title: Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature.
abstract: We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn-Y)2·H2O (en = ethylenediamine; MalCn-Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan. yamasita@agnus.chem.tohoku.ac.jp.
authors.forename: Shohei
authors.initials: S
authors.lastname: Kumagai
authors.forename: Shinya
authors.initials: S
authors.lastname: Takaishi
authors.forename: Brian K
authors.initials: BK
authors.lastname: Breedlove
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Okamoto
authors.forename: Hisaaki
authors.initials: H
authors.lastname: Tanaka
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Kuroda
authors.forename: Masahiro
authors.initials: M
authors.lastname: Yamashita