title: Hypervalent iodine mediated synthesis of C-2 deoxy glycosides and amino acid glycoconjugates.
abstract: A simple, efficient, and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl esters were intramolecularly converted into 2-iodo serinyl glycosides which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research, Pune 411 008, India.
authors.forename: Maidul
authors.initials: M
authors.lastname: Islam
authors.forename: Nishanth D
authors.initials: ND
authors.lastname: Tirukoti
authors.forename: Shyamapada
authors.initials: S
authors.lastname: Nandi
authors.forename: Srinivas
authors.initials: S
authors.lastname: Hotha
mesh_terms: D000596:Amino Acids / Q000138:chemical synthesis* / Q000737:chemistry; D006001:Glycoconjugates / Q000138:chemical synthesis* / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D007455:Iodine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000596:Amino Acids; D006001:Glycoconjugates; D006027:Glycosides; D007455:Iodine; D012238:Rhodium