Cu-catalyzed C(sp³)-H bond activation reaction for direct preparation of cycloallyl esters from cycloalkanes and aromatic aldehydes.
Cu-catalyzed dehydrogenation-olefination and esterification of C(sp(3))-H bonds of cycloalkanes with TBHP as an oxidant has been developed. The reaction involves four C-H bond activations and gives cycloallyl ester products directly from cycloalkanes and aromatic aldehydes.
School of Chemistry and Chemical Engineering, Nanjing University , Nanjing, 210093, China.
Jincan
J
Zhao
Hong
H
Fang
Jianlin
J
Han
Yi
Y
Pan