title: Smart composite nanosheets with adaptive optical properties.
abstract: We report efficient design and facile synthesis of size-tunable organic/inorganic nanosheets, via a straightforward liquid exfoliation-adsorption process, of a near percolating gold (Au) thin film deposited onto a branched polyethylenimine (bPEI) matrix. The nanosheets are stiff enough to sustain their two-dimensional (2D) nature in acidic conditions, yet flexible enough to undergo a perfect reversible shape transformation to 1D nanoscrolls in alkaline conditions. The shape transformations, and associated optical property changes, at different protonation states are monitored by transmission electron microscopy (TEM), atomic force microscopy (AFM), UV-visible spectroscopy and zeta potential measurements. Because of their large surface area, both nanosheets and nanoscrolls could be used as capturing substrates for surface-enhanced Raman scattering (SERS) applications.
authors.affiliation: Okinawa Institute of Science and Technology , 1919-1 Tancha, Onna-Son, Okinawa 904-0495, Japan.
authors.forename: Jeong-Hwan
authors.initials: JH
authors.lastname: Kim
authors.forename: Murtaza
authors.initials: M
authors.lastname: Bohra
authors.forename: Vidyadhar
authors.initials: V
authors.lastname: Singh
authors.forename: Cathal
authors.initials: C
authors.lastname: Cassidy
authors.forename: Mukhles
authors.initials: M
authors.lastname: Sowwan