Morphology change and improved efficiency in organic photovoltaics via hexa-peri-hexabenzocoronene templates.
The morphology of the active layer in organic photovoltaics (OPVs) is of crucial importance as it greatly influences charge generation and transport. A templating interlayer between the electrode and the active layer can change active layer morphology and influence the domain orientation. A series of amphiphilic interface modifiers (IMs) combining a hydrophilic polyethylene-glycol (PEG) oligomer and a hydrophobic hexabenzocoronene (HBC) were designed to be soluble in PEDOT:PSS solutions, and surface accumulate on drying. These IMs are able to self-assemble in solution. When IMs are deposited on top of a poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) film, they induce a morphology change of the active layer consisting of discotic fluorenyl-substituted HBC (FHBC) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM). However, when only small amounts (0.2 wt %) of IMs are blended into PEDOT:PSS, a profound change of the active layer morphology is also observed. Morphology changes were monitored by grazing incidence wide-angle X-ray scattering (GIWAXS), transmission electron microscopy (TEM), TEM tomography, and low-energy high-angle angular dark-field scanning transmission electron microscopy (HAADF STEM). The interface modification resulted in a 20% enhancement of power conversion efficiency.
School of Chemistry, Bio21 Institute, The University of Melbourne , 30 Flemmington Road, Parkville, Victoria 3010, Australia.
Henk H
HH
Dam
Kuan
K
Sun
Eric
E
Hanssen
Jonathan M
JM
White
Tomasz
T
Marszalek
Wojciech
W
Pisula
Jens
J
Czolk
Jens
J
Ludwig
Alexander
A
Colsmann
Marina
M
Pfaff
Dagmar
D
Gerthsen
Wallace W H
WW
Wong
David J
DJ
Jones