title: Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry.
abstract: A cationic rhodium(I) catalyst turns 2-silyl-1-alkenylboronate, readily prepared from a terminal alkyne, into the corresponding allylboronate species, which immediately undergoes nucleophilic addition to an aldehyde to give a syn-homoallylic alcohol stereoselectively.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University , Katsura, Kyoto 615-8510, Japan.
authors.forename: Tomoya
authors.initials: T
authors.lastname: Miura
authors.forename: Yui
authors.initials: Y
authors.lastname: Nishida
authors.forename: Masahiro
authors.initials: M
authors.lastname: Murakami