Polyoxoniobate-based 3D framework materials with photocatalytic hydrogen evolution activity.
Two phosphoniobate-based 3D frameworks were firstly constructed using the hexa-capped Keggin polyoxoniobates [PNb12O40(VO)6](3-) and copper cations. Photocatalytic studies indicated that the hybrid materials exhibit photocatalytic hydrogen evolution activity.
Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, Jilin 130024, P. R. China. zhangzm178@nenu.edu.cn wangeb889@nenu.edu.cn.
Jian-Qiang
JQ
Shen
Ying
Y
Zhang
Zhi-Ming
ZM
Zhang
Yang-Guang
YG
Li
Yan-Qing
YQ
Gao
En-Bo
EB
Wang
D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D009556:Niobium / Q000737:chemistry*; D014638:Vanadates / Q000737:chemistry*
D009556:Niobium; D014638:Vanadates; D006859:Hydrogen