title: New insight into relaxation dynamics of an epoxy/hydroxy functionalized polybutadiene from dielectric and mechanical spectroscopy studies.
abstract: Dielectric and mechanical spectroscopy methods have been employed to describe the temperature dependencies of the segmental and macromolecular relaxation rates in epoxy/hydroxy functionalized polybutadiene. Dielectric studies on the dynamics of segments of the polymer as well as the mobility of small ions trapped in the system have been carried out both as a function of temperature and pressure under isobaric and isothermal conditions, respectively.
authors.affiliation: Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland.
authors.forename: S
authors.initials: S
authors.lastname: Hensel-Bielowka
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
authors.forename: Z
authors.initials: Z
authors.lastname: Wojnarowska
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
authors.forename: J
authors.initials: J
authors.lastname: Knapik
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
authors.forename: M
authors.initials: M
authors.lastname: Paluch
keywords: Dielectric spectroscopy; Liquid-glass transition; Relaxation dynamics
references.citation: J Phys Chem B. 2005 Sep 22;109(37):17356-60
references.pmid: 16853218
references.citation: Mol Pharm. 2013 Jun 3;10(6):2270-82
references.pmid: 23594226
references.citation: J Chem Phys. 2005 Feb 22;122(8):84511
references.pmid: 15836067
references.citation: J Chem Phys. 2004 Jan 8;120(2):857-73
references.pmid: 15267922
references.citation: Mol Pharm. 2013 Oct 7;10(10):3612-27
references.pmid: 24070615
references.citation: Solid State Nucl Magn Reson. 2005 Jan;27(1-2):132-9
references.pmid: 15589734
references.citation: J Chem Phys. 2005 Jun 15;122(23):234506
references.pmid: 16008461
references.citation: Phys Rev Lett. 2003 Oct 10;91(15):155702
references.pmid: 14611476
references.citation: J Phys Condens Matter. 2011 Oct 26;23(42):425901
references.pmid: 21983107
references.citation: J Chem Phys. 2005 Nov 22;123(20):204507
references.pmid: 16351281
references.citation: J Chem Phys. 2005 Jul 1;123(1):014502
references.pmid: 16035850
references.citation: Mol Pharm. 2012 Apr 2;9(4):894-904
references.pmid: 22384922
references.citation: Science. 2013 Sep 20;341(6152):1371-4
references.pmid: 24052303