title: Chemistry of phosphorylated formaldehyde derivatives. Part I.
abstract: The underinvestigated derivatives of unstable phosphorylated formaldehyde acetals and some of the structurally related compounds, such as thioacetals, aminonitriles, aminomethylphosphinoyl compounds, are considered. Separately considered are halogen aminals of phosphorylated formaldehyde, acetals of phosphorylated formaldehyde of H-phosphinate-type and a phosphorylated gem-diol of formaldehyde. Synthetic methods, chemical properties and examples of practical applications are given.
authors.affiliation: Laboratory of Organophosphorus Compounds, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, Moscow 119991, Russia. morgaliuk@mail.ru.
authors.forename: Vasily P
authors.initials: VP
authors.lastname: Morgalyuk
mesh_terms: D000080:Acetals / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry; D005557:Formaldehyde / Q000031:analogs & derivatives / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry; D007659:Ketones / Q000737:chemistry; D010766:Phosphorylation
chemical_list: D000080:Acetals; D005030:Ethylenes; D006219:Halogens; D007659:Ketones; D005557:Formaldehyde; C008223:ketene