Enantioselective inclusion of alcohols by solvent-controlled assembled flexible metal-organic frameworks.
Through judicious choice of the ligands and patient regulation of the solvent conditions, three unique chiral coordination polymeric isomers have been synthesized. Their structures, gas adsorption, and structural interconversion have been studied. One of the isomers displays dynamic behavior, and its use in the enantioselective separation of chiral alcohols has also been reported.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 35002, China.
Lang
L
Lin
Rongmin
R
Yu
Xiao-Yuan
XY
Wu
Wen-Bin
WB
Yang
Jian
J
Zhang
Xiang-Guang
XG
Guo
Zu-Jin
ZJ
Lin
Can-Zhong
CZ
Lu