title: Copper-promoted oxidative-fluorination of arylphosphine under mild conditions.
abstract: An efficient method for the synthesis of phosphoric fluoride via oxidative coupling between hydrophosphine oxide and NaF is reported. DDQ serves as the oxidizing reagent as well as the hydrogen acceptor. The process involves a Cu(II) catalysis and exhibits great functional group tolerance under mild reaction conditions.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China. yangshd@lzu.edu.cn.
authors.forename: Na
authors.initials: N
authors.lastname: Liu
authors.forename: Liu-Liang
authors.initials: LL
authors.lastname: Mao
authors.forename: Bin
authors.initials: B
authors.lastname: Yang
authors.forename: Shang-Dong
authors.initials: SD
authors.lastname: Yang
mesh_terms: D016227:Benzoquinones / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D054879:Halogenation; D010084:Oxidation-Reduction; D010720:Phosphines / Q000737:chemistry*; D012969:Sodium Fluoride / Q000737:chemistry
chemical_list: D016227:Benzoquinones; D010720:Phosphines; C000928:dichlorodicyanobenzoquinone; D003300:Copper; D012969:Sodium Fluoride; C044646:phosphine