title: A meso-macro compartmentalized bioreactor obtained through silicalization of "green" double emulsions: W/O/W and W/SLNs/W.
abstract: We report a straightforward approach for both structuring and entrapping enzymes into hierarchical silica materials with hexagonally ordered mesopores (12 nm) and tailored macroporosity by converting a double emulsion colloidal template (tens of microns) into solid lipid nanoparticles (hundreds of nanometres). The supported biocatalyst efficiently catalyzes the methanolysis of colza oil.
authors.affiliation: SRSMC UMR 7565, Université de Lorraine, CNRS, BP 70239, F-54506 Vandoeuvre-lès-Nancy cedex, France. andreea.pasc@univ-lorraine.fr.
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Blin
authors.forename: Jonathan
authors.initials: J
authors.lastname: Jacoby
authors.forename: Sanghoon
authors.initials: S
authors.lastname: Kim
authors.forename: Marie-José
authors.initials: MJ
authors.lastname: Stébé
authors.forename: Nadia
authors.initials: N
authors.lastname: Canilho
authors.forename: Andreea
authors.initials: A
authors.lastname: Pasc
mesh_terms: D055162:Biocatalysis; D019149:Bioreactors / Q000382:microbiology; D029688:Brassica napus / Q000737:chemistry; D003102:Colloids / Q000737:chemistry; D004655:Emulsions / Q000737:chemistry; D004800:Enzymes, Immobilized / Q000737:chemistry / Q000378:metabolism*; D008049:Lipase / Q000737:chemistry / Q000378:metabolism*; D008055:Lipids / Q000737:chemistry; D000432:Methanol / Q000378:metabolism; D009089:Mucor / Q000201:enzymology*; D053758:Nanoparticles / Q000737:chemistry; D010938:Plant Oils / Q000302:isolation & purification / Q000378:metabolism*; D016062:Porosity; D012639:Seeds / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry*
chemical_list: D003102:Colloids; D004655:Emulsions; D004800:Enzymes, Immobilized; D008055:Lipids; D010938:Plant Oils; D012822:Silicon Dioxide; D008049:Lipase; D000432:Methanol