title: Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.
abstract: A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.
authors.affiliation: Department of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA. dwj@uoregon.edu haley@uoregon.edu.
authors.forename: Jesse V
authors.initials: JV
authors.lastname: Gavette
authors.forename: Christina M
authors.initials: CM
authors.lastname: Klug
authors.forename: Lev N
authors.initials: LN
authors.lastname: Zakharov
authors.forename: Matthew P
authors.initials: MP
authors.lastname: Shores
authors.forename: Michael M
authors.initials: MM
authors.lastname: Haley
authors.forename: Darren W
authors.initials: DW
authors.lastname: Johnson
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D014508:Urea / Q000031:analogs & derivatives* / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D005296:Ferrous Compounds; D008024:Ligands; D015082:2,2'-Dipyridyl; D014508:Urea; C029451:ferrous chloride