title: Novel Br-DPQ blue light-emitting phosphors for OLED.
abstract: A new series of blue light-emitting 2,4-diphenylquinoline (DPQ) substituted blue light-emitting organic phosphors namely, 2-(4-methoxy-phenyl)-4-phenyl-quinoline (OMe-DPQ), 2-(4-methyl-phenyl)-4-phenylquinoline (M-DPQ), and 2-(4-bromo-phenyl)-4-phenylquinoline (Br-DPQ) were synthesized by substituting methoxy, methyl and bromine at the 2-para position of DPQ, respectively by Friedländer condensation of 2-aminobenzophenone and corresponding acetophenone. The synthesized phosphors were characterized by different techniques, e.g., Fourier transform infra-red (FTIR), differential scanning calorimeter (DSC), UV-visible absorption and photoluminescence spectra. FTIR spectra confirms the presence of chemical groups such as C=O, NH, or OH in all the three synthesized chromophores. DSC studies show that these complexes have good thermal stability. Although they are low-molecular-weight organic compounds, they have the potential to improve the stability and operating lifetime of a device made out of these complexes. The synthesized polymeric compounds demonstrate a bright emission in the blue region in the wavelength range of 405-450 nm in solid state. Thus the attachment of methyl, methoxy and bromine substituents to the diphenyl quinoline ring in these phosphors results in colour tuning of the phosphorescence. An electroluminescence (EL) cell of Br-DPQ phosphor was made and its EL behaviour was studied. A brightness-voltage characteristics curve of Br-DPQ cell revealed that EL begins at 400 V and then the brightness increases exponentially with applied AC voltage, while current-voltage (I-V) characteristics revealed that the turn on voltage of the fabricated EL cell was 11 V. Hence this phosphor can be used as a promising blue light material for electroluminescent devices.
authors.affiliation: Department of Physics Shivaji Science College, Nagpur, 440012, India.
authors.forename: H K
authors.initials: HK
authors.lastname: Dahule
authors.forename: N
authors.initials: N
authors.lastname: Thejokalyani
authors.forename: S J
authors.initials: SJ
authors.lastname: Dhoble
mesh_terms: D001966:Bromine; D002152:Calorimetry, Differential Scanning; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry*; D008163:Luminescent Measurements; D011804:Quinolines / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: C000605852:2,4-diphenylquinoline; C000605853:2-(4-bromo-phenyl)-4-phenylquinoline; C000605854:2-(4-methoxy-phenyl)-4-phenyl-quinoline; D049408:Luminescent Agents; D011804:Quinolines; D001966:Bromine
keywords: DPQ; OLED; electroluminescence cell; phosphor; quinoline