title: The synthesis and structure of chiral enamine N-oxides.
abstract: Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.
authors.affiliation: Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK. ion@liv.ac.uk.
authors.forename: I A
authors.initials: IA
authors.lastname: O'Neil
authors.forename: M
authors.initials: M
authors.lastname: McConville
authors.forename: K
authors.initials: K
authors.lastname: Zhou
authors.forename: C
authors.initials: C
authors.lastname: Brooke
authors.forename: C M
authors.initials: CM
authors.lastname: Robertson
authors.forename: N G
authors.initials: NG
authors.lastname: Berry
mesh_terms: D018360:Crystallography, X-Ray; D061565:Cycloaddition Reaction; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D010087:Oxides / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D010087:Oxides