title: Ru-catalyzed rearrangement of N-methyl isoxazolidines to N-H 1,3-oxazinanes: a strategy of self-hydride transferring cleavage of N-O bonds.
abstract: A strategy of ruthenium-catalyzed self-hydride transferring cleavage of N-O bonds was designed and utilized in a cascade 1,3-dipolar cyclization of alkenes and N-methyl nitrones followed by an N-demethylative rearrangement, furnishing synthetically useful N-H 1,3-oxazinanes.
authors.affiliation: Department of Chemistry, University of Science and Technology of China , 96 Jinzhai Road, Hefei, Anhui 230026, China.
authors.forename: Chuan-Zhi
authors.initials: CZ
authors.lastname: Yao
authors.forename: Zu-Feng
authors.initials: ZF
authors.lastname: Xiao
authors.forename: Jie
authors.initials: J
authors.lastname: Liu
authors.forename: Xiao-Shan
authors.initials: XS
authors.lastname: Ning
authors.forename: Yan-Biao
authors.initials: YB
authors.lastname: Kang