title: The halogen bond in thiirane···ClF: an example of a Mulliken inner complex.
abstract: The halogen bond in the thiirane···ClF complex is shown to be unusually strong using high-accuracy ab initio methods. Investigating the underlying mechanism of the interaction reveals a significant increase in charge transfer and suggests it should be labelled as a Mulliken inner complex.
authors.affiliation: Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK. grant.hill@sheffield.ac.uk.
authors.forename: J
authors.initials: J
authors.lastname: Grant Hill