title: Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles.
abstract: C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triaryl-methyl (TAM) radicals as the major products. The only byproducts were symmetrical TAMs.
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm ; Department of Natural Sciences, National Research University, Novosibirsk State University, 2 Pirogov St., Novosibirsk 630090, Russia.
authors.forename: Victor M
authors.initials: VM
authors.lastname: Tormyshev
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
authors.forename: Olga Yu
authors.initials: OY
authors.lastname: Rogozhnikova
authors.affiliation: Department of Chemistry, The University of Alabama, Box 870336, Tuscaloosa, Alabama 35487-0336, USA.
authors.forename: Michael K
authors.initials: MK
authors.lastname: Bowman
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
authors.forename: Dmitry V
authors.initials: DV
authors.lastname: Trukhin
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
authors.forename: Tatiana I
authors.initials: TI
authors.lastname: Troitskaya
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
authors.forename: Vladimir G
authors.initials: VG
authors.lastname: Vasiliev
authors.affiliation: Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Acad. M.A. Lavrentjev Ave., Novosibirsk 630090, Russia, http://www.nioch.nsc.ru/eng/labs/mcg_e.htm.
authors.forename: Leonid A
authors.initials: LA
authors.lastname: Shundrin
authors.affiliation: The Center for EPR Imaging in vivo Physiology, Department of Radiation and Cellular Oncology, The University of Chicago, Chicago, IL 60637, USA, http://epri.uchicago.edu/
authors.forename: Howard J
authors.initials: HJ
authors.lastname: Halpern
keywords: Carbocations; Electron transfer; Nucleophilic addition; Radicals; Reaction mechanisms