title: Practical and convenient synthesis of 1,6-di- or 1,2,5,6-tetra-arylhexa-1,3,5-trienes by the dimerization of Pd(0)-complexed alkenylcarbenes generated from π-allylpalladium intermediates.
abstract: Pd(0)-complexed 3-aryl or 2,3-diaryl propenylcarbenes generated from α-silyl-, α-germyl-, or α-boryl-σ-allylpalladium intermediates undergo self-dimerization to provide 1,6-di- or 1,2,5,6-tetraarylhexa-1,3,5-trienes in good to high yields. This method allows the use of a π-allylpalladium intermediate for a carbenoid precursor. Furthermore, the obtained 1,2,5,6-tetraarylhexa-1,3,5-trienes exhibit aggregation-induced emission enhancement property.
authors.affiliation: Department of Applied Chemistry and ‡Department of Chemistry, Graduate School of Science and Engineering, University of Toyama , Gofuku, Toyama 930-855, Japan.
authors.forename: Yoshikazu
authors.initials: Y
authors.lastname: Horino
authors.forename: Yu
authors.initials: Y
authors.lastname: Takahashi
authors.forename: Kaori
authors.initials: K
authors.lastname: Koketsu
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Abe
authors.forename: Kiyoshi
authors.initials: K
authors.lastname: Tsuge