title: Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation.
abstract: We have succeeded in the visible light-mediated synthetic use of α-aminoalkyl radicals derived from α-silyl secondary amines toward addition to α,β-unsaturated carbonyl compounds. The resulting γ-aminocarbonyl compounds are converted into γ-lactams and pyrroles in a one-pot process.
authors: Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan. ynishiba@sogo.t.u-tokyo.ac.jp.
authors: Kazunari
authors: K
authors: Nakajima
authors: Mai
authors: M
authors: Kitagawa
authors: Yuya
authors: Y
authors: Ashida
authors: Yoshihiro
authors: Y
authors: Miyake
authors: Yoshiaki
authors: Y
authors: Nishibayashi
mesh_terms: D000588:Amines / Q000737:chemistry* / Q000528:radiation effects*; D005609:Free Radicals / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008027:Light; D055668:Photochemical Processes
chemical_list: D000588:Amines; D005609:Free Radicals; D006571:Heterocyclic Compounds