title: Structure and properties of nitrogen-rich 1,4-dicyanotetrazine, C4N6: a comparative study with related tetracyano electron acceptors.
abstract: The crystal structure, redox electrochemical stability, and reaction chemistry of 1,4-dicyanotetrazine (DCNT) has been experimentally characterized. These experimental results were rationalized by the results of theoretical calculations of the electronic structure, spin and charge distributions, electronic absorption spectra, and electron affinity and compared with the results for related the tetracyano electron acceptors tetracyanoethylene (TCNE), 7,7,8,8-tetracyano-p-quinodimethane (TCNQ), and 2,3,5,6-tetracyanopyrazine (TCNP). DCNT is made from the dehydration of 1,2,4,5-tetrazine-3,6-dicarboxamide, and because of the unusual deep-magenta color of the dicarboxamide in the solid state, its hydrogen-bonded layered structure, electronic structure, and electronic absorption spectra were determined. The magenta color is attributed to its absorptions at 532 nm (18 800 cm(-1)), and this corresponds to normalized chromaticity coordinates of x = 0.42 and y = 0.31 in the pink/red/orange part of the 1931 CIE chromaticity diagram. In contrast with previous reports, DCNT exhibits an irreversible one-electron reduction at -0.09 V vs SCE (MeCN), and reduced forms of DCNT have yet to be isolated and characterized. In addition, the reactions of DCNT with V(CO)6, Fe(II)(C5Me5)2, and I(-) are discussed.
authors.affiliation: Department of Chemistry, University of Utah , 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112-0850, United States.
authors.forename: Hoa-Lan
authors.initials: HL
authors.lastname: Vo
authors.forename: Jordan L
authors.initials: JL
authors.lastname: Arthur
authors.forename: Marçal
authors.initials: M
authors.lastname: Capdevila-Cortada
authors.forename: Saul H
authors.initials: SH
authors.lastname: Lapidus
authors.forename: Peter W
authors.initials: PW
authors.lastname: Stephens
authors.forename: Juan J
authors.initials: JJ
authors.lastname: Novoa
authors.forename: Atta M
authors.initials: AM
authors.lastname: Arif
authors.forename: Ramneet K
authors.initials: RK
authors.lastname: Nagi
authors.forename: Michael H
authors.initials: MH
authors.lastname: Bartl
authors.forename: Joel S
authors.initials: JS
authors.lastname: Miller