title: Poly(exTTF): a novel redox-active polymer as active material for li-organic batteries.
abstract: The first polymer bearing exTTF units intended for the use in electrical charge storage is presented. The polymer undergoes a redox reaction involving two electrons at -0.20 V vs Fc/Fc(+) and is applied as active cathode material in a Li-organic battery. The received coin cells feature a theoretical capacity of 132 mAh g(-1) , a cell potential of 3.5 V, and a lifetime exceeding more than 250 cycles.
authors.affiliation: Laboratory of Organic and Macromolecular Chemistry, Friedrich Schiller University Jena, Humboldtstr. 10, 07743, Jena, Germany; Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, 07743, Jena, Germany.
authors.forename: Bernhard
authors.initials: B
authors.lastname: Häupler
authors.forename: René
authors.initials: R
authors.lastname: Burges
authors.forename: Christian
authors.initials: C
authors.lastname: Friebe
authors.forename: Tobias
authors.initials: T
authors.lastname: Janoschka
authors.forename: Daniel
authors.initials: D
authors.lastname: Schmidt
authors.forename: Andreas
authors.initials: A
authors.lastname: Wild
authors.forename: Ulrich S
authors.initials: US
authors.lastname: Schubert
mesh_terms: D011211:Electric Power Supplies; D004566:Electrodes; D005609:Free Radicals / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008094:Lithium / Q000737:chemistry*; D010084:Oxidation-Reduction; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D005609:Free Radicals; D006571:Heterocyclic Compounds; D007477:Ions; D011108:Polymers; D008094:Lithium; C063887:tetrathiafulvalene