title: Investigation of waste incineration of fluorotelomer-based polymers as a potential source of PFOA in the environment.
abstract: In light of the widespread presence of perfluorooctanoic acid (PFOA) in the environment, a comprehensive laboratory-scale study has developed data requested by the U.S. Environmental Protection Agency (EPA) to determine whether municipal and/or medical waste incineration of commercial fluorotelomer-based polymers (FTBPs) at end of life is a potential source of PFOA that may contribute to environmental and human exposures. The study was divided into two phases (I and II) and conducted in accordance with EPA Good Laboratory Practices (GLPs) as described in the quality assurance project plan (QAPP) for each phase. Phase I testing determined that the PFOA transport efficiency across the thermal reactor system to be used in Phase II was greater than 90%. Operating at 1000°C over 2s residence time with 3.2-6.6mgdscm(-1) hydrogen fluoride (HF), corrected to 7% oxygen (O2), and continuously monitored exhaust oxygen of 13%, Phase II testing of the FTBP composites in this thermal reactor system yielded results demonstrating that waste incineration of fluorotelomer-based polymers does not result in the formation of detectable levels of PFOA under conditions representative of typical municipal waste combustor (MWC) and medical waste incinerator (MWI) operations in the U.S. Therefore, waste incineration of these polymers is not expected to be a source of PFOA in the environment.
authors.affiliation: University of Dayton Research Institute, Environmental Engineering Group, 300 College Park, Dayton, OH 45469, United States. Electronic address: ptaylor1@udayton.edu.
authors.forename: P H
authors.initials: PH
authors.lastname: Taylor
authors.affiliation: University of Dayton Research Institute, Environmental Engineering Group, 300 College Park, Dayton, OH 45469, United States.
authors.forename: T
authors.initials: T
authors.lastname: Yamada
authors.affiliation: University of Dayton Research Institute, Environmental Engineering Group, 300 College Park, Dayton, OH 45469, United States.
authors.forename: R C
authors.initials: RC
authors.lastname: Striebich
authors.affiliation: University of Dayton Research Institute, Environmental Engineering Group, 300 College Park, Dayton, OH 45469, United States.
authors.forename: J L
authors.initials: JL
authors.lastname: Graham
authors.affiliation: E.I. du Pont de Nemours and Company, Inc., 1007 Market Street, Wilmington, DE 19898, United States.
authors.forename: R J
authors.initials: RJ
authors.lastname: Giraud
mesh_terms: D002210:Caprylates / Q000737:chemistry*; D004777:Environment; D004785:Environmental Pollutants / Q000737:chemistry*; D005465:Fluorocarbon Polymers / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D006801:Humans; D017745:Incineration; D008506:Medical Waste / Q000032:analysis*; D014481:United States
chemical_list: D002210:Caprylates; D004785:Environmental Pollutants; D005465:Fluorocarbon Polymers; D005466:Fluorocarbons; D008506:Medical Waste; C023036:perfluorooctanoic acid
keywords: End of life; Fluorotelomer; Incineration; MSW; Municipal waste; PFOA