title: Hybrid photocatalysts using graphitic carbon nitride/cadmium sulfide/reduced graphene oxide (g-C3N4/CdS/RGO) for superior photodegradation of organic pollutants under UV and visible light.
abstract: Graphitic carbon nitride (g-C3N4) was hybridized with CdS nanoparticles and reduced graphene oxide (RGO) sheets using a facile chemical method, for the application of catalytic photodegradation of Rhodamine B and Congo red dyes under irradiation with UV and visible light. Fourier-transform infrared (FTIR) spectroscopy and X-ray photoemission spectroscopy (XPS) analyses confirmed the formation of pure g-C3N4, as well as g-C3N4/CdS, g-C3N4/RGO, and g-C3N4/CdS/RGO composites. The large surface area of the g-C3N4/CdS/RGO composite (70.42 m(2) g(-1)) resulted in rapid dye adsorption onto the surface of the photocatalyst, leading to effective photodegradation of organic pollutants. The addition of CdS and RGO increased the photocatalytic activity of g-C3N4 by a factor of approximately twenty compared with that of the commercially available TiO2 catalyst under visible light, and the g-C3N4/CdS/RGO composite was found to significantly enhance the catalytic effect compared with pure g-C3N4 and with the g-C3N4/CdS and g-C3N4/RGO composites. The superior photocatalytic activity of the g-C3N4/CdS/RGO composite is attributed to enhanced separation of the photogenerated electron-hole pairs, as well as increased visible-light absorption. The improved transport of photoelectrons was consistent with the results of transient photocurrent measurements. Therefore, g-C3N4/CdS/RGO composites using a facile method are applicable to the development of high-efficiency photocatalytic devices for industrial applications.
authors.affiliation: Department of Materials Engineering, Hanyang University, Ansan 426-791, Gyeonggi-do, South Korea. sunyonglee@hanyang.ac.kr.
authors.forename: Rajendra C
authors.initials: RC
authors.lastname: Pawar
authors.forename: Varsha
authors.initials: V
authors.lastname: Khare
authors.forename: Caroline Sunyong
authors.initials: CS
authors.lastname: Lee