Extended and functionalized porous iron(III) tri- or dicarboxylates with MIL-100/101 topologies.
A series of nanometric isoreticular and/or functionalized analogues of the mesoporous environmentally-friendly iron(III) polycarboxylates MIL-100/101 have been successfully synthesized. Their exceptional pore size, of up to 68 Å, together with their relatively good stability in solvents, makes them promising candidates for heterogeneous catalysis or inclusion of large molecules, among others.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex, France. horcajada-cortes@uvsq.fr serre@uvsq.fr.
Patricia
P
Horcajada
Hubert
H
Chevreau
Daniela
D
Heurtaux
Farah
F
Benyettou
Fabrice
F
Salles
Thomas
T
Devic
Alfonso
A
Garcia-Marquez
Cihang
C
Yu
Hubert
H
Lavrard
Claire L
CL
Dutson
Emmanuel
E
Magnier
Guillaume
G
Maurin
Erik
E
Elkaïm
Christian
C
Serre