title: Embedding covalency into metal catalysts for efficient electrochemical conversion of CO2.
abstract: CO2 conversion is an essential technology to develop a sustainable carbon economy for the present and the future. Many studies have focused extensively on the electrochemical conversion of CO2 into various useful chemicals. However, there is not yet a solution of sufficiently high enough efficiency and stability to demonstrate practical applicability. In this work, we use first-principles-based high-throughput screening to propose silver-based catalysts for efficient electrochemical reduction of CO2 to CO while decreasing the overpotential by 0.4-0.5 V. We discovered the covalency-aided electrochemical reaction (CAER) mechanism in which p-block dopants have a major effect on the modulating reaction energetics by imposing partial covalency into the metal catalysts, thereby enhancing their catalytic activity well beyond modulations arising from d-block dopants. In particular, sulfur or arsenic doping can effectively minimize the overpotential with good structural and electrochemical stability. We expect this work to provide useful insights to guide the development of a feasible strategy to overcome the limitations of current technology for electrochemical CO2 conversion.
authors: Graduate School of Energy, Environment, Water, and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST) , Yuseong-gu, Daejeon 305-701, Korea.
authors: Hyung-Kyu
authors: HK
authors: Lim
authors: Hyeyoung
authors: H
authors: Shin
authors: William A
authors: WA
authors: Goddard
authors: Yun Jeong
authors: YJ
authors: Hwang
authors: Byoung Koun
authors: BK
authors: Min
authors: Hyungjun
authors: H
authors: Kim