title: Simple strategies for fabrication of a periodic mesoporous aluminosilicate with crystalline walls.
abstract: An alkali-assisted cooperative assembly process of two different templating systems with aluminosilicate precursors is described. A highly ordered mesoporous zeolite with the 2D hexagonal symmetry mesospores and MFI zeolitic framework walls is synthesized. This method also allows the preparation of ZSM-5 with c- or b-axis-aligned mesopores. The materials have promising catalytic activities for organic reactions involving bulky molecules.
authors.affiliation: Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, Zhejiang, China; Institute of Chemical Technology, Vietnamese Academy of Science and Technology, 01 Mac Dinh Chi, District 1, Ho Chi Minh, Vietnam.
authors.forename: Manh Huy
authors.initials: MH
authors.lastname: Do
authors.forename: Tuo
authors.initials: T
authors.lastname: Wang
authors.forename: Dang-guo
authors.initials: DG
authors.lastname: Cheng
authors.forename: Fengqiu
authors.initials: F
authors.lastname: Chen
authors.forename: Xiaoli
authors.initials: X
authors.lastname: Zhan
authors.forename: Robert M
authors.initials: RM
authors.lastname: Rioux
authors.forename: Jinlong
authors.initials: J
authors.lastname: Gong
keywords: catalyst; crystalline walls; mesoporous materials; microporous materials; nanorods; template; zeolite