title: Synthesis of silver embedded poly(o-anisidine) molybdophosphate nano hybrid cation-exchanger applicable for membrane electrode.
abstract: Poly(o-anisidine) molybdophosphate was expediently obtained by sol-gel mixing of Poly(o-anisidine) into the inorganic matrices of molybdophosphate, which was allowed to react with silver nitrate to the formation of poly(o-anisidine) molybdophosphate embedded silver nano composite. The composite was characterized by Fourier Transform Infrared Spectroscopy, X-ray powder diffraction, UV-Vis Spectrophotometry, Fluorescence Spectroscopy, Scanning Electron Microscopy/Energy-dispersive X-ray Spectroscopy and Thermogravimertic Analysis. Ion exchange capacity and distribution studies were carried out to understand the ion-exchange capabilities of the nano composite. On the basis of highest distribution studies, this nano composite cation exchanger was used as preparation of heavy metal ion selective membrane. Membrane was characterized for its performance as porosity and swelling later on was used for the preparation of membrane electrode for Hg(II), having better linear range, wide working pH range (2-4.5) with fast response in the real environment.
authors.affiliation: Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia; Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia.
authors.forename: Anish
authors.initials: A
authors.lastname: Khan
authors.affiliation: Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia; Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia.
authors.forename: Aftab Aslam Parwaz
authors.initials: AA
authors.lastname: Khan
authors.affiliation: Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia; Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia.
authors.forename: Abdullah M
authors.initials: AM
authors.lastname: Asiri
authors.affiliation: Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia; Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia.
authors.forename: Malik Abdul
authors.initials: MA
authors.lastname: Rub
mesh_terms: D000814:Aniline Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D004566:Electrodes; D008564:Membrane Potentials; D008567:Membranes, Artificial; D019216:Metals, Heavy / Q000737:chemistry / Q000302:isolation & purification*; D008855:Microscopy, Electron, Scanning; D053761:Nanocomposites / Q000737:chemistry; D053758:Nanoparticles / Q000737:chemistry*; D012834:Silver / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry; D014874:Water Pollutants, Chemical / Q000302:isolation & purification* / Q000378:metabolism; D014961:X-Ray Diffraction
chemical_list: D000814:Aniline Compounds; D002412:Cations; D008567:Membranes, Artificial; D019216:Metals, Heavy; D014874:Water Pollutants, Chemical; D012834:Silver; C003898:2-anisidine