title: The syntheses of α-ketoamides via(n)Bu4NI-catalyzed multiple sp(3)C-H bond oxidation of ethylarenes and sequential coupling with dialkylformamides.
abstract: The (n)Bu4NI-catalyzed sequential C-O and C-N bond formation via multiple sp(3)C-H bond activation of ethylarenes, using N,N-dialkylformamide as the amino source, provided α-ketoamides with moderate yields.
authors.affiliation: Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China.
authors.forename: Bingnan
authors.initials: B
authors.lastname: Du
authors.forename: Bo
authors.initials: B
authors.lastname: Jin
authors.forename: Peipei
authors.initials: P
authors.lastname: Sun
mesh_terms: D002384:Catalysis; D005559:Formamides / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D020122:tert-Butylhydroperoxide / Q000737:chemistry
chemical_list: D005559:Formamides; D007659:Ketones; D047028:Macrocyclic Compounds; D000644:Quaternary Ammonium Compounds; D020122:tert-Butylhydroperoxide; C009405:tetrabutylammonium