title: Incorporation of iron hydrogenase active sites into a highly stable metal-organic framework for photocatalytic hydrogen generation.
abstract: A new biomimetic heterogeneous photocatalyst ([FeFe]@ZrPF) has been synthesized through the incorporation of homogeneous complex 1 [(í-SCH2)2NC(O)C5H4N]-[Fe2(CO)6] into the highly robust zirconium-porphyrin based metal-organic framework (ZrPF). The immobilized biomimetic [Fe2S2] catalyst inside the MOF shows great improvement in hydrogen generation compared to the reference homogeneous catalyst complex 1.
authors: Department of Chemistry, University of California, Riverside, California CA 92521, USA.
authors: Koroush
authors: K
authors: Sasan
authors: Qipu
authors: Q
authors: Lin
authors: ChengYu
authors: C
authors: Mao
authors: Pingyun
authors: P
authors: Feng
mesh_terms: D001672:Biocompatible Materials / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D002384:Catalysis; D020134:Catalytic Domain; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007501:Iron / Q000737:chemistry; D007506:Iron-Sulfur Proteins / Q000737:chemistry* / Q000378:metabolism; D008027:Light; D011166:Porphyrins / Q000737:chemistry*; D015040:Zirconium / Q000737:chemistry*
chemical_list: D001672:Biocompatible Materials; D056831:Coordination Complexes; D007506:Iron-Sulfur Proteins; D011166:Porphyrins; D006859:Hydrogen; D015040:Zirconium; D007501:Iron; C118830:iron hydrogenase; D006864:Hydrogenase