title: Metal-templated enantioselective enamine/H-bonding dual activation catalysis.
abstract: An octahedral bis-cyclometalated iridium(III) complex catalyzes the enantioselective α-amination of aldehydes with catalyst loadings down to 0.1 mol%. In this metal-templated design, the metal serves as a structural center and provides the exclusive source of chirality, whereas the catalysis is mediated through the organic ligand sphere.
authors: Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany. meggers@chemie.uni-marburg.de.
authors: Haohua
authors: H
authors: Huo
authors: Chen
authors: C
authors: Fu
authors: Chuanyong
authors: C
authors: Wang
authors: Klaus
authors: K
authors: Harms
authors: Eric
authors: E
authors: Meggers