Crystal structure, physical properties, and electronic and magnetic structure of the spin S = 5/2 zigzag chain compound Bi2Fe(SeO3)2OCl3.
We report the synthesis and characterization of the new bismuth iron selenite oxochloride Bi2Fe(SeO3)2OCl3. The main feature of its crystal structure is the presence of a reasonably isolated set of spin S = 5/2 zigzag chains of corner-sharing FeO6 octahedra decorated with BiO4Cl3, BiO3Cl3, and SeO3 groups. When the temperature is lowered, the magnetization passes through a broad maximum at Tmax ≈ 130 K, which indicates the formation of a magnetic short-range correlation regime. The same behavior is demonstrated by the integral electron spin resonance intensity. The absorption is characterized by the isotropic effective factor g ≈ 2 typical for high-spin Fe(3+) ions. The broadening of ESR absorption lines at low temperatures with the critical exponent β = 7/4 is consistent with the divergence of the temperature-dependent correlation length expected for the quasi-one-dimensional antiferromagnetic spin chain upon approaching the long-range ordering transition from above. At TN = 13 K, Bi2Fe(SeO3)2OCl3 exhibits a transition into an antiferromagnetically ordered state, evidenced in the magnetization, specific heat, and Mössbauer spectra. At T < TN, the (57)Fe Mössbauer spectra reveal a low saturated value of the hyperfine field Hhf ≈ 44 T, which indicates a quantum spin reduction of spin-only magnetic moment ΔS/S ≈ 20%. The determination of exchange interaction parameters using first-principles calculations validates the quasi-one-dimensional nature of magnetism in this compound.
Faculty of Chemistry, Lomonosov Moscow State University , Moscow 119991, Russia.
Peter S
PS
Berdonosov
Elena S
ES
Kuznetsova
Valery A
VA
Dolgikh
Alexei V
AV
Sobolev
Igor A
IA
Presniakov
Andrei V
AV
Olenev
Badiur
B
Rahaman
Tanusri
T
Saha-Dasgupta
Konstantin V
KV
Zakharov
Elena A
EA
Zvereva
Olga S
OS
Volkova
Alexander N
AN
Vasiliev