title: Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides.
abstract: A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using di-tert-butyl peroxide (DTBP) as an oxidant catalyzed by Pd(OAc)2 has been reported. The C-H bonds in various alkanes or ethers were successfully converted into C-S bonds to yield the corresponding sulfides in moderate to good yields.
authors: College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China. jnxiang@hnu.edu.cn.
authors: Sheng-rong
authors: SR
authors: Guo
authors: Wei-ming
authors: WM
authors: He
authors: Jian-nan
authors: JN
authors: Xiang
authors: Yan-qin
authors: YQ
authors: Yuan
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D002384:Catalysis; D004987:Ethers / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D010545:Peroxides / Q000737:chemistry*; D013440:Sulfides / Q000138:chemical synthesis*
chemical_list: D000473:Alkanes; D004987:Ethers; D010545:Peroxides; D013440:Sulfides; C111570:di-tert-butyl peroxide; D010165:Palladium