title: Oxidative rearrangements during fungal biosynthesis.
abstract: Oxidative rearrangements are key reactions during the biosyntheses of many secondary metabolites in fungi. This review highlights the most important examples of these reactions and aims to draw together key mechanistic themes to allow a better understanding and future exploitation of this key class of fungal catalysts.
authors: Institute for Organic Chemistry, Leibniz University of Hannover, Schneiderberg 1B, 30167 Hannover, Germany. russell.cox@oci.uni-hannover.de.
authors: Russell
authors: R
authors: Cox
mesh_terms: D000348:Aflatoxins / Q000737:chemistry / Q000378:metabolism; D001572:Benzofurans / Q000737:chemistry / Q000378:metabolism; D001688:Biological Products / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D002511:Cephalosporins / Q000737:chemistry / Q000378:metabolism; D005658:Fungi / Q000737:chemistry / Q000378:metabolism; D007553:Isotope Labeling; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D000348:Aflatoxins; D001572:Benzofurans; D001688:Biological Products; D002511:Cephalosporins; C052047:geodin