title: ¹⁹F NMR indicator displacement assay using a synthetic receptor with appended paramagnetic relaxation agent.
abstract: An admixture of zinc(II)-bis(dipicolylamine) receptor with covalently attached paramagnetic relaxation agent and fluorine-labeled phosphate indicator enables (19)F NMR detection of phosphorylated analytes with amplified switched-on signal intensity.
authors: Department of Chemistry and Biochemistry, University of Notre Dame, 236 Nieuwland Science Hall, Notre Dame, IN, USA. smith.115@nd.edu.
authors: Adam J
authors: AJ
authors: Plaunt
authors: Kasey J
authors: KJ
authors: Clear
authors: Bradley D
authors: BD
authors: Smith
mesh_terms: D000588:Amines / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008280:Magnetics; D009942:Organometallic Compounds / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry; D010848:Picolinic Acids / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: C501847:2,2'-dipicolylamine; D000588:Amines; D056831:Coordination Complexes; D009942:Organometallic Compounds; D010710:Phosphates; D010848:Picolinic Acids; C529174:bis-dipicolylamine-Zinc(II); D005461:Fluorine; D015032:Zinc