title: Cationic copper(II)-containing surfactants: molecular structures, film morphology, and influence on the alignment of nematic mesogens.
abstract: We discuss the synthesis and amphiphilic behavior of the cationic metallosurfactants [(L(Py14))2Cu(II)ClO4]ClO4 (1), [(L(Py16))2Cu(II)ClO4]ClO4 (2), [(L(Py18))2Cu(II)ClO4]ClO4 (3), [(L(Py18))2Cu(II)NO3]NO3 (4), [(L(Py18))2Cu(II)Cl]Cl (5), and [(L(Py18))2Cu(II)Br]Br (6) obtained by treatment of the appropriate alkylaminemethyl-2-pyridine ligand containing tetra-, hexa-, or octadecyl chains with copper salts. These metallosurfactants show excellent agreement between infrared spectroscopic bands, spectrometric masses with isotopic patterns, and elemental composition. Single-crystal X-ray data available for 1, 2, 5 and the previously published 3 reveal a trigonal bipyramidal copper(II) ion bound at the basal plane to the amine and pyridine of each alkylaminemethylpyridine ligand and an anionic coligand to the apical position. Except for the surfactant with the shortest tetradecyl (C14) chain, these species yield Langmuir films with collapse pressures of 45-55 mN·m(-1) and average areas of ca. 50 Å(2). A plateau around 15 mN·m(-1) is observed for 3, 4, and 5 and associated with the formation of dendritic domains about 50 μm in size. Species 2 and 6 lack this plateau and show domains of ca. 5 μm. Once transferred onto solid substrates, the resulting Langmuir-Blodgett film of 3 at 18 mN·m(-1) influences the alignment of the nematic liquid crystal N-(4-methoxybenzylidene)-4-butylaniline.
authors.affiliation: Department of Chemistry and ‡Department of Physics and Astronomy, Wayne State University , 5101 Cass Avenue, Room 161, Detroit, Michigan 48202, United States.
authors.forename: Cláudio N
authors.initials: CN
authors.lastname: Verani
authors.forename: Jeffery
authors.initials: J
authors.lastname: Driscoll
authors.forename: Paul H
authors.initials: PH
authors.lastname: Keyes
authors.forename: Mary Jane
authors.initials: MJ
authors.lastname: Heeg