title: A Mn(III)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers.
abstract: A novel Mn(III)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers with an unactivated C=C bond has been explored, generating α-aryl-alkyl β-azido ketones with an α-quaternary stereocenter.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, P. R. China.
authors.forename: Zhi-Min
authors.initials: ZM
authors.lastname: Chen
authors.forename: Zhen
authors.initials: Z
authors.lastname: Zhang
authors.forename: Yong-Qiang
authors.initials: YQ
authors.lastname: Tu
authors.forename: Ming-Hui
authors.initials: MH
authors.lastname: Xu
authors.forename: Fu-Min
authors.initials: FM
authors.lastname: Zhang
authors.forename: Chen-Chen
authors.initials: CC
authors.lastname: Li
authors.forename: Shao-Hua
authors.initials: SH
authors.lastname: Wang
mesh_terms: D001386:Azides / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D003497:Cyclic N-Oxides / Q000737:chemistry*; D004987:Ethers / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D001386:Azides; D003497:Cyclic N-Oxides; D004987:Ethers; D007659:Ketones; D020005:Propanols; C006463:allyl alcohol; D008345:Manganese; D002244:Carbon; C003959:TEMPO