Electrochemical synthesis of a microporous conductive polymer based on a metal-organic framework thin film.
A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China).
Chunjing
C
Lu
Teng
T
Ben
Shixian
S
Xu
Shilun
S
Qiu
adsorption; conducting polymers; electrochemical synthesis; metal-organic frameworks; polyaniline