title: Controlling the orientation of nanowrinkles and nanofolds by patterning strain in a thin skin layer on a polymer substrate.
abstract: We describe herein how to control the orientation of polymer nanowrinkles and nanofolds with large amplitudes. Nanowrinkles were created by chemically treating thermoplastic polystyrene sheets to form a thin skin layer and then heating the substrate to relieve strain. By manipulating the strain globally and locally in the skin layer, we could tune whether wrinkles or folds formed, as well as the distances over which these structures could be produced. This unique materials system provided access to high strain regimes, which enabled mechanisms behind the spontaneous formation of complex structures to be explored.
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (USA).
authors.forename: Mark D
authors.initials: MD
authors.lastname: Huntington
authors.forename: Clifford J
authors.initials: CJ
authors.lastname: Engel
authors.forename: Teri W
authors.initials: TW
authors.lastname: Odom
keywords: materials science; nanofolds; nanowrinkles; polymers; reactive ion etching