Size-selected gold clusters on porous titania as the most "gold-efficient" heterogeneous catalysts.
Research on homogeneous and heterogeneous catalysis is indeed convergent and finds subnanometric particles to be at the heart of catalytically active species. Here, monodisperse gold clusters are deposited from the gas phase onto porous titania generating well-defined model systems and the resulting composite materials exhibit a sharp size-dependency on the number of gold atoms per cluster and exceptionally high-turnovers toward the bromination of 1,4-dimethoxybenzene are observed. This indicates that the deliberate generation of active centres is of utmost importance for the creation of the most "gold-efficient" catalysts.
Fachbereich für Physik, Universität Konstanz, Universitätsstrasse 10, 78464 Konstanz, Germany. gerd.gantefoer@uni-konstanz.de sebastian.proch@uni-konstanz.de.
Andreas
A
Dollinger
Lukas
L
Stolch
Yuan
Y
Luo
Martin
M
Beck
Christoph H
CH
Strobel
Matthias
M
Hagner
Stefan
S
Dilger
Malin
M
Bein
Sebastian
S
Polarz
Gerd F
GF
Gantefoer
Young-Dok
YD
Kim
Sebastian
S
Proch