title: Temperature-dependent phase transition and desorption free energy of sodium dodecyl sulfate at the water/vapor interface: approaches from molecular dynamics simulations.
abstract: Adsorption of surfactants at the water/vapor interface depends upon their chemical potential at the interface, which is generally temperature-dependent. Molecular dynamics simulations have been performed to reveal temperature influences on the microstructure of sodium dodecyl sulfate (SDS) molecule adsorption layer. At room temperature, SDS molecules aggregate at the interface, being in a liquid-expanded phase, whereas they tend to spread out and probably transit to a gaseous phase as the temperature increases to above 318 K. This phase transition has been confirmed by the temperature-dependent changes in two-dimensional array, tilt angles, and immersion depths to the aqueous phase of SDS molecules. The aggregation of SDS molecules accompanies with larger immersion depths, more coordination of Na(+) ions, and less coordination of water. Desorption free energy profiles show that higher desorption free energy appears for SDS molecules at the aggregate state at low temperatures, but no energy barrier is observed. The shapes of desorption free energy profiles depend upon the distribution of SDS at the interface, which, in turn, is related to the phase state of SDS. Our study sheds light on the development of adsorption thermodynamics and kinetics theories.
authors.affiliation: State Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University , Nanjing, Jiangsu 210093, People's Republic of China.
authors.forename: Meng
authors.initials: M
authors.lastname: Chen
authors.forename: Xiancai
authors.initials: X
authors.lastname: Lu
authors.forename: Xiandong
authors.initials: X
authors.lastname: Liu
authors.forename: Qingfeng
authors.initials: Q
authors.lastname: Hou
authors.forename: Youyi
authors.initials: Y
authors.lastname: Zhu
authors.forename: Huiqun
authors.initials: H
authors.lastname: Zhou
mesh_terms: D056004:Molecular Dynamics Simulation; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry*; D013227:Steam; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D013227:Steam; D014867:Water; D012967:Sodium Dodecyl Sulfate