title: A survey of enoldiazo nucleophilicity in selective C-C bond forming reactions for the synthesis of natural product-like frameworks.
abstract: A survey of in situ, catalytically generated carbocations for coupling with enoldiazoacetate nucleophiles was performed. These couplings facilitate the rapid assembly of complex organodiazo compounds that provide a template for the synthesis of a variety of carbocyclic and heterocyclic ring systems.
authors.affiliation: Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA. mdoyle3@umd.edu.
authors.forename: Yuxiao
authors.initials: Y
authors.lastname: Liu
authors.forename: Yu
authors.initials: Y
authors.lastname: Liu
authors.forename: Charles S
authors.initials: CS
authors.lastname: Shanahan
authors.forename: Xichen
authors.initials: X
authors.lastname: Xu
authors.forename: Michael P
authors.initials: MP
authors.lastname: Doyle
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D001688:Biological Products / Q000138:chemical synthesis*; D002384:Catalysis; D003503:Cyclobutanes / Q000138:chemical synthesis; D003517:Cyclopentanes / Q000138:chemical synthesis; D015394:Molecular Structure; D011720:Pyrazoles / Q000138:chemical synthesis; D013237:Stereoisomerism; D044024:Tetralones / Q000138:chemical synthesis
chemical_list: D001391:Azo Compounds; D001688:Biological Products; D003503:Cyclobutanes; D003517:Cyclopentanes; D011720:Pyrazoles; D044024:Tetralones