title: X-ray Absorption Study of Graphene Oxide and Transition Metal Oxide Nanocomposites.
abstract: The surface properties of the electrode materials play a crucial role in determining the performance and efficiency of energy storage devices. Graphene oxide and nanostructures of 3d transition metal oxides were synthesized for construction of electrodes in supercapacitors, and the electronic structure and oxidation states were probed using near-edge X-ray absorption fine structure. Understanding the chemistry of graphene oxide would provide valuable insight into its reactivity and properties as the graphene oxide transformation to reduced-graphene oxide is a key step in the synthesis of the electrode materials. Polarized behavior of the synchrotron X-rays and the angular dependency of the near-edge X-ray absorption fine structures (NEXAFS) have been utilized to study the orientation of the σ and π bonds of the graphene oxide and graphene oxide-metal oxide nanocomposites. The core-level transitions of individual metal oxides and that of the graphene oxide nanocomposite showed that the interaction of graphene oxide with the metal oxide nanostructures has not altered the electronic structure of either of them. As the restoration of the π network is important for good electrical conductivity, the C K edge NEXAFS spectra of reduced graphene oxide nanocomposites confirms the same through increased intensity of the sp2-derived unoccupied states π* band. A pronounced angular dependency of the reduced sample and the formation of excitonic peaks confirmed the formation of extended conjugated network.
authors.affiliation: NASA Ames Research Center, Moffett Field, Mountain View, California 94035, United States.
authors.forename: Ram P
authors.initials: RP
authors.lastname: Gandhiraman
authors.affiliation: Stanford Synchrotron Radiation Lightsource, Stanford Linear Accelerator Center, Menlo Park, California 94025, United States.
authors.forename: Dennis
authors.initials: D
authors.lastname: Nordlund
authors.affiliation: NASA Ames Research Center, Moffett Field, Mountain View, California 94035, United States.
authors.forename: Cristina
authors.initials: C
authors.lastname: Javier
authors.affiliation: NASA Ames Research Center, Moffett Field, Mountain View, California 94035, United States.
authors.forename: Jessica E
authors.initials: JE
authors.lastname: Koehne
authors.affiliation: NASA Ames Research Center, Moffett Field, Mountain View, California 94035, United States.
authors.forename: Bin
authors.initials: B
authors.lastname: Chen
authors.affiliation: NASA Ames Research Center, Moffett Field, Mountain View, California 94035, United States.
authors.forename: M
authors.initials: M
authors.lastname: Meyyappan