title: Copper-catalyzed intermolecular C-H amination of (hetero)arenes via transient unsymmetrical λ³-iodanes.
abstract: A one-pot two-step method for intermolecular C-H amination of electron-rich heteroarenes and arenes has been developed. The approach is based on a room-temperature copper-catalyzed regioselective reaction of the in situ formed unsymmetrical (hetero)aryl-λ(3)-iodanes with a wide range of primary and secondary aliphatic amines and anilines.
authors.affiliation: Latvian Institute of Organic Synthesis , Aizkraukles 21, LV-1006, Riga, Latvia.
authors.forename: Igors
authors.initials: I
authors.lastname: Sokolovs
authors.forename: Dmitrijs
authors.initials: D
authors.lastname: Lubriks
authors.forename: Edgars
authors.initials: E
authors.lastname: Suna