title: Pd(0)-catalyzed alkenylation and allylic dearomatization reactions between nucleophile-bearing indoles and propargyl carbonate.
abstract: Spiroindolenine derivatives were synthesized by intermolecular Pd-catalyzed dearomatization of indoles. The reaction between nucleophile bearing indoles and propargyl carbonate proceeds in a cascade fashion providing spiroindolenines or spiroindolines in good to excellent yields.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Lu, Shanghai 200032, China.
authors.forename: Run-Duo
authors.initials: RD
authors.lastname: Gao
authors.forename: Chuan
authors.initials: C
authors.lastname: Liu
authors.forename: Li-Xin
authors.initials: LX
authors.lastname: Dai
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.forename: Shu-Li
authors.initials: SL
authors.lastname: You
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D007211:Indoles / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013141:Spiro Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D002254:Carbonates; D007211:Indoles; D013141:Spiro Compounds; D010165:Palladium