title: Photochemical degradation of Corexit components in ocean water.
abstract: Due to the large quantities of dispersants used during the Deepwater Horizon spill in 2010, there were immediate concerns with regards to the fate and transport of the mixture in ocean waters. Direct and sensitized photolysis experiments were carried out for two compounds chosen as surrogates for the Corexit mixture (9500 and 9527) that were applied to surface waters during the oil spill in the Gulf of Mexico. The results showed that direct photolysis did not contribute significantly to the overall degradation (max ∼30%), therefore the focus shifted to sensitized photolysis, specifically the degradation stemming from the reaction rate with hydroxyl radical (HO). The direct photochemical degradation rates for two of the compounds, dioctyl sulfosuccinate (DOSS) and dipropylene glycol butyl ether (DGBE) were measured as 4.29×10(-6)s(-1) and 5.95×10(-6)s(-1), respectively; whereas the overall degradation rate in ocean water was 1.56×10(-5)s(-1) and 2.23×10(-5)s(-1). The formation rates and apparent quantum yields for HO formation were determined for six ocean water samples. The values ranged from 1.81×10(-5) near shore to 0.061×10(-5) for the open ocean. These degradation rates suggest the possibility for photolysis to play a role in the overall fate of Corexit.
authors.affiliation: Department of Civil, Environmental and Architectural Engineering, 428 UCB, University of Colorado, Boulder, CO 80309, USA.
authors.forename: Caitlin M
authors.initials: CM
authors.lastname: Glover
authors.affiliation: Department of Chemistry and Biochemistry, California State University at Long Beach, 1250 Bellflower Blvd., Long Beach, CA 90840, USA.
authors.forename: Stephen P
authors.initials: SP
authors.lastname: Mezyk
authors.affiliation: Department of Civil, Environmental and Architectural Engineering, 428 UCB, University of Colorado, Boulder, CO 80309, USA.
authors.forename: Karl G
authors.initials: KG
authors.lastname: Linden
authors.affiliation: Department of Civil, Environmental and Architectural Engineering, 428 UCB, University of Colorado, Boulder, CO 80309, USA. Electronic address: Fernando.rosario@colorado.edu.
authors.forename: Fernando L
authors.initials: FL
authors.lastname: Rosario-Ortiz
mesh_terms: D004143:Dioctyl Sulfosuccinic Acid / Q000032:analysis / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry; D008800:Mexico; D009792:Oceans and Seas; D059392:Petroleum Pollution / Q000032:analysis*; D010782:Photolysis; D011409:Propylene Glycols / Q000032:analysis / Q000737:chemistry*; D014867:Water / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D011409:Propylene Glycols; D014874:Water Pollutants, Chemical; D014867:Water; D004143:Dioctyl Sulfosuccinic Acid; D017665:Hydroxyl Radical
keywords: Corexit; DOM; Dispersants; Oil spill; Photochemistry