title: Palladium-catalyzed/norbornene-mediated ortho-amination/N-tosylhydrazone insertion reaction: an approach to the synthesis of ortho-aminated vinylarenes.
abstract: ortho-Aminated vinylarene derivatives were obtained via a reaction of aryl iodides, N-benzoyloxyamines, and N-tosylhydrazones. This approach involves a palladium-catalyzed, norbornene-mediated ortho-amination/N-tosylhydrazone insertion reaction. In this transformation, one C-N bond and one C-C bond are formed and an amine group is introduced at the ortho position successfully.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University , Lanzhou 730000, China.
authors.forename: Ping-Xin
authors.initials: PX
authors.lastname: Zhou
authors.forename: Yu-Ying
authors.initials: YY
authors.lastname: Ye
authors.forename: Jun-Wei
authors.initials: JW
authors.lastname: Ma
authors.forename: Lan
authors.initials: L
authors.lastname: Zheng
authors.forename: Qian
authors.initials: Q
authors.lastname: Tang
authors.forename: Yi-Feng
authors.initials: YF
authors.lastname: Qiu
authors.forename: Bo
authors.initials: B
authors.lastname: Song
authors.forename: Zi-Hang
authors.initials: ZH
authors.lastname: Qiu
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Xu
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Liang