title: Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@I(h)-C80.
abstract: A hydrogen-containing endohedral metallofullerene, Sc4C2H@Ih-C80, was synthesized and its paramagnetism was measured by the low-temperature EPR spectrometry with a broad EPR signal. The electron-spin excitation by implanting the H-atom would be a new method for preparation of stable paramagnetic metallofullerenes.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. wangtais@iccas.ac.cn crwang@iccas.ac.cn.
authors.forename: Yongqiang
authors.initials: Y
authors.lastname: Feng
authors.forename: Taishan
authors.initials: T
authors.lastname: Wang
authors.forename: Jingyi
authors.initials: J
authors.lastname: Wu
authors.forename: Zhuxia
authors.initials: Z
authors.lastname: Zhang
authors.forename: Li
authors.initials: L
authors.lastname: Jiang
authors.forename: Hongbin
authors.initials: H
authors.lastname: Han
authors.forename: Chunru
authors.initials: C
authors.lastname: Wang
mesh_terms: D004578:Electron Spin Resonance Spectroscopy; D004583:Electrons; D037741:Fullerenes / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D011789:Quantum Theory; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature
chemical_list: D037741:Fullerenes; D006859:Hydrogen