title: Zinc(II) Complexes with Dangling Functional Organic Groups.
abstract: Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctionalp-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction withp-aminobenzoic acid, the compound [Zn2(OOCCH3)(OOC-C6H4-NH2)3]∞was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.
authors.affiliation: Institute of Materials Chemistry, Vienna University of Technology 1060 Wien, Austria.
authors.forename: Jingxia
authors.initials: J
authors.lastname: Yang
authors.affiliation: Institute of Materials Chemistry, Vienna University of Technology 1060 Wien, Austria.
authors.forename: Michael
authors.initials: M
authors.lastname: Puchberger
authors.affiliation: Institute of Organic Chemistry, University of Vienna 1090 Vienna, Austria.
authors.forename: Renzhe
authors.initials: R
authors.lastname: Qian
authors.affiliation: Institute of Materials Chemistry, Vienna University of Technology 1060 Wien, Austria.
authors.forename: Christian
authors.initials: C
authors.lastname: Maurer
authors.affiliation: Institute of Materials Chemistry, Vienna University of Technology 1060 Wien, Austria.
authors.forename: Ulrich
authors.initials: U
authors.lastname: Schubert
keywords: Carboxylate ligands; Coordination polymers; Schiff bases; Zinc