title: A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group.
abstract: Combining Fe(ii) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)2](ClO4)2 which shows an abrupt spin transition with a T1/2 of ca. 380 K and a TLIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.
authors.affiliation: Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán 2, 46980 Paterna, Spain. miguel.clemente@uv.es eugenio.coronado@uv.es.
authors.forename: Alexandre
authors.initials: A
authors.lastname: Abhervé
authors.forename: Miguel
authors.initials: M
authors.lastname: Clemente-León
authors.forename: Eugenio
authors.initials: E
authors.lastname: Coronado
authors.forename: Carlos J
authors.initials: CJ
authors.lastname: Gómez-García
authors.forename: Maurici
authors.initials: M
authors.lastname: López-Jordà