title: CuO nanostructures: optical properties and morphology control by pyridinium-based ionic liquids.
abstract: Copper oxide nanostructures have been synthesized by a simple reflux method in aqueous medium of pyridinium based ionic liquids. The structural and optical properties of CuO nanostructures were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy (PL) and UV-visible. The morphologies of the nanostructures can be controlled by changing the amount of NaOH and ionic liquids. The results show that the use identical pyridinium based ionic liquids in ratio of 4:1 NaOH/Cu(OAc)2⋅H2O yield minor differences in morphology of CuO nanostructures. Different morphologies of CuO nanostructures were obtained by changing the ratio NaOH/Cu(OAc)2⋅H2O to 2:1. Ionic liquids play an important role on optical properties of CuO nanostructures. The results of optical measurements of the CuO nanostructures illustrate that band gaps are estimated to be 1.67-1.85 eV. PL patterns studies show that the ionic liquids can be effect on PL patterns of the samples. The reasons of these phenomena are discussed.
authors.affiliation: Chemistry Department, Faculty of Sciences, Shahid Rajaee Teacher Training University, PO Box 16785-163, Tehran, Iran. Electronic address: sabbaghan@srttu.edu.
authors.forename: Maryam
authors.initials: M
authors.lastname: Sabbaghan
authors.affiliation: Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran.
authors.forename: Ashraf Sadat
authors.initials: AS
authors.lastname: Shahvelayati
authors.affiliation: Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran.
authors.forename: Kamelia
authors.initials: K
authors.lastname: Madankar
mesh_terms: D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D052578:Ionic Liquids / Q000737:chemistry*; D049449:Luminescence; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D055620:Optical Phenomena; D010316:Particle Size; D011726:Pyridinium Compounds / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D014961:X-Ray Diffraction
chemical_list: D052578:Ionic Liquids; D011726:Pyridinium Compounds; D003300:Copper; C000520:cuprous oxide
keywords: CuO nanostructure; Green synthesis; Ionic liquid; Nanosheet; Optical properties; PL patterns