title: Copper metal-organic framework nanocrystal for plane effect nonenzymatic electro-catalytic activity of glucose.
abstract: This work describes the first demonstration of nanocrystal plane dependent nonenzymatic electro-catalytic glucose activity of [Cu3(btc)2] nanocrystals with different shapes (nanocube, truncated cube, cuboctahedron, and octahedron). From electrochemical results, the obtained [Cu3(btc)2] nanocube modified electrode shows the best nonenzymatic electro-catalytic glucose activity. Interestingly, decreasing the {100} crystal planes from cubes to octahedra, changes the nonenzymatic electro-catalytic activity from highly sensitive to general.
authors.affiliation: College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, 455002, Henan, P. R. China.
authors.forename: Yuanying
authors.initials: Y
authors.lastname: Liu
authors.forename: Youjuan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Jing
authors.initials: J
authors.lastname: Chen
authors.forename: Huan
authors.initials: H
authors.lastname: Pang
mesh_terms: D015374:Biosensing Techniques / Q000379:methods; D002384:Catalysis; D003217:Conductometry / Q000379:methods*; D003300:Copper / Q000737:chemistry*; D003460:Crystallization / Q000379:methods; D005947:Glucose / Q000032:analysis* / Q000737:chemistry*; D008422:Materials Testing; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure*; D009930:Organic Chemicals / Q000737:chemistry; D010316:Particle Size; D013499:Surface Properties
chemical_list: D009930:Organic Chemicals; D003300:Copper; D005947:Glucose