Bis(1,10-phenanthrolin-1-ium) tetra-chlorido-zincate monohydrate.
In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol-ecule and the tetrahedral tetrachloridozincate anion via N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C-H⋯Cl hydrogen bonds and a number of π-π inter-actions [centroid-centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N-H⋯N inter-action.
Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.
E
E
Govindan
Department of Chemistry, Pondicherry University, Pondicherry 605 014, India.
Subramani
S
Thirumurugan
Department of Chemistry, Pondicherry University, Pondicherry 605 014, India.
Ayyakannu Sundaram
AS
Ganeshraja
Department of Chemistry, Pondicherry University, Pondicherry 605 014, India.
Krishnamoorthy
K
Anbalagan
Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.
A
A
Subbiahpandi