title: The jamming elasticity of emulsions stabilized by ionic surfactants.
abstract: Oil-in-water emulsions composed of colloidal-scale droplets are often stabilized using ionic surfactants that provide a repulsive interaction between neighboring droplet interfaces, thereby inhibiting coalescence. If the droplet volume fraction is raised rapidly by applying an osmotic pressure, the droplets remain disordered, undergo an ergodic-nonergodic transition, and jam. If the applied osmotic pressure approaches the Laplace pressure of the droplets, then the jammed droplets also deform. Because solid friction and entanglements cannot play a role, as they might with solid particulate or microgel dispersions, the shear mechanical response of monodisperse emulsions can provide critical insight into the interplay of entropic, electrostatic, and interfacial forces. Here, we introduce a model that can be used to predict the plateau storage modulus and yield stress of a uniform charge-stabilized emulsion accurately if the droplet radius, interfacial tension, surface potential, Debye screening length, and droplet volume fraction are known.
authors.affiliation: Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg, Switzerland. Frank.Scheffold@unifr.ch.
authors.forename: Frank
authors.initials: F
authors.lastname: Scheffold
authors.forename: James N
authors.initials: JN
authors.lastname: Wilking
authors.forename: Jakub
authors.initials: J
authors.lastname: Haberko
authors.forename: Frédéric
authors.initials: F
authors.lastname: Cardinaux
authors.forename: Thomas G
authors.initials: TG
authors.lastname: Mason
mesh_terms: D004548:Elasticity; D045703:Emulsifying Agents / Q000737:chemistry*; D004655:Emulsions / Q000737:chemistry*; D019277:Entropy; D008956:Models, Chemical; D009821:Oils / Q000737:chemistry; D009997:Osmotic Pressure; D055672:Static Electricity; D013499:Surface Properties; D014867:Water / Q000737:chemistry
chemical_list: D045703:Emulsifying Agents; D004655:Emulsions; D009821:Oils; D014867:Water