title: Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption.
abstract: The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2·H2O (·H2O). This compound is a ditopically-bridged copper carbonate kagome lattice where desolvation of the MOF allows subtle tuning of the metamagnetic and uniaxial ZTE behaviour.
authors.affiliation: Chemistry, University of Southampton, University Road, Highfield, Southampton, SO17 1BJ, UK.
authors.forename: Tony D
authors.initials: TD
authors.lastname: Keene
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Murphy
authors.forename: Jason R
authors.initials: JR
authors.lastname: Price
authors.forename: Natasha F
authors.initials: NF
authors.lastname: Sciortino
authors.forename: Peter D
authors.initials: PD
authors.lastname: Southon
authors.forename: Cameron J
authors.initials: CJ
authors.lastname: Kepert