title: Capture, isolation and electrochemical detection of industrially-relevant engineered aerosol nanoparticles using poly (amic) acid, phase-inverted, nano-membranes.
abstract: Workplace exposure to engineered nanoparticles (ENPs) is a potential health and environmental hazard. This paper reports a novel approach for tracking hazardous airborne ENPs by applying online poly (amic) acid membranes (PAA) with offline electrochemical detection. Test aerosol (Fe2O3, TiO2 and ZnO) nanoparticles were produced using the Harvard (Versatile Engineered Generation System) VENGES system. The particle morphology, size and elemental composition were determined using SEM, XRD and EDS. The PAA membrane electrodes used to capture the airborne ENPs were either stand-alone or with electron-beam gold-coated paper substrates. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to conceptually illustrate that exposure levels of industry-relevant classes of airborne nanoparticles could be captured and electrochemically detected at PAA membranes filter electrodes. CV parameters showed that PAA catalyzed the reduction of Fe2O3 to Fe(2+) with a size-dependent shift in reduction potential (E(0)). Using the proportionality of peak current to concentration, the amount of Fe2O3 was found to be 4.15×10(-17)mol/cm(3) PAA electrodes. Using EIS, the maximum phase angle (Φmax) and the interfacial charge transfer resistance (Rct) increased significantly using 100μg and 1000μg of TiO2 and ZnO respectively. The observed increase in Φmax and Rct at increasing concentration is consistent with the addition of an insulating layer of material on the electrode surface. The integrated VENGES/PAA filter sensor system has the potential to be used as a portable monitoring system.
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States.
authors: Veronica A
authors: VA
authors: Okello
authors: Center for Nanotechnology and Nanotoxicology, Harvard School of Public Health, Department of Environmental Health, 665 Huntington Avenue, Boston, MA 02115-6021, United States.
authors: Samuel
authors: S
authors: Gass
authors: Center for Nanotechnology and Nanotoxicology, Harvard School of Public Health, Department of Environmental Health, 665 Huntington Avenue, Boston, MA 02115-6021, United States.
authors: Georgios
authors: G
authors: Pyrgiotakis
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States.
authors: Nian
authors: N
authors: Du
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States.
authors: Andrew
authors: A
authors: Lake
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States.
authors: Victor
authors: V
authors: Kariuki
authors: Center for Nanotechnology and Nanotoxicology, Harvard School of Public Health, Department of Environmental Health, 665 Huntington Avenue, Boston, MA 02115-6021, United States.
authors: Georgios A
authors: GA
authors: Sotiriou
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States.
authors: Jessica
authors: J
authors: Addolorato
authors: Center for Nanotechnology and Nanotoxicology, Harvard School of Public Health, Department of Environmental Health, 665 Huntington Avenue, Boston, MA 02115-6021, United States. Electronic address: pdemokri@hsph.harvard.edu.
authors: Philip
authors: P
authors: Demokritou
authors: Department of Chemistry, Center for Advanced Sensors & Environmental Systems (CASE), State University of New York at Binghamton, P.O. Box 6000, Binghamton, NY 13902, United States. Electronic address: osadik@binghamton.edu.
authors: Omowunmi A
authors: OA
authors: Sadik
mesh_terms: D000336:Aerosols; D004563:Electrochemistry; D004785:Environmental Pollutants / Q000737:chemistry*; D005374:Filtration; D008567:Membranes, Artificial; D008855:Microscopy, Electron, Scanning; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*
chemical_list: D000336:Aerosols; D004785:Environmental Pollutants; D008567:Membranes, Artificial; D011108:Polymers
keywords: Electrochemistry; Impedance spectroscopy; Nanoparticles; Phase-inverted membrane; Poly (amic) acid; VENGES