title: Stereoselective one-pot synthesis of β-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions.
abstract: A stereoselective one-pot procedure was developed to prepare S-substituted (Z)-enol esters through a base-triggered rearrangement. This transition metal-free multicomponent approach can be performed under an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generally affords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O-acyl migration.
authors.affiliation: INFIQC-CONICET, Dpto. de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, X5000HUA Córdoba, Argentina. fbisogno@fcq.unc.edu.ar penenory@fcq.unc.edu.ar.
authors.forename: Adrián A
authors.initials: AA
authors.lastname: Heredia
authors.forename: Silvia M
authors.initials: SM
authors.lastname: Soria-Castro
authors.forename: Lydia M
authors.initials: LM
authors.lastname: Bouchet
authors.forename: Gabriela
authors.initials: G
authors.lastname: Oksdath-Mansilla
authors.forename: Cecilia A
authors.initials: CA
authors.lastname: Barrionuevo
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Caminos
authors.forename: Fabricio R
authors.initials: FR
authors.lastname: Bisogno
authors.forename: Juan E
authors.initials: JE
authors.lastname: Argüello
authors.forename: Alicia B
authors.initials: AB
authors.lastname: Peñéñory