title: A crystalline porous coordination polymer decorated with nitroxyl radicals catalyzes aerobic oxidation of alcohols.
abstract: A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.
authors.affiliation: Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Liangchun
authors.initials: L
authors.lastname: Li
authors.forename: Ryotaro
authors.initials: R
authors.lastname: Matsuda
authors.forename: Iku
authors.initials: I
authors.lastname: Tanaka
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Sato
authors.forename: Prakash
authors.initials: P
authors.lastname: Kanoo
authors.forename: Hyung Joon
authors.initials: HJ
authors.lastname: Jeon
authors.forename: Maw Lin
authors.initials: ML
authors.lastname: Foo
authors.forename: Atsushi
authors.initials: A
authors.lastname: Wakamiya
authors.forename: Yasujiro
authors.initials: Y
authors.lastname: Murata
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa