title: Altered transport of lindane caused by the retention of natural particles in saturated porous media.
abstract: Attachment and straining of colloidal particles in porous media result in their reversible and irreversible retention. The retained particles may either increase the retention of hydrophobic pollutants by sorption onto the particles, or enhance pollutant transport when particles, loaded with the pollutants, are remobilized. The present study examines the effects of retained particles on the transport of the hydrophobic pesticide lindane (gamma-hexachlorocyclohexane) in saturated porous media. The lignite particles used have median diameters of about 3 μm, 1 μm, 0.8 μm, and 0.2 μm, respectively. Laboratory column experiments were analyzed by numerical modeling in order to identify and understand the processes involved in the transport of the particles and of lindane. Four scenarios were considered in which the solution containing lindane is injected either during or after the elution of the particles. The results show that lignite particles retained in a sandy porous medium alter the transport of the invading lindane. Particle retention was high in all scenarios and increased with increasing particle size. Remobilization of particles occurred due to a change in solution chemistry, and continuous particle detachment was observed over time. Numerical modeling of particle transport suggests that both reversible attachment and irreversible straining affected the transport of the particles. Lindane was retarded in all scenarios due to the strong particle retention in conjunction with the sorption of lindane onto the sand and onto retained particles, and the limited number of mobile particles carrying lindane. Moreover, it was found that intra-particle diffusion limited adsorption/desorption of lindane onto/from both limestone fragments of the sand and lignite particles. We assume that retention of lindane is reversible even though lindane recovery was incomplete over the duration of the experiments. The analysis of the effluent concentration suggests that retained particles loaded with lindane may become a secondary source of lindane. Models describing the transport of lindane fitted the experimental data very well and indicated the specific contribution of retained particles to the retardation of lindane. Since the properties of lignite also known as brown coal are similar to those of biochar, the results of the present study could be extended to the potential effects of biochar on lindane and other contaminants in soils, which would include both their retention and their enhanced transport. However, while the transport mechanisms of lindane are similar in water-unsaturated soils and saturated porous media considered here, the behavior of particles is more complex, requiring additional studies.
authors.affiliation: Center for Applied Geoscience, University of Tübingen, Hölderlinstrasse 12, 72074 Tübingen, Germany.
authors.forename: Stéphane K
authors.initials: SK
authors.lastname: Ngueleu
authors.affiliation: Center for Applied Geoscience, University of Tübingen, Hölderlinstrasse 12, 72074 Tübingen, Germany.
authors.forename: Peter
authors.initials: P
authors.lastname: Grathwohl
authors.affiliation: Center for Applied Geoscience, University of Tübingen, Hölderlinstrasse 12, 72074 Tübingen, Germany. Electronic address: olaf.cirpka@uni-tuebingen.de.
authors.forename: Olaf A
authors.initials: OA
authors.lastname: Cirpka
mesh_terms: D000327:Adsorption; D003031:Coal; D052918:Environmental Restoration and Remediation; D060587:Groundwater / Q000737:chemistry*; D001556:Hexachlorocyclohexane / Q000032:analysis / Q000737:chemistry*; D008956:Models, Chemical; D010316:Particle Size; D016062:Porosity; D012987:Soil; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D003031:Coal; D012987:Soil; D014874:Water Pollutants, Chemical; D001556:Hexachlorocyclohexane
keywords: Colloidal particles; Diffusion; Groundwater; Lindane; Modeling; Particle-facilitated transport; Retention; Sorption