title: Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(IV) species with monoamido ligation: a putative reactive species generated from iron-bleomycin.
abstract: The preparation and characterisation of an oxoiron(IV) species with monoamido ligation are described. Reactivity studies revealed the important role of the amido ligand in enhancing the ability of oxoiron(IV) complexes to promote hydrogen atom transfer from external alkanes.
authors.affiliation: Department of Molecular Chemistry and Biochemistry, Doshisha University, 1-3 TataraMiyakodani, Kyotanabe, Kyoto 610-0321, Japan. yhitomi@mail.doshisha.ac.jp.
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Hitomi
authors.forename: Kengo
authors.initials: K
authors.lastname: Arakawa
authors.forename: Masahito
authors.initials: M
authors.lastname: Kodera
mesh_terms: D001761:Bleomycin / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000378:metabolism; D019159:Nonheme Iron Proteins / Q000138:chemical synthesis* / Q000378:metabolism; D055550:Protein Stability; D017382:Reactive Oxygen Species / Q000138:chemical synthesis* / Q000378:metabolism
chemical_list: D019159:Nonheme Iron Proteins; D017382:Reactive Oxygen Species; C023503:iron bleomycin; D001761:Bleomycin