title: Influence of reactivation on the electrochemical performances of activated carbon based on coconut shell.
abstract: Coconut shell-based activated carbon (AC) were prepared by CO2 activation, and then the ACs with higher mesopore ratio were obtained by steam activation and by impregnating iron catalyst followed by steam activation, respectively. The AC with the highest mesopore ratio (AChmr) shows superior capacitive behavior, power output and high-frequency performance in supercapacitors. The results should attribute to the connection of its wide micropores and mesopores larger than 3 nm, which is more favorable for fast ionic transportation. The pore size distribution exhibits that the mesopore ratios of the ACs are significantly increased by reactivation of steam or catalyst up to 75% and 78%, respectively. As evidenced by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic measurements, the AChmr shows superior capacitive behaviors, conductivity and performance of electrolytic ionic transportation. The response current densities are evidently enhanced through the cyclic voltammery test at 50 mV/sec scan rate. The electrochemical impedance spectroscopy demonstrates that the conductivity and ion transport performance of the ACs are improved. The specific capacitances of the ACs were increased from 140 to 240 F/g at 500 mA/g current density. The AChmr can provide much higher power density while still maintaining good energy density, and demonstrate excellent high-frequency performances. The pore structure and conductivity of the AChmr also improve the cycleability and self-discharge of supercapacitors. Such AChmr exhibits a great potential in supercapacitors, particularly for applications where high power output and good high-frequency capacitive performances are required.
authors: Institute for Materials Electrochemistry Process Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China.  gengxin60@163.com
authors: Xin
authors: X
authors: Geng
authors: Institute for Materials Electrochemistry Process Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China.
authors: Lixiang
authors: L
authors: Li
authors: Metallurgy Coking Engineering Technology Co. Liaoning, Anshan 114051, China.
authors: Meiling
authors: M
authors: Zhang
authors: Institute for Materials Electrochemistry Process Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China.
authors: Baigang
authors: B
authors: An
authors: Institute for Materials Electrochemistry Process Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China.
authors: Xiaoming
authors: X
authors: Zhu
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry*; D003059:Cocos / Q000737:chemistry*; D025802:Electric Capacitance; D004563:Electrochemistry / Q000379:methods*; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D013696:Temperature
chemical_list: D002606:Charcoal; D009584:Nitrogen
keywords: activated carbon; electrochemical performance; supercapacitor