title: Synthesis and characterization of the ZnO/mpg-C₃N₄ heterojunction photocatalyst with enhanced visible light photoactivity.
abstract: The ZnO/mpg-C3N4 composite photocatalyst with high visible light activity was successfully synthesized by a facile solvothermal method and characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and UV-vis diffuse reflectance spectroscopy (DRS). The results indicated that ZnO particles dispersed uniformly on the mpg-C3N4 sheet. The photocatalytic activity of ZnO/mpg-C3N4 for photodegradation of MB was much higher than that of pure mpg-C3N4 both under the visible light and simulated solar irradiation. The optimal ZnO content for the photocatalytic activity of the ZnO/mpg-C3N4 composites is 24.9%, which is almost 2.3 times as high as that of pure mpg-C3N4 under visible light, and 1.9 times higher than that under simulated solar irradiation. The enhancement in photocatalytic activity should be assigned to the effective separation and transfer of photogenerated charges coming from the well-matched overlapping band-structure between mpg-C3N4 and ZnO. Radical trap experiments show that both ZnO/mpg-C3N4 composites and mpg-C3N4 have the same photodegradation mechanism, and the holes are their main oxidative species for MB degradation.
authors.affiliation: National Laboratory of Mineral Materials, School of Materials Sciences and Technology, China University of Geosciences, Beijing 100083, China. chendaimei@cugb.edu.cn chendaimei0611.student@sina.com.
authors.forename: Daimei
authors.initials: D
authors.lastname: Chen
authors.forename: Kewei
authors.initials: K
authors.lastname: Wang
authors.forename: Tiezhen
authors.initials: T
authors.lastname: Ren
authors.forename: Hao
authors.initials: H
authors.lastname: Ding
authors.forename: Yongfa
authors.initials: Y
authors.lastname: Zhu