title: N-Methyl-2-(1-methyl-3-phenyl-prop-2-en-1-yl-idene)hydrazinecarbo-thio-amide.
abstract: In the title compound, C12H15N3S, the mol-ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N-N-C-N fragment of -7.04 (16)°. In the crystal, mol-ecules are linked by N-H⋯S hydrogen-bond inter-actions, forming centrosymmetric dimers. Additionally, one weak intra-molecular N-H⋯N hydrogen-bond inter-action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.
authors.affiliation: Instituto de Química, Universidade Estadual Paulista, Rua Francisco Degni s/n, 14801-970 Araraquara-SP, Brazil.
authors.forename: Fillipe Vieira
authors.initials: FV
authors.lastname: Rocha
authors.affiliation: Instituto de Química, Universidade Estadual Paulista, Rua Francisco Degni s/n, 14801-970 Araraquara-SP, Brazil.
authors.forename: Adelino Vieira
authors.initials: AV
authors.lastname: de Godoy Netto
authors.affiliation: Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany.
authors.forename: Johannes
authors.initials: J
authors.lastname: Beck
authors.affiliation: Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany.
authors.forename: Jörg
authors.initials: J
authors.lastname: Daniels
authors.affiliation: Departamento de Química, Universidade Federal de Sergipe, Av. Marechal Rondon s/n, Campus, 49100-000 São Cristóvão-SE, Brazil.
authors.forename: Adriano Bof
authors.initials: AB
authors.lastname: de Oliveira
keywords: crystal structure