title: High thermal robustness of molecularly thin perovskite nanosheets and implications for superior dielectric properties.
abstract: A systematic study has been conducted to examine the thermal stability of layer-by-layer assembled films of perovskite-type nanosheets, (Ca2Nb3O10(-))n (n = 1-10), which exhibit superior dielectric and insulating properties. In-plane and out-of-plane X-ray diffraction data as well as observations by atomic force microscopy and transmission electron microscopy indicated the high thermal robustness of the nanosheet films. In a monolayer film with an extremely small thickness of ∼2 nm, the nanosheet was stable up to 800 °C, the temperature above which segregation into CaNb2O6 and Ca2Nb2O7 began. The critical temperature moderately decreased as the film thickness, or the number of nanosheet layers, increased, and reached 700 °C for seven- and 10-layer films, which is comparable to the phase transformation temperature for a bulk phase of the protonic layered oxide of HCa2Nb3O10·1.5H2O as a precursor of the nanosheet. This thermal stabilization of perovskite-type nanosheets should be associated with restricted nucleation and crystal growth peculiar to such ultrathin 2D bound systems. The stable high-k dielectric response (εr = 210) and highly insulating nature (J < 10(-7) A cm(-2)) remained substantially unchanged even after the nanosheet film was annealed up to 600 °C. This study demonstrates the high thermal stability of 2D perovskite-type niobate nanosheets in terms of structure and dielectric properties, which suggests promising potential for future high-k devices operable over a wide temperature range.
authors.affiliation: International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science , Tsukuba, Ibaraki 305-0044, Japan.
authors.forename: Bao-Wen
authors.initials: BW
authors.lastname: Li
authors.forename: Minoru
authors.initials: M
authors.lastname: Osada
authors.forename: Yasuo
authors.initials: Y
authors.lastname: Ebina
authors.forename: Kosho
authors.initials: K
authors.lastname: Akatsuka
authors.forename: Katsutoshi
authors.initials: K
authors.lastname: Fukuda
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Sasaki