title: Poly(vinyl chloride) blend with biodegradable cellulose acetate in presence of N-(phenyl amino) maleimides.
abstract: Wider plastic applications of poly(vinyl chloride) (PVC) has raised serious problem to the environment. Since (PVC) waste products resist biodegradation and persist in the environment for longer time. The object of this study is to blend (PVC) with biodegradable cellulose acetate to thermally support the polymer during the molding process as well as to enhance the biodegradability of (PVC) waste products. Blending of poly(vinyl chloride) and cellulose acetate (CA) in presence of N-(phenyl amino) maleimides (R-PhAM) where (R=H, 4-NO2) led to improvement in the thermal stability of the blend film at high temperatures as shown from the high values of initial decomposition temperature (To) determined from their thermogravimetry (TG) curves. Also, blending (PVC) with (CA) led to improvement in the mechanical properties of the blend films as compared to (PVC). The crystalline regions of cellulose acetate enhanced the elasticity of the blend films as shown from their high Young's modulus values.
authors: Chemistry Department, Faculty of Science, Fayium University, Fayium 63111 Egypt. Electronic address: abirabdelnaby@hotmail.com.
authors: Abir S
authors: AS
authors: Abdel-Naby
authors: Chemistry Department, Faculty of Science, Dammam University, Dammam, Saudi Arabia.
authors: Azza A
authors: AA
authors: Al-Ghamdi
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry*; D002152:Calorimetry, Differential Scanning; D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry; D008301:Maleimides / Q000737:chemistry*; D013818:Thermogravimetry; D014752:Vinyl Chloride / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D001672:Biocompatible Materials; D008301:Maleimides; C005062:acetylcellulose; D002482:Cellulose; D014752:Vinyl Chloride
keywords: Cellulose acetate; Mechanical properties; N-(phenyl amino) maleimides; Poly(vinyl chloride); Thermogravimetry