title: Microstructural and mechanical characteristics of porous iron prepared by powder metallurgy.
abstract: The demand for porous biodegradable load-bearing implants has been increasing recently. Based on investigations of biodegradable stents, porous iron may be a suitable material for such applications. In this study, we prepared porous iron samples with porosities of 34-51 vol.% by powder metallurgy using ammonium bicarbonate as a space-holder material. We studied sample microstructure (SEM-EDX and XRD), flexural and compressive behaviors (universal loading machine) and hardness HV5 (hardness tester) of the prepared samples. Sample porosity increased with the amount of spacer in the initial mixtures. Only the pore surfaces had insignificant oxidation and no other contamination was observed. Increasing porosity decreased the mechanical properties of the samples; although, the properties were still comparable with human bone and higher than those of porous non-metallic biomaterials and porous magnesium prepared in a similar way. Based on these results, powder metallurgy appears to be a suitable method for the preparation of porous iron for orthopedic applications.
authors.affiliation: Department of Metals and Corrosion Engineering, Institute of Chemical Technology in Prague, Technická 5, 166 28 Prague 6, Czech Republic. Electronic address: Jaroslav.Capek@vscht.cz.
authors.forename: Jaroslav
authors.initials: J
authors.lastname: Capek
authors.affiliation: Department of Metals and Corrosion Engineering, Institute of Chemical Technology in Prague, Technická 5, 166 28 Prague 6, Czech Republic.
authors.forename: Dalibor
authors.initials: D
authors.lastname: Vojtěch
mesh_terms: D007501:Iron / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D015394:Molecular Structure; D016062:Porosity; D011208:Powders; D013052:Spectrometry, X-Ray Emission
chemical_list: D011208:Powders; D007501:Iron
keywords: Porous iron; Powder metallurgy; Scaffolds