Chlorido[5-meth-oxy-1H-benzimidazole-2(3H)-thione-κS]bis-(tri-phenyl-phos-phane-κP)copper(I) methanol disolvate.
In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth-oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri-phenyl-phosphine ligands in a distorted tetra-hedral geometry. One of the N-bound H atoms is involved in an intra-molecular N-H⋯Cl hydrogen bond, while another one inter-acts with the solvent methanol mol-ecule via an N-H⋯O hydrogen bond. Inter-molecular O-H⋯Cl and O-H⋯O hydrogen bonds link two further complex mol-ecules and four solvent mol-ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π-π inter-actions.
Daxing High School Attached to CNU, Beijing 102600, People's Republic of China.
Qing-Xuan
QX
Meng