title: Palladium-catalyzed γ-selective arylation of zincated Boc-allylamines.
abstract: The regio- and diastereoselective arylation of Boc-protected allylamines was performed via a one-pot lithiation/transmetalation to zinc/cross-coupling sequence, through an appropriate choice of a phosphine ligand. A variety of γ-arylated products were obtained in moderate to good yield, and the products could be directly transformed into valuable γ-arylamines and β-aryl aldehydes.
authors: Université Claude Bernard Lyon 1 , CNRS UMR 5246 - Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne, France.
authors: Anthony
authors: A
authors: Millet
authors: Olivier
authors: O
authors: Baudoin