title: N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals.
abstract: N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 × 10(7) s(-1) at 21 °C).
authors.affiliation: ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, Australia.
authors.forename: Sara H
authors.initials: SH
authors.lastname: Kyne
authors.forename: Carl H
authors.initials: CH
authors.lastname: Schiesser
mesh_terms: D003500:Cyclization; D005609:Free Radicals / Q000737:chemistry*; D007700:Kinetics; D010070:Oxalates / Q000737:chemistry*; D014220:Trialkyltin Compounds / Q000737:chemistry
chemical_list: D005609:Free Radicals; D010070:Oxalates; D014220:Trialkyltin Compounds; C011559:tributyltin