title: Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines.
abstract: A novel one-pot method has been developed for the interfacial hydrogenation of nitriles to synthesize asymmetrical tertiary amines. The active Pt NWs allow for the preparation of a series of tertiary amines in excellent yields (up to 99.0%) and a mixed solvent is vital for the adjustment of the yield. And also, the reaction proceeded under mild conditions and is environmentally friendly.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, China. hongwei@suda.edu.cn.
authors.forename: Shuanglong
authors.initials: S
authors.lastname: Lu
authors.forename: Chao
authors.initials: C
authors.lastname: Li
authors.forename: Jiaqing
authors.initials: J
authors.lastname: Wang
authors.forename: Yue
authors.initials: Y
authors.lastname: Pan
authors.forename: Xueqing
authors.initials: X
authors.lastname: Cao
authors.forename: Hongwei
authors.initials: H
authors.lastname: Gu
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D003641:Deamination; D006865:Hydrogenation; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*
chemical_list: D000588:Amines; D009570:Nitriles