title: The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands.
abstract: A perfluorobutyl-functionalized two-dimensional porous coordination polymer (PCP), {[Cu(bpbtp)(L)(DMF)]·(DMF)}n (H2bpbtp = 2,5-bis(perfluorobutyl)terephthalic acid, L = 2,5-bis(perfluorobutyl)-1,4-bis(4-pyridyl)benzene, DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The pore surface of the PCP is decorated with pendant perfluorobutyl groups which fabricate a densely fluorinated nanospace resulting in unique gas sorption properties.
authors.affiliation: Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. rmatsuda@icems.kyoto-u.ac.jp.
authors.forename: Hyung Joon
authors.initials: HJ
authors.lastname: Jeon
authors.forename: Ryotaro
authors.initials: R
authors.lastname: Matsuda
authors.forename: Prakash
authors.initials: P
authors.lastname: Kanoo
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kajiro
authors.forename: Liangchun
authors.initials: L
authors.lastname: Li
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Sato
authors.forename: Yongtai
authors.initials: Y
authors.lastname: Zheng
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa