title: Development of a selective and pH-independent method for the analysis of ultra trace amounts of nitrite in environmental water samples after dispersive magnetic solid phase extraction by spectrofluorimetry.
abstract: This paper describes an innovative and rapidly dispersive magnetic solid phase extraction spectrofluorimetry (DMSPE-FL) method for the analysis of trace amounts of nitrite in some environmental water samples. The method includes derivatization of aqueous nitrite with 2, 3-diaminonaphthalene (DAN), analysis of highly fluorescent 2, 3-naphthotriazole (NAT) derivative using spectrofluorimetry after DSPME. The novelty of our method is based on forming NAT that was independent with the pH-responsive and was adsorbed on MMWCNT by hydrophobic attractions in both acidic and basic media. The extraction efficiency of the sorbent was investigated by extraction of nitrite. The optimum extraction conditions for NO2(-) were obtained as of extraction time, 1.5 min; 10mg sorbent from 160 mL of the sample solution, and elution with 1 mL of acetone/KOH. Under the optimal conditions, the calibration curves were obtained in the range of 0.1-80 µg L(-1) (R(2)=0.999) and LOD (S/N=3) was obtained in 34 ng L(-1). Relative standard deviations (RSD) were 0.6 % (five replicates at 5 μg L(-1)). In addition, the feasibility of the method was demonstrated with extraction and determination of nitrite from some real samples containing tap, mineral, sea, rain, snow and ground waters, with the recovery in standard addition to real matrix of 94-102 % and RSDs of 1.8-10.6%.
authors: Department of Analytical Chemistry, University College of Science, University of Tehran, PO Box 14155-6455, Tehran, Iran. Electronic address: ghdaneshvartarigh@yahoo.com.
authors: Ghazale
authors: G
authors: Daneshvar Tarigh
authors: Department of Analytical Chemistry, University College of Science, University of Tehran, PO Box 14155-6455, Tehran, Iran. Electronic address: Shemiran@khayam.ut.ac.ir.
authors: Farzaneh
authors: F
authors: Shemirani
mesh_terms: D060766:Drinking Water / Q000032:analysis / Q000737:chemistry; D004784:Environmental Monitoring / Q000379:methods; D060587:Groundwater / Q000032:analysis / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D008280:Magnetics; D008900:Mineral Waters / Q000032:analysis; D009573:Nitrites / Q000032:analysis* / Q000302:isolation & purification; D011891:Rain / Q000737:chemistry; D015203:Reproducibility of Results; D012914:Snow / Q000737:chemistry; D052616:Solid Phase Extraction / Q000379:methods*; D013050:Spectrometry, Fluorescence / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000302:isolation & purification; D062066:Water Resources / Q000032:analysis*; D014881:Water Supply / Q000032:analysis
chemical_list: D060766:Drinking Water; D008900:Mineral Waters; D009573:Nitrites; D014874:Water Pollutants, Chemical
keywords: 2, 3-diaminonaphthalene; 2, 3-naphthotriazole; Derivatization; Dispersive magnetic solid phase extraction; Nitrite; Spectrofluorimetry