Tuning of gate adsorption: modification of a flexible metal-organic framework by secondary organic ligands.
For realizing selective adsorption of targeted molecules, a flexible metal-organic framework (MOF) was modified with monodentate secondary ligands. Although the modified MOF retains CO2 adsorptivities with a vertical adsorption uptake, the material also shows gate adsorptivities of a specific gas molecule that the pristine MOF does not adsorb.
Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan. kondoa@cc.tuat.ac.jp k-maeda@cc.tuat.ac.jp.
Atsushi
A
Kondo
Takuro
T
Fujii
Kazuyuki
K
Maeda
D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D010847:Picolines / Q000737:chemistry*; D016062:Porosity; D011725:Pyridines / Q000737:chemistry*; D013499:Surface Properties
D008024:Ligands; D009942:Organometallic Compounds; D010847:Picolines; D011725:Pyridines; D002245:Carbon Dioxide; D003300:Copper; C582866:4-tert-butylpyridine