title: Tandem [4 + 2]/[2 + 2] cycloaddition reactions involving indene or benzofurans and arynes.
abstract: The reaction of arynes with indene/benzofurans has been developed. The arynes were generated from 2-(trimethylsilyl)aryl triflates by the fluoride-induced 1,2-elimination react with indene or various benzofurans proceeding via a cascade reaction involving the Diels-Alder reaction and a [2 + 2] cycloaddition reaction. The tandem process afforded functionalized dihydrobenzocyclobutaphenanthrenes in moderate to good yields. Moreover, the method has been utilized for the one-pot synthesis of benzo[b]fluoranthene.
authors: Organic Chemistry Division, CSIR-National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune 411008, India.
authors: Sachin Suresh
authors: SS
authors: Bhojgude
authors: Manikandan
authors: M
authors: Thangaraj
authors: Eringathodi
authors: E
authors: Suresh
authors: Akkattu T
authors: AT
authors: Biju