title: Entrapment of alkaloids within silver: from enantioselective hydrogenation to chiral recognition.
abstract: An alkaloid@Ag composite was prepared for the first time and used as a cathode for the enantioselective hydrogenation. Excellent yield and a remarkable enantiomeric excess value were obtained under mild conditions. Moreover, alkaloid@Ag after extraction was demonstrated to retain some chirality by linear sweep voltammetry.
authors: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China. hwang@chem.ecnu.edu.cn jxlu@chem.ecnu.edu.cn.
authors: Hengpan
authors: H
authors: Yang
authors: Dinghui
authors: D
authors: Chi
authors: Qilong
authors: Q
authors: Sun
authors: Wenwen
authors: W
authors: Sun
authors: Huan
authors: H
authors: Wang
authors: Jiaxing
authors: J
authors: Lu
mesh_terms: D000470:Alkaloids / Q000737:chemistry*; D001565:Benzoates / Q000737:chemistry; D004566:Electrodes; D005561:Formates / Q000737:chemistry; D006865:Hydrogenation; D008855:Microscopy, Electron, Scanning; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism; D014961:X-Ray Diffraction
chemical_list: D000470:Alkaloids; D001565:Benzoates; D005561:Formates; D012834:Silver