Influence of pyrolysis temperature on characteristics and heavy metal adsorptive performance of biochar derived from municipal sewage sludge.
To investigate systematically the influence of pyrolysis temperature on properties and heavy metal adsorption potential of municipal sludge biochar, biophysical dried sludge was pyrolyzed under temperature varying from 500°C to 900°C. The biochar yield decreased with the increase in pyrolysis temperature, while the ash content retained mostly, thus transforming the biochars into alkaline. The structure became porous as the temperature increased, and the concentrations of surface functional group elements remained low. Despite the comparatively high content of heavy metal in the biochar, the leaching toxicity of biochars was no more than 20% of the Chinese standard. In the batch experiments of cadmium(II) adsorption, the removal capacity of biochars improved under higher temperature, especially at 800°C and 900°C even one order of magnitude higher than that of the commercial activated carbon. For both energy recovery and heavy metal removal, the optimal pyrolysis temperature is 900°C.
School of Environment, Tsinghua University, Beijing 100084, China.
Tan
T
Chen
College of Environmental Science & Engineering, Hunan University, Changsha 410082, China.
Yaxin
Y
Zhang
School of Environment, Tsinghua University, Beijing 100084, China. Electronic address: htwang@tsinghua.edu.cn.
Hongtao
H
Wang
School of Environment, Tsinghua University, Beijing 100084, China.
Wenjing
W
Lu
School of Environment, Tsinghua University, Beijing 100084, China.
Zeyu
Z
Zhou
School of Environment, Tsinghua University, Beijing 100084, China.
Yuancheng
Y
Zhang
School of Environment, Tsinghua University, Beijing 100084, China.
Lulu
L
Ren
D000327:Adsorption; D002104:Cadmium / Q000302:isolation & purification; D002606:Charcoal / Q000737:chemistry*; D002681:China; D002947:Cities; D006863:Hydrogen-Ion Concentration; D019216:Metals, Heavy / Q000302:isolation & purification*; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D012722:Sewage / Q000737:chemistry*; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013696:Temperature
D019216:Metals, Heavy; D012722:Sewage; D012996:Solutions; C540010:biochar; D002104:Cadmium; D002606:Charcoal; D009584:Nitrogen
Biochar; Fast pyrolysis; Heavy metal adsorption; Municipal sewage sludge; Temperature