title: Rhodium(III)-catalyzed regioselective C-H alkenylation of phenylphosphine sulfides.
abstract: The regioselective alkenylation at the ortho position of phenylphosphine sulfides using alkenes proceeds efficiently in the presence of a cationic Cp*-rhodium(III) catalyst and an appropriate oxidant. A similar rhodium catalyst also promotes the redox-neutral coupling of the phosphine sulfides with alkynes to afford ortho-alkenylated products.
authors: Department of Applied Chemistry, Faculty of Engineering, Osaka University , Suita, Osaka 565-0871, Japan.
authors: Yuki
authors: Y
authors: Yokoyama
authors: Yuto
authors: Y
authors: Unoh
authors: Koji
authors: K
authors: Hirano
authors: Tetsuya
authors: T
authors: Satoh
authors: Masahiro
authors: M
authors: Miura