title: Self-aggregation and liquid crystalline behavior of new ester-functionalized quinuclidinolium surfactants.
abstract: A new type of ester-based cationic surfactant having a quinuclidinolium headgroup has been synthesized starting from linear fatty alcohols and has been characterized using spectroscopic techniques. The self-aggregation and thermodynamic properties of these surfactants have been investigated by pendant-drop surface tensiometry and conductivity measurements. The liquid crystalline behaviors of these surfactants were investigated by small-angle X-ray scattering (SAXS) technique. The quinuclidinolium headgroup demonstrated a unique ability to interlock among themselves thus affecting the physicochemical properties of surfactants in aqueous solution. The current research finding supports the new concept of headgroup interlocking which is supported by 1D and 2D NMR studies.
authors: Department of Pure and Applied Chemistry in Faculty of Science and Technology and Research Institute for Science and Technology, Tokyo University of Science , 2641 Yamazaki, Noda, Chiba 278-8510, Japan.
authors: Avinash
authors: A
authors: Bhadani
authors: Takeshi
authors: T
authors: Endo
authors: Setsuko
authors: S
authors: Koura
authors: Kenichi
authors: K
authors: Sakai
authors: Masahiko
authors: M
authors: Abe
authors: Hideki
authors: H
authors: Sakai