(5-Methyl-pyrazine-2-carboxyl-ato-κ(2) N (1),O)bis-[2-(4-methyl-pyridin-2-yl-κN)-3,5-bis-(tri-fluoro-meth-yl)phenyl-κC (1)]iridium(III) chloro-form hemisolvate.
In the title complex, [Ir(C14H8F6N)2(C6H5N2O2)]·0.5CHCl3, the Ir(III) atom adopts a distorted octa-hedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex mol-ecules pack with no specific inter-molecular inter-actions between them. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155] was used to model a disordered chloro-form solvent mol-ecule; the calculated unit-cell data allow for the presence of half of this mol-ecule in the asymmetric unit.
Department of Chemistry Education and Department of Chemical Materials, Graduate School, Pusan National University, Busan 609-735, Republic of Korea.
Young-Inn
YI
Kim
Department of Chemistry Education and Department of Chemical Materials, Graduate School, Pusan National University, Busan 609-735, Republic of Korea.
Young-Kwang
YK
Song
Department of Chemistry, Chungnam National University, Daejeon 305-764, Republic of Korea.
Sung Kwon
SK
Kang