title: Selective hydrogenation of furan-containing condensation products as a source of biomass-derived diesel additives.
abstract: In this study, we demonstrate that while the energy density and lubricity of the C15 and C16 products of furan condensation of biomass-derived aldehydes with 2-methylfuran are consistent with requirements for diesel, these products do not meet specifications for cetane number and pour point due to their aromatic furan rings. However, a novel class of products that fully meet or exceed most specifications for diesel can be produced by converting the furan rings in these compounds to cyclic ether moieties. Full hydrodeoxygenation of furan condensation products to alkanes would require 55-60% higher hydrogen demand, starting from biomass, compared to the products of furan ring saturation, providing an additional incentive to support the saturated products. We also report here on a tunable class of catalysts that contain Pd nanoparticles supported on ionic liquid-modified SiO2 that can achieve complete saturation of the furan rings in yields of 95% without opening these rings.
authors.affiliation: Department of Chemical and Biomolecular Engineering, University of California, Berkeley, 107 Gilman Hall, Berkeley, CA 94720 (USA).
authors.forename: Madhesan
authors.initials: M
authors.lastname: Balakrishnan
authors.forename: Eric R
authors.initials: ER
authors.lastname: Sacia
authors.forename: Alexis T
authors.initials: AT
authors.lastname: Bell
mesh_terms: D000473:Alkanes / Q000138:chemical synthesis*; D056804:Biofuels; D018533:Biomass; D002384:Catalysis; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D006865:Hydrogenation; D010165:Palladium / Q000737:chemistry*; D014783:Viscosity
chemical_list: D000473:Alkanes; D056804:Biofuels; D004988:Ethers, Cyclic; D010165:Palladium
keywords: biomass; furan hydrogenation; heterogeneous catalysis; renewable fuels; sustainable chemistry