title: A silver(I) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity.
abstract: We report a non-porous silver(i) coordinated phenanthroline-based polymer, which exhibits a high ideal ethylene/ethane adsorption selectivity (15/1) and high ethylene uptake (5.0 mmol g(-1)) at ambient temperature and pressure. Both silver(i) coordination and polymer structures are important for the high uptake of ethylene.
authors.affiliation: Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA. wei.zhang@colorado.edu.
authors.forename: Chao
authors.initials: C
authors.lastname: Yu
authors.forename: Matthew G
authors.initials: MG
authors.lastname: Cowan
authors.forename: Richard D
authors.initials: RD
authors.lastname: Noble
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang