title: The dinitrosyliron complex [Fe₄(μ₃-S)₂(μ₂-NO)₂(NO)₆]²⁻ containing bridging nitroxyls: ¹⁵N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands.
abstract: The fluxional terminal and semibridging NO-coordinate ligands of DNIC [Fe4(μ3-S)2(μ2-NO)2(NO)6](2-), a precursor of Roussin's black salt (RBS), are characterized by IR ν(NO), (15)N (NO) NMR and single-crystal X-ray diffraction.
authors.affiliation: Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan. wfliaw@mx.nthu.edu.tw.
authors.forename: Shih-Wey
authors.initials: SW
authors.lastname: Yeh
authors.forename: Chih-Chin
authors.initials: CC
authors.lastname: Tsou
authors.forename: Wen-Feng
authors.initials: WF
authors.lastname: Liaw
mesh_terms: D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009154:Mutation; D009569:Nitric Oxide / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry*; D009589:Nitrogen Oxides / Q000737:chemistry*; D020027:Pyrococcus furiosus; D012492:Salts / Q000737:chemistry; D015398:Signal Transduction; D055672:Static Electricity; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D008024:Ligands; D009589:Nitrogen Oxides; D012492:Salts; D009569:Nitric Oxide; C073661:dinitrosyl iron complex; D007501:Iron; D009584:Nitrogen