title: Highly active photocatalytic coatings prepared by a low-temperature method.
abstract: Photocatalytic properties of titanium (IV) oxide (TiO2) in anatase form can be used for various purposes, including photocatalytic purification of water. For such an application, suspended or fixed photocatalytic reactors are used. Those with fixed phase seem to be preferred due to some advantages, one of which is the avoidance of photocatalyst filtration. To avoid leaching and exfoliation of the fixed phase, an immobilization procedure leading to a good adhesion of a catalyst to a substrate is crucial. Within this work, we present physical and photocatalytic characterization results of five commercially available TiO2 photocatalysts (P25, P90, PC500, KRONOClean 7000, VPC-10) and one pigment (Hombitan LO-CR-S-M), which were successfully immobilized on glass slides by a "sol suspension" procedure. Different mechanical tests and characterization methods were used to evaluate the stability and morphology of the layers. Evaluation of photocatalytic activity was done by tests under UVA and UV-vis irradiation, using a method based on the detection of the fluorescent oxidation product of terephthalic acid (TPA), i.e., hydroxyterephthalic acid (HTPA). Aeroxide® P90 incorporated into the silica-titania binder was the most photocatalytically active layer and, unlike the others, showed significant increase of photocatalytic activity through the entire range of tested UVA irradiation intensities (2.3 mW/cm(2)-6.1 mW/cm(2)). The high mechanical stability of some photocatalytic layers allows using them in water photocatalytic purification reactions.
authors.affiliation: Laboratory for Environmental Research, University of Nova Gorica, Vipavska 13, 5000, Nova Gorica, Slovenia.
authors.forename: Marko
authors.initials: M
authors.lastname: Kete
authors.forename: Egon
authors.initials: E
authors.lastname: Pavlica
authors.forename: Fernando
authors.initials: F
authors.lastname: Fresno
authors.forename: Gvido
authors.initials: G
authors.lastname: Bratina
authors.forename: Urška Lavrenčič
authors.initials: UL
authors.lastname: Štangar
mesh_terms: D002384:Catalysis; D053758:Nanoparticles / Q000737:chemistry / Q000528:radiation effects; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D010795:Phthalic Acids / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry / Q000528:radiation effects; D013696:Temperature; D014025:Titanium / Q000737:chemistry / Q000528:radiation effects; D014466:Ultraviolet Rays; D018508:Water Purification
chemical_list: D010795:Phthalic Acids; C009495:titanium dioxide; C011363:terephthalic acid; D012822:Silicon Dioxide; D014025:Titanium