Connection of zinc paddle-wheels in a -type metal-organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests.
A microporous metal-organic framework (mIm-MOF-14) has doubly interpenetrated anionic frameworks resulting from 2-methylimidazolate linking Zn(ii) paddle-wheels of charge-neutral -type networks, and allows the inclusion of tetramethylammonium ion to exert an enhanced CO2 affinity.
Institute for Integrative Basic Sciences, Department of Chemistry, Soongsil University, Seoul 156-743, Republic of Korea. parkhyejeong83@gmail.com jaheon@ssu.ac.kr.
Nakeun
N
Ko
Kyungkyou
K
Noh
Siyoung
S
Sung
Hye Jeong
HJ
Park
Sang Youn
SY
Park
Jaheon
J
Kim
D002245:Carbon Dioxide / Q000737:chemistry; D003460:Crystallization; D007093:Imidazoles / Q000737:chemistry*; D008024:Ligands; D009930:Organic Chemicals; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D007093:Imidazoles; D008024:Ligands; D009930:Organic Chemicals; D009942:Organometallic Compounds; D002245:Carbon Dioxide; D015032:Zinc