title: Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system.
abstract: This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc=0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen+black carbon was the dominant CM fraction extracted from the sediments and accounted for >60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that >80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration <1000 μgL(-1). These results show that sorption is likely a significant contributor to the persistence of a TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.
authors.affiliation: Department of Geology, University at Buffalo, State University of New York, Buffalo, NY 14260, USA.
authors.forename: Sungwook
authors.initials: S
authors.lastname: Choung
authors.affiliation: Department of Geology, University at Buffalo, State University of New York, Buffalo, NY 14260, USA.
authors.forename: Lisa R
authors.initials: LR
authors.lastname: Zimmerman
authors.affiliation: Department of Geology, University at Buffalo, State University of New York, Buffalo, NY 14260, USA. Electronic address: richelle@buffalo.edu.
authors.forename: Richelle M
authors.initials: RM
authors.lastname: Allen-King
authors.affiliation: Laboratories for Applied Organic Petrology (LAOP), Institute for Archaeological Sciences, University of Tübingen, Rümelinstr. 23, 72070 Tübingen, Germany.
authors.forename: Bertrand
authors.initials: B
authors.lastname: Ligouis
authors.affiliation: Applied Groundwater Research Ltd., Mississauga, Ontario L5M 2H7, Canada.
authors.forename: Stanley
authors.initials: S
authors.lastname: Feenstra
mesh_terms: D000327:Adsorption; D019015:Geologic Sediments / Q000737:chemistry*; D060587:Groundwater / Q000737:chemistry*; D009518:New York; D014241:Trichloroethylene / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; D014241:Trichloroethylene
keywords: Kerogen; Sorption; Thermally altered carbonaceous matter; Trichloroethylene; Volatile organic compound