title: Influence of alumina binder content on catalytic performance of Ni/HZSM-5 for hydrodeoxygenation of cyclohexanone.
abstract: The influence of the amount of alumina binders on the catalytic performance of Ni/HZSM-5 for hydrodeoxygenation of cyclohexanone was investigated in a fixed-bed reactor. N2 sorption, X-ray diffraction, H2-chemisorption and temperature-programmed desorption of ammonia were used to characterize the catalysts. It can be observed that the Ni/HZSM-5 catalyst bound with 30 wt.% alumina binder exhibited the best catalytic performance. The high catalytic performance may be due to relatively good Ni metal dispersion, moderate mesoporosity, and proper acidity of the catalyst.
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, PR China.
authors.forename: Xiangjin
authors.initials: X
authors.lastname: Kong
authors.affiliation: Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, PR China.
authors.forename: Junhai
authors.initials: J
authors.lastname: Liu
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D000641:Ammonia / Q000737:chemistry; D002384:Catalysis; D003512:Cyclohexanones / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013329:Structure-Activity Relationship; D017641:Zeolites / Q000737:chemistry*
chemical_list: D003512:Cyclohexanones; D017641:Zeolites; C036468:cyclohexanone; D000641:Ammonia; D009532:Nickel; D000537:Aluminum Oxide; D010100:Oxygen