title: Enantioselective synthesis of decalin structures with all-carbon quaternary centers via one-pot sequential Cope/Rauhut-Currier reaction.
abstract: The first example of one-pot sequential Cope/Rauhut-Currier reactions are reported and used to make functionalized decalin structures with all-carbon quaternary stereocenters. The substrates for the new sequential reaction are generated through a six-step sequence including an enantioselective Birch reduction-allylation reaction which makes the overall process asymmetric.
authors.affiliation: Chemistry Department, Bryn Mawr College, Bryn Mawr, PA 19010, USA.
authors.forename: Tina Morgan
authors.initials: TM
authors.lastname: Ross
authors.affiliation: Chemistry Department, Bryn Mawr College, Bryn Mawr, PA 19010, USA.
authors.forename: Sarah
authors.initials: S
authors.lastname: Burke
authors.affiliation: Chemistry Department, Bryn Mawr College, Bryn Mawr, PA 19010, USA.
authors.forename: Wlliam P
authors.initials: WP
authors.lastname: Malachowski
keywords: Cope; Rauhut-Currier; enantioselective; sequential