title: Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment.
abstract: Two new cyanide-bridged heteropolymolybdate complexes have been synthesized by a facile self-assembly process in aqueous solution, which demonstrates a successful tactic to incorporate the cyanometalate fragment into lacunary heteropolymolybdate. Magnetic investigation showed that complex 2 exhibits slow magnetic relaxation behavior.
authors.affiliation: Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China. linxu@nenu.edu.cn lify525@nenu.edu.cn.
authors.forename: Ya
authors.initials: Y
authors.lastname: Wang
authors.forename: Ning
authors.initials: N
authors.lastname: Jiang
authors.forename: Fengyan
authors.initials: F
authors.lastname: Li
authors.forename: Yanzhen
authors.initials: Y
authors.lastname: Zheng
authors.forename: Lin
authors.initials: L
authors.lastname: Xu
authors.forename: Minghui
authors.initials: M
authors.lastname: Sun
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003486:Cyanides / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008280:Magnetics; D008982:Molybdenum / Q000737:chemistry*; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D003486:Cyanides; D014867:Water; C044659:molybdate; D008982:Molybdenum