title: Electrofluorochromic detection of cyanide anions using a nanoporous polymer electrode and the detection mechanism.
abstract: An electrofluorochromic (EFC) conjugated copolymer (PEFC) containing carbazole and benzothiadiazole (BTD) moieties is synthesized through Suzuki coupling followed by electrochemical polymerization, resulting in a nanoporous EFC polymer electrode. The electrode exhibits high sensitivity and selectivity in the EFC detection of cyanide anions (CN(-)) in largely aqueous electrolyte (67 vol % water) because electrochemical oxidation of PEFC leads to significant fluorescence quenching, and the presence of different concentrations (1 to 100 μM) of CN(-) in the electrolyte can weaken the oxidative quenching to substantially different extents. Although PEFC is hydrophobic in the neutral state, it is converted to radical cation/dication states upon oxidation, rendering the PEFC some hydrophilicity. Moreover, its nanoporous morphology provides a large surface area and short diffusion distance, facilitating the movement of CN(-) in the electrolyte into the PEFC film to interact with receptors. Density functional theory calculations show that the noncovalent interaction between electron-deficient BTD and nucleophilic CN(-) is energy favorable in the oxidized states in both aqueous and organic media, suggesting that the specific π(-)-π(+) interaction plays the main role in the CN(-) detection.
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore, Fax: (+65) 6790-9081.
authors.forename: Guoqiang
authors.initials: G
authors.lastname: Ding
authors.forename: TingTing
authors.initials: T
authors.lastname: Lin
authors.forename: Rui
authors.initials: R
authors.lastname: Zhou
authors.forename: Yuliang
authors.initials: Y
authors.lastname: Dong
authors.forename: Jianwei
authors.initials: J
authors.lastname: Xu
authors.forename: Xuehong
authors.initials: X
authors.lastname: Lu
keywords: conjugation; cyanide detection; electrochemistry; electrofluorochromic; fluorescence; polymers