title: Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
abstract: Stereoselective palladium-catalyzed Kumada-Corriu reactions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearing β-hydrogen atoms and sensitive functional groups, can be carried out at room temperature using a new combination of reagents.
authors.affiliation: The Dow Chemical Company, Core R&D, 1776 Building, E4-A, Midland, Michigan 48674, United States.
authors.forename: Arkady L
authors.initials: AL
authors.lastname: Krasovskiy
authors.forename: Stephen
authors.initials: S
authors.lastname: Haley
authors.forename: Karl
authors.initials: K
authors.lastname: Voigtritter
authors.forename: Bruce H
authors.initials: BH
authors.lastname: Lipshutz
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D006846:Hydrocarbons, Halogenated / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
chemical_list: D000475:Alkenes; D006846:Hydrocarbons, Halogenated; D010165:Palladium
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