μ-1,6,7,12-Tetra-aza-perylene-κ(4) N (1),N (12):N (6),N (7)-bis-[chlorido-(η(6)-p-cymene)ruthenium(II)] bis-(hexa-fluorido-phosphate) acetone disolvate.
In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}2(μ-tape)](2+), built up by a planar 1,6,7,12-tetra-aza-perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexa-fluorido-phosphate anion and the asymmetric unit is completed by an acetone mol-ecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C-H⋯O/F/Cl inter-actions.
Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.
Thomas
T
Brietzke
Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.
Daniel
D
Kässler
Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.
Alexandra
A
Kelling
Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.
Uwe
U
Schilde
Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.
Hans-Jürgen
HJ
Holdt