title: Exploration of the slow relaxation behavior in the manganese phosphate network.
abstract: Our endeavors are devoted to the explanation of the nature of the magnetic relaxation phenomena in the herein prepared [Mn(II)5(HPO4)2(PO4)2(H2O)4]n (1). The behavior investigation indicates the prominence of the half-occupied magnetic centers and the competence of the antiferromagnetic interactions and non-zero magnetic moments. The investigation suggests that the design and synthesis of unusual magnetic center materials with innate unquenched magnetic moments could provide a new route for the production of molecular magnets with magnetic relaxation.
authors.affiliation: Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering; College of Public Health, Hebei United University, Tangshan 063009, Hebei, China.
authors.forename: Bo
authors.initials: B
authors.lastname: Li
authors.forename: Ning
authors.initials: N
authors.lastname: Jiang
authors.forename: Jumei
authors.initials: J
authors.lastname: Tian
authors.forename: Tingting
authors.initials: T
authors.lastname: Li
authors.forename: Guixiang
authors.initials: G
authors.lastname: Hou
authors.forename: Jingping
authors.initials: J
authors.lastname: Zhang