title: Effect of lithiation potential and cycling on chemical and morphological evolution of Si thin film electrode studied by ToF-SIMS.
abstract: Si thin films obtained by plasma enhanced chemical vapor deposition (PECVD) were used to investigate chemical and morphological modifications induced by lithiation potential and cycling. These modifications were thoughtfully analyzed by time-of-flight secondary ion mass spectrometry (ToF-SIMS) depth profiling, which allows to distinguish the surface and bulk processes related to the formation of the solid electrolyte interphase (SEI) layer, and Li-Si alloying, respectively. The main results are a volume expansion/shrinkage and a dynamic behavior of the SEI layer during the single lithiation/delithiation process and multicycling. Trapping of lithium and other ions corresponding to products of electrolyte decomposition are the major reasons of electrode modifications. It is shown that the SEI layer contributes to 60% of the total volume variation of Si electrodes (100 nm). The apparent diffusion coefficient of lithium (DLi) calculated from the Fick's second law directly from Li-ion ToF-SIMS profiles is of the order of ∼5.9 × 10(-15) cm(2).s(-1). This quite low value can be explained by Li trapping in the bulk of electrode material, at the interfaces, continuous growth of the SEI layer and increase of SiO2 quantity. These modifications can result in limitation the ionic transport of Li.
authors: Institut de Recherche de Chimie Paris, CNRS-Chimie ParisTech , 11 rue Pierre et Marie Curie, 75005 Paris, France.
authors: Catarina
authors: C
authors: Pereira-Nabais
authors: Jolanta
authors: J
authors: Światowska
authors: Michel
authors: M
authors: Rosso
authors: François
authors: F
authors: Ozanam
authors: Antoine
authors: A
authors: Seyeux
authors: Aurélien
authors: A
authors: Gohier
authors: Pierre
authors: P
authors: Tran-Van
authors: Michel
authors: M
authors: Cassir
authors: Philippe
authors: P
authors: Marcus