title: Synthesis of carbon nanospheres using fallen willow leaves and adsorption of Rhodamine B and heavy metals by them.
abstract: This paper focuses on the synthesis of carbon nanospheres (CNSs) using fallen willow leaves as a low-cost precursor. The scanning electron microscopy (SEM) image and transmission electron microscopy (TEM) image demonstrated that the structure of synthesized CNSs was spherical, with a diameter of 100 nm. The crystal structure and chemical information were characterized by Raman spectrum and energy-dispersive spectrum (EDS), respectively. BET results showed that the CNSs had a larger specific surface area of 294.32 m(2) g(-1), which makes it a potentially superior adsorbent. Rh-B and heavy metal ions such as Cu(2+), Zn(2+), and Cr(6+) were used as targets to investigate the adsorption capacity of the CNSs. The effects of adsorption parameters such as adsorption equilibrium time, dose of CNSs, adsorption kinetics, and effect factors were also studied. These findings not only established a cost-effective method of synthesizing CNSs using fallen willow leaves but also broadened the potential application range of these CNSs.
authors.affiliation: School of Chemistry and Chemical Engineering, Bohai University, Jinzhou, Liaoning, 121013, China, qujiao@bhu.edu.cn.
authors.forename: Jiao
authors.initials: J
authors.lastname: Qu
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
authors.forename: Yunsheng
authors.initials: Y
authors.lastname: Xia
authors.forename: Qiao
authors.initials: Q
authors.lastname: Cong
authors.forename: Chunqiu
authors.initials: C
authors.lastname: Luo
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D007700:Kinetics; D019216:Metals, Heavy / Q000032:analysis / Q000302:isolation & purification; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D054118:Nanospheres / Q000737:chemistry* / Q000648:ultrastructure; D018515:Plant Leaves / Q000737:chemistry*; D012235:Rhodamines / Q000032:analysis / Q000302:isolation & purification; D032108:Salix / Q000737:chemistry*; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D002244:Carbon; D019216:Metals, Heavy; D012235:Rhodamines; D062065:Wastewater; D014874:Water Pollutants, Chemical; C029773:rhodamine B