title: Partial hydrogenation of a tetranuclear titanium nitrido complex with ammonia borane.
abstract: The treatment of [{Ti(η(5)-C5Me5)}4(μ3-N)4] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(η(5)-C5Me5)}4(μ3-N)3(μ3-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].
authors.affiliation: Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá , 28871 Alcalá de Henares-Madrid, Spain.
authors.forename: Jorge
authors.initials: J
authors.lastname: Caballo
authors.forename: Mariano
authors.initials: M
authors.lastname: González-Moreiras
authors.forename: Maider
authors.initials: M
authors.lastname: Greño
authors.forename: Miguel
authors.initials: M
authors.lastname: Mena
authors.forename: Adrián
authors.initials: A
authors.lastname: Pérez-Redondo
authors.forename: Carlos
authors.initials: C
authors.lastname: Yélamos