Biomimetic synthesis of silver nanoparticles using the fish scales of Labeo rohita and their application as catalysts for the reduction of aromatic nitro compounds.
In this article, a cleaner, greener, cheaper and environment friendly method for the generation of self assembled silver nanoparticles (Ag NPs) applying a simple irradiation technique using the aqueous extract of the fish scales (which is considered as a waste material) of Labeo rohita is described. Gelatin is considered as the major ingredient responsible for the reduction as well as stabilisation of the self assembled Ag NPs. The size and morphology of the individual Ag NPs can be tuned by controlling the various reaction parameters, such as temperature, concentration, and pH. Studies showed that on increasing concentration and pH Ag NPs size decreases, while on increasing temperature, Ag NPs size increases. The present process does not need any external reducing agent, like sodium borohydride or hydrazine or others and gelatin itself can play a dual role: a 'reducing agent' and 'stabilisation agent' for the formation of gelatin-Ag NPs colloidal dispersion. The synthesized Ag NPs were characterised by Ultraviolet-Visible spectroscopy (UV-Vis), Transmission electron microscopy (TEM) and Selected area electron diffraction (SAED) analyses. The synthesized Ag NPs was used to study the catalytic reduction of various aromatic nitro compounds in aqueous and three different micellar media. The hydrophobic and electrostatic interaction between the micelle and the substrate is responsible for the catalytic activity of the nanoparticles in micelle.
Department of Chemistry, National Institute of Technology, Silchar-788010, Assam, India.
Tanur
T
Sinha
Department of Chemistry, National Institute of Technology, Silchar-788010, Assam, India. Electronic address: md_2002@rediffmail.com.
M
M
Ahmaruzzaman
Department of Chemistry, National Institute of Technology, Silchar-788010, Assam, India.
A K
AK
Sil
Department of Chemistry, National Institute of Technology, Silchar-788010, Assam, India.
Archita
A
Bhattacharjee
D000818:Animals; D032701:Biomimetics / Q000379:methods; D002384:Catalysis; D003530:Cyprinidae / Q000033:anatomy & histology; D005780:Gelatin / Q000737:chemistry*; D055772:Green Chemistry Technology / Q000379:methods*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D009574:Nitro Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D019163:Reducing Agents / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D006841:Hydrocarbons, Aromatic; D009574:Nitro Compounds; D019163:Reducing Agents; D012834:Silver; D005780:Gelatin
Fish scales; Gelatin; Micelle; Nitro-compounds; Reduction; Silver nanoparticles