title: Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4'-di-tert-butylbiphenyl.
abstract: An oligomeric gold(III) compound containing dicarbanionic chelating 4,4'-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.
authors.affiliation: Fachbereich C, Anorganische Chemie, Bergische Universität Wuppertal, Gaußstr. 20, 42119 Wuppertal, Germany. fmohr@uni-wuppertal.de.
authors.forename: B
authors.initials: B
authors.lastname: David
authors.forename: U
authors.initials: U
authors.lastname: Monkowius
authors.forename: J
authors.initials: J
authors.lastname: Rust
authors.forename: C W
authors.initials: CW
authors.lastname: Lehmann
authors.forename: L
authors.initials: L
authors.lastname: Hyzak
authors.forename: F
authors.initials: F
authors.lastname: Mohr