title: Accurate determination and certification of bromine in plastic by isotope dilution inductively coupled plasma mass spectrometry.
abstract: The accurate analytical method of bromine (Br) in plastic was developed by an isotope dilution inductively coupled plasma mass spectrometry (ID-ICPMS). The figures of merit of microwave acid digestion procedures using polytetrafluoroethylene (PTFE) or quartz vessels were studied and the latter one was suitable for Br analysis since its material was free from Br contamination. The sample dilution procedures using Milli-Q water or ammonium (NH3) solution were also studied to remove memory effect for ICPMS measurement. Although severe memory effect was observed on Milli-Q water dilution, NH3 solution could remove it successfully. The accuracy of the ID-ICPMS was validated by a certified reference material (CRM) as well as the comparison with the analytical result obtained by an instrumental neutron activation analysis (INAA) as different analytical method. From these results, the ID-ICPMS developed in the present study could be evaluated as accurate analytical method of Br in plastic materials and it could apply to certification of Br in candidate plastic CRM with respect to such regulations related to RoHS (restriction of the use of hazardous substances in electrical and electronics equipment) directive.
authors.affiliation: National Metrology Institute of Japan, Inorganic Analytical Chemistry Division, Inorganic Standards Section, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8563, Japan. Electronic address: m-oohata@aist.go.jp.
authors.forename: Masaki
authors.initials: M
authors.lastname: Ohata
authors.affiliation: National Metrology Institute of Japan, Inorganic Analytical Chemistry Division, Inorganic Standards Section, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8563, Japan.
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Miura
keywords: Bromine analysis in plastic; Certified reference material (CRM); Isotope dilution inductively coupled plasma mass spectrometry (ID-ICPMS); Memory effect; Microwave acid digestion procedure; RoHS directive