title: Copper-catalyzed reductive coupling of aryl sulfonyl chlorides with H-phosphonates leading to S-aryl phosphorothioates.
abstract: An efficient protocol for copper-catalyzed reductive cross-coupling of aryl sulfonyl chlorides with H-phosphonates has been developed. The various S-aryl phosphorothioates were afforded in up to 86% yield for 20 examples. This protocol features high efficiency, wide functional group tolerance, commercially available aryl sulfonyl chlorides as starting materials and base-free conditions.
authors: Department of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou, 450052, P. R. China. cuixl@zzu.edu.cn wyj@zzu.edu.cn.
authors: Jie
authors: J
authors: Bai
authors: Xiuling
authors: X
authors: Cui
authors: Hui
authors: H
authors: Wang
authors: Yangjie
authors: Y
authors: Wu
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D063065:Organophosphonates / Q000737:chemistry; D009946:Organothiophosphorus Compounds / Q000138:chemical synthesis*; D013441:Sulfinic Acids / Q000737:chemistry*
chemical_list: D063065:Organophosphonates; D009946:Organothiophosphorus Compounds; D013441:Sulfinic Acids; C044255:sulfonyl chloride; D003300:Copper