title: A concise synthesis of (alkynyl)(trifluoromethyl)sulfanes via a bismuth(III)-promoted reaction of trimethyl(alkynyl)silane with trifluoromethanesulfanylamide.
abstract: A bismuth(III)-promoted reaction of trimethyl(alkynyl)silanes with trifluoromethanesulfanylamide is developed, giving rise to (alkynyl)(trifluoromethyl)sulfanes in good yields.
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China. jie_wu@fudan.edu.cn.
authors.forename: Jie
authors.initials: J
authors.lastname: Sheng
authors.forename: Jie
authors.initials: J
authors.lastname: Wu
mesh_terms: D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D060326:Chemistry Techniques, Synthetic; D012821:Silanes / Q000737:chemistry*; D000077145:Sulfanilamide; D013424:Sulfanilamides / Q000737:chemistry*
chemical_list: D000480:Alkynes; D000577:Amides; D012821:Silanes; D013424:Sulfanilamides; D000077145:Sulfanilamide; D001729:Bismuth