title: Rhodium(III)-catalyzed intramolecular amidoarylation and hydroarylation of alkyne via C-H activation: switchable synthesis of 3,4-fused tricyclic indoles and chromans.
abstract: The controllable intramolecular amidoarylation and hydroarylation of alkynes has been achieved via rhodium(III)-catalyzed C-H activation. The merger of two distinct reaction pathways allows for the development of atom- and step-economic protocols for the switchable synthesis of 3,4-fused indoles and chromans, respectively.
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun 130024, China. xuxx677@nenu.edu.cn liuqun@nenu.edu.cn.
authors.forename: Xue
authors.initials: X
authors.lastname: Zhang
authors.forename: Yifei
authors.initials: Y
authors.lastname: Li
authors.forename: Hui
authors.initials: H
authors.lastname: Shi
authors.forename: Lunan
authors.initials: L
authors.lastname: Zhang
authors.forename: Shanshan
authors.initials: S
authors.lastname: Zhang
authors.forename: Xianxiu
authors.initials: X
authors.lastname: Xu
authors.forename: Qun
authors.initials: Q
authors.lastname: Liu
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D002839:Chromans / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D000480:Alkynes; D002839:Chromans; D007211:Indoles; D012238:Rhodium