title: Synthesis and characterization of guar-alginate hybrid bead templated mercury sorbing titania spheres.
abstract: Present communication reports on the synthesis and characterization of Hg(II) sorbing millimeter sized porous titania spheres (TSP). The synthesis utilizes guar gum-alginate hybrid beads as sacrificial template to polymerize titanium(IV) isopropoxide. The hybrid beads are crafted by pouring guar-alginate mixed solution to calcium bath. The mechanical strength of the beads depended on guar to alginate ratio in the mixed solution. The equal weight ratio of the two polysaccharides is appropriate for adequate mechanical strength beads. The unique performance of the templating beads is attributed to the synergistic interaction between guar gum and sodium alginate. FTIR, BET, SEM, TEM, XRD, TGA, and DTG analyses have been used for the characterization of the optimum performance TSP (TSPAG2). TSPAG2 is a mesoporous material that has higher surface area and narrower pore size distribution than pure alginate derived titania spheres (TSPA). TEM study demonstrated that TSPAG2 spheres are constituted of aggregated TiO2 nanoparticles of ∼ 10 nm size. TSPAG2 is able to capture >95% Hg(II) from synthetic Hg(II) solution in 10h at pH 5 as opposed to only 68% removal by TSPA.
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India. Electronic address: singhvandanasingh@rediffmail.com.
authors.forename: Vandana
authors.initials: V
authors.lastname: Singh
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India.
authors.lastname: Preeti
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India.
authors.forename: Angela
authors.initials: A
authors.lastname: Singh
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India.
authors.forename: Devendra
authors.initials: D
authors.lastname: Singh
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India.
authors.forename: Yadveer
authors.initials: Y
authors.lastname: Singh
authors.affiliation: Department of Chemistry, University of Allahabad, Allahabad-211002, India.
authors.forename: Arvind Kumar
authors.initials: AK
authors.lastname: Pandey
mesh_terms: D000327:Adsorption; D000464:Alginates / Q000138:chemical synthesis / Q000737:chemistry*; D031293:Cyamopsis / Q000737:chemistry; D020723:Glucuronic Acid / Q000138:chemical synthesis / Q000737:chemistry; D006603:Hexuronic Acids / Q000138:chemical synthesis / Q000737:chemistry; D008628:Mercury / Q000737:chemistry* / Q000633:toxicity; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D014025:Titanium / Q000737:chemistry
chemical_list: D000464:Alginates; D006603:Hexuronic Acids; C009495:titanium dioxide; D020723:Glucuronic Acid; D014025:Titanium; D008628:Mercury
keywords: Guar-alginate hybrid bead; Mercury; Titania spheres