title: Silver(I) and copper(I) cocatalyzed tandem reaction of 2-alkynylbenzaldoximes with aldehydes or alcohols: approach to 4-carboxylated isoquinolines.
abstract: A novel and efficient route for the preparation of 4-carboxylated isoquinolines via a Ag(I) and Cu(I) cocatalyzed tandem reaction of 2-alkynylbenzaldoximes with aldehydes or alcohols in moderate to good yields is described. The reaction proceeds smoothly to produce C-N and C-O bonds in a one-pot procedure with structural complexity and molecular diversity.
authors.affiliation: Department of Chemistry, Nanchang University , 999 Xuefu Road, Nanchang, Jiangxi 330031, People's Republic of China.
authors.forename: Xianbo
authors.initials: X
authors.lastname: Wang
authors.forename: Xingxin
authors.initials: X
authors.lastname: Yu
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D007546:Isoquinolines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010091:Oximes / Q000737:chemistry*; D012834:Silver / Q000737:chemistry
chemical_list: D000438:Alcohols; D000447:Aldehydes; D002264:Carboxylic Acids; D007546:Isoquinolines; D010091:Oximes; D012834:Silver; D003300:Copper