title: Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex.
abstract: A rare 3D tetranuclear {In4(μ2-OH)3} building block based MOF {[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.
authors.affiliation: Department of Chemistry, Harbin Institute of Technology, Harbin 150001, P. R. China. fanruiqing@hit.edu.cn ylyang@hit.edu.cn.
authors.forename: Xin-Ming
authors.initials: XM
authors.lastname: Wang
authors.forename: Rui-Qing
authors.initials: RQ
authors.lastname: Fan
authors.forename: Liang-Sheng
authors.initials: LS
authors.lastname: Qiang
authors.forename: Ping
authors.initials: P
authors.lastname: Wang
authors.forename: Yu-Lin
authors.initials: YL
authors.lastname: Yang
authors.forename: Yu-Lei
authors.initials: YL
authors.lastname: Wang