Metalloporphyrinic framework containing multiple pores for highly efficient and selective epoxidation.
Metalloporphyrin Mn(III)Cl-5,10,15,20-tetrakis(3,5-biscarboxylphenyl)porphyrin, having eight carboxylate groups in multiple coordination modes, connects with paddle-wheel Zn2(COO)4 units for the construction of an interesting porous porphyrinic framework that demonstrates high efficiency and stability upon epoxidation of olefins with excellent substrate size selectivity.
Center for Chemistry of High-Performance and Novel Materials, Department of Chemistry, Zhejiang University , Hangzhou 310027, P. R. China.
Xiu-Li
XL
Yang
Chuan-De
CD
Wu