title: Characterization of fast photoelectron packets in weak and strong laser fields in ultrafast electron microscopy.
abstract: The development of ultrafast electron microscopy (UEM) and variants thereof (e.g., photon-induced near-field electron microscopy, PINEM) has made it possible to image atomic-scale dynamics on the femtosecond timescale. Accessing the femtosecond regime with UEM currently relies on the generation of photoelectrons with an ultrafast laser pulse and operation in a stroboscopic pump-probe fashion. With this approach, temporal resolution is limited mainly by the durations of the pump laser pulse and probe electron packet. The ability to accurately determine the duration of the electron packets, and thus the instrument response function, is critically important for interpretation of dynamics occurring near the temporal resolution limit, in addition to quantifying the effects of the imaging mode. Here, we describe a technique for in situ characterization of ultrashort electron packets that makes use of coupling with photons in the evanescent near-field of the specimen. We show that within the weakly-interacting (i.e., low laser fluence) regime, the zero-loss peak temporal cross-section is precisely the convolution of electron packet and photon pulse profiles. Beyond this regime, we outline the effects of non-linear processes and show that temporal cross-sections of high-order peaks explicitly reveal the electron packet profile, while use of the zero-loss peak becomes increasingly unreliable.
authors.affiliation: Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue SE, Minneapolis, MN 55455, USA.
authors.forename: Dayne A
authors.initials: DA
authors.lastname: Plemmons
authors.affiliation: Physical Biology Center for Ultrafast Science & Technology, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125, USA.
authors.forename: Sang
authors.initials: S
authors.lastname: Tae Park
authors.affiliation: Physical Biology Center for Ultrafast Science & Technology, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125, USA.
authors.forename: Ahmed H
authors.initials: AH
authors.lastname: Zewail
authors.affiliation: Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue SE, Minneapolis, MN 55455, USA. Electronic address: flan0076@umn.edu.
authors.forename: David J
authors.initials: DJ
authors.lastname: Flannigan
keywords: Instrument response function; Photon-induced near-field electron microscopy; Ultrafast electron microscopy