title: Disinfection byproduct formation from lignin precursors.
abstract: Lignin is the most abundant aromatic plant component in terrestrial ecosystems. This study was conducted to determine the contribution of lignin residues in natural water to the formation of disinfection byproducts (DBPs) in drinking water. We investigated the formation of different classes of DBPs from lignin model compounds, lignin polymers, and humic substances using two common disinfection techniques, chlorination and chloramination. The contributions of lignin to the overall formation of DBPs from these organic products were determined based on the observed abundances of individual lignin phenols and their DBP yields. Model lignin phenols generally produced higher trichloroacetic acid (TCAA) yields than chloroform and dichloroacetic acid (DCAA) during chlorination. Lignin phenols generally produced higher DBP yields but lower percentages of unknown total organic halogen compared to bulk humic substances and lignin polymers. The relative significance of lignin phenols as chlorination DBP precursors generally follows the order of TCAA > DCAA&chloroform. The relative significance of lignin phenols to DBP formation by chloramination follows the order: TCAA > DCAA&DCAN > chloroform. Overall, lignin phenols are more important as TCAA precursors than as chloroform and DCAA precursors.
authors.affiliation: Department of Civil and Environmental Engineering, South Dakota State University, Brookings, SD 57007, USA. Electronic address: guanghui.hua@sdstate.edu.
authors.forename: Guanghui
authors.initials: G
authors.lastname: Hua
authors.affiliation: Science and Engineering Department, Tampa Bay Water, Clearwater, FL 33763, USA.
authors.forename: Junsung
authors.initials: J
authors.lastname: Kim
authors.affiliation: Department of Civil and Environmental Engineering, University of Massachusetts, Amherst, MA 01003, USA.
authors.forename: David A
authors.initials: DA
authors.lastname: Reckhow
mesh_terms: D000586:Amination; D002851:Chromatography, High Pressure Liquid; D003300:Copper / Q000378:metabolism; D004202:Disinfectants / Q000378:metabolism*; D004203:Disinfection; D060766:Drinking Water / Q000032:analysis*; D054879:Halogenation; D006812:Humic Substances / Q000032:analysis; D008031:Lignin / Q000378:metabolism*; D010084:Oxidation-Reduction; D010636:Phenols / Q000378:metabolism*; D011108:Polymers / Q000032:analysis
chemical_list: D004202:Disinfectants; D060766:Drinking Water; D006812:Humic Substances; D010636:Phenols; D011108:Polymers; D003300:Copper; D008031:Lignin; C030973:cupric oxide
keywords: Chloramine; Chlorine; CuO oxidation; Disinfection byproducts; Lignin phenols; Natural organic matter