title: Hydrophobic-modified nano-cellulose fiber/PLA biodegradable composites for lowering water vapor transmission rate (WVTR) of paper.
abstract: New biodegradable nanocomposites have been successfully prepared by incorporating modified nano-cellulose fibers (NCF) in a biodegradable polylactic acid (PLA) matrix in this work. The hydrophobic-modified NCF was obtained by grafting hydrophobic monomers on NCF to improve the compatibility between NCF and PLA during blending. The resulting NCF/PLA composites were then applied on paper surface via a cast-coating process in an attempt to reduce the water vapor transmission rate (WVTR) of paper. The WVTR tests, conducted under various testing conditions and with different coating weights, demonstrated that the modified NCF/PLA composites coating played a critical role in lowering WVTR of paper. The lowest WVTR value was 34 g/m(2)/d, which was obtained with an addition of 1% of modified NCF to PLA and the composites coating weight at 40 g/m(2) and substantially lower than the control value at 1315 g/m(2)/d. The paper coated with the modified biodegradable composite is promising as green-based packaging materials.
authors.affiliation: Department of Chemical Engineering, University of New Brunswick, Fredericton, NB, Canada E3B5A3. Electronic address: m748i@unb.ca.
authors.forename: Zhaoping
authors.initials: Z
authors.lastname: Song
authors.affiliation: Department of Chemical Engineering, University of New Brunswick, Fredericton, NB, Canada E3B5A3; School of Environmental Science & Engineering, North China Electric Power University, Baoding, China 071003. Electronic address: hxiao@unb.ca.
authors.forename: Huining
authors.initials: H
authors.lastname: Xiao
authors.affiliation: School of Environmental Science & Engineering, North China Electric Power University, Baoding, China 071003. Electronic address: zhaoyi9515@163.com.
authors.forename: Yi
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D006813:Humidity; D057927:Hydrophobic and Hydrophilic Interactions; D019344:Lactic Acid / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry / Q000648:ultrastructure; D057139:Nanofibers / Q000737:chemistry* / Q000648:ultrastructure; D010209:Paper; D011091:Polyesters; D011108:Polymers / Q000737:chemistry*; D013227:Steam / Q000032:analysis*
chemical_list: D011091:Polyesters; D011108:Polymers; D013227:Steam; D019344:Lactic Acid; C033616:poly(lactide); D002482:Cellulose
keywords: Biodegradable; Nano-cellulose Fiber; Nanocomposites; PLA; WVTR