Mild Rh(III)-catalyzed direct C-H bond arylation of (hetero)arenes with arylsilanes in aqueous media.
An efficient rhodium(III)-catalyzed C-H bond activation and further direct arylation of (hetero)arenes with organosilanes in aqueous media was developed. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent regioselectivity.
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China , Hefei, 230026, China.
Ming-Zhu
MZ
Lu
Ping
P
Lu
Yun-He
YH
Xu
Teck-Peng
TP
Loh
D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D014867:Water
D006571:Heterocyclic Compounds; D012821:Silanes; D014867:Water; D012238:Rhodium