title: Crystal melting by light: X-ray crystal structure analysis of an azo crystal showing photoinduced crystal-melt transition.
abstract: Trans-cis photoisomerization in an azo compound containing azobenzene chromophores and long alkyl chains leads to a photoinduced crystal-melt transition (PCMT). X-ray structure analysis of this crystal clarifies the characteristic coexistence of the structurally ordered chromophores through their π···π interactions and disordered alkyl chains around room temperature. These structural features reveal that the PCMT starts near the surface of the crystal and propagates into the depth, sacrificing the π···π interactions. A temporal change of the powder X-ray diffraction pattern under light irradiation and a two-component phase diagram allow qualitative analysis of the PCMT and the following reconstructive crystallization of the cis isomer as a function of product accumulation. This is the first structural characterization of a compound showing the PCMT, overcoming the low periodicity that makes X-ray crystal structure analysis difficult.
authors.affiliation: Department of Chemistry and Materials Science, Tokyo Institute of Technology , Meguro-ku, Tokyo 152-8551, Japan.
authors.forename: Manabu
authors.initials: M
authors.lastname: Hoshino
authors.forename: Emi
authors.initials: E
authors.lastname: Uchida
authors.forename: Yasuo
authors.initials: Y
authors.lastname: Norikane
authors.forename: Reiko
authors.initials: R
authors.lastname: Azumi
authors.forename: Shunsuke
authors.initials: S
authors.lastname: Nozawa
authors.forename: Ayana
authors.initials: A
authors.lastname: Tomita
authors.forename: Tokushi
authors.initials: T
authors.lastname: Sato
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Adachi
authors.forename: Shin-ya
authors.initials: SY
authors.lastname: Koshihara