Anion-coordination-induced turn-on fluorescence of an oligourea-functionalized tetraphenylethene in a wide concentration range.
A tetrakis(bisurea)-decorated tetraphenylethene (TPE) ligand (L(2)) was designed, which, upon coordination with phosphate ions, displays fluorescence "turn-on" over a wide concentration range, from dilute to concentrated solutions and to the solid state. The fluorescence enhancement can be attributed to the restriction of the intramolecular rotation of TPE by anion coordination. The crystal structure of the A4L2 (A=anion) complex of L(2) with monohydrogen phosphate provides direct evidence for the coordination mode of the anion. This "anion-coordination-induced emission" (ACIE) is another approach for fluorescence turn-on in addition to aggregation-induced emission (AIE).
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China).
Jie
J
Zhao
Dong
D
Yang
Yanxia
Y
Zhao
Xiao-Juan
XJ
Yang
Yao-Yu
YY
Wang
Biao
B
Wu
anion coordination; fluorescence turn-on; oligourea; phosphate; tetraphenylethene