title: The role of hydrothermally prepared supported photocatalytic composite in organic micro-pollutants removal from the water.
abstract: This work deals with the non-biodegradable micro-pollutants degradation by supported photocatalyst based heterogeneous photocatalytic reaction. TiO2 based supported photocatalyst was prepared by the hydrothermal technique to improve the photocatalytic performance along with easy recovery of suspended photocatalyst from aqueous medium after photoreaction. TO2 deposited calcium alumino-silicate beads (CASB) supports were prepared under mild hydrothermal conditions (Temparature-200 degrees C, Duration-24 h). In the present study, industrial dyes such as Amaranth and Brilliant Yellow were used as model micro-pollutants in aqueous solution. A real time pesticide industrial effluent was tested for its photocatalytic removal of organic pollutants using TO2 deposited CASB supported photocatalytic composite as an effective photocatalyst. Photocatalytic degradation of micro-pollutants present in aqueous medium was carried out in a batch photoreactor, at atmospheric pressure and temperature (28 degrees C). The influence of different light sources, irradiation time, catalyst load and catalytic performance is discussed. The photocatalytic degradation of micro-pollutants in aqueous medium was evaluated by determination of COD and %T. Easy separation and recovery of suspended photocatalysts from aqueous solution is the major advantage of hydrothermally prepared supported photocatalytic composite.
authors.forename: H P
authors.initials: HP
authors.lastname: Shivaraju
authors.forename: K
authors.initials: K
authors.lastname: Byrappa
mesh_terms: D017607:Aluminum Compounds / Q000737:chemistry; D000548:Amaranth Dye / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D001557:Benzenesulfonates / Q000737:chemistry*; D017610:Calcium Compounds / Q000737:chemistry; D004396:Coloring Agents / Q000737:chemistry*; D010575:Pesticides / Q000737:chemistry*; D010782:Photolysis; D017640:Silicates / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D014025:Titanium / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D017607:Aluminum Compounds; D001391:Azo Compounds; D001557:Benzenesulfonates; D017610:Calcium Compounds; D004396:Coloring Agents; D010575:Pesticides; D017640:Silicates; D014874:Water Pollutants, Chemical; C035219:calcium aluminate; C009495:titanium dioxide; C059622:Direct Yellow 4 dye; D000548:Amaranth Dye; D014025:Titanium; C031293:calcium silicate