Methyl (2Z)-2-{(2Z)-3-[(cyclo-pentyl-idene)amino]-4-oxo-2-phenyl-imino-1,3-thia-zol-idin-5-yl-idene}acetate.
In the title compound, C17H17N3O3S, the thia-zole ring is nearly planar [maximum deviation = 0.015 (1) Å for the ring N atom] and the cyclo-pentane ring has a twist conformation. The mol-ecular conformation is stabilized by a hypervalent inter-action between the S atom and the ester group carbonyl O atom, with an S⋯O distance of 2.7931 (10) Å. In the crystal, C-H⋯O inter-actions generate chains of mol-ecules propagating along [110] and π-π stacking inter-actions [centroid-centroid distance = 3.4677 (7) Å] between the thia-zole rings organize these chains into (001) layers.
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Joel T
JT
Mague
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
Mehmet
M
Akkurt
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Shaaban K
SK
Mohamed
Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Alaa A
AA
Hassan
Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq.
Mustafa R
MR
Albayati