title: Carba-closo-dodecaborate anions with two functional groups: [1-R-12-HC≡C-closo-1-CB₁₁H₁₀]⁻ (R = CN, NC, CO₂H, C(O)NH₂, NHC(O)H).
abstract: Disubstituted carba-closo-dodecaborate anions with one functional group bonded to the cluster carbon atom and one ethynyl group bonded to the antipodal boron atom were synthesized from easily accessible {closo-1-CB11} clusters. [Et4N][1-NC-12-HC≡C-closo-1-CB11H10] ([Et4N]4b) was prepared starting from Cs[12-Et3SiC≡C-closo-1-CB11H11] (Cs1c) via salts of the anions [1-HO(O)C-12-HC≡C-closo-1-CB11H10](-) (2b) and [1-H2N(O)C-12-HC≡C-closo-1-CB11H10](-) (3b). In a similar reaction sequence [Et4N][1-CN-12-HC≡C-closo-1-CB11H10] ([Et4N]7b) was obtained from Cs[1-H2N-12-HC≡C-closo-1-CB11H10] (Cs5b) by formamidation to yield [Et4N][1-H(O)CHN-12-HC≡C-closo-1-CB11H10] ([Et4N]6b) and successive dehydration. In addition, the synthesis of the isonitrile [Et4N][1-CN-closo-1-CB11H11] ([Et4N]7a) is presented. The {closo-1-CB11} derivatives were characterized by multinuclear NMR as well as vibrational spectroscopy, mass spectrometry, and elemental analysis. The crystal structures of [Et4N][1-HO(O)C-12-HC≡C-closo-1-CB11H10] ([Et4N]2b), [Et4N][1-H2N(O)C-12-HC≡C-closo-1-CB11H10] ([Et4N]3b), [Et4N][1-NC-12-HC≡C-closo-1-CB11H10] ([Et4N]4b), [Et4N][1-H(O)CHN-12-HC≡C-closo-1-CB11H10] ([Et4N]6b), [Et4N][1-CN-12-HC≡C-closo-1-CB11H10] ([Et4N]7b), and K[1-H(O)CHN-closo-1-CB11H11] ([Et4N]6a) were determined. The transmission of electronic effects through the carba-closo-dodecaboron cage was studied based on (13)C NMR spectroscopic data, by results derived from density functional theory calculations, and by a comparison to the data of related benzene and bicyclo[2.2.2]octane derivatives.
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg , Am Hubland, 97074 Würzburg, Germany.
authors.forename: Michael
authors.initials: M
authors.lastname: Hailmann
authors.forename: Szymon Z
authors.initials: SZ
authors.lastname: Konieczka
authors.forename: Alexander
authors.initials: A
authors.lastname: Himmelspach
authors.forename: Jochen
authors.initials: J
authors.lastname: Löblein
authors.forename: Guido J
authors.initials: GJ
authors.lastname: Reiss
authors.forename: Maik
authors.initials: M
authors.lastname: Finze