title: Syntheses and ligating properties of molybdocene alkoxides-the first heterodimetallic alkoxide containing molybdenum and bismuth.
abstract: Fluorinated alkoxide ligands RO(-) (R=CH(CF3 )2 ) are the key to the isolation of compounds of the type [Cp2 Mo(OR)2 ]. When electron-donating groups R are employed, the Mo(OR)2 moiety can, and necessarily has to, serve as a ligand for Lewis acidic fragments, allowing the isolation and structural characterization of the first heterodimetallic alkoxide containing a Bi and a Mo center (1).
authors.affiliation: Anorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, Fax: (+49) 6221-545707.
authors.forename: M
authors.initials: M
authors.lastname: Hunger
authors.forename: C
authors.initials: C
authors.lastname: Limberg
authors.forename: P
authors.initials: P
authors.lastname: Kircher
keywords: Alkoxides; Bismuth; Heterodimetallic compounds; Molybdenum