title: Investigating uranium distribution in surface sediments and waters: a case study of contamination from the Juniper Uranium Mine, Stanislaus National Forest, CA.
abstract: The uranium concentrations and isotopic compositions of waters, sediment leachates and sediments from Red Rock Creek in the Stanislaus National Forest of California were measured to investigate the transport of uranium from a point source (the Juniper Uranium Mine) to a natural surface stream environment. The ((234)U)/((238)U) composition of Red Rock Creek is altered downstream of the Juniper Mine. As a result of mine-derived contamination, water ((234)U)/((238)U) ratios are 67% lower than in water upstream of the mine (1.114-1.127 ± 0.009 in the contaminated waters versus 1.676 in the clean branch of the stream), and sediment samples have activity ratios in equilibrium in the clean creek and out of equilibrium in the contaminated creek (1.041-1.102 ± 0.007). Uranium concentrations in water, sediment and sediment leachates are highest downstream of the mine, but decrease rapidly after mixing with the clean branch of the stream. Uranium content and compositions of the contaminated creek headwaters relative to the mine tailings of the Juniper Mine suggest that uranium has been weathered from the mine and deposited in the creek. The distribution of uranium between sediment surfaces (leachable fraction) and bulk sediment suggests that adsorption is a key element of transfer along the creek. In clean creek samples, uranium is concentrated in the sediment residues, whereas in the contaminated creek, uranium is concentrated on the sediment surfaces (∼70-80% of uranium in leachable fraction). Contamination only exceeds the EPA maximum contaminant level (MCL) for drinking water in the sample with the closest proximity to the mine. Isotopic characterization of the uranium in this system coupled with concentration measurements suggest that the current state of contamination in Red Rock Creek is best described by mixing between the clean creek and contaminated upper branch of Red Rock Creek rather than mixing directly with mine sediment.
authors.affiliation: Lawrence Livermore National Laboratory, Chemical Sciences Division, USA. Electronic address: kayzar1@llnl.gov.
authors.forename: Theresa M
authors.initials: TM
authors.lastname: Kayzar
authors.affiliation: Lawrence Livermore National Laboratory, Chemical Sciences Division, USA; California State University East Bay, Department of Chemistry, USA.
authors.forename: Adam C
authors.initials: AC
authors.lastname: Villa
authors.affiliation: Lawrence Livermore National Laboratory, Chemical Sciences Division, USA; University of Cincinnati, Nuclear and Radiological Engineering Program, School of Dynamic Systems, USA.
authors.forename: Megan L
authors.initials: ML
authors.lastname: Lobaugh
authors.affiliation: Lawrence Livermore National Laboratory, Chemical Sciences Division, USA.
authors.forename: Amy M
authors.initials: AM
authors.lastname: Gaffney
authors.affiliation: Lawrence Livermore National Laboratory, Chemical Sciences Division, USA.
authors.forename: Ross W
authors.initials: RW
authors.lastname: Williams
mesh_terms: D002140:California; D004784:Environmental Monitoring; D005618:Fresh Water / Q000032:analysis*; D019015:Geologic Sediments / Q000032:analysis*; D013058:Mass Spectrometry; D008906:Mining; D014501:Uranium / Q000032:analysis*; D014875:Water Pollutants, Radioactive / Q000032:analysis*
chemical_list: D014875:Water Pollutants, Radioactive; D014501:Uranium
keywords: Geochemistry; MC-ICP-MS; Sediment contamination; Uranium isotopes; Uranium mining; Water chemistry