title: Nitrogen-centered radical-mediated C-H imidation of arenes and heteroarenes via visible light induced photocatalysis.
abstract: The C-H imidation of arenes and heteroarenes has been achieved via visible light induced photocatalysis. In the presence of an iridium(III) photoredox catalyst, the reaction of aromatic substrates with N-chlorophthalimide furnishes the N-aryl products at room temperature through a nitrogen-centered radical mediated aromatic substitution.
authors.affiliation: Department of Chemistry, Seoul National University, Seoul 151-747, Republic of Korea. chulbom@snu.ac.kr.
authors.forename: Hyejin
authors.initials: H
authors.lastname: Kim
authors.forename: Taehoon
authors.initials: T
authors.lastname: Kim
authors.forename: Dong Gil
authors.initials: DG
authors.lastname: Lee
authors.forename: Sang Weon
authors.initials: SW
authors.lastname: Roh
authors.forename: Chulbom
authors.initials: C
authors.lastname: Lee
mesh_terms: D002384:Catalysis; D006838:Hydrocarbons / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D008027:Light; D055668:Photochemical Processes
chemical_list: D006838:Hydrocarbons; D007094:Imides