[(Me)2NH2][BiGeS4]: the first organically directed bismuth thiogermanate with Rb+ ion exchange property.
The first organically directed bismuth thiogermanate, namely [(Me)2NH2][BiGeS4] (), has been solvothermally synthesized and characterized. The structure features a two-dimensional anionic network of [BiGeS4]n(n-), with dimethylammonium as a counterion and a structure-directing agent. is able to undergo ion exchange with Rb(+) ions.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China. xyhuang@fjirsm.ac.cn.
Mei-Ling
ML
Feng
Xing-Hui
XH
Qi
Bo
B
Zhang
Xiao-Ying
XY
Huang