title: Determining pore length scales and pore surface relaxivity of rock cores by internal magnetic fields modulation at 2MHz NMR.
abstract: Pore length scales and pore surface relaxivities of rock cores with different lithologies were studied on a 2MHz Rock Core Analyzer. To determine the pore length scales of the rock cores, the high eigenmodes of spin bearing molecules satisfying the diffusion equation were detected with optimized encoding periods in the presence of internal magnetic fields Bin. The results were confirmed using a 64MHz NMR system, which supports the feasibility of high eigenmode detection at fields as low as 2MHz. Furthermore, this methodology was combined with relaxometry measurements to a two-dimensional experiment, which provides correlation between pore length and relaxation time. This techniques also yields information on the surface relaxivity of the rock cores. The estimated surface relaxivities were then compared to the results using an independent NMR method.
authors.affiliation: Victoria University of Wellington, PO Box 600, Wellington, New Zealand; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.
authors.forename: Huabing
authors.initials: H
authors.lastname: Liu
authors.affiliation: Victoria University of Wellington, PO Box 600, Wellington, New Zealand; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.
authors.forename: Marcel
authors.initials: M
authors.lastname: Nogueira d'Eurydice
authors.affiliation: Victoria University of Wellington, PO Box 600, Wellington, New Zealand; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.
authors.forename: Sergei
authors.initials: S
authors.lastname: Obruchkov
authors.affiliation: Victoria University of Wellington, PO Box 600, Wellington, New Zealand; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand. Electronic address: Petrik.Galvosas@vuw.ac.nz.
authors.forename: Petrik
authors.initials: P
authors.lastname: Galvosas
keywords: Low-field NMR; Pore length scales; Pore surface relaxivity