title: Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111).
abstract: Based on a combined scanning tunnelling microscopy and X-ray photoelectron spectroscopy study we present detailed insights into pronounced changes of long-range order and intramolecular conformation during the self-metalation of 2H-5,10,15,20-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin (2HTTBPP) to CuTTBPP on Cu(111). Upon metalation, the porphyrin literally "pops up" from the surface, due to a drastically reduced molecule-substrate interaction.
authors: Lehrstuhl für Physikalische Chemie II, Egerlandstrasse 3 and Interdisciplinary Center for Molecular Materials (ICMM), Universität Erlangen-Nürnberg, D-91058 Erlangen, Germany. hubertus.marbach@fau.de.
authors: M
authors: M
authors: Stark
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authors: S
authors: Ditze
authors: M
authors: M
authors: Lepper
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authors: Zhang
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authors: Schlott
authors: F
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authors: Buchner
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authors: Röckert
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authors: Chen
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authors: Lytken
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authors: Steinrück
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authors: Marbach