title: Direct on-strip analysis of size- and time-resolved aerosol impactor samples using laser induced fluorescence spectra excited at 263 and 351 nm.
abstract: We report a novel atmospheric aerosol characterization technique, in which dual wavelength UV laser induced fluorescence (LIF) spectrometry marries an eight-stage rotating drum impactor (RDI), namely UV-LIF-RDI, to achieve size- and time-resolved analysis of aerosol particles on-strip. The UV-LIF-RDI technique measured LIF spectra via direct laser beam illumination onto the particles that were impacted on a RDI strip with a spatial resolution of 1.2mm, equivalent to an averaged time resolution in the aerosol sampling of 3.6 h. Excited by a 263 nm or 351 nm laser, more than 2000 LIF spectra within a 3-week aerosol collection time period were obtained from the eight individual RDI strips that collected particles in eight different sizes ranging from 0.09 to 10 μm in Djibouti. Based on the known fluorescence database from atmospheric aerosols in the US, the LIF spectra obtained from the Djibouti aerosol samples were found to be dominated by fluorescence clusters 2, 5, and 8 (peaked at 330, 370, and 475 nm) when excited at 263 nm and by fluorescence clusters 1, 2, 5, and 6 (peaked at 390 and 460 nm) when excited at 351 nm. Size- and time-dependent variations of the fluorescence spectra revealed some size and time evolution behavior of organic and biological aerosols from the atmosphere in Djibouti. Moreover, this analytical technique could locate the possible sources and chemical compositions contributing to these fluorescence clusters. Advantages, limitations, and future developments of this new aerosol analysis technique are also discussed.
authors.affiliation: U.S. Army Research Laboratory, Adelphi, MD 20783, USA; Mississippi State University, Starkville, MS, 39759, USA.
authors.forename: Chuji
authors.initials: C
authors.lastname: Wang
authors.affiliation: U.S. Army Research Laboratory, Adelphi, MD 20783, USA. Electronic address: yongle.pan.civ@mail.mil.
authors.forename: Yong-Le
authors.initials: YL
authors.lastname: Pan
authors.affiliation: U.S. Army Research Laboratory, Adelphi, MD 20783, USA.
authors.forename: Deryck
authors.initials: D
authors.lastname: James
authors.affiliation: U.S. Army Research Laboratory, Adelphi, MD 20783, USA.
authors.forename: Alan E
authors.initials: AE
authors.lastname: Wetmore
authors.affiliation: Yale University, New Haven, CT 06510, USA.
authors.forename: Brandon
authors.initials: B
authors.lastname: Redding
mesh_terms: D000336:Aerosols / Q000737:chemistry*; D000465:Algorithms; D001272:Atmosphere / Q000737:chemistry; D007834:Lasers; D010316:Particle Size; D012399:Rotation; D013050:Spectrometry, Fluorescence / Q000379:methods*; D013997:Time Factors; D014466:Ultraviolet Rays
chemical_list: D000336:Aerosols
keywords: Atmospheric aerosol particles; Fluorescence cluster; Laser induced fluorescence spectra; Rotating drum impactor