title: Structure-kinetic relationship study of organozinc reagents.
abstract: Phenylzinc reagents prepared from various zinc halides show distinct kinetic features in the palladium-catalyzed Negishi-type oxidative coupling reaction, in which the phenylzinc reagent prepared from ZnI2 gives the highest rate. In situ infrared and X-ray absorption spectroscopy studies show that the higher reaction rate was observed for longer Zn-C bond distances.
authors: College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, China. aiwenlei@whu.edu.cn.
authors: Guanghui
authors: G
authors: Zhang
authors: Jing
authors: J
authors: Li
authors: Yi
authors: Y
authors: Deng
authors: Jeffrey T
authors: JT
authors: Miller
authors: A Jeremy
authors: AJ
authors: Kropf
authors: Emilio E
authors: EE
authors: Bunel
authors: Aiwen
authors: A
authors: Lei