Gorlos-Phos for palladium-catalyzed borylation of aryl chlorides.
Using a readily available form of the mono-phosphine ligand, Gorlos-Phos·HBF4, Pd-catalyzed borylation of aryl chlorides afforded aryl boronates in high yields. A variety of functional groups are well compatible with this palladium catalyzed borylation reaction.
Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, P. R. China. masm@mail.sioc.ac.cn.
Pengbin
P
Li
Chunling
C
Fu
Shengming
S
Ma