title: Mesoporous cerium phosphonate nanostructured hybrid spheres as label-free Hg²⁺ fluorescent probes.
abstract: Porous phosphonate-based organic-inorganic hybrid materials have been shown to have novel and amazing physicochemical properties due to the integration of superiorities from both inorganic components and organic moieties. Herein, mesoporous cerium phosphonate nanostructured hybrid spheres are prepared with the assistance of cationic surfactant cetyltrimethylammonium bromide while using ethylene diamine tetra(methylene phosphonic acid) as the coupling molecule. The resulting hybrid is constructed from the cerium phosphonate nanoparticles, accompanied by high specific surface area of 455 m(2) g(-1). The uniform incorporation of rare-earth element cerium and organophosphonic functionalities endows mesoporous cerium phosphonate with excellent fluorescence properties for the development of an optical sensor for selective Hg(2+) detection on the basis of the fluorescence-quenching mechanism. The signal response of mesoporous cerium phosphonate against the Hg(2+) concentration is linear over the range from 0.05 to 1.5 μmol L(-1), giving a limit of detection of 16 nmol L(-1) (at a signal-to-noise ratio of 3). Most of the common physiologically relevant cations and anions did not interfere with the detection of Hg(2+). This label-free system provides a promising platform for further use in bioimaging and biomedical fields.
authors.affiliation: Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University , Tianjin 300071, China.
authors.forename: Yun-Pei
authors.initials: YP
authors.lastname: Zhu
authors.forename: Tian-Yi
authors.initials: TY
authors.lastname: Ma
authors.forename: Tie-Zhen
authors.initials: TZ
authors.lastname: Ren
authors.forename: Zhong-Yong
authors.initials: ZY
authors.lastname: Yuan
mesh_terms: D002563:Cerium / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D057230:Limit of Detection; D008628:Mercury / Q000032:analysis*; D049329:Nanostructures / Q000737:chemistry*; D016062:Porosity; D013050:Spectrometry, Fluorescence
chemical_list: D005456:Fluorescent Dyes; D002563:Cerium; D008628:Mercury
keywords: Hg2+ detection; cerium phosphonate; fluorescence quenching; mesoporosity; sensor