Ferroelectric coupling effect on the energy-band structure of hybrid heterojunctions with self-organized P(VDF-TrFE) nanomatrices.
Ferroelectric coupling effects on the energy-band structure of hybrid heterojunctions are investigated using hybrid photovoltaic devices with poly(3-hexylthiophene-2,5-diyl) (P3HT)/ZnO and poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)). The self-organized P(VDF-TrFE):P3HT photoactive layer forms a novel architecture consisting of P3HT domains in a P(VDF-TrFE) matrix. The energy-band structure at the interface of the p-n heterojunction is tuned by artificial control of the ferroelectric polarization of the P(VDF-TrFE) material, consequently modulating the photovoltaic performance of the hybrid photovoltaic devices.
School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon, 440-746, Republic of Korea.
Kyung-Sik
KS
Shin
Tae Yun
TY
Kim
Gyu Cheol
GC
Yoon
Manoj Kumar
MK
Gupta
Sung Kyun
SK
Kim
Wanchul
W
Seung
Hyeok
H
Kim
Sungjin
S
Kim
SeongMin
S
Kim
Sang-Woo
SW
Kim
ferroelectric polarization; hybrid materials; optoelectronic devices; photovoltaic devices; poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)); self-assembly