2-((1E)-1-{2-[(2Z)-3,4-Diphenyl-2,3-di-hydro-1,3-thia-zol-2-yl-idene]hydrazin-1-yl-idene}eth-yl)pyridin-1-ium bromide monohydrate.
In the title compound, C22H19N4S(+)·Br(-)·H2O, the dihedral angles between the phenyl groups and the mean plane of the thia-zolyl-idene ring are 34.69 (13) and 64.27 (13)°, respectively, while that between the thia-zolyl-idene and pyridinium rings is 14.73 (13)°. In the crystal, zigzag chains of alternating bromide ions and water mol-ecules associate through O-H⋯Br inter-actions run in channels approximately parallel to the b axis. These chains help form parallel chains of cations through N-H⋯O, C-H⋯N and C-H⋯Br hydrogen bonds.
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
Mehmet
M
Akkurt
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Joel T
JT
Mague
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Shaaban K
SK
Mohamed
Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Alaa A
AA
Hassan
Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq.
Mustafa R
MR
Albayati