title: Chemical sulphate removal for treatment of construction and demolition debris leachate.
abstract: Construction and demolition debris (CDD) is a product of construction, renovation or demolition activities. It has a high gypsum content (52.4% of total gypsum), concentrated in the CDD sand (CDDS) fraction. To comply with the posed limit of the maximum amount of sulphate present in building sand, excess sulphate needs to be removed. In order to enable reuse of CDDS, a novel treatment process is developed based on washing of the CDDS to remove most of the gypsum, and subsequent sulphate removal from the sulphate-rich CDDS leachate. This study aims to assess chemical techniques, i.e. precipitation and adsorption, for sulphate removal from the CDDS leachate. Good sulphate removal efficiencies (up to 99.9%) from the CDDS leachate can be achieved by precipitation with barium chloride (BaCl2) and lead(II) nitrate (Pb(NO3)2). Precipitation with calcium chloride (CaCl2), calcium carbonate (CaCO3) and calcium oxide (CaO) gave less efficient sulphate removal. Adsorption of sulphate to aluminium oxide (Al2O3) yielded a 50% sulphate removal efficiency, whereas iron oxide-coated sand as adsorbent gave only poor (10%) sulphate removal efficiencies.
authors: Pimluck
authors: P
authors: Kijjanapanich
authors: Ajit P
authors: AP
authors: Annachhatre
authors: Giovanni
authors: G
authors: Esposito
authors: Piet N L
authors: PN
authors: Lens
mesh_terms: D000327:Adsorption; D017609:Barium Compounds / Q000737:chemistry; D011232:Chemical Precipitation; D002712:Chlorides / Q000737:chemistry; D003252:Construction Materials; D007854:Lead / Q000737:chemistry; D009566:Nitrates / Q000737:chemistry; D013431:Sulfates / Q000302:isolation & purification*; D014876:Water Pollution / Q000517:prevention & control*
chemical_list: D017609:Barium Compounds; D002712:Chlorides; D009566:Nitrates; D013431:Sulfates; C024986:barium chloride; D007854:Lead; C017461:lead nitrate