title: A bifunctional copolymer additive to utilize photoenergy transfer and to improve hole mobility for organic ternary bulk-heterojunction solar cell.
abstract: To realize the high efficiency organic photovoltaics (OPVs), two critical requirements have to be fulfilled: (1) increasing the photon energy absorption range of the active layer, and (2) improving charge separation and transport in the active layer. This study reports the utilization of THC8, a novel fluorescence-based polymer containing propeller-shaped di-triarylamine and fluorene moieties in the active layer consisting of poly-3-hexylthiophene and [6,6]-phenyl-C61-butyric acid methyl ester to form a ternary bulk heterojunction. The results showed that the high absorbance and strong fluorescence of THC8 at 420 and 510 nm, respectively, broadened the spectral absorption of the OPV, possibly through Förster resonance energy transfer. In addition, the morphology of the device active layer was improved with the addition of a suitable amount of THC8. Consequently, the charge transport property of the active layer was improved. The best power conversion efficiency (PCE) of the device with THC8 was 3.88%, a 25% increase compared to the PCE of a pristine OPV.
authors.affiliation: Department of Chemical Engineering, National Taiwan University of Science and Technology , Taipei 10617, Taiwan.
authors.forename: Cheng-Yu
authors.initials: CY
authors.lastname: Chi
authors.forename: Ming-Chung
authors.initials: MC
authors.lastname: Chen
authors.forename: Der-Jang
authors.initials: DJ
authors.lastname: Liaw
authors.forename: Han-Yu
authors.initials: HY
authors.lastname: Wu
authors.forename: Ying-Chi
authors.initials: YC
authors.lastname: Huang
authors.forename: Yian
authors.initials: Y
authors.lastname: Tai