title: A 3D aluminoborate open framework interpenetrated by 2D zinc-amine coordination-polymer networks in its 11-ring channels.
abstract: A new inorganic-organic hybrid solid, [Zn(dap)2 ][AlB5 O10 ], combining the structural features of 3D open-framework inorganic solids and 2D metal-organic coordination polymers has been synthesized under solvothermal conditions. The compound displays extensive luminescence and moderate second-harmonic-generation efficiency.
authors.affiliation: MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing 100081 (China).
authors.forename: Li
authors.initials: L
authors.lastname: Wei
authors.forename: Qi
authors.initials: Q
authors.lastname: Wei
authors.forename: Zhi-En
authors.initials: ZE
authors.lastname: Lin
authors.forename: Qin
authors.initials: Q
authors.lastname: Meng
authors.forename: Huan
authors.initials: H
authors.lastname: He
authors.forename: Bai-Feng
authors.initials: BF
authors.lastname: Yang
authors.forename: Guo-Yu
authors.initials: GY
authors.lastname: Yang
keywords: aluminoborates; coordination polymers; open frameworks; organic-inorganic hybrid composites; supramolecular templates