Direct evidence of Lowenstein's rule violation in swelling high-charge micas.
The structure of high-charged micas, Na-n-micas (n = 2 and 4), a family of synthetic silicates with a wide range of applications, was investigated through the use of (17)O solid-state NMR at natural abundance in order to preserve quantitative spectral information. The use of a very high-field and highly sensitive probehead, together with (17)O NMR literature data allowed for the detection of an isolated signal at 26 ppm, assigned partially to AlOAl, as evidence of the violation of Lowenstein's rule for Na-4-mica.
Unité de Catalyse et de Chimie du Solide, UCCS CNRS, UMR8181, Université Lille Nord de France, 59655 Villeneuve d'Ascq, France. laurent.delevoye@ensc-lille.fr.
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