title: Photochemistry of matrix isolated (trifluoromethyl)sulfonyl azide, CF₃SO₂N₃.
abstract: The photochemistry of matrix isolated (trifluoromethylsulfonyl) azide, CF3SO2N3, has been studied at low temperatures. Upon ArF laser irradiation (λ = 193 nm), the azide eliminates N2 and furnishes triplet [(trifluoromethyl)sulfonyl]nitrene, CF3SO2N, which has been characterized by IR and EPR spectroscopy. Upon subsequent UV light irradiation (λ = 260-400 nm) the nitrene converts to CF3N═SO2 and CF3S(O)NO through a Curtius-type rearrangement. Further two new species CF2N═SO2F and FSNO were identified together with CF2NF, SO2, F2CO, CF3NO, and SO as side products. In addition, triplet nitrene CF3N was detected by its EPR and IR spectra. The complex stepwise photodecomposition of matrix isolated CF3SO2N3 is discussed in terms of the observed photolysis products and quantum chemical calculations.
authors: †College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 215123 Suzhou, China.
authors: Xiaoqing
authors: X
authors: Zeng
authors: ‡FB C-Anorganische Chemie, Bergische Universität Wuppertal, Gaussstrasse 20, 42119 Wuppertal, Germany.
authors: Helmut
authors: H
authors: Beckers
authors: ‡FB C-Anorganische Chemie, Bergische Universität Wuppertal, Gaussstrasse 20, 42119 Wuppertal, Germany.
authors: Helge
authors: H
authors: Willner
authors: §Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, Universitätsstraß 150, 44780 Bochum, Germany.
authors: Patrik
authors: P
authors: Neuhaus
authors: §Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, Universitätsstraß 150, 44780 Bochum, Germany.
authors: Dirk
authors: D
authors: Grote
authors: §Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, Universitätsstraß 150, 44780 Bochum, Germany.
authors: Wolfram
authors: W
authors: Sander