title: What is the acceptable margin of error for the oxygen uptake method in evaluating the reactivity of organic waste?
abstract: The acceptable margin of error for the organic waste reactivity measured by the oxygen uptake method was assessed. Oxygen uptake was determined by the Dynamic Respiration Index (DRI) (mgO2/kgVS h). The composed uncertainty (uC) of the experimental set up used for the DRI test was evaluated and the uncertainty (u) of all the components of the apparatus was evaluated. A procedure for calculating the uC of the apparatus is proposed. The components affecting the uC of the DRI to a more significant extent were the one of the oxygen mass rate and the u of the amount of VS in the sample analyzed. For a confidence level of 99.73%, the extended uC (UC) interval for a DRI = 1024 mgO2/kgVS h was ± 440 mgO2/kgVS h, whereas for a DRI = 3,489 mgO2/kgVS h, the UC interval was ± 1288 mgO2/kgVS h. When oxygen consumption and VS content become lower than 600 mgO2/h and 0.9 kg, respectively, the UC interval is similar to the measured DRI.
authors.affiliation: LAR - Dipartimento di Ingegneria, Universtiy of Perugia, Via G. Duranti 67, 06125 Perugia, Italy. Electronic address: francesco.dimaria@unipg.it.
authors.forename: Francesco
authors.initials: F
authors.lastname: Di Maria
authors.affiliation: LAR - Dipartimento di Ingegneria, Universtiy of Perugia, Via G. Duranti 67, 06125 Perugia, Italy.
authors.forename: Caterina
authors.initials: C
authors.lastname: Micale
mesh_terms: D001673:Biodegradation, Environmental; D009930:Organic Chemicals / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010101:Oxygen Consumption; D012037:Refuse Disposal / Q000379:methods*; D015203:Reproducibility of Results
chemical_list: D009930:Organic Chemicals; D010100:Oxygen
keywords: Assessment of biological reactivity; Dynamic respiration index; Municipal solid waste; Respiration activity; Uncertainty