title: Mechanism of aggregate formation in simplified industrial silica styrene-butadiene nanocomposites: effect of chain mass and grafting on rheology and structure.
abstract: The formation of aggregates in simplified industrial styrene-butadiene nanocomposites with silica filler has been studied using a recent model based on a combination of electron microscopy, computer simulations, and small-angle X-ray scattering. The influence of the chain mass (40 to 280 kg mol(-1), PI < 1.1), which sets the linear rheology of the samples, was investigated for a low (9.5 vol%) and high (19 vol%) silica volume fraction. 50% of the chains bear a single graftable end-group, and it is shown that the (chain-mass dependent) grafting density is the structure-determining parameter. A model unifying all available data on this system is proposed and used to determine a critical aggregate grafting density. The latter is found to be closely related to the mushroom-to-brush transition of the grafted layer. To our best knowledge, this is the first comprehensive evidence for the control of the complex nanoparticle aggregate structure in nanocomposites of industrial relevance by the physical parameters of the grafted layer.
authors: Université Montpellier 2, Laboratoire Charles Coulomb UMR 5221, F-34 095, Montpellier, France. acgenix@univ-montp2.fr.
authors: Guilhem P
authors: GP
authors: Baeza
authors: Anne-Caroline
authors: AC
authors: Genix
authors: Christophe
authors: C
authors: Degrandcourt
authors: Jérémie
authors: J
authors: Gummel
authors: Marc
authors: M
authors: Couty
authors: Julian
authors: J
authors: Oberdisse