title: Recovery of oil from oil-in-water emulsion using biopolymers by adsorptive method.
abstract: In the present study, it is aimed to identify, a low cost sorbent for the recovery of oil from oil-in-water emulsion using biopolymers such as chitin and chitosan. Chitin has the greater adsorption capacity than chitosan due to its hydrophobic nature. The characterizations of chitin and chitosan were done using FTIR, SEM, EDAX, XRD, TGA and DSC techniques. Under batch equilibrium mode, a systematic study was performed to optimize the various equilibrium parameters viz., contact time, pH, dosage, initial concentration of oil, and temperature. The adsorption process reached equilibrium at 40 min of contact time and the percentage removal of oil was found to be higher (90%) in the acidic medium. The Freundlich and Langmuir models were applied to describe the equilibrium isotherms and the isotherm constants were calculated. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were calculated to find out the nature of the sorption mechanism. The kinetic studies were investigated with reaction-based and diffusion-based models. The suitable mechanism for the removal of oil has been established.
authors.affiliation: Department of Chemistry, The Gandhigram Rural Institute-Deemed University, Gandhigram - 624 302, Tamil Nadu, India.
authors.forename: S Sd
authors.initials: SS
authors.lastname: Elanchezhiyan
authors.affiliation: Department of Chemistry, The Gandhigram Rural Institute-Deemed University, Gandhigram - 624 302, Tamil Nadu, India.
authors.forename: N
authors.initials: N
authors.lastname: Sivasurian
authors.affiliation: Department of Chemistry, The Gandhigram Rural Institute-Deemed University, Gandhigram - 624 302, Tamil Nadu, India. Electronic address: drs_meena@rediffmail.com.
authors.forename: Sankaran
authors.initials: S
authors.lastname: Meenakshi
mesh_terms: D000327:Adsorption; D001704:Biopolymers / Q000737:chemistry*; D002686:Chitin / Q000737:chemistry; D048271:Chitosan / Q000737:chemistry; D004655:Emulsions / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D057927:Hydrophobic and Hydrophilic Interactions; D009821:Oils / Q000737:chemistry* / Q000302:isolation & purification*; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry; D014961:X-Ray Diffraction
chemical_list: D001704:Biopolymers; D004655:Emulsions; D009821:Oils; D002686:Chitin; D048271:Chitosan
keywords: Adsorption; Chitin; Chitosan; Isotherms; Oil removal