title: n-Bu₄NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp³)-H with anilines under metal-free conditions.
abstract: A novel and efficient n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp(3))-H with anilines to form N-substituted anilines under metal-free conditions has been developed.
authors.affiliation: Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China. leiwang@chnu.edu.cn.
authors.forename: Xusheng
authors.initials: X
authors.lastname: Zhang
authors.forename: Min
authors.initials: M
authors.lastname: Wang
authors.forename: Pinhua
authors.initials: P
authors.lastname: Li
authors.forename: Lei
authors.initials: L
authors.lastname: Wang
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000586:Amination; D000814:Aniline Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D001593:Benzyl Compounds / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D020122:tert-Butylhydroperoxide / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D000814:Aniline Compounds; D001593:Benzyl Compounds; D009942:Organometallic Compounds; D020122:tert-Butylhydroperoxide; C023650:aniline