title: Hair-inspired crystal growth of HOA in cavities of cellulose matrix via hydrophobic-hydrophilic interface interaction.
abstract: As one of the most ordinary phenomena in nature, numerous pores on animal skins induce the growth of abundant hairs. In this study, cavities of a cellulose matrix were used as hard templates to lead the hair-inspired crystal growth of 12-hydroxyoctadecanoic acid (HOA) through hydrophobic-hydrophilic interface interaction, and short hair-like HOA crystals with a smooth surface were formed on cellulose films. In our findings, by using solvent evaporation induced crystallization, hydrophobic HOA grew along the hydrophilic cellulose pore wall to form regular vertical worm-like and pillar-like crystals with an average diameter of about 200 nm, depending on the experimental conditions and HOA concentration. The formation mechanism of the short hair-like HOA crystals as well as the structure and properties of the cellulose/HOA submicrometer composite films were studied. The pores of the cellulose matrix supplied not only cavities for the HOA crystals fixation but also hydrophilic shells to favor the vertical growth of the relatively hydrophobic HOA crystals. The cellulose/HOA submicrometer composite films exhibited high hydrophobicity, as a result of the formation of the solid/air composite surface. Furthermore, 4-(1,2,2-triphenylethenyl) benzoic acid, an aggregation-induced emission luminogen, was used to aggregate on the cellulose surface with HOA to emit and monitor the HOA crystal growth, showing bifunctional photoluminscence and self-cleaning properties. This work opens up a novel one-step pathway to design bio-inspired submicrometer materials by utilizing natural products, showing potential applications in self-cleaning optical devices.
authors.affiliation: Department of Chemistry, Wuhan University , Wuhan 430072, China.
authors.forename: Meng
authors.initials: M
authors.lastname: He
authors.forename: Ryan T K
authors.initials: RT
authors.lastname: Kwok
authors.forename: Zhenggang
authors.initials: Z
authors.lastname: Wang
authors.forename: Bo
authors.initials: B
authors.lastname: Duan
authors.forename: Ben Zhong
authors.initials: BZ
authors.lastname: Tang
authors.forename: Lina
authors.initials: L
authors.lastname: Zhang
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D003460:Crystallization; D005231:Fatty Acids, Unsaturated / Q000138:chemical synthesis / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties
chemical_list: D005231:Fatty Acids, Unsaturated; D012997:Solvents; C495366:hydroxyoctadecadienoic acid; D002482:Cellulose