title: A metal-free strategy to release chemisorbed H2 from hydrogenated boron nitride nanotubes.
abstract: Chemisorbed hydrogen on boron nitride nanotubes (BNNT) can only be released thermally at very high temperatures above 350 °C. However, no catalyst has been identified that could liberate H2 from hydrogenated BN nanotubes under moderate conditions. Using different density functional methods we predict that the desorption of chemisorbed hydrogen from hydrogenated BN nanotubes can be facilitated catalytically by triflic acid at low free-energy activation barriers and appreciable rates under metal free conditions and mildly elevated temperatures (40-50 °C). Our proposed mechanism shows that the acid is regenerated in the process and can further facilitate similar catalytic release of H2 , thus suggesting all the chemisorbed hydrogen on the surface of the hydrogenated nanotube can be released in the form of H2 . These findings essentially raise hope for the development of a sustainable chemical hydrogen storage strategy in BN nanomaterials.
authors.affiliation: Raman Centre for Atomic Molecular and Optical Sciences, Indian Association for the Cultivation of Science, 2A & 2B, Raja S.C. Mullick Road, Kolkata, 700032 (India).
authors.forename: Lisa
authors.initials: L
authors.lastname: Roy
authors.forename: Sourav
authors.initials: S
authors.lastname: Bhunya
authors.forename: Ankan
authors.initials: A
authors.lastname: Paul
keywords: Brønsted acid; dehydrogenation; density functional calculations; main group elements; nanotubes