title: N-Substituted hydroxylamines as synthetically versatile amino sources in the iridium-catalyzed mild C-H amidation reaction.
abstract: N-Substituted hydroxylamines such as aroyloxy- or acyloxycarbamates were successfully employed as synthetically versatile amino precursors in the iridium-catalyzed direct C-H amidation of arenes. The reaction proceeds smoothly at room temperature over a broad range of substrates with high functional group tolerance to afford N-substituted arylamine products.
authors.affiliation: Center for Catalytic Hydrocarbon Functionalizations, Institute of Basic Science (IBS) , Daejeon 305-701, Korea.
authors.forename: Pitambar
authors.initials: P
authors.lastname: Patel
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang
mesh_terms: D000577:Amides / Q000737:chemistry*; D002219:Carbamates / Q000737:chemistry; D002384:Catalysis; D006898:Hydroxylamines / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000577:Amides; D002219:Carbamates; D006898:Hydroxylamines; D007495:Iridium