title: Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids.
abstract: Ammonium- and phosphonium-based polyoxometalate ionic liquids (POM-ILs) have been synthesized and characterized. The results of small-angle XRD indicate that phosphonium-based POM-IL possesses a layered type structure. They are temperature control-type POM-ILs and can exhibit a phase transformation below 100 °C. Phosphonium-based POM-IL exhibits higher thermal stability and conductivity than its ammonium analogue.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou 310027, PR China. qywu@zju.edu.cn.
authors.forename: Yunyan
authors.initials: Y
authors.lastname: Li
authors.forename: Xuefei
authors.initials: X
authors.lastname: Wu
authors.forename: Qingyin
authors.initials: Q
authors.lastname: Wu
authors.forename: Hong
authors.initials: H
authors.lastname: Ding
authors.forename: Wenfu
authors.initials: W
authors.lastname: Yan