title: Photophysical and electrochemical characterization of a helical viologen, N,N'-dimethyl-5,10-diaza[5]helicene.
abstract: The first helical viologen (4,4'-bipyridinium salt) has been prepared and characterized. Its reduction to the radical cation at -0.22 V vs SCE makes it the most easily reduced redox-active helicene known. It exhibits absorption at 397 nm for the S1 ← S0 transition, and it is luminescent allowing measurement of both its singlet (59.3 ± 0.1 kcal/mol) and triplet (54 ± 1 kcal/mol) energies. In contrast to neutral helicenes, it is not aromatic π-stacked in the crystal and has a shortest interdication distance of 4.977 Å. Its racemization barrier is calculated to be a sensitive function of its redox state.
authors.affiliation: Department of Chemistry, University of Wyoming , Laramie, Wyoming 82071, United States.
authors.forename: Xiaoping
authors.initials: X
authors.lastname: Zhang
authors.forename: Edward L
authors.initials: EL
authors.lastname: Clennan
authors.forename: Navamoney
authors.initials: N
authors.lastname: Arulsamy