title: Preparation and electric property of polysilsesquioxane thin films incorporating carbazole groups.
abstract: New silsesquioxane incorporating a carbazole groups (PCTSQ) has been synthesized by a click thiol-ene reaction and a subsequent sol-gel reaction. To evaluate the electric property of this hybrid, diode devices have been fabricated by using PCTSQ thin film by spin-coating onto n-type ZnO film prepared by the electrodeposition method. The thin film hybrid devices showed good electric characteristics and high rectification ratio, as well as worked as a rectifier.
authors.affiliation: Electronic Materials Division Osaka Municipal Technical Research Institute 1-6-50 Morinomiya, Joto-ku, 538-8553 Osaka (Japan), Fax: (+81) 6-6963-8040. watase@omtri.or.jp.
authors.forename: Seiji
authors.initials: S
authors.lastname: Watase
authors.forename: Daiki
authors.initials: D
authors.lastname: Fujisaki
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Watanabe
authors.forename: Koji
authors.initials: K
authors.lastname: Mitamura
authors.forename: Noboru
authors.initials: N
authors.lastname: Nishioka
authors.forename: Kimihiro
authors.initials: K
authors.lastname: Matsukawa
keywords: carbazole groups; semiconductors; silicon; sol-gel processes; thiol-enes