title: On the role of low-permeability beds in the acquisition of F and SO4 concentrations in a multi-layer aquifer, South-West France.
abstract: Fluoride (F(-)) commonly threatens groundwater quality. This is the case around the city of Bordeaux (France), where numerous wells tapping the thick and complex Eocene aquifer are contaminated by fluoride, which presents an issue for drinking water supply. The joint analysis of the spatial distribution of fluoride with other species like sulfate suggests that concentrations are mainly related to the occurrence of low-permeability layers containing evaporites or fluorite deposits. In order to identify the origin of the observed concentrations, a radial flow and transport model is implemented at the borehole scale. The hydraulic conductivity of the low-permeability layers and the vertical dispersivity of the aquifer were optimized to match the observed values of sulfate and fluoride concentrations. Interestingly, each of these parameters influences differently the simulated concentrations. This model has been successfully implemented to a neighboring well with the same parameter values, which tests the approach. The major conclusions drawn are: (i) the contamination in fluoride originates from the low-permeability layers, (ii) every low-permeability layer intercepted by the well releases fluoride (iii) Contamination not only originates from pore water of low-permeability layers, but may persist with long-term pumping due to mineral dissolution. As a consequence, fluoride contamination is likely to persist for a long time and the only solution to reduce fluoride concentration in abstracted water is to seal well screens facing low-permeability layers.
authors.affiliation: CFG Services, 3 Avenue C. Guillemin, BP 6429, 45064 Orléans Cedex 2, France. Electronic address: e.malcuit@cfg.brgm.fr.
authors.forename: E
authors.initials: E
authors.lastname: Malcuit
authors.affiliation: ENSEGID-IPB, 1 allée Daguin, 33607 Pessac, France. Electronic address: olivier.atteia@ipb.fr.
authors.forename: O
authors.initials: O
authors.lastname: Atteia
authors.affiliation: ENSEGID-IPB, 1 allée Daguin, 33607 Pessac, France. Electronic address: franceschi@ipb.fr.
authors.forename: F
authors.initials: F
authors.lastname: Larroque
authors.affiliation: ENSEGID-IPB, 1 allée Daguin, 33607 Pessac, France. Electronic address: larroque@ipb.fr.
authors.forename: M
authors.initials: M
authors.lastname: Franceschi
authors.affiliation: ENSEGID-IPB, 1 allée Daguin, 33607 Pessac, France. Electronic address: alexandre.pryet@ensegid.fr.
authors.forename: A
authors.initials: A
authors.lastname: Pryet
mesh_terms: D004784:Environmental Monitoring; D005459:Fluorides / Q000032:analysis*; D005602:France; D019015:Geologic Sediments / Q000737:chemistry*; D060587:Groundwater / Q000737:chemistry*; D008962:Models, Theoretical; D013431:Sulfates / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014877:Water Pollution, Chemical / Q000032:analysis*; D014881:Water Supply / Q000032:analysis*
chemical_list: D013431:Sulfates; D014874:Water Pollutants, Chemical; D005459:Fluorides
keywords: Fluoride; Geochemistry; Groundwater; Modeling