title: 3-NO2-5,10,15-triarylcorrolato-Cu as a versatile platform for synthesis of novel 3-functionalized corrole derivatives.
abstract: β-Nitrocorroles are potentially valuable platforms for the preparation of a wide range of more elaborated corrole derivatives possessing unique chemical functionalities and electronic properties. Here we report our results on the chemical manipulation of a copper 3-NO2-triarylcorrolate using different organic reactions, all involving the reduction of -NO2 to -NH2 at an early stage, followed by further transformations. By way of a β-acylated copper corrolate, a novel corrole derivative bearing an alkyl azide group on the peripheral positions was obtained and exploited in the Huisgen 1,3-dipolar cycloaddition.
authors.affiliation: Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, 00133 Roma, Italy. nardis@scienze.uniroma2.it.
authors.forename: M
authors.initials: M
authors.lastname: Stefanelli
authors.forename: M
authors.initials: M
authors.lastname: Mancini
authors.forename: M
authors.initials: M
authors.lastname: Raggio
authors.forename: S
authors.initials: S
authors.lastname: Nardis
authors.forename: F R
authors.initials: FR
authors.lastname: Fronczek
authors.forename: G T
authors.initials: GT
authors.lastname: McCandless
authors.forename: K M
authors.initials: KM
authors.lastname: Smith
authors.forename: R
authors.initials: R
authors.lastname: Paolesse
mesh_terms: D000215:Acylation; D057930:Click Chemistry; D003300:Copper / Q000737:chemistry*; D061565:Cycloaddition Reaction; D008968:Molecular Conformation; D009585:Nitrogen Dioxide / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D011166:Porphyrins; C431863:corrole; D003300:Copper; D009585:Nitrogen Dioxide