title: Storable N-phenylcarbamate palladacycles for rapid functionalization of an alkyne-encoded protein.
abstract: Here we report the synthesis of storable N-phenylcarbamate palladacycles that showed robust reactivity in the cross-coupling reaction with an alkyne-encoded protein with a second-order rate constant approaching 19 770 ± 930 M(-1) s(-1).
authors.affiliation: Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260, USA. qinglin@buffalo.edu.
authors.forename: Gang
authors.initials: G
authors.lastname: Cheng
authors.forename: Reyna K V
authors.initials: RK
authors.lastname: Lim
authors.forename: Carlo P
authors.initials: CP
authors.lastname: Ramil
authors.forename: Qing
authors.initials: Q
authors.lastname: Lin
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D007700:Kinetics; D010165:Palladium / Q000737:chemistry*; D048448:Phenylcarbamates / Q000737:chemistry*; D014452:Ubiquitins / Q000737:chemistry*
chemical_list: D000480:Alkynes; D048448:Phenylcarbamates; D014452:Ubiquitins; C551041:homopropargylglycine; D010165:Palladium; D005998:Glycine