title: Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. Formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate.
abstract: The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.
authors.affiliation: Institut für Anorganische Chemie, Universität Bremen , Leobener Str., 28359 Bremen, Germany.
authors.forename: Ole
authors.initials: O
authors.lastname: Mallow
authors.forename: Jens
authors.initials: J
authors.lastname: Bolsinger
authors.forename: Pamela
authors.initials: P
authors.lastname: Finke
authors.forename: Malte
authors.initials: M
authors.lastname: Hesse
authors.forename: Yu-Sheng
authors.initials: YS
authors.lastname: Chen
authors.forename: Andrew
authors.initials: A
authors.lastname: Duthie
authors.forename: Simon
authors.initials: S
authors.lastname: Grabowsky
authors.forename: Peter
authors.initials: P
authors.lastname: Luger
authors.forename: Stefan
authors.initials: S
authors.lastname: Mebs
authors.forename: Jens
authors.initials: J
authors.lastname: Beckmann