title: Desymmetrization of meso-aziridines with TMSNCS using metal salts of novel chiral imidazoline-phosphoric acid catalysts.
abstract: Highly enantioselective desymmetrization of aziridines with TMSNCS has been developed. Good yield and enantioselectivity were observed by using novel chiral imidazoline-phosphoric acid catalysts. The obtained product can be converted to a chiral β-aminothiol and a β-aminosulfonic acid.
authors.affiliation: Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology , Gokiso, Showa-ku, Nagoya 466-8555, Japan.
authors.forename: Shuichi
authors.initials: S
authors.lastname: Nakamura
authors.forename: Mutsuyo
authors.initials: M
authors.lastname: Ohara
authors.forename: Madoka
authors.initials: M
authors.lastname: Koyari
authors.forename: Masashi
authors.initials: M
authors.lastname: Hayashi
authors.forename: Kengo
authors.initials: K
authors.lastname: Hyodo
authors.forename: Nadaf Rashid
authors.initials: NR
authors.lastname: Nabisaheb
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Funahashi