Identification of unresolved complex mixtures (UCMs) of hydrocarbons in commercial fish oil supplements.
BACKGROUND
Heightened awareness of the health benefits of fish oil consumption has led to a great increase in the number of fish oil supplements available to the consumer. Therefore manufacturers are continually looking for ways to distinguish their products from those of competitors. Minimally refined or virgin fish oils provide a unique feature; however, petroleum hydrocarbon contamination from oil spills is a reality in the world's oceans. The question arises whether oil produced from fish species caught in these polluted areas is free of petroleum hydrocarbons, with particular interest in unresolved complex mixtures (UCMs). This study investigates the presence of UCMs in commercially available fish oil supplements advertised as being virgin, as well as refined.


RESULTS
Weathered petroleum hydrocarbons in the form of a UCM were found at 523 µg g(-1) in a virgin Alaskan salmon oil supplement. Supplements that were refined were free of this contamination.


CONCLUSIONS
Fish used in the production of fish oil supplements appear to have accumulated petrogenic hydrocarbons in their tissues which were not removed by minimal oil refining. Further study is required to determine if there are any health implications associated with long-term consumption of these contaminated supplements.
Department of Process Engineering and Applied Science, Dalhousie University, 1360 Barrington St., PO Box 15000, Halifax, NS, B3H 4R2, Canada.
Anna-Jean M
AJ
Reid
Suzanne M
SM
Budge
D000818:Animals; D003132:Commerce; D045424:Complex Mixtures / Q000032:analysis; D019587:Dietary Supplements; D005395:Fish Oils / Q000737:chemistry*; D005506:Food Contamination / Q000032:analysis*; D006801:Humans; D006838:Hydrocarbons / Q000032:analysis*; D007219:Industrial Oils; D010578:Petroleum; D012474:Salmon; D014874:Water Pollutants, Chemical / Q000032:analysis*
D045424:Complex Mixtures; D005395:Fish Oils; D006838:Hydrocarbons; D010578:Petroleum; D014874:Water Pollutants, Chemical; C030341:salmon oil
dietary supplements; fish oil refining; petrogenic hydrocarbons; salmon oil; unresolved complex mixture