title: A physical pulverization strategy for preparing a highly active composite of CoOx and crushed graphite for lithium-oxygen batteries.
abstract: A new physical pulverization strategy has been developed to prepare a highly active composite of CoOx and crushed graphite (CG) for the cathode in lithium-oxygen batteries. The effect of CoOx loading on the charge potential in the oxygen evolution reaction (Li(2)O(2) →2 Li(+) +O(2) +2e(-)) was investigated in coin-cell tests. The CoOx (38.9 wt %)/CG composite showed a low charge potential of 3.92 V with a delivered capacity of 2 mAh cm(-2) under a current density of 0.2 mA cm(-2). The charge potential was 4.10 and 4.15 V at a capacity of 5 and 10 mAh cm(-2), respectively, with a current density of 0.5 mA cm(-2). The stability of the electrolyte and discharge product on the gas-diffusion layer after the cycling were preliminarily characterized by (1)H nuclear magnetic resonance spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. The high activity of the composite was further analyzed by electrochemical impedance spectroscopy, cyclic voltammetry, and potential-step chronoamperometry. The results indicate that our near-dry milling method is an effective and green approach to preparing a nanocomposite cathode with high surface area and porosity, while using less solvent. Its relative simplicity compared with the traditional solution method could facilitate its widespread application in catalysis, energy storage, and materials science.
authors: Department of Energy Engineering, Hanyang University, 133-791 (Republic of Korea), Fax: (+82) 2 2282 7329.
authors: Jun
authors: J
authors: Ming
authors: Won-Jin
authors: WJ
authors: Kwak
authors: Jin-Bum
authors: JB
authors: Park
authors: Chang-Dae
authors: CD
authors: Shin
authors: Jun
authors: J
authors: Lu
authors: Larry
authors: L
authors: Curtiss
authors: Khalil
authors: K
authors: Amine
authors: Yang-Kook
authors: YK
authors: Sun
keywords: batteries; cobalt; graphite; material science; synthetic methods