title: Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration.
abstract: A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, People's Republic of China. xuxp@suda.edu.cn shunjun@suda.edu.cn.
authors.forename: Xue-Qiang
authors.initials: XQ
authors.lastname: Chu
authors.forename: You
authors.initials: Y
authors.lastname: Zi
authors.forename: Hua
authors.initials: H
authors.lastname: Meng
authors.forename: Xiao-Ping
authors.initials: XP
authors.lastname: Xu
authors.forename: Shun-Jun
authors.initials: SJ
authors.lastname: Ji
mesh_terms: D060326:Chemistry Techniques, Synthetic / Q000379:methods*; D010710:Phosphates / Q000138:chemical synthesis* / Q000378:metabolism; D020005:Propanols / Q000138:chemical synthesis* / Q000378:metabolism
chemical_list: D010710:Phosphates; D020005:Propanols; C006463:allyl alcohol