title: Palladium/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination.
abstract: The Pd/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.
authors.affiliation: Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China. chenjiarong@mail.ccnu.edu.cn wxiao@mail.ccnu.edu.cn.
authors.forename: Bin
authors.initials: B
authors.lastname: Feng
authors.forename: Hong-Gang
authors.initials: HG
authors.lastname: Cheng
authors.forename: Jia-Rong
authors.initials: JR
authors.lastname: Chen
authors.forename: Qiao-Hui
authors.initials: QH
authors.lastname: Deng
authors.forename: Liang-Qiu
authors.initials: LQ
authors.lastname: Lu
authors.forename: Wen-Jing
authors.initials: WJ
authors.lastname: Xiao
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D004987:Ethers / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013454:Sulfoxides / Q000737:chemistry*
chemical_list: D000475:Alkenes; D004987:Ethers; D010720:Phosphines; D013454:Sulfoxides; D010165:Palladium; C044646:phosphine