title: Source contributions of PAHs and toxicity in reed wetland soils of Liaohe estuary using a CMB-TEQ method.
abstract: 16 US EPA priority PAHs were analyzed in surface soils collected from reed wetland of Liaohe estuary. Total concentrations of the sixteen PAHs ranged from 235 ng g(-1) to 374 ng g(-1), while the total concentrations of seven carcinogenic PAHs (cPAHs) varied from 82.6 ng g(-1) to 109 ng g(-1). Toxicity of PAHs was assessed using toxic equivalent quantity (TEQ). The BaP and DBahA were the major contributors to TEQBaP, although IND showed the highest concentration level. Quantitative source apportionment of PAHs and toxicity (i.e. TEQBaP) were performed, using the CMB-TEQ (chemical mass balance model and TEQ) method. Results showed that, the vehicular sources (gasoline and diesel engine emissions) yielded a higher contribution to TEQBaP (95.7%) than that to PAHs (57.1%), while petrogenic source and biomass burning, two important contributors for total PAHs (21.6% and 21.3%, respectively), contributed a little to TEQBaP (3.6% and 0.7%, respectively).
authors.affiliation: Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China.
authors.forename: Guoliang
authors.initials: G
authors.lastname: Li
authors.affiliation: Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China. Electronic address: yhlang@ouc.edu.cn.
authors.forename: Yinhai
authors.initials: Y
authors.lastname: Lang
authors.affiliation: Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Yang
authors.affiliation: Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China.
authors.forename: Peng
authors.initials: P
authors.lastname: Peng
authors.affiliation: Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China.
authors.forename: Xiaomei
authors.initials: X
authors.lastname: Wang
mesh_terms: D004784:Environmental Monitoring / Q000379:methods*; D063366:Estuaries; D019015:Geologic Sediments / Q000737:chemistry; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis*; D053833:Wetlands
chemical_list: D011084:Polycyclic Aromatic Hydrocarbons; D012987:Soil; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical
keywords: Chemical mass balance model; PAHs; Reed wetland; TEQ