title: Synthesis and surface properties of a pH-regulated and pH-reversible anionic gemini surfactant.
abstract: A new series of N,N'-dialkyl-N,N'-diacetate ethylenediamine, differing by the length of the carbon tails (8, 10, and 12), was synthesized in two steps. Their surface properties and aggregation behavior were studied in aqueous solution using pH titration, surface tension, zeta potential, dynamic light scattering (DLS), transmission electron microscopy (TEM), and fluorescence measurements. On the basis of the pKa values obtained, surface tension was measured, as well as key surface property parameters. Combined with the zeta potential and DLS results, the experiments produced vesicles and reflected their pH-controllability through subsequent TEM and fluorescence measurements. pH-switchability was found to be reversible by light transmittance. Emulsion stability of dodecane-in-water in different pH showed that emulsion type was reversed between "on" for the O/W emulsion type and "off" for the W/O.
authors: State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology , Dalian, 116024, P. R. China.
authors: Jing
authors: J
authors: Lv
authors: Weihong
authors: W
authors: Qiao
authors: Chongqiao
authors: C
authors: Xiong