title: Energy-efficient green catalysis: supported gold nanoparticle-catalyzed aminolysis of esters with inert tertiary amines by C-O and C-N bond activations.
abstract: Catalyzed by supported gold nanoparticles, an aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of tertiary amides. Comparison studies indicated that the gold nanoparticles could perform energy-efficient green catalysis at room temperature, whereas Pd(OAc)2 could not.
authors.affiliation: College of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University , Hohhot 010022, China.
authors.forename: Yong-Sheng
authors.initials: YS
authors.lastname: Bao
authors.forename: Menghe
authors.initials: M
authors.lastname: Baiyin
authors.forename: Bao
authors.initials: B
authors.lastname: Agula
authors.forename: Meilin
authors.initials: M
authors.lastname: Jia
authors.forename: Bao
authors.initials: B
authors.lastname: Zhaorigetu
mesh_terms: D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D000577:Amides; D000588:Amines; D004952:Esters; D006046:Gold