title: Size-induced chemical and magnetic ordering in individual Fe-Au nanoparticles.
abstract: Formation of chemically ordered compounds of Fe and Au is inhibited in bulk materials due to their limited mutual solubility. However, here we report the formation of chemically ordered L12-type Fe3Au and FeAu3 compounds in Fe-Au sub-10 nm nanoparticles, suggesting that they are equilibrium structures in size-constrained systems. The stability of these L12-ordered Fe3Au and FeAu3 compounds along with a previously discovered L10-ordered FeAu has been explained by a size-dependent equilibrium thermodynamic model. Furthermore, the spin ordering of these three compounds has been computed using ab initio first-principle calculations. All ordered compounds exhibit a substantial magnetization at room temperature. The Fe3Au had a high saturation magnetization of about 143.6 emu/g with a ferromagnetic spin structure. The FeAu3 nanoparticles displayed a low saturation magnetization of about 11 emu/g. This suggests a antiferromagnetic spin structure, with the net magnetization arising from uncompensated surface spins. First-principle calculations using the Vienna ab initio simulation package (VASP) indicate that ferromagnetic ordering is energetically most stable in Fe3Au, while antiferromagnetic order is predicted in FeAu and FeAu3, consistent with the experimental results.
authors.affiliation: Department of Mechanical & Materials Engineering, ‡Nebraska Center for Materials and Nanoscience, and §Department of Physics & Astronomy, University of Nebraska , Lincoln, Nebraska 68588, United States.
authors.forename: Pinaki
authors.initials: P
authors.lastname: Mukherjee
authors.forename: Priyanka
authors.initials: P
authors.lastname: Manchanda
authors.forename: Pankaj
authors.initials: P
authors.lastname: Kumar
authors.forename: Lin
authors.initials: L
authors.lastname: Zhou
authors.forename: Matthew J
authors.initials: MJ
authors.lastname: Kramer
authors.forename: Arti
authors.initials: A
authors.lastname: Kashyap
authors.forename: Ralph
authors.initials: R
authors.lastname: Skomski
authors.forename: David
authors.initials: D
authors.lastname: Sellmyer
authors.forename: Jeffrey E
authors.initials: JE
authors.lastname: Shield