tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy.
tBu3P-Coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes via C-H activation strategy. The readily accessibility and easy handling nature oftBu3P- coordinated 2-aminobiphenyl-based palladacycle complex and the high yields of the reaction makestBu3P-coordinated 2-aminobiphenyl-based palladacycle complex an attractive precatalyst for the cross-coupling reaction of aryl halides with polyfluoroarenes.
Department of Chemistry, College of Staten Island and Graduate Center of the City University of New York, Staten Island, New York, 10314, United States.
Hong-Hai
HH
Zhang
Department of Chemistry, College of Staten Island and Graduate Center of the City University of New York, Staten Island, New York, 10314, United States.
Jie
J
Dong
Department of Chemistry, College of Staten Island and Graduate Center of the City University of New York, Staten Island, New York, 10314, United States.
Qiao-Sheng
QS
Hu
Aryl halides; C-H Activation; Coupling Reaction; Fluoroarenes; Palladacycle Complex