From serendipitous assembly to controlled synthesis of 3d-4f single-molecule magnets.
Learning from serendipitous assembly, we have prepared a new family of designed 3d-4f Mn6Ln complexes. The dynamics of relaxation of the magnetization via alternating-current magnetic susceptibility for the new Mn6Ln complexes 1 (Ln = La), 2 (Ln = Tb), and 4 (Ln = Dy) have been studied down to 0.2 K.
Departament de Química Inorgànica and Institut de Nanociència i Nanotecnologia, Universitat de Barcelona , Diagonal 645, 08028 Barcelona, Spain.
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Ledezma-Gairaud
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Grangel
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Aromí
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T
Fujisawa
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Yamaguchi
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Sumiyama
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EC
Sañudo