title: A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids.
abstract: The first example of a dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of catalytic amounts of Selectfluor and DABCO was reported, which provides a facile access to organoboronates. This reaction represents an unprecedented dyotropic rearrangement consisting of cleavage of two vicinal bonds (one C-C bond and one C=C bond).
authors.affiliation: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P. R. China. jlzhang@chem.ecnu.edu.cn.
authors.forename: Weimin
authors.initials: W
authors.lastname: Ye
authors.forename: Wenbo
authors.initials: W
authors.lastname: Li
authors.forename: Junliang
authors.initials: J
authors.lastname: Zhang