title: Migration of antimony from polyethylene terephthalate used in mineral water bottles.
abstract: The influence of storage time and temperature on Sb migration from PET bottles into mineral water was studied in short-term tests lasting up to 15 days and long-term studies lasting up to 220 days. Samples purchased were stored in three different coloured bottles: clear (CL), light blue (LB) and dark blue (DB). Sb migration was assayed by HG-AFS for total determination and HPLC-ICP-MS for speciation analysis. Migration studies showed that waters stored at 4 and 20 °C were not subject to Sb migration. At 40 °C there was a significant increase in Sb concentration, although the maximum limit established by the European Union (5.0 μgL(-)(1)) was not exceeded, whereas at 60 °C samples were subject to considerable Sb migration after 30 days of storage. In this case, the maximum limit established by the European Union was exceeded and both Sb (V) and Sb (III) were detected.
authors: Departament de Química Analítica, Universitat de Barcelona, Martí i Franqués, 1-11, 08028 Barcelona, Spain. Electronic address: sergio_carneado@ub.edu.
authors: S
authors: S
authors: Carneado
authors: Departament de Química Analítica, Universitat de Barcelona, Martí i Franqués, 1-11, 08028 Barcelona, Spain. Electronic address: edith.nataren@gmail.com.
authors: E
authors: E
authors: Hernández-Nataren
authors: Departament de Química Analítica, Universitat de Barcelona, Martí i Franqués, 1-11, 08028 Barcelona, Spain. Electronic address: fermin.lopez@ub.edu.
authors: J F
authors: JF
authors: López-Sánchez
authors: Departament de Química Analítica, Universitat de Barcelona, Martí i Franqués, 1-11, 08028 Barcelona, Spain. Electronic address: angels.sahuquillo@ub.edu.
authors: A
authors: A
authors: Sahuquillo
mesh_terms: D000965:Antimony / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid; D060766:Drinking Water / Q000032:analysis*; D005062:European Union; D005506:Food Contamination / Q000032:analysis*; D018857:Food Packaging; D061353:Food Storage / Q000379:methods; D013058:Mass Spectrometry; D008900:Mineral Waters / Q000032:analysis*; D011093:Polyethylene Terephthalates / Q000737:chemistry*; D013696:Temperature
chemical_list: D060766:Drinking Water; D008900:Mineral Waters; D011093:Polyethylene Terephthalates; D000965:Antimony
keywords: Antimony speciation; Inductively coupled plasma-mass spectrometry; Migration; Polyethylene terephthalate bottle; Water