title: Dispersed-nanoparticle loading synthesis for monodisperse Au-titania composite particles and their crystallization for highly active UV and visible photocatalysts.
abstract: Submicrometer-sized amorphous titania spheres incorporating Au nanoparticles (NPs) were prepared in a one-pot synthesis consisting of a sol-gel reaction of titanium(IV) isopropoxide in the presence of chloroauric acid and a successive reduction with sodium borohydride in a mixed solvent of ethanol/acetonitrile. The synthesis was allowed to prepare monodisperse titania spheres that homogeneously incorporated Au NPs with sizes of ca. 7 nm. The Au NP-loaded titania spheres underwent different crystallization processes, including 500 °C calcination in air, high-temperature hydrothermal treatment (HHT), and/or low-temperature hydrothermal treatment (LHT). Photocatalytic experiments were conducted with the Au NP-loaded crystalline titania spheres under irradiation of UV and visible light. A combined process of LHT at 80 °C followed by calcination at 500 °C could effectively crystallize titania spheres maintaining the dispersion state of Au NPs, which led to photocatalytic activity higher than that of commercial P25 under UV irradiation. Under visible light irradiation, the Au NP-titania spheres prepared with a crystallization process of LHT at 80 °C for 6 h showed photocatalytic activity much higher than a commercial product of visible light photocatalyst. Structure analysis of the visible light photocatalysts indicates the importance of prevention of the Au NPs aggregation in the crystallization processes for enhancement of photocatalytic activity.
authors.affiliation: Department of Chemical Engineering, ‡Graduate School of Engineering, Tohoku University , 6-6-07 Aoba Aramaki-aza, Aoba-ku, Sendai 980-8579, Japan.
authors.forename: Takeshi
authors.initials: T
authors.lastname: Sakamoto
authors.forename: Daisuke
authors.initials: D
authors.lastname: Nagao
authors.forename: Masahiro
authors.initials: M
authors.lastname: Noba
authors.forename: Haruyuki
authors.initials: H
authors.lastname: Ishii
authors.forename: Mikio
authors.initials: M
authors.lastname: Konno