title: Nanotube liquid crystal elastomers: photomechanical response and flexible energy conversion of layered polymer composites.
abstract: Elastomeric composites based on nanotube liquid crystals (LCs) that preserve the internal orientation of nanotubes could lead to anisotropic physical properties and flexible energy conversion. Using a simple vacuum filtration technique of fabricating nanotube LC films and utilizing a transfer process to poly (dimethyl) siloxane wherein the LC arrangement is preserved, here we demonstrate unique and reversible photomechanical response of this layered composite to excitation by near infra-red (NIR) light at ultra-low nanotube mass fractions. On excitation by NIR photons, with application of small or large pre-strains, significant expansion or contraction of the sample occurs, respectively, that is continuously reversible and three orders of magnitude larger than in pristine polymer. Schlieren textures were noted in these LC composites confirming long range macroscopic nematic order of nanotubes within the composites. Order parameters of LC films ranged from S(optical) = 0.51-0.58 from dichroic measurements. Film concentrations, elastic modulus and photomechanical stress were all seen to be related to the nematic order parameter. For the same nanotube concentration, the photomechanical stress was almost three times larger for the self-assembled LC nanotube actuator compared to actuator based on randomly oriented carbon nanotubes. Investigation into the kinetics of photomechanical actuation showed variation in stretching exponent β with pre-strains, concentration and orientation of nanotubes. Maximum photomechanical stress of ∼ 0.5 MPa W(-1) and energy conversion of ∼ 0.0045% was achieved for these layered composites. The combination of properties, namely, optical anisotropy, reversible mechanical response to NIR excitation and flexible energy conversion all in one system accompanied with low cost makes nanotube LC elastomers important for soft photochromic actuation, energy conversion and photo-origami applications.
authors.affiliation: Small Systems Laboratory, Department of Mechanical Engineering, University of Louisville, KY 40292, USA.
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Fan
authors.forename: Benjamin C
authors.initials: BC
authors.lastname: King
authors.forename: James
authors.initials: J
authors.lastname: Loomis
authors.forename: Eva M
authors.initials: EM
authors.lastname: Campo
authors.forename: John
authors.initials: J
authors.lastname: Hegseth
authors.forename: Robert W
authors.initials: RW
authors.lastname: Cohn
authors.forename: Eugene
authors.initials: E
authors.lastname: Terentjev
authors.forename: Balaji
authors.initials: B
authors.lastname: Panchapakesan