title: Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction.
abstract: We observed an ordered-to-disordered structural transformation in a Cu(2+) coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 °C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.
authors: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. horike@sbchem.kyoto-u.ac.jp.
authors: Satoshi
authors: S
authors: Horike
authors: Wenqian
authors: W
authors: Chen
authors: Tomoya
authors: T
authors: Itakura
authors: Munehiro
authors: M
authors: Inukai
authors: Daiki
authors: D
authors: Umeyama
authors: Hiroyuki
authors: H
authors: Asakura
authors: Susumu
authors: S
authors: Kitagawa