title: Pd-containing organopolyoxometalates derived from Dawson polyoxometalate [P₂W₁₅V₃O₆₂]⁹⁻: Lewis acidity and dual site catalysis.
abstract: Grafting of a palladium complex to the Dawson vanadotungstate polyanion [P2W15V3O62](9-) via an organic ligand generates a large family of pincer-type hybrid polyoxometalates. The palladium-POM derivatives have dual catalytic properties. Unlike their parent inorganic polyanions, they catalyze allylations while retaining their oxidant character, which leads to single-pot dual site catalysis. This opens a new route for multicatalytic reactions.
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06 , Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005 Paris, France.
authors.forename: Benoît
authors.initials: B
authors.lastname: Riflade
authors.forename: David
authors.initials: D
authors.lastname: Lachkar
authors.forename: Julie
authors.initials: J
authors.lastname: Oble
authors.forename: Joaquim
authors.initials: J
authors.lastname: Li
authors.forename: Serge
authors.initials: S
authors.lastname: Thorimbert
authors.forename: Bernold
authors.initials: B
authors.lastname: Hasenknopf
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Lacôte