title: The effects of organic matter-mineral interactions and organic matter chemistry on diuron sorption across a diverse range of soils.
abstract: Sorption of non-ionic organic compounds to soil is usually expressed as the carbon-normalized partition coefficient (KOC), because it is assumed that the main factor that influences the amount sorbed is the organic carbon content of the soil. However, KOC can vary by a factor of at least ten across a range of soils. We investigated two potential causes of variation in diuron KOC - organic matter-mineral interactions and organic matter chemistry - for a diverse set of 34 soils from Sri Lanka, representing a wide range of soil types. Treatment with hydrofluoric acid (HF-treatment) was used to concentrate soil organic matter. HF-treatment increased KOC for the majority of soils (average factor 2.4). We attribute this increase to the blocking of organic matter sorption sites in the whole soils by minerals. There was no significant correlation between KOC for the whole soils and KOC for the HF-treated soils, indicating that the importance of organic matter-mineral interactions varied greatly amongst these soils. There was as much variation in KOC across the HF-treated soils as there was across the whole soils, indicating that the nature of soil organic matter is also an important contributor to KOC variability. Organic matter chemistry, determined by solid-state (13)C nuclear magnetic resonance (NMR) spectroscopy, was correlated with KOC for the HF-treated soils. In particular, KOC increased with the aromatic C content (R=0.64, p=1×10(-6)), and decreased with O-alkyl C (R=-0.32, p=0.03) and alkyl C (R=-0.41, p=0.004) content.
authors: Soils Group, School of Agriculture, Food and Wine and Waite Research Institute, The University of Adelaide, Waite Campus, Urrbrae, South Australia 5064, Australia. Electronic address: ronald.smernik@adelaide.edu.au.
authors: Ronald J
authors: RJ
authors: Smernik
authors: Soils Group, School of Agriculture, Food and Wine and Waite Research Institute, The University of Adelaide, Waite Campus, Urrbrae, South Australia 5064, Australia; CSIRO, Land & Water, PMB 2, Glen Osmond SA 5064, Australia.
authors: Rai S
authors: RS
authors: Kookana
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D004237:Diuron / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008903:Minerals / Q000737:chemistry*; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D008903:Minerals; D012987:Soil; D012989:Soil Pollutants; D002244:Carbon; D004237:Diuron
keywords: Clay–organic matter interactions; Diuron; NMR spectroscopy; Organo–mineral interactions; Sorption