title: A combination of the "pillaring" strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors.
abstract: Utilizing enantiopure camphorsulfonic acid as a chiral induction agent, 3D homochiral complexes were obtained from achiral 2D layers and MoO4(2-) pillars. This methodology combines the "pillaring" strategy with chiral induction, providing a new way to synthesize homochiral 3D coordination polymers intentionally from achiral precursors.
authors.affiliation: State key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China. wxt@fjirsm.ac.cn.
authors.forename: Yuehong
authors.initials: Y
authors.lastname: Wen
authors.forename: Tianlu
authors.initials: T
authors.lastname: Sheng
authors.forename: Zhihao
authors.initials: Z
authors.lastname: Sun
authors.forename: Zhenzhen
authors.initials: Z
authors.lastname: Xue
authors.forename: Yanlong
authors.initials: Y
authors.lastname: Wang
authors.forename: Yong
authors.initials: Y
authors.lastname: Wang
authors.forename: Shengmin
authors.initials: S
authors.lastname: Hu
authors.forename: Xiao
authors.initials: X
authors.lastname: Ma
authors.forename: Xintao
authors.initials: X
authors.lastname: Wu
mesh_terms: D002942:Circular Dichroism; D056831:Coordination Complexes / Q000737:chemistry; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry; D010087:Oxides / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D013237:Stereoisomerism; D013451:Sulfonic Acids / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D010087:Oxides; D011108:Polymers; D013451:Sulfonic Acids; D008982:Molybdenum; D015032:Zinc