title: N8 (-) polynitrogen stabilized on multi-wall carbon nanotubes for oxygen-reduction reactions at ambient conditions.
abstract: Polynitrogen (PN) species (Nn , n from 3 to 8) as highly energetic materials have attracted many theoretical calculations and predictions. N3 , N4 , N5 or their ions were experimentally detected under high-pressure and high-temperature conditions. Herein, a N8 (-) PN stabilized on the positively charged sidewalls of multi-walled carbon nanotubes (MWNTs) has been synthesized using cyclic voltammetry (CV) under ambient conditions. ATR-FTIR and Raman spectroscopic data assigned on the basis of density functional theory (DFT) calculations support the successful synthesis of a C2h symmetry chain structure of the N8 anion stabilized as MWNT(+) N8 (-) . Temperature programmed desorption (TPD) data show that MWNT(+) N8 (-) is thermally stable up to 400 °C. Oxygen-reduction reaction (ORR) experiments carried out using MWNT(+) N8 (-) as the cathodic catalyst shows that it is very active for ORR with an even higher current density than that of a commercial Pt/carbon catalyst.
authors.affiliation: Department of Materials Science and Engineering, New Jersey Institute of Technology, Newark, NJ 07102 (USA).
authors.forename: Zhiyi
authors.initials: Z
authors.lastname: Wu
authors.forename: El Mostafa
authors.initials: el M
authors.lastname: Benchafia
authors.forename: Zafar
authors.initials: Z
authors.lastname: Iqbal
authors.forename: Xianqin
authors.initials: X
authors.lastname: Wang
keywords: MWNTs; electrocatalysis; oxygen reduction reaction; polynitrogen