title: Temporal pulse shaping: a key parameter for the laser welding of dental alloys.
abstract: This study aims to describe the effect of pulse shaping on the prevention of internal defects during laser welding for two dental alloys mainly used in prosthetic dentistry. Single spot, weld beads, and welds with 80 % overlapping were performed on Co-Cr-Mo and Pd-Ag-Sn cast plates with a pulsed neodymium-doped yttrium aluminum garnet (Nd:YAG) laser. A specific welding procedure using adapted parameters to each alloy was completed. All the possibilities for pulse shaping were tested: (1) the square pulse shape as a default setting, (2) a rising edge slope for gradual heating, (3) a falling edge slope to slow the cooling process, and (4) a combination of rising and falling edges. The optimization of the pulse shape is supposed to produce defect-free welds (crack, pores, voids). Cross-section SEM observations and Vickers microhardness measurements were made. Pd-Ag-Sn was highly sensitive to hot cracking, and Co-Cr-Mo was more sensitive to voids and small porosities (sometimes combined with cracks). Using a slow cooling ramp allowed a better control on the solidification process for those two alloys always preventing internal defects. A rapid slope should be preferred for Co-Cr-Mo alloys due to its low-laser beam reflectivity. On the opposite, for Pd-Ag-Sn alloy, a slow rising slope should be preferred because this alloy has a high-laser beam reflectivity.
authors.affiliation: Institut de la Chimie de la Matière Condensée de Bordeaux (ICMCB), C.N.R.S., UPR9048, Université Bordeaux, 87 Avenue du Dr. Albert Schweitzer, 33608, Pessac, France, caroline.bertrand@u-bordeaux.fr.
authors.forename: Caroline
authors.initials: C
authors.lastname: Bertrand
authors.forename: Angeline
authors.initials: A
authors.lastname: Poulon-Quintin
mesh_terms: D002858:Chromium Alloys / Q000737:chemistry*; D012994:Dental Soldering / Q000379:methods*; D006244:Hardness; D053844:Lasers, Solid-State; D010165:Palladium / Q000737:chemistry; D016062:Porosity
chemical_list: D002858:Chromium Alloys; D010165:Palladium