title: Modulating H2 sorption in metal-organic frameworks via ordered functional groups.
abstract: Herein, we present the use of presynthetic and postsynthetic modification (PSM) approaches to regulate the structural organization of functional groups in the pores of isoreticular metal-organic frameworks (IRMOFs). It has been found that the structural ordering of aryl groups within the IRMOF pores results in hysteretic H2 sorption, while the same aryl groups introduced in a disordered manner displays reversible H2 sorption that is more typical of the IRMOF family.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla 92093, USA. scohen@ucsd.edu.
authors.forename: Phuong V
authors.initials: PV
authors.lastname: Dau
authors.forename: Seth M
authors.initials: SM
authors.lastname: Cohen