title: Novel Na(+) doped Alq3 hybrid materials for organic light-emitting diode (OLED) devices and flat panel displays.
abstract: Pure and Na(+) -doped Alq3 complexes were synthesized by a simple precipitation method at room temperature, maintaining a stoichiometric ratio. These complexes were characterized by X-ray diffraction, Fourier transform infrared (FTIR), UV/Vis absorption and photoluminescence (PL) spectra. The X-ray diffractogram exhibits well-resolved peaks, revealing the crystalline nature of the synthesized complexes, FTIR confirms the molecular structure and the completion of quinoline ring formation in the metal complex. UV/Vis absorption and PL spectra of sodium-doped Alq3 complexes exhibit high emission intensity in comparison with Alq3 phosphor, proving that when doped in Alq3 , Na(+) enhances PL emission intensity. The excitation spectra of the synthesized complexes lie in the range 242-457 nm when weak shoulders are also considered. Because the sharp excitation peak falls in the blue region of visible radiation, the complexes can be employed for blue chip excitation. The emission wavelength of all the synthesized complexes lies in the bluish green/green region ranging between 485 and 531 nm. The intensity of the emission wavelength was found to be elevated when Na(+) is doped into Alq3 . Because both the excitation and emission wavelengths fall in the visible region of electromagnetic radiation, these phosphors can also be employed to improve the power conversion efficiency of photovoltaic cells by using the solar spectral conversion principle. Thus, the synthesized phosphors can be used as bluish green/green light-emitting phosphors for organic light-emitting diodes, flat panel displays, solid-state lighting technology - a step towards the desire to reduce energy consumption and generate pollution free light.
authors.affiliation: Kamla Nehru College, Sakkardara Square, Nagpur, 440009, India.
authors.forename: S A
authors.initials: SA
authors.lastname: Bhagat
authors.forename: S V
authors.initials: SV
authors.lastname: Borghate
authors.forename: N Thejo
authors.initials: NT
authors.lastname: Kalyani
authors.forename: S J
authors.initials: SJ
authors.lastname: Dhoble
mesh_terms: D000535:Aluminum / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D004581:Electronics / Q000295:instrumentation; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry*; D008163:Luminescent Measurements; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D012964:Sodium; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
chemical_list: D049408:Luminescent Agents; D009942:Organometallic Compounds; C547306:tris-(8-hydroxyquinoline)aluminum; D012964:Sodium; D000535:Aluminum
keywords: OLEDs; flat panel displays; photoluminescence; photovoltaic cells; power efficiency