2,9-Bis(5-sulfanylidene-4,5-di-hydro-1,3,4-oxa-diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate.
In the title compound, C16H8N6O2S2·2C2H6OS, the phenanthroline mol-ecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] mol-ecule of dimethyl sulfoxide. The O atoms of the solvent mol-ecule accept hydrogen bonds from the N-H groups of the five-membered 2,3-di-hydro-1,3,4-oxa-diazole-2-thione ring. This ring is nearly coplanar with the phenanthroline ring, with a dihedral angle between their least-squares planes of 8.86 (6)°. In the crystal, the mol-ecules are linked by C-H⋯O inter-actions.
Department of Chemistry, Boswell Science Complex, Tennessee State University, Nashville, 3500 John A. Merritt Blvd, Nashville, TN 37209, USA.
Md A
MA
Rahman
Department of Chemistry, Boswell Science Complex, Tennessee State University, Nashville, 3500 John A. Merritt Blvd, Nashville, TN 37209, USA.
Mohammad
M
Karim
Department of Chemistry, Iowa State University, Ames, IA 50011-3111, USA.
Md
M
Arifuzzaman
Department of Chemistry, Boswell Science Complex, Tennessee State University, Nashville, 3500 John A. Merritt Blvd, Nashville, TN 37209, USA.
Tasneem
T
Siddiquee
Agilent Technologies, 5301 Stevens Creek Blvd, Santa Clara, CA 95051, USA.
Lee M
LM
Daniels