Designing polar and magnetic oxides: Zn2FeTaO6--in search of multiferroics.
Polar oxides are technically of great interest but difficult to prepare. Our recent discoveries predicted that polar oxides can be synthesized in the corundum-derivative A2BB'O6 family with unusually small cations at the A-site and a d(0) electron configuration ion at B'-site. When magnetic transition-metal ions are incorporated more interesting polar magnetic oxides can form. In this work we experimentally verified this prediction and prepared LiNbO3 (LN)-type polar magnetic Zn2FeTaO6 via high pressure and temperature synthesis. The crystal structure analysis indicates highly distorted ZnO6 and (Fe/Ta)O6 octahedra, and an estimated spontaneous polarization (PS) of ∼50 μC/cm(2) along the c-axis was obtained from point charge model calculations. Zn2Fe(3+)Ta(5+)O6 has a lower magnetic transition temperature (TN ∼ 22 K) than the Mn2FeTaO6 analogue but is less conductive. The dielectric and polarization measurements indicate a potentially switchable component.
Department of Chemistry and Chemical Biology, Rutgers, the State University of New Jersey , 610 Taylor Road, Piscataway, New Jersey 08854, United States.
Man-Rong
MR
Li
Peter W
PW
Stephens
Maria
M
Retuerto
Tapati
T
Sarkar
Christoph P
CP
Grams
Joachim
J
Hemberger
Mark C
MC
Croft
David
D
Walker
Martha
M
Greenblatt