title: Direct condensation of functionalized sp(3) carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst.
abstract: The efficient synthesis of functionalized enamines including β-enaminoesters was effectively accomplished by the direct condensation of functionalized sp(3) carbanions such as acetates with formamides using in situ generated HMDS base from catalytic cesium fluoride and stoichiometric tristrimethylsilylamine.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan. ykondo@m.tohoku.ac.jp.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Taneda
authors.forename: Kiyofumi
authors.initials: K
authors.lastname: Inamoto
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Kondo
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D005559:Formamides / Q000737:chemistry*; D017646:Organosilicon Compounds / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: D000588:Amines; D005559:Formamides; D017646:Organosilicon Compounds; C045976:N-phenylformamide; D002244:Carbon; C024548:hexamethylsilazane