title: Rhodium(III)-catalyzed olefinic C-H alkynylation of enamides at room temperature.
abstract: Rh(III)-catalyzed C-H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z-type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore. teckpeng@ntu.edu.sg.
authors.forename: Chao
authors.initials: C
authors.lastname: Feng
authors.forename: Daming
authors.initials: D
authors.lastname: Feng
authors.forename: Teck-Peng
authors.initials: TP
authors.lastname: Loh