title: Low-energy-electron induced permanently reactive CO₂ molecules.
abstract: Ab initio quantum chemical studies show that a very weak molecular complexation of CO2 with a dipolar molecule is able to suppress the autoionization of the electron from its transient negative ion states. Since the autoionization is suppressed, the transient negative ion can efficiently relax its geometry to form the reductively activated CO2 moiety. Unlike the reductively activated isolated CO2 molecules, which are deactivated immediately due to their thermodynamic metastability, the reductively activated CO2 moieties of the weak molecular complexes are infinitely long-lived and, hence, permanently reactive.
authors.affiliation: Department of Nuclear and Atomic Physics, Tata Institute of Fundamental Research, Mumbai 400 005, India. sajeevy@barc.gov.in.
authors.forename: Daly
authors.initials: D
authors.lastname: Davis
authors.forename: Y
authors.initials: Y
authors.lastname: Sajeev