title: Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties.
abstract: A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic properties of this low-coordinate and aromatic phosphorus heterocycle substantially.
authors: Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany. c.mueller@fu-berlin.de.
authors: Antonia
authors: A
authors: Loibl
authors: Iris
authors: I
authors: de Krom
authors: Evgeny A
authors: EA
authors: Pidko
authors: Manuela
authors: M
authors: Weber
authors: Jelena
authors: J
authors: Wiecko
authors: Christian
authors: C
authors: Müller