title: A molecular "screw-clamp": accelerating click reactions in miniemulsions.
abstract: The interface as a "screw clamp": the copper-free 1,3-dipolar azide-alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil-water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.
authors: Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany. wurm@mpip-mainz.mpg.de.
authors: Evandro M
authors: EM
authors: Alexandrino
authors: Philipp
authors: P
authors: Buchold
authors: Manfred
authors: M
authors: Wagner
authors: Adrian
authors: A
authors: Fuchs
authors: Andreas
authors: A
authors: Kreyes
authors: Clemens K
authors: CK
authors: Weiss
authors: Katharina
authors: K
authors: Landfester
authors: Frederik R
authors: FR
authors: Wurm