title: UV curable lens production using molecular weight controlled PEEK based acrylic oligomer (Ac-PEEK).
abstract: We produced UV curable lenses with properties blocking short wave UV light. In the UV-curable formulations, we used an oligomer (Ac-PEEK) with another urethan oligomer (Mw = 2000). Radically active, molecular weight controlled Ac-PEEK was obtained by reacting 2-hydroxyl ethyl methacrylate with molecular- weight- controlled and isocyanate terminated PEEK (Mn = 4500). We characterized all synthesized monomer, oligomer and optical materials with UV/Vis spectrophotometer with interferogram, elemental analyser, mass spectrophotometer, proton nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermal gravimetric analyzer, differential scanning calorimeter, scanning electron microscopy and gas chromatography. Results suggested that newly synthesized oligomer with the structure of PEEK absorbs short wave UV-light. Ageing tests [ISO 11979-5, Ophthalmic implants-intraocular lenses (IOL)-Part 5: Biocompatibility] performed on the IOL materials were successful. High contact angle of the obtained lenses suggests that all lenses were hydrophobic and SEM results revealed that lenses are morphologically homogeneous. Based on all positive properties just mentioned, we safely conclude that the lenses produced in this study are very promising for IOL production.
authors.affiliation: TUBITAK Marmara Research Center, Chemistry Institute, 41470, Gebze, Kocaeli, Turkey, tulayinan2012@gmail.com.
authors.forename: Tulay Y
authors.initials: TY
authors.lastname: İnan
authors.forename: Emel
authors.initials: E
authors.lastname: Yıldız
authors.forename: Birsen
authors.initials: B
authors.lastname: Karaca
authors.forename: Hacer
authors.initials: H
authors.lastname: Dogan
authors.forename: Alican
authors.initials: A
authors.lastname: Vatansever
authors.forename: Muhammed
authors.initials: M
authors.lastname: Nalbant
authors.forename: Koray
authors.initials: K
authors.lastname: Eken
mesh_terms: D002152:Calorimetry, Differential Scanning; D008855:Microscopy, Electron, Scanning; D008970:Molecular Weight; D011108:Polymers / Q000737:chemistry*; D066244:Proton Magnetic Resonance Spectroscopy; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D014466:Ultraviolet Rays
chemical_list: D011108:Polymers