title: A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties.
abstract: A new polyoxomolybdate-based hybrid platform TBA4[PMo11O39{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.
authors: Institut Parisien de Chimie Moléculaire Sorbonne Universités, UPMC Univ Paris 06, CNRS UMR 8232, Université Pierre et Marie Curie, 4 place Jussieu, case courrier 42, 75252 Paris Cedex 05, France. anna.proust@upmc.fr.
authors: Corentin
authors: C
authors: Rinfray
authors: Séverine
authors: S
authors: Renaudineau
authors: Guillaume
authors: G
authors: Izzet
authors: Anna
authors: A
authors: Proust
mesh_terms: D055664:Electrochemical Techniques / Q000379:methods*; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D000644:Quaternary Ammonium Compounds; D008982:Molybdenum; C009405:tetrabutylammonium