title: Heterodinuclear complexes of 4,5-diazafluorene derivatives displaying η(5),κ(2)-[N,N] and η(5),κ(1)-N coordination modes.
abstract: The syntheses and structures for a series of heterodinuclear complexes of 4,5-diazafluorenyl (L(-)) and 3,6-dimesityl-4,5-diazafluorenyl (LMes(-)) ligands are reported herein. In all these heterodinuclear complexes, the Ru(II) centre is sandwiched between a pentamethylcyclopentadienyl (Cp*) ligand and the C5 ring of L(-) or LMes(-) in a double η(5) fashion, while the other metal (Fe(II), Co(II), Pt(II), or Cu(I)) is bound to the N-donors.
authors.affiliation: Davenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6. dsong@chem.utoronto.ca.
authors.forename: Rhys
authors.initials: R
authors.lastname: Batcup
authors.forename: Vincent T
authors.initials: VT
authors.lastname: Annibale
authors.forename: Datong
authors.initials: D
authors.lastname: Song