title: Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer.
abstract: A new metalloporphyrin-based conjugated microporous polymer, NiP-CMP, was constructed via a homo-coupling polymerization reaction. NiP-CMP possesses a high BET surface area of over 2600 m(2) g(-1), a large pore volume of 2.288 cm(3) g(-1), good stability, and displays excellent guest uptake of 202 wt% in iodine vapour. We also highlight that the polymer exhibits outstanding performance for the reversible adsorption of iodine in solution.
authors.affiliation: State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China. xm_liu@jlu.edu.cn.
authors.forename: Sigen
authors.initials: S
authors.lastname: A
authors.forename: Yuwei
authors.initials: Y
authors.lastname: Zhang
authors.forename: Zhongping
authors.initials: Z
authors.lastname: Li
authors.forename: Hong
authors.initials: H
authors.lastname: Xia
authors.forename: Ming
authors.initials: M
authors.lastname: Xue
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Liu
authors.forename: Ying
authors.initials: Y
authors.lastname: Mu