title: Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis.
abstract: The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates.
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Mirim
authors.initials: M
authors.lastname: Kim
authors.forename: Satyasheel
authors.initials: S
authors.lastname: Sharma
authors.forename: Neeraj Kumar
authors.initials: NK
authors.lastname: Mishra
authors.forename: Sangil
authors.initials: S
authors.lastname: Han
authors.forename: Jihye
authors.initials: J
authors.lastname: Park
authors.forename: Minyoung
authors.initials: M
authors.lastname: Kim
authors.forename: Youngmi
authors.initials: Y
authors.lastname: Shin
authors.forename: Jong Hwan
authors.initials: JH
authors.lastname: Kwak
authors.forename: Sang Hoon
authors.initials: SH
authors.lastname: Han
authors.forename: In Su
authors.initials: IS
authors.lastname: Kim
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis*; D001549:Benzamides / Q000138:chemical synthesis*; D002254:Carbonates / Q000138:chemical synthesis; D002384:Catalysis; D010165:Palladium / Q000737:chemistry; D011759:Pyrrolidines / Q000138:chemical synthesis*; D012238:Rhodium / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D001549:Benzamides; D002254:Carbonates; D011759:Pyrrolidines; D010165:Palladium; D012428:Ruthenium; D012238:Rhodium