title: Triboluminescence and vapor-induced phase transitions in the solids of methyltriphenylphosphonium tetrahalomanganate(II) complexes.
abstract: Triboluminescence (TL) of the methyltriphenylphosphonium tetrahalomanganate(II) complexes such as bis(methyltriphenylphosphonium) tetrabromomanganate (PMBB) and bis(methyltriphenylphosphonium) dibromodichloromanganate (PMBC) was switched ON and OFF reversibly by vapors of aprotic and protic solvents, respectively, for the first time. Detailed analyses indicate that solids of the PMBB and the PMBC undergo phase transitions depending on the environment, which regulate the TL activity of these compounds. The combined results of luminescence, powder X-ray diffraction, differential scanning calorimetry, and electron paramagnetic resonance were used to demonstrate crystal dynamism as well as the TL emission of PMBB and PMBC.
authors.affiliation: Corrosion and Materials Protection Division and ‡Functional Materials Division, CSIR-Central Electrochemical Research Institute , Karaikudi 630006, Tamil Nadu, India.
authors.forename: Sujitha
authors.initials: S
authors.lastname: Balsamy
authors.forename: Palani
authors.initials: P
authors.lastname: Natarajan
authors.forename: Rathinavel
authors.initials: R
authors.lastname: Vedalakshmi
authors.forename: Srinivasan
authors.initials: S
authors.lastname: Muralidharan