forename: Wenye
authors.initials: W
authors.lastname: Shi
authors.forename: Li
authors.initials: L
authors.lastname: Lin
authors.forename: Yuwen
authors.initials: Y
authors.lastname: Liu
authors.forename: Renjie
authors.initials: R
authors.lastname: Li
authors.forename: Tianyou
authors.initials: T
authors.lastname: Peng
authors.forename: Xingguo
authors.initials: X
authors.lastname: Li