Electrochemical oxidation of textile industry wastewater by graphite electrodes.
In the present article, studies have been performed on the electrochemical (EC) oxidation of actual textile industry wastewater by graphite electrodes. Multi-response optimization of four independent parameters namely initial pH (pHo): 4-10, current density (j): 27.78-138.89 A/m(2), NaCl concentration (w): 0-2 g/L and electrolysis time (t): 10-130 min have been performed using Box-Behnken (BB) experimental design. It was aimed to simultaneously maximize the chemical oxygen demand (COD) and color removal efficiencies and minimize specific energy consumption using desirability function approach. Pareto analysis of variance (ANOVA) showed a high coefficient of determination value for COD (R(2) = 0.8418), color (R(2) = 0.7010) and specific energy (R(2) = 0.9125) between the experimental values and the predicted values by a second-order regression model. Maximum COD and color removal and minimum specific energy consumed was 90.78%, 96.27% and 23.58 kWh/kg COD removed, respectively, were observed at optimum conditions. The wastewater, sludge and scum obtained after treatment at optimum condition have been characterized by various techniques. UV-visible study showed that all azo bonds of the dyes present in the wastewater were totally broken and most of the aromatic rings were mineralized during EC oxidation with graphite electrode. Carbon balance showed that out of the total carbon eroded from the graphite electrodes, 27-29.2% goes to the scum, 71.1-73.3% goes into the sludge and rest goes to the treated wastewater. Thermogravimetric analysis showed that the generated sludge and scum can be dried and used as a fuel in the boilers/incinerators.
a Department of Hydrology, Indian Institute of Technology Roorkee , Roorkee , Uttarakhand , India.
Rajendra
R
Bhatnagar
Himanshu
H
Joshi
Indra D
ID
Mall
Vimal C
VC
Srivastava
D057919:Biological Oxygen Demand Analysis; D004396:Coloring Agents / Q000737:chemistry; D004566:Electrodes; D004572:Electrolysis; D052918:Environmental Restoration and Remediation / Q000295:instrumentation / Q000379:methods*; D006108:Graphite / Q000737:chemistry*; D010084:Oxidation-Reduction; D013783:Textile Industry; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
D004396:Coloring Agents; D006108:Graphite; D062065:Wastewater; D014874:Water Pollutants, Chemical
Electrochemical techniques; carbon balance; electrode; graphite; textile industry wastewater