2-((1E)-1-{2-[(2Z)-4-(4-Bromo-phen-yl)-3-phenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.
In the title hydrated molecular salt, C22H18BrN4S(+)·Br(-)·H2O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thia-zole ring. In the crystal, mol-ecules are linked into chains running parallel to the a axis by association of the bromide ions and the water mol-ecules of crystallization with the cations via N-H⋯O, O-H⋯Br, C-H⋯N and C-H⋯Br hydrogen-bonding inter-actions. C-H⋯π and C-Br⋯π [3.7426 (11) Å, 161.73 (7)°] inter-actions are also observed, forming infinite chains extending along the b-axis direction.
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Joel T
JT
Mague
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Shaaban K
SK
Mohamed
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
Mehmet
M
Akkurt
Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Ahmed T
AT
Abd El-Alaziz
Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq.
Mustafa R
MR
Albayati