title: Catalytic combustion of soot over ceria-zinc mixed oxides catalysts supported onto cordierite.
abstract: Modified substrates as outer heterogeneous catalysts was employed to reduce the soot generated from incomplete combustion of diesel or diesel/biodiesel blends, a process that harms the environment and public health. The unique storage properties of ceria (CeO2) makes it one of the most efficient catalysts available to date. Here, we proposed that ceria-based catalysts can lower the temperature at which soot combustion occurs; more specifically, from 610°C to values included in the diesel exhausts operation range (300-450°C). The sol-gel method was used to synthesize mixed oxide-based catalysts (CeO2:ZnO); the resulting catalysts were deposited onto cordierite substrates. In addition, the morphological and structural properties of the material were evaluated by XRD, BET, TPR-H2, and SEM. Thermogravimetric (TG/DTA) analysis revealed that the presence of the catalyst decreased the soot combustion temperature by 200°C on average, indicating that the oxygen species arise at low temperatures in this situation, promoting highly reactive oxidation reactions. Comparative analysis of soot emission by diffuse reflectance spectroscopy (DRS) showed that catalyst-impregnated cordierite samples efficiently oxidized soot in a diesel/biodiesel stationary motor: soot emission decreased by more than 70%.
authors: Department of Chemistry, FFCLRP, University of São Paulo, Av. Bandeirantes 3900, CEP 14040-901 Ribeirão Preto, SP, Brazil. Electronic address: nascimento@pg.ffclrp.usp.br.
authors: Leandro Fontanetti
authors: LF
authors: Nascimento
authors: Department of Chemistry, FFCLRP, University of São Paulo, Av. Bandeirantes 3900, CEP 14040-901 Ribeirão Preto, SP, Brazil.
authors: Renata Figueredo
authors: RF
authors: Martins
authors: Department of Chemistry, FFCLRP, University of São Paulo, Av. Bandeirantes 3900, CEP 14040-901 Ribeirão Preto, SP, Brazil.
authors: Rodrigo Ferreira
authors: RF
authors: Silva
authors: Department of Chemistry, FFCLRP, University of São Paulo, Av. Bandeirantes 3900, CEP 14040-901 Ribeirão Preto, SP, Brazil. Electronic address: osaserra@usp.br.
authors: Osvaldo Antonio
authors: OA
authors: Serra
mesh_terms: D000397:Air Pollution / Q000517:prevention & control; D002384:Catalysis; D002516:Ceramics / Q000737:chemistry*; D002563:Cerium / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D053260:Soot / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D013818:Thermogravimetry; D014961:X-Ray Diffraction; D015034:Zinc Oxide / Q000737:chemistry*
chemical_list: D053260:Soot; C055335:cordierite; D002563:Cerium; C030583:ceric oxide; D015034:Zinc Oxide
keywords: ceria; mixed oxides; soot oxidation