N-Arylations of sulfoximines with 2-arylpyridines by copper-mediated dual N-H/C-H activation.
A high-yielding method providing rapid access to new N-arylated sulfoximines has been developed. A stoichiometric amount of copper facilitates the C-H activation of 2-arylpyridines which then undergo oxidative C-N cross-couplings with various sulfoximine derivatives.
Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, 52056 Aachen, Germany.
Long
L
Wang
Daniel L
DL
Priebbenow
Wanrong
W
Dong
Carsten
C
Bolm
D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011725:Pyridines / Q000737:chemistry*; D013457:Sulfur Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D011725:Pyridines; D013457:Sulfur Compounds; D003300:Copper